• Title/Summary/Keyword: Ammonia emission

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Composting Chemical Treated Hog Wastewater Excess Sludge Amended with Sawdust and Compost Biofiltration (화학적처리 양돈폐수 잉여오니와 톱밥 혼합물 퇴비화 및 퇴비탈취처리)

  • Hong Ji-Hyung;Park Keum-Joo
    • Journal of Animal Environmental Science
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    • v.12 no.1
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    • pp.29-34
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    • 2006
  • The effects of turning frequency were examined on the efficiency of composting lime treated excess sludge amended with sawdust from the activated sludge process after a liquid/solids separation process. The raw and excess sludge from the activated sludge process associated with the hog wastewater treatment system is a significant problem and composting is an effective method far reducing the pollution potential of hog wastewater sludge. The coagulant used sludge composting and ammonia emissions from composting are not well established. The effect of compost properties such as high total carbon, C/N ratio and pH value on performance of composting sludge and biofiltration of ammonia from composting process were investigated. The ammonia emission was not significantly increased during composting. The ammonia concentrations of the exhaust air of composter were ranged from 0.5 and 7 ppm about 12 days after composting. The performance of the hog wastewater sludge composting was the most sensitive to chemical treated sludge properties such as high total carbon and high C/N ratio of the initial compost mixes. Temperature in compost and ammonia emission were not greatly affected by the turning frequency.

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Comparison of spray characteristics for ammonia, ethanol, n-decane by using numerical simulation (시뮬레이션을 이용한 암모니아, 에탄올, 노말데케인 분무 특성 비교)

  • Lee, Jaejin;Yeom, Eunseop
    • Journal of the Korean Society of Visualization
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    • v.20 no.2
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    • pp.38-44
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    • 2022
  • Due to increasingly strict emission regulations for carbon-based fuels in the shipping industry, there is a significant motivation to investigate the alternative fuel. Ammonia is one of the attractive alternative fuels as a carbon-free fuel. Since ammonia has different properties such as high vapor pressure and low boiling point compared to conventional fuels, further research into ammonia spray behavior is important. In this work, the spray characteristics of ammonia and other fluids (ethanol, n-decane) were compared by using numerical simulation. The results show that the spray characteristics of ammonia differs from those of the others due to the occurrence of flash boiling. The narrow-dispersed spray with accelerated velocity at the center have been observed for ammonia. It is also found that droplets of ammonia achieve smaller diameter with more uniform distribution, leading to better atomization behavior compared to the others.

Potential to mitigate ammonia emission from slurry by increasing dietary fermentable fiber through inclusion of tropical byproducts in practical diets for growing pigs

  • Nguyen, Quan Hai;Le, Phung Dinh;Chim, Channy;Le, Ngoan Duc;Fievez, Veerle
    • Asian-Australasian Journal of Animal Sciences
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    • v.32 no.4
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    • pp.574-584
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    • 2019
  • Objective: Research was conducted to test the effect of including fiber-rich feedstuffs in practical pig diets on nutrient digestibility, nitrogen balance and ammonia emissions from slurry. Methods: Three Vietnamese fiber sources were screened, namely cassava leaf meal (CL), cassava root residue (CR), and tofu by-product (TF). Accordingly, a control diet (Con) with 10% of dietary non-starch polysaccharides (NSP) and three test diets including one of the three fiber-rich feedstuffs to reach 15% of NSP were formulated. All formulated diets had the same level of crude protein (CP), in vitro ileal protein digestible and metabolisable energy, whereas the in vitro hindgut volatile fatty acid (VFA) production of the test diets was 12% to 20% higher than the control diet. Forty growing barrows with initial body weight at $28.6{\pm}1.93kg$ ($mean{\pm}standard$ deviation) were allocated to the four treatments. When pigs reached about 50 kg of body weight, four pigs from each treatment were used for a nitrogen balance trial and ammonia emission assessment, the remaining six pigs continued the second period of the feeding trial. Results: The TF treatment increased fecal VFA by 33% as compared with the control treatment (p = 0.07), suggesting stimulation of the hindgut fermentation. However, urinary N was not significantly reduced or shifted to fecal N, nor was slurry pH decreased. Accordingly, ammonia emissions were not mitigated. CR and CL treatments failed to enhance in vivo hindgut fermentation, as assessed by fecal VFA and purine bases. On the contrary, the reduction of CP digestibility in the CL treatment enhanced ammonia emissions from slurry. Conclusion: Dietary inclusion of cassava and tofu byproducts through an increase of dietary NSP from 10% to 15% might stimulate fecal VFA excretion but this does not guarantee a reduction in ammonia emissions from slurry, while its interaction with protein digestibility even might enhance enhanced ammonia emission.

Study on the Emission Characteristics of Air Pollutants from Agricultural Area (농업지역(밭) 암모니아 등 대기오염물질 계절별 모니터링 연구)

  • Kim, Min-Wook;Kim, Jin-Ho;Kim, Kyeong-Sik;Hong, Sung-Chang
    • Korean Journal of Environmental Agriculture
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    • v.40 no.3
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    • pp.211-218
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    • 2021
  • BACKGROUND: Fine particulate matter (PM2.5) is produced by chemical reactions between various precursors. PM2.5 has been found to create greater human risk than particulate matter (PM10), with diameters that are generally 10 micrometers and smaller. Ammonia (NH3) and nitrogen oxides (NOx) are the sources of secondary generation of PM2.5. These substances generate PM2.5 through some chemical reactions in the atmosphere. Through chemical reactions in the atmosphere, NH3 generates PM2.5. It is the causative agent of PM2.5. In 2017 the annual ammonia emission recorded from the agricultural sector was 244,335 tons, which accounted for about 79.3% of the total ammonia emission in Korea in that year. To address this issue, the agricultural sector announced the inclusion of reducing fine particulate matter and ammonia emissions by 30% in its targets for the year 2022. This may be achieved through analyses of its emission characteristics by monitoring the PM2.5 and NH3. METHODS AND RESULTS: In this study, the PM2.5 concentration was measured real-time (every 1 hour) by using beta radiation from the particle dust measuring device (Spirant BAM). NH3 concentration was analyzed real-time by Cavity Ring-Down Spectroscopy (CRDS). The concentrations of ozone (O3) and nitrogen dioxide (NO2) were continuously measured and analyzed for the masses collected on filter papers by ultraviolet photometry and chemiluminescence. CONCLUSION: This study established air pollutant monitoring system in agricultural areas to analyze the NH3 emission characteristics. The amount of PM2.5 and NH3 emission in agriculture was measured. Scientific evidence in agricultural areas was obtained by identifying the emission concentration and characteristics per season (monthly) and per hour.

Reduction of Odor Emission from Swine Excreta using Silver Nano Colloid (은 나노 콜로이드를 이용한 돼지분뇨의 악취 저감 효과)

  • Kim, Koo-Pil;Choi, Young-Soo;Oh, Kwang-Hyun;Koo, Kyung-Bon;Suh, Sang-Ryong;Yoo, Soo-Nam;Lee, Kyeong-Hwan
    • Journal of Biosystems Engineering
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    • v.36 no.5
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    • pp.342-347
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    • 2011
  • The effect of SNC(silver nano colloid) on the emission reduction of odors such as ammonia ($NH_3$), hydrogen sulfide ($H_2S$), and methane ($CH_4$) from swine excreta was studied. Silver has been used as an universal antibiotic substance and can reduce the emission of some gases by sterilizing action. Therefore, an apparatus which produces SNC was developed and was conducted its performance test. Also, the SNC made by the apparatus was applied to swine excreta sampled from a piggery in oder to find the effect on the reduction of odor emission. An electrolysis apparatus was developed to produce SNC and its capacity was 0.024 ppm/$hr{\cdot}L$. The effects of SNC on the reduction of odor emission from swine excreta were tested for bad smell gases of ammonia ($NH_3$), hydrogen sulfide ($H_2S$) and methane ($CH_4$). For ammonia gas, factorial experiments were conducted to find the effects of concentration and application rate of SNC. The test results for the different concentrations of 20 ppm, 50 ppm, and 100 ppm showed that the more concentration of SNC was increased, the more emission reduction of ammonia gas increased. From the test results about the effect of application rate, the more SNC was applied, the more emission reduction of $NH_3$ increased. In order to reduce the concentration of $NH_3$ below 5 ppm, SNC of 50 ppm is recommended to be applied at an interval of 6 hours, and is mixed with swine excreta in the volumetric ratio of 4:1. For hydrogen sulfide gas, the concentration was decreased as time went by and was reduced rapidly in the first stage of the tests for all applied concentrations of SNC (20 ppm, 50 ppm, and 100 ppm). Especially, when 100 ml of SNC with 100 ppm was applied, emission of hydrogen sulfide gas was reduced rapidly during early 4 hours after the application of SNC. And, concentration of hydrogen sulfide gas was maintained below 20 ppm after 12 hours. For methane gas, t-test showed that there was no significance on the effect of its application for all applied concentrations of SNC. Therefore, it was concluded that the application of SNC on swine excreta had no effect on the emission reduction of $CH_4$.

A Study on Ammonia Reforming Catalyst and Reactor Design for 10 kW Class Ammonia-Hydrogen Dual-Fuel Engine (10 kW 급 암모니아-수소 혼소엔진을 위한 암모니아 개질 촉매 및 반응기 설계에 관한 연구)

  • LEE, SANGHO;CHOI, YOUNG;PARK, CHEOLWOONG;KIM, HONGSUK;LEE, YOUNG DUK;KIM, YOUNG SANG
    • Transactions of the Korean hydrogen and new energy society
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    • v.31 no.4
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    • pp.372-379
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    • 2020
  • Ammonia-hydrogen dual-fuel engine is a way to reduce greenhouse gas emission because ammonia and hydrogen are carbon-free fuels. In ammonia-hydrogen dual-fuel engine, hydrogen is supplied to improve the combustion characteristic of ammonia. In this study, an ammonia reformer was developed to supply hydrogen for 10 kW class ammonia-hydrogen dual-fuel engine. Thermodynamic characteristic and catalyst were investigated for ammonia reforming. Heat transfer was important for high ammonia conversion of ammonia reformer. 99% of ammonia conversion was obtained when 10 LPM of ammonia and 610℃ of hot gas were supplied to the ammonia reformer.

Ammonification and NH3 emission in the Soil Amended with Different Animal Manures

  • Wang, Xin-Lei;Zhang, Qian;Park, Sang-Hyun;Lee, Bok-Rye;Kim, Tae-Hwan
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.37 no.1
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    • pp.56-60
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    • 2017
  • Mineralization is an important biological process for conversion of organic nitrogen (N) to inorganic N which can be used by plants directly. To investigate the effect of different manures on soil mineralization, the soil amended with cattle (CtM), goat (GM), chicken manure (ChM) and pig slurry (PS) were incubated under in vitro condition and ammonium N ($NH_4{^+}-N$), ammonification rate and ammonia emission were determined for eighty-four days. $NH_4{^+}-N$ was the highest in PS-amended soil for the whole experimental period. $NH_4{^+}-N$ in PS-amended soil was gradually decreased until day 84, whereas it was rapidly decreased for the first 14 days and then slightly increased until 84 days in ChM-, CtM- and GM-amended soil. The ammonification rate showed negative value for the first 14 days in all treatments. From day 14, ammonification rate started to increase in CtM- and ChM-amended soil, whereas it was maintained in GM- and PS-amended soil until day 84. The daily ammonia emission was the highest in PS-amended soil ($41mg\;kg^{-1}d^{-1}$), followed by CtM-, ChM-, and GM-amended soil at day 1. It was gradually decreased until day 84 in all treatments. The total $NH_3$ emission was the highest in PS-amended soil with $0.6mg\;kg^{-1}$ for 84 days, while less than $0.1mg\;kg^{-1}$ in three other plots. These results indicate that different manures showed different soil ammonification rate and $NH_3$ emission.

Effects of Charcoal Application on Ammonia Emission and Nitrogen Use Efficiency of Pig Slurry in the Vegetative Growth of Maize (Zea Mays L.)

  • Lee, Seung Bin;Park, Sang Hyun;Kim, Tae Hwan
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.41 no.4
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    • pp.280-286
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    • 2021
  • The objective of this study was to prove the effect of pig slurry application with charcoal on nitrogen use efficiency (NUE), feed value and ammonia (NH3) emission from maize forage. The four treatments were applied: 1) non-pig slurry (only water as a control), 2) only pig slurry application (PS), 3) pig slurry application with large particle charcoal (LC), 4) pig slurry application with small particle charcoal (SC). The pig slurry was applied at a rate of 150 kg N ha-1, and the charcoal was applied at a rate of 300 kg ha-1 regardless of the size. To determine the feed value of maize, crude protein, dry matter intake, digestible dry matter, total digestible nutrient, and relative feed value were investigated. All feed value was increased by charcoal treatment compared to water and PS treatment. Also, the NUE for plant N was significantly higher in charcoal treatments (LC and SC) compared to PS treatment. On the other hand, there is no significant difference for feed value and NUE between LC and SC. The NH3 emission was significantly reduced 15.2% and 27.9% by LC and SC, respectively, compared to PS. Especially, SC significantly decreased NH3 emission by 15% compared to LC. The present study clearly showed that charcoal application exhibited positive potential in nitrogen use efficiency, feed value and reducing N losses through NH3 emission.

PRELIMINARY STUDY ON COMPOSTING OF THE CATTLE MANURE AND RICE HULLS MIXTURES BY NEGATIVE AERATION

  • Park, K. J.;J. H. Hong;Park, M. H.;Park, W. C.
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2000.11c
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    • pp.777-783
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    • 2000
  • Composting by negative aeration is a reasonable proposition to control odor generated during composting process. Cattle manure and rice hulls mixtures were composted in a bin composting system by negative aeration. Continuous(CA) and intermittent(IA) aeration methods were applied to analyze the composting characteristics. The composting temperature and the ammonia emission during composting were investigated according to the aeration methods. The main problem for the negative aeration was the generation of condensate in the suction line of blower. The quantity of condensate was significant for continuous aeration. The aeration method should be modified to escape from the cooling effect of continuous aeration at the initial stage of composting. It took a longer time to finish a composting for intermittent aeration on account of lower aeration. It was concluded that the composting by negative aeration could be accomplished by either continuous or intermittent aeration method if the flow rate would be controlled more efficiently and the water vapor in suction line of blower could be removed effectively. Ammonia emission increased up to maximum value of 675ppm for continuous aeration while 300ppm for intermittent aeration. However, the cumulative value of ammonia emission was larger for intermittent aeration than for continuous aeration.

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Effects of Dietary Supplementation of Lactobacillus reuteri on Performance of Swine, Fecal and Rectumal Microflora and Carcass Grade (유산균(L. reuteri)의 첨가가 돼지의 생산성, 분과 결장내 미생물균총 및 육등급에 미치는 영향)

  • Son, Jang-Ho;Kim, Sang-Ho
    • Korean Journal of Organic Agriculture
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    • v.13 no.2
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    • pp.185-195
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    • 2005
  • Two hundred [(Duroc${\times}$Yorkshire)${\times}$Landrace] pigs were used in a 117-d growth assay (including four growth stages) to determine the effects of dietary supplementation of Lactobacillus reuteri on performance of swine, fecal and rectumal microflora and carcass grade. Pig diet was divided tow types, commercial diet (Control group) and supplemention of 0.1% Lactobacillus reuteri (Treatmental group). There was tend to increased in average daily gain (ADG) and feed efficiency (Feed/gain) in treatmental group than control group during the whole experimental period. The number of Lactobacilius spp. into rectum and feaces and carcass rate tended to increase in treatmental group than control group. Ammonia emission from excreta were decrease by supplemention of 0.1% Lactobacillus reuteri in feed (P<0.05). These results indicated that the dietary Lactobacillus reuteri were effective in performance, increasing of Lactobacilius spp. into rectum and feaces, decreasing ammonia emission from excreta, and it had also effective the carcass rate in swine.

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