• Title/Summary/Keyword: Ammonia gas

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Effects of Application of Rendered Carcass Residue on Greenhouse Gases and Pepper Growth (랜더링된 가축사체 잔류물 시용이 온실가스 및 고추 생육에 미치는 영향)

  • Jae-Hyuk Park;Dong-Wook Kim;Se-Won Kang;Ju-Sik Cho
    • Korean Journal of Environmental Agriculture
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    • v.42 no.4
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    • pp.457-464
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    • 2023
  • The rendering residue generated by rendering disposal, an eco-friendly livestock carcass disposal method, is a useful agricultural resource. Methods for recycling this are being actively researched, and this study investigated the impact of applying rendered residue directly to soil on crop productivity and the agricultural environment. The chemical properties of the rendering residue were examined. The pH, OM, T-N, T-P, CaO, K2O, and MgO content values were 5.47%, 59.8%, 9.22%, 2.96%, 2.16%, 0.51% and 0.10%, respectively. Treatment conditions were divided into control, inorganic fertilizer, and rendering residue, and rendering residue corresponding to 50, 100, and 200% nitrogen content was applied based on the amount of inorganic fertilizer nitrogen input. Greenhouse gases and ammonia were collected during the cultivation period. Rendering residue increased both the yield and growth of peppers and was effective in improving nutrients such as pH and OM of the soil after harvest. However, compared to inorganic fertilizer treatment, it increased emissions of nitrous oxide and methane as well as ammonia. It is judged that the direct agricultural use of rendering residue is difficult, and a utilization method is needed.

Denitrification of Anaerobic Sludge in Hybrid type Anaerobic Reactor(I): Acetate as Substrate (Hybrid type 반응조에서의 혐기성 슬러지의 탈질(I): 초산을 기질로 사용한 경우)

  • Shin, Hang-Sik;Kim, Ku-Yong;Lee, Chae-Young
    • Journal of Korean Society of Water and Wastewater
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    • v.13 no.4
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    • pp.35-44
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    • 1999
  • In this study, it was attempted to remove nitrate and carbon in a single-stage reactor using acetate as substrate. Hybrid type upflow sludge baffled filter reactor was adopted using anaerobic sludge. Sludge bed in the bottom of reactor was intended to remove carbon and nitrate by denitrification and methanogenesis. And floating media in the upper part of reactor were intended to remove remaining carbon which was not removed due to the inhibition of nitrogen oxide on methane producing bacteria. The reactor removed over 96% of COD and most of nitrate with volumetric loading rate of $4.0kgCOD/m^3{\cdot}day$, hydraulic retention time of 24hr, 4,000mgCOD/L, and $266mgNO_3-N/L$. Nitrate in anaerobic sludge was converted to nitrogen gas(denitrification) or ammonia (ammonification) according to pH of influent, COD removal efficiency was easily affected by the change of volumetric loading rates and nitrate concentration. And when influent pH was about 4.7, most nitrate changed to ammonia while when influent pH was about 6.8~7.0, most nitrate denitrified independent of $COD/NO_3-N$ ratio. Most granules were gray and a few were black. In gray-colored granule, black inner side was covered with gray substance and SEM illustrated Methanoccoci type microorganisms which were compact spherical shape. Anaerobic filter removed residual COD effectively which was left in sludge bed due to the inhibition of nitrogen oxide.

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A Study on the Corrosion According to Post-Forming Treatment of a Horizontal Side Wall Sprinkler Head Deflector (측벽형 스프링클러 헤드 디플렉터의 성헝후처리에 따른 부식특성에 관한 연구)

  • 민인홍;전동일;김형종;박종연
    • Fire Science and Engineering
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    • v.16 no.1
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    • pp.77-83
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    • 2002
  • The objective of this study is to propose a method to prevent the possible stress corrosion cracking of a horizontal side-wall sprinkler head deflector in the same atmosphere of ammonia gas as it regulated in the UL (Underwriters Laboratory). A corrosion test is carried out for three types of specimen according to post-forming treatment, one of which is annealing, another sand blasting and the other no treatment. The observation of the test specimens with a metal micro-scope says that the tensile residual stress is a major factor causing corrosion cracking, and that a proper heat treatment can remove or reduce the residial stress and prevent a crack from occurring even in a severe corrosive atmosphers.

By the GNC Solution, Removal Effect Offensive Odorous Compounds Generated from Food (GNC용액을 이용한 음식물 쓰레기처리장에서 발생되는 악취 규제물질 제거 효과에 관한 연구)

  • Hong, Jong-Soon;Kim, Jae-Woo
    • Journal of environmental and Sanitary engineering
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    • v.22 no.2
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    • pp.35-40
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    • 2007
  • It disposes positively in the air pollution damage which is serious, in order help period the place where it improves the quality of existence and life of the local residents. It removed the offensive odor regulation material and the technique it will be able to prevent to sleep it researched it did. After scattering the GNC solution which develops the offensive odor regulation material which occurs from the food and trash treatment plant which is located to the S from the H, company after scattering the GNC solution which it develops collection it did a control criminal record control kind air and it analyzed. In this study, we investigated the emission concentrations of offensive odorous compounds of hydrogen sulfide, methyl mercaptan, dimethyl sulfide and dimethyl disulfide, trimethylamine, formaldehyde, acetaldehyde, propionaldehyde, buthylaldehyde, iso-valeric aldehyde, n-valeric aldehyde, ammonia. The concentrations of odorous compounds are determined by gas chromatography, HPLC and uv-vis spectroscopy. Hydrogen sulfide, methyl mercaptan, dimethyl sulfide and dimethyl disulfide were not detected at any point examined.

Component Analysis and Determination of Bioactivity of Oriental Therapeutic Drug for Hepatitis B (간염 치료제인 민간제제의 성분 분석 및 생리 활성 검색)

  • 김승호;이종우;이현선;함경수
    • Microbiology and Biotechnology Letters
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    • v.20 no.6
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    • pp.699-703
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    • 1992
  • An oriental drug, named NP-S, traditionally used as a therapeutic agent for hepatitis B was characterized by separating into volatile and non-volatile fractions. The volatile fraction contained ammonia as determined by ammonia kit and eight peaks when it was analyzed by gas chromatography that are not identified yet. The elemental analysis showed that the non-volatile fraction contained 15.5% carbon, 4.8% hydrogen, 11% nitrogen, and 10% sulfur along with a few trace elements such as Cl, Si, Mg and Zn. NP-S contained 6.7% peptide, 0.3% free amino acids such as Lys, Pro, Arg, lie, Tyr, Phe, His, Thr and Ser and 0.1% inorganic phosphate. The drug showed antimicrobial activity against Salmonella typhimurium, StaPhylococcus aureus and Candida albieans and also had antioxidant activity when thiobarbituric acid reacting substances(TBARS) method was applied.

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Removal of Malodorous Gases from Swine Manure by a Polyurethane Biofilter Inoculated with Heterotrophic and Autotrophic Bacteria. (종속영양세균과 독립영양세균을 고정화한 Polyurethane Biofilter의 돈분뇨 악취제거)

  • 이연옥;조춘구;류희욱;조경숙
    • Microbiology and Biotechnology Letters
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    • v.30 no.1
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    • pp.91-97
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    • 2002
  • Removal of malodorous gases from swine manure by a polyurethane biofilter inoculated with heterotrophic and autotrophic bacteria was investigated. Ammonia, hydrogen sulfide and other gases could be efficiently treated at 3~3.6 second of empty bed retention time by the polyurethane biofilter. In the range of SV $200~l,200h^{-1}$ , the average removal efficiency of odor was about 89% when the odor unit of inlet gas was below 4100. Odor elimination capacity of the polyurethane biofilter was$ 1.8$\times$10^{5}$ $~5.0$\times$10^{7}$OUㆍm$^{-3}$$h^{-1}$ that were 84~90% of the inlet load. The critical loads of $NH_3$ and $H_2$S, which mean 97% removal with respect to the inlet loads, were 31 and $27 g.m^{-3}$$h^{-1}$ , respectively. The maximum elimination capacities of $NH_3$ and $H_2$S were 56 and $157 gㆍm^{-3}$ ㆍh$^{-1}$ , respectively. Although the removability for$ NH_3$ and $H_2$S was not influenced by $H_2$S$NH_3$ ratio (ppmv/ppmv), the $H_2$S removability was inhibited by high $H_2$S concentration more than 80 ppmv.

Decrease of the Hydrogen Sulfide($H_2S$) in the Produced Biogas by the Anaerobic Digestion (혐기성소화 시 발생되는 $H_2S$ 감소에 관한 연구)

  • Hong, Jong-Soon;Kim, Jae-Woo
    • Journal of environmental and Sanitary engineering
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    • v.24 no.4
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    • pp.80-89
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    • 2009
  • In the organic waste, food waste is the most difficult controls. In the study, food waste was treatmented to removal only the dockage. To decrease the hydrogen sulfide($H_2S$) in the produced biogas, iron chloride put in the anaerobic digester. Respectively treatment quantity of the food waste, content of the methane($CH_4S$) gas in the biogas, produced gases quantity, put in the quantity of the Iron chloride, pH, TS, Alkalinity, VFA, Ammonia. The results obtained from the experiment are as follows: 1. The produced biogases quantity/the treatment quantity of the food waste was $83.82{\sim}129.41m^3/ton$. 2. The content of the hydrogen sulfide($H_2S$) in the produced biogas is below of the 500ppm. The iron chloride put in the anaerobic digester. 200~300kg of the iron chloride put in the anaerobic digester at the steady-state. 400~850kg of the iron chloride put in the anaerobic digester at the unsteady-state. 3. Factor of the operator was the pH: 7.7~8.4, content of mathane: 55~65%. 4. TS(total solid) of the digestor sludge was 17~20%, Alkalinity was 38,500~41,750ppm, VFA(Volatile Fatty Acids) was 2,800~2,420ppm, Ammonia was 4,300~3,650ppm.

Synthesis and reactivity over molybdenum carbide crystallites

  • Choi, Jeong-Gil
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.2
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    • pp.74-79
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    • 2010
  • The synthesis and reactivities of molybdenum carbide crystallites were examined in this study. Especially, the effect of synthesis conditions were scrutinized on the preparation of molybdenum carbide crystallites. In order to perform this purpose, various characterization techniques such as BET surface area and oxygen uptake measurements were employed for the synthesized molybdenum carbide crystallites. First of all, the molybdenum carbide crystallites were synthesized using molybdenum oxide crystallites and methane gas or methane-hydrogen mixture. The experimental results showed that BET surface areas ranged from $7.4m^2/g$ to $31m^2/g$ and oxygen uptake values varied from $8.1{\mu}mol/g$ to $24.3{\mu}mol/g$. The Mo compounds were found to be active for ammonia decomposition reaction. Even though there are some molybdenum carbide crystallites that were exceeded by Pt/$Al_2O_3$ crystallite, the steady state reactivities for other molybdenum carbide crystallites were comparable to or even higher than that determined for the Pt/$Al_2O_3$ crystallite. These results implied that molybdenum carbide crystallites could be one of the promising crystallites that might be substitutes for Pt-like noble metal crystallites in the petroleum processes.

Piggery Slurry Composting Using Batch Operating Autothermal Thermophilic Aerobic Digestion System

  • Ahn, Hee K.;Choi, Hong L.
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.2
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    • pp.273-279
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    • 2006
  • The performance of an autothermal thermophilic aerobic digestion (ATAD) system was studied to determine if nitrogen loss, as ammonia, was affected by an exhaust gas condenser. The system was run with and without a condenser while treating $8m^3$ of piggery slurry for 8 days. The system with a condenser (SWC) maintained the reactor temperatures above $40^{\circ}C$ for 2 days during the 8 days run, while the system without a condenser (SWOC) remained above $40^{\circ}C$ for 6 days. The SWC maintained the reactor temperatures mostly at mesophilic conditions while the SWOC at thermophilc conditions. Differences in operation conditions for the two runs were mainly caused by differences in atmospheric temperatures. Soluble chemical oxygen demand (SCOD) and volatile solids (VS) removal efficiencies of the SWC (SCOD: 62%, VS: 41%) were higher than those of the SWOC (SCOD: 40%, VS: 20%). The total Kjeldal nitrogen (TKN) removal efficiency of the SWC (7%) was less than that of the SWOC (25%). The concentration of total volatile fatty acids (VFA) in the SWC was observed to be lower than the threshold value of 0.23 g total VFA/L after 6 days, while the SWOC progressed below the threshold value after 3 days. No offensive odor emissions were observed in either run, which suggest that the use of the ATAD system may be a good odor removal strategy.

Simple Measurement of Livestock Foul Smells by Gas Detector Tube (검지관을 이용한 축산 악취 간이 측정방법 연구)

  • Jung, Jae-Chil;Ahn, Min-Ho;Jeong, Jong-Won;Choi, Hee-Seon;Kim, Tai-Jin
    • KSBB Journal
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    • v.24 no.5
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    • pp.420-424
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    • 2009
  • The present study was aimed for the fetor in the livestock facilities. Simple detection systems for ammonia and hydrogen sulfide were examined to see the mechanism making the discoloration length of malodorous substance concentration. Detector tube for ammonia showed a good linearity of 99.6% while hydrogen sulfide detector tube gave 99.7% linearity with reproductivity of 95%.