• 열처리공학회지
• /
• 제8권3호
• /
• pp.236-243
• /
• 1995

Since amorphous alloys have been known to have better mechanical and chemical properties than crystalline alloys of the same composition, a great number of studies on the formation of Al-based amorphous alloys have been carried out actively. However, little has been obtained about the effect of Rare-Earth metal and Transition metal addition on amorphous phase formed by melt spinning method. This study included fabrication of amorphous alloy $Al_{85}Ce_5Ni_{10}$ by melt spinning methods and DTA, XRD, TEM analysis to determine crystalization behavoir. Annealing treatments were carried out in Ar atmosphere under isothermal and nonisothermal conditions. The diffraction pattern of non-heated ribbons showed broad form characteristic of glass metallic alloy. The crystallization of amorphous $Al_{85}Ce_5Ni_{10}$ takes place eutedtoidly by homogeneous formation of Al and MS-1, followed by precipitation of the $Al_{11}Ce_3$ and later $MS-1{\rightarrow}Al_3Ni$ transformation.

• 한국재료학회지
• /
• 제14권7호
• /
• pp.477-481
• /
• 2004

High quality polycrystalline silicon is very critical part of the high quality thin film transistor(TFT) for display devices. Metal induced lateral crystallization(MILC) is one of the most successful technologies to crystallize the amorphous silicon at low temperature(below $550^{\circ}C$) and uses conventional and large glass substrate. In this study, we observed that the MILC behavior changed with abrupt variation of the amorphous silicon active pattern width. We explained these phenomena with the novel MILC mechanism model. The 10 nm thick Ni layers were deposited on the glass substrate having various amorphous silicon patterns. Then, we annealed the sample at $550^{\circ}C$ with rapid thermal annealing(RTA) apparatus and measured the crystallized length by optical microscope. When MILC progress from narrow-width-area(the width was $w_2$) to wide-width-area(the width was $w_1$), the MILC rate decreased dramatically and was not changed for several hours(incubation time). Also the incubation time increased as the ratio, $w_1/w_2$, get larger. We can explain these phenomena with the tensile stress that was caused by volume shrinkage due to the phase transformation from amorphous silicon to crystalline silicon.

• 한국재료학회:학술대회논문집
• /
• 한국재료학회 2008년도 춘계학술발표대회 및 제14회 신소재 심포지엄
• /
• pp.11.1-11.1
• /
• 2008

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2011년도 제40회 동계학술대회 초록집
• /
• pp.434-434
• /
• 2011

Electrochemical method have been employed in this work to modify the chemical vapour deposited nitrogen doped hydrogen amorphous diamond-like carbon (N-DLC) film to fabricate nickel and copper nano particle modified N-DLC electrodes. The electrochemical behaviour of the metal nano particle modified N-DLC electrodes have been characterized at the presence of glucose in electrolyte. Meanwhile, the N-DLC film structure and the morphology of metal nano particles on the N-DLC surface have been investigated using micro-Raman spectroscopy, X-ray photoelectron spectroscopy and atomic force microscopy. The nickel nano particle modified N-DLC electrode exhibits a high catalytic activity and low background current, while the advantage of copper modified N-DLC electrode is drawn back by copper oxidizations at anodic potentials. The results show that metal nano particle modification of N-DLC surface could be a promising method for controlling the electrochemical properties of N-DLC electrodes.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
• /
• pp.210-213
• /
• 2004

The phase transition between amorphous and crystalline states in chalcogenide semiconductor films can controlled by electric pulses or pulsed laser beam; hence some chalcogenide semiconductor films can be applied to electrically write/erase nonvolatile memory devices, where the low conductive amorphous state and the high conductive crystalline state are assigned to binary states. Memory switching in chalcogenides is mostly a thermal process, which involves phase transformation from amorphous to crystalline state. The nonvolatile memory cells are composed of a simple sandwich (metal/chalcogenide/metal). It was formed that the threshold voltage depends on thickness, electrode distance, annealing time and temperature, respectively.

• 한국진공학회지
• /
• 제7권s1호
• /
• pp.123-133
• /
• 1998

Amorphous silicon (a-Si) was crystallized by metal induced crystallization using metal solution. The a-Si films spin coated with a 50,000 ppm Ni solution were crystallized at as low as $500^{\circ}C$. Needlelike morphology, developed as a result of the migration of $NiSi_2$, precipitates, appears in the MIC poly-Si. The growth of the needlelike crystallites proceeds to a direction parallel to (111). The crystallization temperature can be lowered to $450^{\circ}C$ by Au addition. The enhancement of crystallization results from the decrease of interfacial energy at the NiSi2/Si interface by Au addition.

• 한국정보디스플레이학회:학술대회논문집
• /
• 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
• /
• pp.87-90
• /
• 2007

VIATRON TECHNOLOGIES has developed an $\underline{A}$tmospheric $\underline{M}$etal $\underline{D}$oping (AMD) system which uniformly dopes metal species onto a substrate. The AMD system injects metal-organic vapor over substrate using an injection head with a scan motion. One of important application of this system is a metalinduced crystallization of amorphous Si for manufacturing AMOLED poly-Si panels. The AMD system with a use of Ni vapor source produces doping of trace amount of Ni onto amorphous Si, enabling uniform MIC crystallization. Also, the operation without vacuum condition offers advantages such as easy maintenance, low cost production, and large glass processes.

• 한국토양환경학회지
• /
• 제4권3호
• /
• pp.77-84
• /
• 1999

본 논문에서는 고농도의 중금속 (납, 구리)으로 오염된 세 가지의 토양을 대상으로 sequential extraction 방법을 사용하여 토양과 중금속의 차이에 따른 결합 특성을 밝혀내고자 하였다. 고농도의 납과 구리로 오염된 토양을 형태별로 추출하였을 때 토양의 특성과 중금속의 종류에 따라 다른 결과를 보였다. 납은 문화동 토양에서는 Carbonate 형태가 37.7%로 가장 높았고 농토는 Amorphous Fe oxide 형태가 23.9%, 공단 토양에서는 Exchangeable 형태가 22.9%로 나타났다. 이에 비하여 구리는 세 가지 토양에서 공통적으로 Organically bound 형태가 농토에서 26.1%, 문화동 토양은 20.4%. 공단 토양에서는 24.1%로 높게 나타났고 Carbonate 형태와 Amorphous Fe oxide형태의 비율도 높게 나타났다. 또한 Crystallized Fe oxide 형태와 Residuals 형태도 납보다 높은 비율을 나타냄으로서 구리가 납보다는 토양과 강한 결합을 형성하는 것으로 생각된다. 이러한 토양과 중금속의 결합 특성은 오염 토양의 복원시 유용한 자료가 될 수 있다.

• 한국항해항만학회지
• /
• 제34권1호
• /
• pp.27-31
• /
• 2010

본 논문에서는 항만 물류 시스템에서 사용하는 중심주파수 433 MHz에서 동작하는 전파흡수체를 설계 개발하였다. 먼저 자성손실 재료인 AMP (Amorphous Metal Powder)와 지지재인 CPE (Chlorinated Polyethylene)를 이용하여 AMP:CPE의 조성비가 각각 80:20 wt.%와 85:15 wt.%의 전파흡수체 샘플을 제작한 후, 입력임피던스를 측정하여 샘플의 재료정수를 계산하고 시뮬레이션에 의하여 최적의 전파흡수체를 설계하였다. 그 결과 AMP:CPE=85:15 wt.% 의 조성비에 두께 5.5 mm일 때 최적의 전파흡수특성이 얻어짐을 확인하고, 실제 제작하여 측정한 결과 433 MHz 주파수대역에서 17.5 dB의 흡수능이 얻어졌으며, 이는 본 연구에서 목표로 하는 15 dB 보다 우수한 결과이다.

• 대한화학회지
• /
• 제67권4호
• /
• pp.222-225
• /
• 2023

Metallic salts of C10-18 aliphatic carboxylic acids were prepared and their scanning electron microscopic images were analyzed for the morphology dependency with the metal and the carboxylic acid. Regardless of metal ion, metal salts of dicarboxylic acids showed a high crystallinity with a fiber image (SuA-Na). The aromatic dicarboxylates also represented a morphology of a rectangular-rod or board shapes (IA-Li, IA-Ba). With Na ion, most aliphatic carboxylate (MA, PA, SA) showed a fiber-like crystallinity. However, other monovalent Li, K and multivalent Mg, especially Al ion resulted a glassy-amorphous in the metallic salts of acids (MA, PA, SA). With divalent Ba and Ca ions, the metal salt of aliphatic acids expressed a branched round cluster shape as in SA-Ca, SA-Ba. Both Li and Mg ions with a similar size showed a strong morphological similarity in the metallic salts of aliphatic acids MA, PA, SA. In the case of Na and Ca ions with a similar size (98, 106 pm), both ionic salts of stearic acid gave a branching effect for a fiber or round granular image. In the case of hydroxyl-aliphatic acids (HLA, HPA, HSA), the fiber images in HLA-Na and HSA-Na was appeared about 100 nm thicker than those of nonhydroxycarboxylates (LA-Na, SA-Na). The metallic salts of unsaturated C-18 carboxylic acids (OlA, LeA and LnA) showed an amorphous glassy image due to a kinked carbon chain.