• Title/Summary/Keyword: Amphibole

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A Study on Functionality of the Ulreungdo Seokganju as Korean Traditional Red Pigment (한국 전통 적색광물안료 울릉도석간주의 기능성 연구)

  • Do, Jin-Young;Kim, Soo-Jin;Lee, Sang-Jin;Ahn, Byung-Chan;Yun, Seong-Chul;Kim, Kwang-Jong
    • Journal of the Mineralogical Society of Korea
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    • v.22 no.2
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    • pp.153-162
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    • 2009
  • The main compositions of "Seokganju", a Korean traditional red mineral pigment, are iron oxides. To investigate its mineralogical and functional properties, we had got its ore from Juto cave in Ulreoung island, which was a famous field of it in Korean documents. The ore occurs as a paleosol between the olivine basalt and amphibole trachyte in discontinuously. It is reddish brown and yellowish brown and consists mainly of clay minerals with minor debris. Its reddish and yellowish brown color are due to the hematite and ferrihydrate, respectively. These iron oxides are precipitated as ferrihydrate from the ferrous water in the paleosol and partly changed to hematite. The color reproduced in timber by using seokganju pigment with traditional tools and methods is similar to that in heritage building. The moistureproofing and fire resistance of Ulreungdo seokganju is far better than that of artificial seokganju. Moreover, the combustion tests show that the artificial seokganju promote the ignition and combustion of the timber. Ulreungdo seokganju is regarded as a pigment with fungicidal efficacy because growth of two wood decay fungi (cov. and typ.) are inhibited in solid medium with it.

Characteristics of Surface Deterioration and Materials for Stone Guardian and Stone Memorial Tablets from Muryeong Royal Tomb of Baekje Kingdom in Ancient Korea (백제 무령왕릉 석수와 지석의 재질 및 표면손상 특성)

  • Park, Jun Hyoung;Lee, Chan Hee;Choi, Gi Eun
    • Journal of Conservation Science
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    • v.33 no.4
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    • pp.241-254
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    • 2017
  • The Stone Guardian and Memorial Tablets from the Muryeong Royal Tomb are composed of the same kind of plutonic igneous rocks, the so-called hornblendite. Color of the rocks show greenish gray, and both of them occurred with medium-grained granular texture. The rock-forming minerals composed mainly of amphibole and plagioclase. Magnetic susceptibility of the Stone Guardian is 0.15 to 0.63 (mean $0.42{\times}10^{-3}SI\;unit$), the King's Stone Memorial Tablet is 0.11 to 0.38 (mean $0.24{\times}10^{-3}SI\;unit$) and the Queen's Stone Memorial Tablet ranges from 0.10 to 0.33 (mean $0.18{\times}10^{-3}SI\;unit$). The rocks of the artifacts are hard to find in the Gongju area. Large scaled out crop of hornblendite is not distributed, but found in many places that the form of dike. The lithology and occurrences indicate that the artifacts are made of plutonic rock rather than dike. Reddish brown and pale brown contaminants, are also distributed on the surface of the Stone Guardian and Memorial Tablets. The reddish brown color is due to Fe oxide, and the pale brown color occurs due to the elution of Ca. The reddish brown contaminants are influenced by the internal components of the rock and oxidation of burial iron accessories. In contrast, the pale brown contaminants are considered to have flown from the carbonate materials used in the Royal Tomb, with a little added Fe oxide. Physical and chemical deterioration operate intricately in the Stone Guardian and Memorial Tablets. Physical deterioration is extremely rare and chemical deterioration is stable except for a part of the Stone Guardian and the front of the Queen Stone Memorial Tablet.

High-pressure amphibolite of the Imjingang belt in the Yeoncheon-Cheongok area (연천-전곡 지역에 분포하는 임진강대의 고압 각섬암)

  • ;;;Eizo Nakamura
    • The Journal of the Petrological Society of Korea
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    • v.4 no.1
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    • pp.1-19
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    • 1995
  • In order to characterize the petrogenesis of the E-W trending Imjinganag belt, we studied the metamorphic rocks of the Yeoncheon Group near its type locality, Yeoncheon - Cheongok area, belonging to the southern part of this fold-thrust belt. The Samgot Formation of the Yeoncheon Group consists of calc-silicate and metapsammitic rocks together with amphibolite and amphibole gneiss. Layers of these metamorphic rocks concordantly occur in a wide area with its length greater than 15 km along their strike direction. Major mineral assemblages of the amphibolite are hornblende + plagioclase ${\pm}$ garnet ${\pm}$ diopside ${\pm}$ biotite ${\pm}$ quartz. Accessory rutile and ilmenite are characteristically replaced by titanite. Metamorphic temperatures and pressures estimated from the garnet - hornblende - plagioclase - quartz geothermo-barometers are 632-$736^{\circ}C$ and 7.9-11.1 kbar, respectively. Thus, the regional metamorphism of the study area belongs to the upper amphibolite facies. Furthermore, Sm-Nd and Rb-Sr data of garnet, plagioclase, and whole rock of an amphibolite define mineral isochrons of $231{\pm}30$ Ma and $222{\pm}24$ Ma, respectively, suggesting the Triassic metamorphism. These results are consistent with P-T conditions and metamorphic ages reported in the Shandong Peninsula, and support the hypothesis that the Chinese collision belt may extend into the Imjingang belt in the Korean Peninsula.

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The Mineralogical Characteristics on the Polder Soils Development from Alluvio-marine Deposits near to Sapgyo-lake (삽교천유역의 하해혼성충적층에서 발달된 토양의 광물학적 특성)

  • Zhang, Yong-Seon;Um, Myung-Ho;Jung, Pil-Kyun;Shin, Jae-Sung
    • Korean Journal of Soil Science and Fertilizer
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    • v.33 no.6
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    • pp.377-383
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    • 2000
  • The composition of primary minerals of sand fractions and secondary minerals of clay fractions were investigated on the polder soils developed from alluvio-marine deposits near to Sapgyo-lake, constructed a sea dike across river estuary located in the west coast. The effects of a topographical sequence on the physico-chemical properties and mineralogical characteristics were evaluated using XRD, DTA, and TG with the chemical composition of $H^+$ saturated clays. Soils located on the seashore side were more silt fraction, higher pH and exchangeable cations than the others. The dominant minerals of soil parent materials are in the order of quartz, feldspars, micas, chlorite and amphibole. According to the greater distance from the lake, the amount of 1:1 minerals increased, but 2:1 minerals decreased. The dominant clay minerals of polder soils are kaolinite, vermiculite and illite. Hydroxy interlayer minerals are abundant in the clay fractions derived from the soil parent materials which have relatively low soil pH.

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Mineral Distribution in the Southeastern Yellow Sea Surface Sediments; KORDI Cruise Samples in 2010 (황해 남동부 표층 해양 퇴적물의 광물 분포; 2010년 한국해양연구원 탐사 시료)

  • Cho, Hyen-Goo;Kim, Soon-Oh;Yi, Hi-Il;Shin, Kyung-Hoon
    • Journal of the Mineralogical Society of Korea
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    • v.24 no.3
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    • pp.205-216
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    • 2011
  • Mineral compositions of 69 southeastern Yellow Sea surface sediments collected at the Korea Ocean Research and Development Institute (KORDI) cruise in 2010, were determined using the quantitative X-ray diffraction analysis. Southeastern Yellow Sea surface sediments are composed of major minerals (quartz 49.1%, plagioclase 13.0% and alkali feldspar 9.3%), clay minerals, calcite, and aragonite. Illite (9.4%) is the most abundant clay mineral, chlorite (4.6%) is the second, and kaolinite (0.8%) is few. Quartz and alkali feldspar contents are high in coarse-grained sediments, whereas amphibole and clay mineral contents are high in fine-grained sediments. Quartz, plagioclase, alkali feldspar, chlorite, and kaolinite contents are higher, and illite content is lower in mud zone 1 corresponding to south margin of Central Yellow Sea Mud than in mud zone 2, a part of Southeastern Yellow Sea Mud. Difference of mineral composition between two mud zone suggests that source of fine sediment may be different in two mud zone and Southeastern Yellow Sea Mud might be largely supplied from the Keum and Youngsan rivers in southern part of the west coast in the Korean Peninsula.

Spectmscopic and Magnetic Properties of Yanggiseok, Yeonok and Eumgiseok used as Mineral Medicine (광물성 한약으로 이용되는 양기석, 연옥,음기석의 분광학적 및 자기적 특성)

  • 김선옥;박맹언;정율필
    • Economic and Environmental Geology
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    • v.35 no.4
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    • pp.317-323
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    • 2002
  • Mineral medicines are single or mixtures of minerals and rocks which have been used to treat disease. Recently, their application has been increased by emphasizing the physical properies of the medicines, in addition to their chemical properies. In this study, mineralogical, chemical, spectroscopic and magnetic properties were measured using X-ray diffraction analysis, X-ray fluorescence spectrometry, Ff-Infrared spectroscopy, nuclear magnetic resonance spectroscopy, mass magnetic susceptibility. Experiments were done using these properties to evaluate application of traditional mineral medicines such as Yanggiseok, Yeonok and Eumgiseok. Mineralogical study proves that Yanggiseok, generally known as tremolite, consists of actinolite. Yeonok for medical usage mostly consists of fine grained tremolite. Eumgiseok is mainly composed of vermiculite and minor kaolinite and halloysite. Yeonok and Yanggiseok, belong to the amphibole group among inosilicates and both have similar emission power properties. The intensity of emission power, calculated from FT-IR measurements, follows in the order of Yeonok, Yanggiseok and Eumgiseok at 40$^{\circ}$C and Yanggiseok, Yeonok and Eumgiseok in such order at 150$^{\circ}$C. As a result of NMR analysis after 20 days in distilled water, the three mineral medicines decreased in the following order; Eumgiseok, Yanggiseok and Yeonok. However, the same minerals decreased in the order of Eumgiseok, Yeonok and Yanggiseok after 80 days. In response temperature, magnetic susceptibility of Yanggiseok and Eumgiseok systematically increased by heating to 25$^{\circ}$C, 100$^{\circ}$C and 700$^{\circ}$C. Magnetic susceptibility of Yeonok shows a decreasing pattern due to heating.

Petrology of the Syenites in Hapcheon, Korea (경남 합천 지역의 섬장암에 관한 암석학적 연구)

  • Ok, Eun-Young;Kim, Jong-Sun;Lee, Sang-Won
    • The Journal of the Petrological Society of Korea
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    • v.26 no.1
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    • pp.13-43
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    • 2017
  • In the Hapcheon area, hypersthene-bearing monzonite (mangerite) and syenite are recognized. The main minerals of syenite are alkali feldspar, plagioclase, amphibole, biotite, and quartz. Anhedral hornblende and biotite are interstitial between feldspar and quartz, indicating that the hydrous minerals were crystallized later on. Based on petrochemical studies of major elements, syenite is alkaline series, metaluminous, and I-type. The variation patterns in the trace and rare earth elements of mangerite and syenite show the features of subduction-related igneous rock such as depletion of HFSE, relative enrichment in LILE to LREE, and negative Nb-P-Ti anomalies. Based on the experimental data and petrographic characteristics of the syenite, Hapcheon syenitic magma is considered to be formed by partial melting in a dry system. SHRIMP U-Pb zircon data yield the Triassic age as $227.4{\pm}1.4Ma$ in mangerite, $215.3{\pm}1.2Ma$ in syenite, and $217.9{\pm}2.6Ma$ in coarse-grained syenite, respectively. The mangerite age is similar to those of post-collisional plutonic rocks in Hongseong (226~233 Ma), Yangpyeong (227~231 Ma), and Odaesan (231~234 Ma) areas in the Gyeonggi Massif. Syenites were intruded after about 10 Ma. The features seen in the mangereite and syenite rocks can be explained by models such as the continental collision and slab break-off and the lithosphere thinning and asthenosphere upwelling model.

Implication for the emplacement depth of the granites in the Yeongnam Massif, using the aluminum-in-hernblende barometry (각섬석 지압계를 이용한 영남육괴 내 화강암의 정치심도와 그 의미)

  • 홍세선
    • The Journal of the Petrological Society of Korea
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    • v.10 no.1
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    • pp.36-55
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    • 2001
  • Hornblende geobarometry has been applied to estimate the emplacement depth of the Jurassic Yeongiu, Andong, and Gimcheon granites in the Yeongnam Massif. Geobarometry was determined from the twenty two samples of the Yeongiu granite, ten samples of the Andong granite and twelve samples of the Gimcheon granite, using the composition of hornblende rims coexisting with the mineral assemblage required for pressure determination. Amphibole compositions in the three granites vary from edenite to ferropargasite with the increase of pressure. According to the equation of Schmidt(1992), the pressures of emplacement of the Yeongiu, Andong, and Gimcheon granites are 5.6 to 7.9 kb, 5.5 to 7.5 kb, and 4.1 kb to 5.3 kb, respectively. The emplacement depth in the Yeongiu granites increase systematically from about 6 kb in the northwest to about 7.5 kb in the southeast. Andong granite shows no systematic change of the pressure estimates. The Gimcheon granite shows almost consistent pressure distribution. The pressure difference of about 1.5 kb across the Yeongiu granite may be explained by a model combining late postemplacement upsurge of a deeper part of the pluton in the south with tilting of the batholith by Yecheon shear zone.

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Petrology and Geochemical Characteristics of A-type Granite with Particular Reference to the Namsan Granite, Kyeongju (경주 남산일대의 A-형 화강암의 암석학 및 지화학적 특성)

  • 고정선;윤성효;이상원
    • The Journal of the Petrological Society of Korea
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    • v.5 no.2
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    • pp.142-160
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    • 1996
  • Petrological and geochemical characteristics of A-type granite were studied from the Namsan and Tohamsan granites in the vicinity of Kyeongju city, southeastern Korea. The Namsan granite consists of hypersolvus alkali-feldspar granite in the northern part and subsolvus alkali-feldspar to biotite granite in the southern part. This hypersolvus granite usually has miarolitic cavities and is characteristically composed of quartz, single homogeneous one-feldspar (alkali feldspar) forming tabular microperthite crystals, or micrographic intergrowth with quartz, and interstitial biotite (Fe-rich annite), alkali amphibole (riebeckitic arfvedsonite) and fluorite. Petrographic and petrochemical characteristics indicate that the hypersolvus granite and subsolvus granite from the Namsan belogn to the A-type and I-type granitoid, respectively. The A-type granite is petrochemically distinguished from the I-type Bulgugsa granites of Late Cretaceous in South Korea, by higher abundance of $SiO_2$, $Na_2O$, $Na_2O+K_2O$, large highly charged cations such as Rb, Nb, Y, Zr, Ga, Th, Ce. U the REEs and Ga/Al ratio, and lower abundance of $TiO_2$, $Al_2O_3$, CaO, $P_2O_5$, MnO, MgO, Ba, Sr, Eu. The total abundance of REEs is 293 ppm to 466 ppm, showing extensively fractionated granitic compositon, and REEs/chondrite normalized pattern shows flat form with strong Eu '-' anomaly ($Eu/Eu^{\ast}$=0.03-0.05). A-type granite from the Namsan area is thought to have been generated late in the magmatic/orogenic cycle after the production of I-type granite and by direct, high-temperature partial melting of melt-depleted, relatively dry tonalitic/granulitic lower crustal material with underplating by mantle-derived basaltic magmas associated with subduction.

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Quantitative X-ray Diffraction Analysis of the Gyeonggi Bay Surface Sediments (경기만 표층퇴적물의 X선 광물정량분석)

  • Moon, Dong-Hyeok;Cho, Hyen-Goo;Kim, Soon-Oh;Yi, Hi-Il;Do, Jin-Young
    • Journal of the Mineralogical Society of Korea
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    • v.22 no.4
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    • pp.279-288
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    • 2009
  • Mineral compositions of the Gyeonggi Bay surface sediments were determined using the high resolution X-ray diffractometer and Siroquant v. 3.0 program. Surface sediments are composed of rock forming minerals (quartz 63.8%, plagioclase 12.9%, alkali feldspar 11.7%, muscovite 4.3%, amphibole 1.2%, biotite 0.5% on average), clay minerals (illite 2.4%, chlorite 1.4%, kaolinite 0.4%) and carbonate minerals (calcite 0.1%, aragonite 0.3%). Coarse sediments are high in the northern, southern and central parts of the study area, whereas fine sediments are high in the northern and southern parts of the central area. Coarse sediments have relatively a high quartz content in the northern part, and relatively high plagioclase and muscovite contents in the southern part of the study area. In the southern part and the northern part of central area, fine sediments have relatively a high illite content, and chlorite and kaolinite contents, respectively.