• Title/Summary/Keyword: Ammonia solution

검색결과 366건 처리시간 0.028초

새로운 식물조직 바이오센서에 의한 글루타민의 정량 (Determination of Glutamine Utilizing New Plant Tissue Bio-Sensor)

  • 인권식;김봉원;전영국
    • 대한화학회지
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    • 제34권6호
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    • pp.622-628
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    • 1990
  • 장미 구성요소 중 꽃잎 부분을 $NH_3$ 감응센서에 고정시켜서 글루타민 조직센서를 제조하여 pH, 완충용액, 조직 양 및 여러 가지 방해물질의 영향과 전극의 수명 등에 관하여 조사하였다. 그 결과 37$^{\circ}C$에서 pH 7.8, 0.2M 인산완충용액을 사용하였을 때, $8.0 {\times} 10^{-4}$$5.0 {\times} 10^{-2}$ M 글루타민 직선범위와 52 mV/decade의 감응기울기를 나타내었다. 이 때 사용한 조직 양은 50 mg이었다. 본 센서는 선택성이 탁월한 것으로 나타났다. 이 센서를 장미의 다른 구성요소와 비교하였다. 실제 글루타민의 정량에 유용하게 사용될 것으로 나타났다.

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Bacteria 및 Organelle을 이용한 Cytidine Biosensor (Cytidine Biosensor Using Bacteria and Organelle)

  • 인권식;김정숙;전영국;김봉원
    • 대한화학회지
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    • 제35권1호
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    • pp.38-45
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    • 1991
  • Proteus mirabilis균과 organelle를 NH$_3$ 기체감응전극에 고정시켜 cytidine에 대한 바이오센서를 제조하였다. 박테리아 센서에 대한 pH, 온도, 완충용액, 균량 및 방해물질의 영향과 수명을 조사하였다. 그 결과 0.1M phosphate 완충용액에서 pH 7.8, 온도 30$^{\circ}C$, 균량 3mg이었을 때, 5.0 ${times}$ 10$^{-4}$M ∼ 1.0 ${times}$ 10$^{-2}$M cytidine 직선범위 내에서 56 mV/decade 의 감응기울기를 나타내었다. 이 박테리아 전극의 감응특성을 organelle 전극의 경우와 비교하였다.

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순환식 양액재배에서 상추의 성장에 따른 양액성분의 변화 (Changes in the Nutrient Components Associated with the Growth of Lettuce in Circulating Hydroponics)

  • 김동석;박영식
    • 한국환경과학회지
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    • 제24권8호
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    • pp.1075-1084
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    • 2015
  • This study was conducted to investigated the changes in the nutrient components ($NO_3{^-}-N$, $NH_4{^+}-N$, $PO_4{^{3-}}P$, $K^+$, $Ca^{2+}$, and $Mg^{2+}$) and environmental parameters (electrical conductivity, total dissolved solids and pH) on the leaf lettuce (Lactuca sativa L.) grown with hydroponics. Recirculating hydroponic cultivation system was consisted of planting port, LED lamp, water tank, and circulating pump for hydroponic. Nutrient solution was used in the standard solution for Japan vegetables experimental station and commercial hydroponic. The result showed that electrical conductivity (EC), total dissolved solids (TDS) and pH, depending on the growth of lettuce decreased continuously. With the growth of the lettuce, nitrate nitrogen, ammonia nitrogen, phosphate phosphorus were required for periodic replacement. The number of pH compensation due to the growth of lettuce are the most high. The concentration of $Ca^{2+}$ and $Mg^{2+}$ during the lettuce growth showed no significant change. However, $K^+$ concentration increased due to the replacement with nitrogen and phosphorus. Electric conductivity and total dissolved solids with total nutrient concentration showed the linear relationship and the correlation coefficient $R^2$ were 0.8601 and the 0.827, respectively.

표면처리한 알루미나의 표면물성과 계면전위분포 (Surface Properties and interfacial Potential Distribution of Surface Treated-Alumina)

  • 홍영호;함영민
    • 한국세라믹학회지
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    • 제33권7호
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    • pp.823-831
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    • 1996
  • Due to the intrinsic low surface activation of ${\gamma}$-alumina it has been used limitely in practice. Accordingly forward enhancing its utility ${\gamma}$-alumina surface was treated with slfuricf aicd nitric acid and chloric acid respec-tively. Subsequently the effects of surface activity on the surface electrical characteristics were investigated. The ${\gamma}$-alumina was prepared by the precipitation of aluminium nitrate [Al(NO3)3.9H2O] using ammonia water as a precipitator and it was chemically treated with such acids mentioned above. The surface and morphology of the acid-treated ${\gamma}$-alumina were analysed by XRD, BET and the surface activities were measured by the amine titration methods. The interfacial properties of the ${\gamma}$-alumina dispersed in electrolyte solution were esti-mated by the surface charge density measured using potentiometric tiration. Based on the relation between surface charge density and the acid amount the following results were drawn for the surface and interfacial electrical properties ; Acidic properties of surface-treated alumina increase with anion load on alumina surface. P. Z. C decreases with acid amount on alumina surface. The surface charge densities were apart from electrolyte ionic strength. The acidity of ${\gamma}$-alumina is linearly dependent on the P. Z,.C when the ${\gamma}$-alumina was dispersed in aqueous electrolyte solution.

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THE EFFECTS OF UREA NITROGEN ON THE METABOLISM OF PLANTS (II) The response of some nitrogen components of barley to urea and other nitrogen in water culture.

  • Kim, . Joon Ho
    • Journal of Plant Biology
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    • 제5권2호
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    • pp.6-12
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    • 1962
  • For the comparison with the previous paper (4) the present report deals with the absorption and metabolism of urea and other nitrogen ions in barley seedling absorbed through root. 1. The amount of nitrate in barley treated with urea reach it peak on the 8th day. NO3 on the 4th, NH4 on the 6th or 8th, respectively. 2. The ammonia content in urea group reaches its peak on the 6th day but other groups on the 4th day. The present data in the urea group show to shorten 4 days compared with that of the previous paper(4). 3. the content of total amide from the present data aare gradully increased on all of the groups during this experiment. These are agreement with the result of the previous paper (4). 4. the alcohol solution nitrogen in the urea gorup shows the similar tendency to the NaNO3 group but reaches it peak 2 days later than in the (NH4)2SO4 group. 5. The content of total nitrogen in the urea series has the lowest amount at the beginning while the richest from the 4th day after. These would be explained on that the absorption of urea is delayed and the PH in the urea solution does not change, so called "physiological neutrality". The author should like express his sincere thanks to Prof. M.J.Lee of Seoul National University for his valuable advices.e advices.

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Effect of Monensin and Fish Oil Supplementation on Biohydrogenation and CLA Production by Rumen Bacteria In vitro When Incubated with Safflower Oil

  • Wang, J.H.;Choi, S.H.;Yan, C.G.;Song, M.K.
    • Asian-Australasian Journal of Animal Sciences
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    • 제18권2호
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    • pp.221-225
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    • 2005
  • An in vitro study was conducted to examine the effect of monensin or fish oil addition on bio-hydrogenation of $C_{18^-} unsaturated fatty acids and CLA production by mixed ruminal bacteria when incubated with safflower oil. Commercially manufactured concentrate (1%, w/v) with safflower oil (0.2%, w/v) were added to mixed solution (600 ml) of strained rumen fluid and McDougalls artificial saliva (control). Monensin $Rumensin^{(R)}$, 10 ppm, w/v, MO), mixed fish oil (0.02%, w/v, absorbed to 0.2 g alfalfa hay, FO) or similar amounts of monensin and fish oil (MO+FO) to MO and FO was also added into the control solution. All the culture solutions prepared were incubated in the culture jar anaerobically at $39^{\circ}C$ up to 12 h. Higher pH (p<0.047) and ammonia concentration (p<0.042) were observed from the culture solution containing MO at 12 h incubation than those from the culture solutions of control or FO. The MO supplementation increased (p<0.0001-0.007) propionate proportion of culture solution but reduced butyrate proportion at 6 h (p<0.018) and 12 h (p<0.001) of incubations. Supplementation of MO or MO+FO increased (p<0.001) the proportions of $C_{18:2}$. The MO alone reduced (p<0.022-0.025) the proportion of c9,t11-CLA compared to FO in all incubation times. The FO supplementation increased the proportion of c9,t11-CLA. An additive effect of MO to FO in the production of c9,t11-CLA was observed at 6 h incubation. In vitro supplementation of monensin reduced hydrogenation of $C_{18^-}$UFAs while fish oil supplementation increased the production of CLA.

공기 압축기와 암모니아 냉동기의 진동 측정 및 분석 (Vibration Measurement and Analysis of Air compressor and Ammonia Refrigerator)

  • 장용석;정재환;정한얼;최병근
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회A
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    • pp.1015-1019
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    • 2007
  • The necessity of diagnosis of the rotating machinery which is widely used in the industry is increasing. Because vibration diagnosis can avoid sudden breakdown of machine and reduce the maintenance costs. In chemical factory, Air-compressor and refrigerator which can affect the performance and capacity of output is important machine. Therefore, in this paper, the vibration of reassembled air-compressor and refrigerator after explosion is measured for checking the machine condition. The result of diagnosis and solution is discussed in this paper.

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THE STUDY ON THE MICROCRYSTAL GROWTH OF SILVER HALIDE IN PHOTOGRAPHIC EMULSION WITH MODIFIERS

  • Kang, Tai-Sung;Ahn, Hong-Chan;Park, In-Yeong;Kim, Chan-Rae
    • Journal of Photoscience
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    • 제1권1호
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    • pp.63-66
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    • 1994
  • Silver chlorobromoiodide cubic seed emulsion was prepared'in the presence of ammonia and phenylcarbamyl gelatin solution. When benzenethiosulfonate sodium salt (BTS) and 4-hydroxy6-methyl-1,3,3a,7-tetraazaindene (TAI), as growth modifiers, were added in the seed emulsion, the silver halide microcrystals were obtained in the forms of cubo-octahedrons, octahedrons, rhombic dodecahedron by variation of pAg value through controlled double jet. The crystal habits and shapes were determined by means of X-ray diffraction (D/MAX BIB, Rigaku) and electron microscopy (JSM-840, JEOL), respectively.

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STABILIZATION WITH SULFURIC ACID OF THE CRUDE PROTEIN IN UREA-TREATED RICE STRAW

  • Promma, S.;Tasaki, I.;Cheva-Isarakul, B.;Indratula, T.
    • Asian-Australasian Journal of Animal Sciences
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    • 제7권4호
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    • pp.481-486
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    • 1994
  • The effect of neutralization of urea-treated rice straw with sulfuric acid was investigated. Long-cut (15-20 cm) and short-cut (2-3 cm) rice straw were treated with 6% urea for 21 days, and the treated straw was mixed with an acid-molasses solution to neutralize free ammonia and kept airtightly in a plastic bag for 24 hours. The neutralized and non-neutralized straw were dried and subjected to chemical analysis and in vitro dry matter (DM) digestibility determination. The in vitro DM digestibility as well as crude protein (CP) content were remarkably improved by neutralization. Short-cutting of the straw before treatment gave a better result than the long-cut samples. Neutralization with sulfuric acid also affected the chemical composition and increased sulfur content of samples. The CP thus fixed by neutralization was proven to be kept stable for 3 months, and in vitro DM digestibility was not affected by the storing period.

덕트 유동에서 증발을 수반하는 액상 스프레이의 혼합 특성에 대한 실험적 연구 (An experimental study on the mixing of evaporating liquid spray with duct flow)

  • 김영봉;최상민
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2005년도 제31회 KOSCO SYMPOSIUM 논문집
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    • pp.93-96
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    • 2005
  • High temperature furnace such as Steam power plant and incinerator contribute considerable part of NOx generation and face urgent demand of De-NOx system. Reducing agents are necessary to use De-NOx system. In this study mixing caused by direct injection of reducing agent solution spray into flue gas duct was measured. Carbonated water was used as tracer and simulated agent because ammonia as a reducing agent is not proper to experiment. Mixing and evaporation must occur simultaneously and quickly enough to achieve desirable efficiency. To achieve that, the angle of attack of static mixer and the location is simulated and $CO_2$ concentration is measured.

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