• 약학회지
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• 제24권3_4호
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• pp.159-165
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• 1980

Tetrathiocyanatocobaltate[II] forms complexes with tertiary amine salts or quarternary ammonium salts which were extractable from aqueous solution by organic solvent. In order to study composition of the complex, the colored crystalline complexes produced were evaluated with elemental analysis, infrared and mass spectra. And also a novel spectrophotometric method for the determination of tertiary amine salt or quarternary ammonium salt with tetrathiocyanatocobaltate[II] was established by organic solvent extraction within coefficient of variation of 1.06-1.35%.

• 폴리머
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• 제39권1호
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• pp.122-129
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• 2015

최근 해양 산업에서는 해양환경에 잔류성은 없으면서 방오성능은 우수한 새로운 종류의 방오도료 수지 개발이 해결해야 할 시급한 과제로 대두되고 있다. 본 연구에서는 폴리우레탄계 수지를 방오도료용 수지로 적용하여 평가하였다. Polyethylene glycol(PEG), 4,4'-diphenylmethane diisocyanate(MDI) 2,2'-bis(hydroxyl methyl)propionic acid(DMPA)를 사용하여 중합한 후 방오성능을 발휘하는 치환기로서 quaternary ammonium salt를 치환시켰다. 합성된 수지는 최종적으로 필름화하여 해수 내에서의 마모특성을 확인하였다. 그 결과, PEG의 분자량이 600인 방오도료용 폴리우레탄 수지의 기계적 물성이 가장 양호함을 알 수 있었으며, quaternary ammonium salt의 함량이 일정 이상으로 많은 경우에는 수지에 대한 부착력이 저하됨을 확인하였다.

• 정보학연구
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• 제8권3호
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• pp.51-56
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• 2005

In this paper, we describe a study on the relationship between spectral sensitization and photographic characteristics of color paper. The photographic emulsion used in this study is a green-sensitizing emulsion. U.V maximum absorption peak value of 9-phenyl-5,5'-diphenyl-3,3'-bis(3-sulfopropyl)benzoxazolo carbocyanine triethyl ammonium salt was observed 507nm, and wedge spectrograms maximum peak value of color paper added dye to photographic emulsion was shown 553nm. As compared with the absorption peak of the dye in methanol solution, the sensitizing peaks of 9-phenyl-5,5'-diphenyl-3,3'-bis(3-sulfopropyl)benzoxazolo carbocyanine triethyl ammonium salt have red shifts of 46nm. The photographic characteristics of green-sensitizing emulsion were obtained contrast(2.6), speed(48-57), fog(0.08). Therefore, benzoxazolo carbocyanine dye is of industrial importance as green-sensitizing dye in the spectral sensitization of photographic emulsion.

• 한국응용과학기술학회지
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• 제13권3호
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• pp.73-81
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• 1996

In this study, sensitizing dye was prepared by the reaction of 2-methyl-3-sulfopropyl-4,5-naphthothiazolium(inner salt) with triethyl orthobenzoate in the presence of triethylamine. The product was identified by using various analytical tools such as elemental analyzer, IR spectrophotometer, UV-Vis spectrophotometer, $^1H-NMR$ spectrometer, TGA and DSC. Therefore, it was concluded that 9-phenyl-3,3'-bis(3-sulfopropyl)-4,5,4',5'-naphthothiazolo carbocyanine triethyl ammonium salt can be used as red-sensitizing dye for the spectral sensitization of photographic emulsion.

• Bulletin of the Korean Chemical Society
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• 제24권10호
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• pp.1425-1426
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• 2003

• 정보학연구
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• 제7권2호
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• pp.1-5
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• 2004

본 연구는 산업적으로 중요한 필름 및 인화지 제조시 녹감 사진유제에 필수적으로 들어가는 분광증감색소인 benzoxazolo carbocyanine계를 선택하여 다양한 용매에 대해 경시변화에 대한 안정성이 있는가 또한 용매에 따른 흡수최대피크값이 어느 정도 변화되는가를 측정하여 사진유제에 잘 적용할 수 있는지를 연구 조사한다.

• 한국윤활학회:학술대회논문집
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• 한국윤활학회 2004년도 학술대회지
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• pp.323-329
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• 2004

The electrical and rheological properties pertaining to the electrorheological (ER) behavior of chitosan derivatives, chitosan, chitosan ammonium salt and chitosan phosphate suspensions in silicone oil were investigated. Chitosan derivative suspensions showed a typical ER response (Bingham flow behavior) upon application of an electric field. However, chitosan phosphate suspension exhibited an excellent shear yield stress compared with chitosan and chitosan ammonium salt suspensions. The difference in behavior results from the difference in the conductivity of the disperse phases due to the difference of their polarizability. The shear stress for the chitosan, chitosan ammonium salt and chitosan phosphate suspensions exhibited a linear dependence on the volume fraction of particles and 1.18 ,1.41 and 1.67 powers of the electric field. On the basis of the experimental results, the newly synthesized chitosan derivative suspensions found to be an ER fluid.

• KSTLE International Journal
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• 제5권2호
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• pp.49-51
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• 2004

The electrical and rheological properties pertaining to the electrorheological (ER) behavior of chitosan derivatives, chitosan, chitosan ammonium salt and chitosan phosphated suspensions in silicone oil were investigated. Chitosan derivative suspensions showed a typical ER response (Bingham flow behavior) upon application of an electric field. However, chitosan phosphate suspension exhibited an excellent shear yield stress compared with chitosan and chitosan ammonium salt suspensions. The difference in behavior results from the difference in the conductivity of the disperse phases due to the difference of their polarizability. The shear stress for the chitosan, chitosan ammonium salt and chitosan phosphate suspensions exhibited a linear dependence on the volume fraction of particles and 1.18, 1.41 and 1.67 powers of the electric field. On athe basis of the experimental results, the newly synthesized chitosan dervative suspensions found to be an ER fluid.

• 한국대기환경학회지
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• 제16권2호
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• pp.113-120
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• 2000

Effects of sea-salts on the properties of aerosol collected in a coastal region were studied by applying a gas-particle equilibrium model SCAPE to the measurement data from Korea Cheju Island in summer 1994. It was found that the observed higher ammonium concentrations in fine particles (PM2.5) than in TSP were caused by forced evaporation of ammonium in coarse fraction of aerosol by sea-salts and the degree of evaporation was quantified through an application of SCAPE. By subtracting the sea-salt fraction from the measured concentra-tions the changes of aerosol property were also studied. The concentrations of nitrate at both TSP and PM2.5 decreased when alkaline sea-salt fraction was removed from the measured data. Estimates of aerosol acidity increased for most samples with sea salt loadings, However in some cases with high mass fractions of sea-salt components the aerosol acidity of PM2.5 decreased slightly. This is though to be related with the formation of solid salt with the removal of sea-salts.

• 한국응용과학기술학회지
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• 제32권3호
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• pp.461-468
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• 2015

역상 HPLC에 의한 Cetyltrimetyl ammonium chloride(CTM), Stearamidopropyl dimetylamine(SAP), Behentriammonium chloride(BHT), Dihexadeyldimethyl ammonium chloride (DHDDM)의 양이온계면활성제 4종 동시 정량분석 방법을 개발하였다. 분석조건으로 분리관은 Alltech $C_{18}$($250mm{\times}4.6mm$ i.d., $5{\mu}m$)을 사용하였고, 검출기는 ELSD를 사용하였으며, 이동상은 0.2% TFA/Methanol의 기울기 용리에 의해 분석되었다. 이때 검량선의 상관계수($r^2$)는 $130{\sim}1980.5{\mu}g/mL$농도 범위에서 0.997이상 이었고, 검출한계, 정밀성이 우수하였다. 이 방법은 fatty quaternary ammonium salt 4종의 정량분석 가능함을 보여 주었다.