• Title/Summary/Keyword: Amounts of corrosion

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Characteristic Evaluation Based on the Heat Treatment Conditions of Super Duplex Stainless Steel with 0.2% N as an Additive - Part 1: Mechanical Properties and Microstructure (0.2% N을 첨가한 수퍼 2상 스테인리스강의 열처리 조건에 따른 특성 평가 - 제1보: 기계적 특성 및 미세조직)

  • Ahn, Seok-Hwan;Kang, Heung-Joo;Nam, Ki-Woo
    • Journal of Ocean Engineering and Technology
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    • v.22 no.4
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    • pp.46-50
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    • 2008
  • Super duplex stainless steel has along life in severe environments because of its strength and corrosion resistance. If 0.2$\sim$0.3% Nitrogen in aninterstitial solid solution is added, the austenite structure is reinforced. This improves the solid solution hardening and the anticorrosionability. In this study, the mechanical properties and structures of the super duplex stainless steel with the 0.2% N additive were investigated to determine the effect of various volume fractions on the austenite phase. The various volume fractions and distributions of the austenite structure in the applied test specimens were obtained by changing the heat treatment temperature and cycle. The characteristics by amounts of the $\sigma$ phase obtained from the precipitation heat treatment were alsoinvestigated. From the results, when the austenite volume fraction increases, the tensile strength decreases and elongation increases. And the $\sigma$ phase was rapidly increased by increasing the heat treatment time. When the volume fraction of the $\sigma$ phase increased, tensile strength increased.

Scientific Analysis and Conservation of Goryeo Bronze Bell at Buyeo National Museum (국립부여박물관 소장 고려시대 동종의 과학적 분석과 보존)

  • Lee, Sunmyung;Namkung, Seung;Kim, Yeonmi;Kim, Jongoh
    • Conservation Science in Museum
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    • v.10
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    • pp.1-13
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    • 2009
  • A part of the bronze bell from Goryeo (918-1392) in the collection of Buyeo National Museum was missing, and it was noted to retain corrosion products and burial accretions. Chemical analysis showed that the chemical composition of the bronze bell is Cu (74.18%), Sn (9.58%), Pb (15.77%), and very small amounts of As, Fe, Sb, Bi, and Ag. It was noted that the microstructure of the bronze bell was mainly made up of α phase and α+δ eutectoid phase, and gray (S) and black (Pb segregation) prevailed. Conservation treatment has been done for the preservation of this bronze bell.

Water Quality Control System Development for Cooling Towers (냉각탑 수질관리를 위한 자동화 시스템 개발)

  • Lee, Ki-Keon;Song, Moo-Jun;Lee, Young-Jae;Sung, Sang-Kyung;Kang, Tae-Sam
    • Journal of Institute of Control, Robotics and Systems
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    • v.14 no.1
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    • pp.36-41
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    • 2008
  • Cooling tower is an important equipment of the cooling systems for large buildings like factory and department store. Water used for cooling in cooling tower is reused continuously. If the water is polluted, corrosion and scale can happen at equipments and pipes. In order to prevent this problem, it is necessary to control the water quality using chemicals. To control the water quality, an automatic control system is designed, fabricated, and experimented. The control system is based on an imbedded microcontroller. Relays are used for power driving, an LCD and LED for display, and RS485 for remote data acquisition. Monitoring program is also developed for easy man-machine interface and extraction of data stored in the imbedded processor and EEPROM. The control system calculates amounts of chemicals necessary using sensor data and injects the chemicals into the cooling tower on proper time. The developed water quality control system is expected to reduce cost of maintenance and extend the lifetime of the cooling systems with low cost.

Influence of Carbonation and Freezing-thawing on the Chloride Diffusion in Concrete (탄산화 및 동결융해 현상이 콘크리트 중의 염소이온 확산에 미치는 영향 연구)

  • Kim, Dong-Baek;Kwon, Ki-Jun;Jung, Sang-Hwa;Bok, Hoon
    • Journal of the Korean Society of Safety
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    • v.22 no.3 s.81
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    • pp.57-64
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    • 2007
  • Recently, the corrosion of concrete structures has received great attention related with the deterioration of sea-side structures, such as new airport, bridges, and nuclear power plants. In this regards, many studies have been done on the chloride attack in concrete structures. However, those studies were confined mostly to the single deterioration due to chloride only, although actual environment is rather of combined type. The purpose of the present study is, therefore, to explore the influences of carbonation and freezing-thawing action to chloride attack in concrete structures. The test results indicate that the chloride penetration is more pronounced than the case of single chloride attack when the carbonation process is combined with the chloride attack. It is supposed that the chloride ion concentration of carbonation region is higher than the sound region because of the separation of fixed salts. Though the use of fly ash pronounces the chloride ion concentration in surface, amounts of chloride ion penetration into deep region decreases with the use of fly ash. The small reduction of relative dynamic elastic modulus induced from freezing-thawing increases the chloride ion penetration depths much. The present study allows more realistic assessment of durability for such concrete structures which are subjected to combined attacks of both chlorides and carbonation or freezing-thawing but the future studies for combined environment will assure the precise assessment.

Material Life Cycle Assessment of Extrusion Process of A7003 (A7003 알루미늄 합금 압출공정의 MLCA 산정기술)

  • Jo Huyng-ho;Cho Hoon;Kim Byung-min;Kim Young-jig
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2002.11a
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    • pp.43-49
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    • 2002
  • A7003 alloy has characteristics of their excellent weldability, high corrosion resistance and superior plastic working however the broadening of application for the alloy has been hampered by the lower extrudability associated by Mg content. For improvement of extrudability and enhanced recovery efficiency during Al scrap recyeling, it has been generally practiced to reduce Mg content in A7003 alloy. Therefore, it is necessary to investigate the influence of Mg content on mechanical strength and extrudability of A7003 alloy. For efficient material processing which has small amounts, life cycle assessment in material processing(MLCA) is evaluated. The quantitative analysis of energy requirements and $CO_2$ emission for production of A7003 extruded bar are estimated with different Mg content and billet pre-heating process (heating source by light oil or LPG). In particular, the estimation of energy requirements was performed within shipping and gating range (except the mining and extraction stages)to investigate the influence of the variables on energy requirements and $CO_2$ emission in detail. As Mg content increased, the flow stress and the extrusion pressure for A7003 alloy increased. It has been thought that an increment in extrusion pressure with increasing Mg content is caused by the solid solution hardening of Mg atoms in the matrix and increment in volume fraction of intermetallic compound, $Mg_2Si$. The extrudability and the tensile strength are equal to, or above that of conventional A 7003 alloy even the content of Mg varied from $1.1wt.\%\;to\;0.5wt.\%$ alloy. This means that minimizing the content of Mg in A7003 alloy can enhance recovery efficiency during Al scrap recycling. It can be quoted that rather than Mg content energy source for billet heating is a prime factor to determine the atmospheric $CO_2$ emission.

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Photocatalytic Degradation of Phenol in $UV/TiO_2$ Packed-bed System ($UV/TiO_2$ 충진 반응기에서 페놀의 광산화 반응)

  • Park, Kil-Soon;Kim, Jong-Hwa;Lee, Sang-Wha
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.9
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    • pp.939-945
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    • 2005
  • The Photocatalytic activity was investigated with the increase of flow rate in a $UV/TiO_2$ packed-bed system. The rate of phenol degradation over $UV/TiO_2$ (dia. = 5 mm) was increased up to 300 mL/min and reached a plateau beyond 400 mL/min. The bead photocatalysts did not exhibit a distinct difference of the phenol degradation rate irrespective of corrosion rates of glass beads and $TiO_2$ coating amounts. Degussa P25 exhibited a higher photocatalytic activity in comparison to other $TiO_2$ sols(Ishihara & N). The performance(activity and durability) of $UV/TiO_2$ packed-bed system can be enhanced by the use of $TiO_2$-coated glass beads instead of granular types that is easily attrited by the shearing force of flowing fluids.

Performance and Emission Characteristics of a Diesel Engine Operated with Wood Pyrolysis Oil (목질 열분해유를 사용하는 디젤엔진의 성능 및 배기특성에 관한 연구)

  • Lee, Seok-Hwan;Park, Jun-Hyuk;Choi, Young;Woo, Se-Jong;Kang, Kern-Yong
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.5
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    • pp.102-112
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    • 2012
  • The vast stores of biomass available in the worldwide have the potential to displace significant amounts of fuels that are currently derived from petroleum sources. Fast pyrolysis of biomass is one of possible paths by which we can convert biomass to higher value products. The wood pyrolysis oil (WPO), also known as the bio crude oil (BCO), have been regarded as an alternative fuel for petroleum fuels to be used in diesel engine. However, the use of BCO in a diesel engine requires modifications due to low energy density, high water contents, low acidity, and high viscosity of the BCO. One of the easiest way to adopt BCO to diesel engine without modifications is emulsification of BCO with diesel and bio diesel. In this study, a diesel engine operated with diesel, bio diesel (BD), BCO/diesel, BCO/bio diesel emulsions was experimentally investigated. Performance and gaseous & particle emission characteristics of a diesel engine fuelled by BCO emulsions were examined. Results showed that stable engine operation was possible with emulsions and engine output power was comparable to diesel and bio diesel operation. However, in case of BCO/diesel emulsion operation, THC & CO emissions were increased due to the increased ignition delay and poor spray atomization and NOx & Soot were decreased due to the water and oxygen in the fuel. Long term validation of adopting BCO in diesel engine is still needed because the oil is acid, with consequent problems of corrosion and clogging especially in the injection system.

A Study on Fouling Phenomena of in Petroleum Chemical Process (석유화학공정내에서 원유의 파울링 현상에 관한 연구)

  • Lee, Dong Rak;Ryu, Sang Ryoun;Park, Sang Jin;Cho, Wook Sang;Kim, Sang Wook
    • Applied Chemistry for Engineering
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    • v.7 no.3
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    • pp.443-452
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    • 1996
  • Fouling is caused by sedimentation and corrosion of polymer, heavy paraffine, chemicals, heavy organics, asphaltene, etc. in the entire chemical process of heat exchanger, boiler, desalter, etc. Fouling phenomena remains a serious operating problem which results in increased energy consumption, increased pressure drops, reduction or complete loss of products yield, and increased maintenance costs. In order to calculate the separated amounts of foulants and to control the fouling process, the predictive model is developed which is based on Scott & Magat polymer solution theory, Peng-Robinson EOS, BWR EOS, and continuous and multicomponent thermodynamics.

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Failure Mode of the Positive Plate on Charging Voltage in Gel Type Valve Regulated Lead Acid Batteries (충전전압에 따른 겔형 VRLA전지 양극판의 파손방식)

  • Oh Sanghyub;Kim Myungsoo;Lee Heung Lark
    • Journal of the Korean Electrochemical Society
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    • v.3 no.2
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    • pp.90-95
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    • 2000
  • Cycle life test was carried out to evaluate the failure modes of the gel type nth batteries at $C_5$ currents and $100\%$ DOD. When the batteries were charged at constant voltage of 2.40 V and 2.50 Vi respectively, cycle lift was over 1,000 cycles. The batteries lost 426.4 g and 391.2 g of electrolyte far each case after the weight measurement. The battery charged at 2.50 V was shown to have a better cyclic performance than charged at 2.40 V, and the amounts of electrolyte loss was proportional to charge factor. After cycle test, the micro-structure of positive active material was completely changed and the corrosion layer of positive grid was about $50{\mu}m$. Failure mode of the positive plate of the gel type battery was a shedding of the positive active material, and the cause of discharge capacity decrease was found to be a electrolyte loss.

Quantitative Evaluation for Improvement Effects of Performance After Mechanical Rehabilitation Treatments on Agricultural Groundwater Well (농업용 관정의 기계적 처리 이후 성능 개선 효과의 정량적 평가 사례)

  • Song, Sung-Ho;Lee, Byung-Sun;An, Jung-Gi
    • Journal of Soil and Groundwater Environment
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    • v.21 no.4
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    • pp.42-49
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    • 2016
  • Step-drawdown pumping tests for identifying the improvement of groundwater well performance after rehabilitation treatments were conducted in three longstanding wells. Three selective mechanical treatment methods including power bubble, high-voltage electric pulse, and air surging were applied to these wells and the applicability of these methods to secure additional groundwater resources were evaluated quantitatively. Commonly, drawdown at final stage of stepdrawdown pumping tests after rehabilitation decreased by as much as 0.61~0.70 meters compared to those before rehabilitation. In addition, final specific drawdown values of three wells increased from 9% to 14% after rehabilitation. Formation loss coefficient and well loss coefficient decreased to 6.1% and 60.6%, respectively, indicating some clogging materials by precipitation/corrosion/microbe within pores of aquifer materials, gravel packs, and screens were effectively removed by applied methods. Decrease of formation loss coefficient was higher in the well applied by the power bubble method meanwhile high-voltage electric pulse method demonstrated the higher decrease of well loss coefficient. Additionally secured groundwater amounts after rehabilitation ranged from 23.3 to 32.1 m3/day, which account for 8~16% of initially developed pumping rates of the wells. From the results of this study, the effective selection of rehabilitation treatments considering aquifer characteristics are expected to contribute to secure groundwater resources for irrigation as well as to plan systematic management program for groundwater resources in rural area.