• Title/Summary/Keyword: Ammonia removal rates

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Effect of Aeration Rates on Ammonia Emissions during Composting of Livestock Manure (축분(畜糞) 퇴비화시(堆肥化時) 공기주입율(空氣注入率)이 암모니아 배출(排出)에 미치는 영향(影響))

  • Kang, Hong-Won;Rhee, In-Koo;Park, Hyang-Mee;Ko, Jee-Yeon;Choi, Jyung
    • Korean Journal of Soil Science and Fertilizer
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    • v.32 no.3
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    • pp.304-311
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    • 1999
  • This experiment was conducted to find out the optimum condition of aeration rates for removal of malodor and to improve the compost quality. The aspect of ammonia emission and amounts of volatilization were investigated in the enclosed composting reactor of 242 liters piled with mixed materials of dairy manure and rice straw, which adjusted to 65% of initial moisture content and controlled by four different aeration rates. Mature temperature increased suddenly in initial composting time and decreased with Increasing aeration rates. The treatment of $1.79l\;min^{-1}kg\;dry-solids^{-1}$ results in overcooling and rapid drying of composting materials because of too much aeration. The average concentration of ammonia emitted from composting for 24 days was the range of 25.3 to $239.8mg\;l^{-1}$ and was highest in the treatment of $0.09l\;min^{-1}kg\;dry-solids^{-1}$, followed by 0.90. 0.18 and $1.79l\;min^{-1}kg\;dry-solids^{-1}$. The range of maximum concentration by different aeration rates was $335{\sim}2279mg\;l^{-1}$ and it wan highest in the treatment of $0.09l\;min^{-1}kg\;dry-solids^{-1}$, followed by 0.18, 0.09 and $1.79l\;min^{-1}kg\;dry-solids^{-1}$. Relationship between the ammonia concentration emitted and temperature matured under different aeration rates showed an exponential positive correlation with 1% significance and had a trend of clear increase in ammonia concentration with increasing temperature over $50^{\circ}C$. Most of ammonia volatilized within plays after composting. The volatilization rate of ammonia ranged from 0.056 to 0.453 per dry solids of materials and it was highest in the treatment of $0.09l\;min^{-1}kg\;dry-solids^{-1}$, followed by 0.18, 0.09 and $1.79l\;min^{-1}kg\;dry-solids^{-1}$. Amounts of ammonia volatilized under composting condition of this experiment was estimated to be highest in the aeration range of 0.9 to $1.0l\;min^{-1}kg\;dry-solids^{-1}$.

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Reaction Characteristics of Piggery Wastewater for Biological Nutrient Removal (생물학적 영양염류 제거를 위한 돈사폐수의 반응 특성)

  • 한동준;류재근;임연택;임재명
    • Journal of environmental and Sanitary engineering
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    • v.13 no.1
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    • pp.44-56
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    • 1998
  • This study was performed to investigate the reaction characteristics of piggery wastewater for biological nutrient removal. The reaction characteristics were discussed the fraction of organics, the behavior of nitrogen, nitrification, denitrification, and the behavior of phosphorus. The fraction of readily biodegradable soluble COD was 11-12 percent. The ammonia nitrogen was removed via stripping, nitrification, autotrophic cell synthesis, and heterotrophic cell synthesis. The removal percents by each step were 12.1%, 68.9%, 15.0%, and 4.0%, respectively. Nitrification inhibition of piggery wastewater was found to occur at an influent volumetric loading rate over 0.2 NH$_{3}$-N kg/m$^{3}$/d. Denitrification rates were the highest in the raw wastewater and the lowest in the anaerobic effluent. The denitritation of piggery wastewater came out to be possible, and the rate of organic carbon consumption decreased about 10 percent. The phosphorus removed was released in the form of ortho-p in the aerobic fixed biofilm reactor, it was caused by autooxidation. The synthesis and release of phosphorus were related to the ORP and the boundary value for the phase change was about 170mV. In the synthesis phase, the phosphorus removal rate per COD removed was 0.023mgP$_{syn}$/mgCOD$_{rem}$. The phosphorus contents of the microorganism were 4.3-6.0% on a dry weight basis.

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Simultaneous Removal Characteristics of NOx, SOx from Combustion Gases using Plasma Chemical Reaction (플라즈마 화학반응에 의한 연소가스 중 NOx. SOx 동시제거 특성)

  • 박재윤;고용술;이재동;손성도;박상현;고희석
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.406-409
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    • 1999
  • Experimental Investigations were carried out to remove NOx, SOx simultaneously from simulated flue gas[NO(0.02%)-SO$_2$(0.08%)-$CO_2$-Air-$N_2$] by using a plasma chemical reaction. Ammonia gas(14.81%) balanced by argon was diluted by all and was Introduced to mall simulated flue gas duct through NH$_3$ Injection system which is in downstream of reactor. The NH$_3$ molecular ratio(MR) was determined based on (NH3) to [NO+S0$_2$]. MR is 1, 1.5, 2.5. The NOx removal rate significantly increased with increasing NaOH bubble quantity. The SO$_2$ removal rate was not significantly effected by applied voltage, however it fairly Increased with increasing NH$_3$ molecule ratio. By-product aerosol particle was observed by XRD(X-ray diffraction) after sampling, The NOx, SOx removal rates, when H2O vapour bubbled by dry all was injected to plasma reactor, were better than those of other cases. When aqueous NaOH solution(20%) bubbled by 2.5( ι /min) of $N_2$ and 0.5 ( ι /min) NH$_3$(MR=1.5) were injected to simulated flue gas, The NOx. SOx removal rate was 95 ~ 100[%]

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Effects of Rotational Speed and Hydraulic Residence Time on the Ammonia Removal of a Rotating Biological Contactor (RBC) (회전속도와 수리학적 체류시간이 회전원판식(Rotating Biological Contactor;RBC) 여과조의 암모니아 제거에 미치는 영향)

  • 오승용;조재윤;김종만
    • Journal of Aquaculture
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    • v.16 no.3
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    • pp.142-150
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    • 2003
  • Performance of a biological filter, the rotating biological contactor (RBC), is affected by rotational speed and hydraulic residence time (HRT). A RBC with a disc diameter of 62 cm, total surface area of 48.28 $m^2$, volume of 0.34 ㎥, and submergence ratio of 35.4% was tested for the combinations of five rotational speeds (1, 2, 3, 4 & 5 rpm) and three HRT (0.5, 1.0 & 2.0 hr) to find out the maximum removal efficiencies of total ammonia nitrogen (TAN) and nitrite nitrogen of a simulated recirculating aquaculture system. Ammonia loading rate in the system was 25 g of TAN/ ㎥. day. Removal efficiencies were checked when TAN concentrations in the system stabilized for 3 days in each treatment. The concentration of TAN in the system decreased with increasing rotational speed of the RBC up to 4 rpm in all HRT (P<0.05). At the rotational speed of 5 rpm, the efficiencies decreased in all HRT (P<0.05). When the rotational speeds were 1, 2, 3, 4, and 5 rpm, TAN concentrations in the system were 1.35, 0.94, 0.69, 0.66, and 0.76 mg/L at the 0.5 hr HRT, 2.86, 1.18, 0.96, 0.87, and 1.11 mg/L at the 1.0 hr HRT, and 5.30, 2.44, 1.99, 1.77, and 2.01 mg/L at the 2.0 hr HRT, respectively. The TAN removal efficiencies of the RBC at the rotational speeds of 1, 2, 3, 4, and 5 rpm were 32.9, 49.5, 65.1, 72.9, and 62.9% in 0.5 hr HRT,33.1, 74.1, 87.1, 95.8, and 78.5% in 1.0 hr HRT, and 35.5, 76.7, 89.6, 97.0, and 85.5% in 2.0 hr HRT, respectively. TAN removal efficiency of RBC per pass increased with increasing HRT. However, TAN concentration in the system also increased. The best operating condition among the treatments was obtained at the treatment of 0.5 hr HRT and 4 rpm (P<0.05). The TAN concentration was 0.66 mg/L. Concentrations of nitrite nitrogen (NO$_2$$^{[-10]}$ -N) in the system decreased with increasing rotational speed in all HRT while that in the system increased with increasing HRT in all rotational speeds. The ranges of NO$_2$$^{[-10]}$ -N concentrations at HRT of 0.5, 1.0, and 2.0 hr in the system were 0.26~0.32, 0.31~0.56, and 0.43~l.45 mg/L, respectively. The ranges of daily removal rates of TAN in this system were 20.03~23.0 g TAN/㎥ㆍday and those of nitrite nitrogen were 19.65~30.25 g NO$_2$$^{[-10]}$ -N/㎥ㆍday.

Wastewater Utilization: A Place for Managed Wetlands - Review -

  • Humenik, F.J.;Szogi, A.A.;Hunt, P.G.;Broome, S.;Rice, M.
    • Asian-Australasian Journal of Animal Sciences
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    • v.12 no.4
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    • pp.629-632
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    • 1999
  • Constructed wetlands are being used for the removal of nutrients from livestock wastewater. However, natural vegetation typically used in constructed wetlands does not have marketable value. As an alternative, agronomic plants grown under flooded or saturated soil conditions that promote denitrification can be used. Studies on constructed wetlands for swine wastewater were conducted in wetland cells that contained either natural wetland plants or a combination of soybeans and rice for two years with the objective of maximum nitrogen reduction to minimize the amount of land required for terminal treatment. Three systems, of two 3.6 by 33.5 m wetland cells connected in series were used; two systems each contained a different combination of emergent wetland vegetation: rush/bulrush (system 1) and bur-reed/cattail (system 2). The third system contained soybean (Glycine max) in saturated-soil-culture (SSC) in the first cell, and flooded rice (Oryza sativa) in the second cell. Nitrogen (N) loading rates of 3 and $10kg\;ha^{-1}\;day^{-1}$ were used in the first and second years, respectively. These loading rates were obtained by mixing swine lagoon liquid with fresh water before it was applied to the wetland. The nutrient removal efficiency was similar in the rush/bulrush, bur-reed/cattails and agronomic plant systems. Mean mass removal of N was 94 % at the loading rate of $3kg\;N\;ha^{-1}\;day^{-1}$ and decreased to 71% at the higher rate of $10kg\;N\;ha^{-1}\;day^{-1}$. The two years means for above-ground dry matter production for rush/bulrushes and bur-reed/cattails was l2 and $33Mg\;ha^{-1}$, respectively. Flooded rice yield was $4.5Mg\;ha^{-1}$ and soybean grown in saturation culture yielded $2.8Mg\;ha^{-1}$. Additionally, the performance of seven soybean cultivars using SSC in constructed wetlands with swine wastewater as the water source was evaluated for two years, The cultivar Young had the highest yield with 4.0 and $2.8Mg\;ha^{-1}$ in each year, This indicated that production of acceptable soybean yields in constructed wetlands seems feasible with SSC using swine lagoon liquid. Two microcosms studies were established to further investigate the management of constructed wetlands. In the first microcosm experiment, the effects of swine lagoon liquid on the growth of wetland plants at half (about 175 mg/l ammonia) and full strength (about 350 mg/l ammonia) was investigated. It was concluded that wetland plants can grow well in at least half strength lagoon liquid. In the second microcosm experiment, sequencing nitrification-wetland treatments was studied. When nitrified lagoon liquid was added in batch applications ($48kg\;N\;ha^{-1}\;day^{-1}$) to wetland microcosms the nitrogen removal rate was four to five times higher than when non-nitrified lagoon liquid was added. Wetland microcosms with plants were more effective than those with bare soil. These results suggest that vegetated wetlands with nitrification pretreatment are viable treatment systems for removal of large quantities of nitrogen from swine lagoon liquid.

The Ammonia Removal Capacity of a Few Kinds of Filter Media in a Water Reuse quaculture System (순환 여과식 양식 시설에 이용될 수종의 여과 재료의 효능에 관한 연구)

  • KIM In-Bae;KIM Pyong-Kih;CHEE Young-Ok
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.20 no.6
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    • pp.561-567
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    • 1987
  • The purpose of this study was to find out the removal capacity of harmful ammonia by different filter media in the submerged biological filters in a given space of chamber. Four materials, pile cloth, corrugated skylight roofing plate, embossed plastic plate, and gravel, were used as the experimental filter media. Each filter medium was placed in two aquariums, each aquarium measuring $90cm\times60cm\times60cm\;(depth)$. Under the normal operating condition, the average of mean ammonia removal rates during the first and second functioning periods by each filter material which occupied tile space in the filter chamber (aquarium) was as follows: 1. Pile cloth: $8.381\;g{\cdot}m^{-3}.\;day^{-1}$ 2. Corrugated skylight roofing plate: $7.834\;g{\cdot}m^{-3}.\;day^{-1}$ 3. Embossed plastic plate: $7.797\;g{\cdot}m^{-3}.\;day^{-1}$ 4. Gravel: $7.051\;g{\cdot}m^{-3}.\;day^{-1}$ Thus, there were no significant differences between the media, but at the time of practical application of these materials, some other factors such as investment cost, easiness for the removal of excess detritus accumulated in tile interstices of filter media, etc. should be fallen into consideration. When large units are required, in particular, removal of excess detritus from tile gravel bed is extremely difficult, and in case of pile cloth filters the installation work is much complicated and a problem in supporting the structure when drained also exists. In these respects, corrugated skylight roofing plate and embossed plastic plate seem to be more optimal, but again in practice the local situation for the availability and the price of the materials should be rechecked and the fitness of tile materials in the particular filter chambers under use or under consideration for construction must be taken into account.

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Effects of Operational Condition on N2O Production from Biological Nitrogen Removal Process (생물학적 질소제거시 운전조건의 변화가 N2O 발생에 미치는 영향)

  • Jang, Hyun-Sup;Kim, Tae-Hyeong;Lee, Myoung-Joo;Hwang, Sun-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.23 no.5
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    • pp.547-555
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    • 2009
  • The objectives of this research were focused on the effects of various operating parameters on nitrous oxide emission such as C/N ratio, ammonia concentration and HRT in the hybrid and suspension reactors. With the decreasing of C/N ratios, $N_2O$ emission rates in the both processes were increased because organic carbon source for denitrification was depleted. In case of biofilm reactor operated using medium, $N_2O$ release from the nitrification was not affected by the variation of ammonia concentration. But in the suspension reactor, $N_2O$ production from the nitrification was rapidly increased with the increase of ammonia. Nitrite accumulation caused by undesirable nitrification conditions could be a important reason for the increase in the $N_2O$ production from the aerobic reactor. And rapid increase in $N_2O$ production was reflected by the decrease of HRT, similar to the results observed in the results of ammonia loading changes. So it could be said that it is very important to put in consideration both its optimum conditions for wastewater treatment efficiency and suitable conditions for $N_2O$ diminish, simultaneously, in order to development an eco-friendly and advanced wastewater treatment, especially in BNR process.

A Continuous Process for Phosphorus Recovery from Swine Slurry with Forming Struvite (양돈액비에서 Struvite 형성으로 연속적 인의 회수기술)

  • Oh I.H.;Lee J.H.;Choi B.H.;Burns R.T.
    • Journal of Animal Environmental Science
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    • v.12 no.2
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    • pp.95-100
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    • 2006
  • This study was carried out to develop a continuous process for recovering phosphorus in swine slurry. Magnesium chloride ($MgCl_2$) was used in the test as a magnesium source and the pH was regulated by adding NaOH and aerating. The results showed that the recovery rate of soluble phosphorus (SP) has increased with the molar ratios increased. In case of pH regulated with NaOH, the recovery rates of SP with molar ratio of 1:1.5 were over 95% from both farms. The removal of ammonia-nitrogen was at levels of $4{\sim}9%$. With aeration treatment, the SP recovery rate was 66% and the removal rate of ammonia-nitrogen was 15%. The treatment of NaOH to increase pH showed better SP recovery efficiency than the aeation treatment. However, in case of ammonia-nitrogen removal, the treatment of aeration showed better results than the NaOH treatment.

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Recycling Water Treatment of Aquaculture by Using Trickling Filter Process (살수여상공법을 이용한 양어장 순환수처리)

  • KIM Jeong-Sook;LEE Byung-Hun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.29 no.2
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    • pp.230-237
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    • 1996
  • The objective of the present study is to evaluate organic removal efficiencies, nitrogen removal efficiencies, kinetic constant, sludge production rates, oxygen requirements, and optimum treatment renditions for recycling water treatment of aquaculture by using a trickling filter process. When the loading rates were $0.500\~0.082kg\;COD/m^3/day$ and $0.271\~0.044kg\;NH_4^+-N/m^3/day$, SCOD and ammonia removal efficiencies were $74.5\~84.0\%$ and $43.7\~61.8\%$, respectively. The maximum removal rate of ammonia was 119.5 mg/L/day. Observed cell yield coefficient in the trickling filter reactor was 0.572 kg VSS/kg $BOD_{rem}$. When the hydraulic loading rate was $6.712\~40.341m^3/m^2/day$, oxygen uptake rate was $1.33\~7.22\;mg\;O_2/L/hr$.

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Nitrification Efficiency of the Fluidized Sand Biofilter by TAN Leading Rates and Temperatures in the Simulated Seawater Aquaculture Condition (해수 조건에서 모래유동층 여과조의 TAN 부하량과 수온에 따른 질산화 효율)

  • Park, Jeong-Hwan
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.38 no.6
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    • pp.347-352
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    • 2005
  • These experiments investigated the conditioning pattern and the nitrification efficiency of a fluidized sand biofilter (FSB) for seawater application. The FSB fed artificial nutrient was fully conditioned within 22 weeks. The maximum nitrification efficiency of the FSB was achieved at a superficial water velocity (SWV) of 1.0 cm/sec. After fixing the superficial water velocity at 1.0 cm/sec, the nitrification rates of the FSB were assessed at 3 total ammonia nitrogen (TAN) loading rates (250, 500, 1,000 g TAN/$m^3$/day) and 3 water temperatures (12, 16, $20^{\circ}C$). The TAN concentration in the simulated culture tank ranged from 2.87 to 9.72 mg/L at TAN loading rate of 1,000 g TAN/$m^3$/day, while that ranged from 0.45 to 1.26 mg/L at TAN loading rate of 500 g TAN/$m^3$/day. The ranges of TAN concentration in the former were too high for aquatic organisms and those in the latter were acceptable. Therefore, the safe TAN loading rate for the FSB in seawater conditions was decided as 500 g TA/$m^3$/day. From these results, daily TAN removal rates (g TAN/$m^3$/day) of FSB under conditions of inlet TAN concentration (C, mg/L) and water temperature (T, $^{\circ}C$) were calculated by the following non-linear multi-regression equation: TAN removal rate: f(z)=-1,311.295+655.714LnT+225.775LnC ($r^2=0.962$).