• Title/Summary/Keyword: Ammonia decomposition

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Decomposition of Rice Straw in Paddy Soil as Affected by Application of Liquid Pig Manure (논토양에서 가축분뇨 액비시용이 볏짚 분해에 미치는 영향)

  • Lee, Sang-Bok;Kim, Jong-Gu;Lee, Kyeong-Bo;Lee, Deog-Bae;Kim, Jae-Duk
    • Korean Journal of Soil Science and Fertilizer
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    • v.37 no.2
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    • pp.104-108
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    • 2004
  • This study was conducted to investigate the decomposition rates of rice straw in paddy soil with application of liquid pig manure (LPM). Decomposition rate of rice straw was dramatically increased to 52.3% for 60days after LPM application, the rate was higher in soils of tillage than in soils of no-tillage with higher levels of LPM application. C/N ratio in the tice straw was decreased in soils of tillage with higher levels of LPM application. Contents of $NH_4-N$ and $NO_3-N$ in paddy soils were increased with tillage and higher levels of LPM application. The number of cellulose decomposer, and ammonia-oxidizing and denitrifying bacteria in paddy soils at 90 days after LPM application were more than $1.4{\times}10^5$, $2.6{\times}10^2$ and $1.4{\times}10^2cfu\;g^{-1}$ dry soil, respectively, the numbers were higher in soils of tillage with higher levels of LPM application, Soil tillage after LPM application could enhance the decomposition of rice straw in paddy soil.

Anaerobic Biotreatment of Animal Manure - A review of current knowledge and direction for future research -

  • Hong, Jihyung
    • Journal of Animal Environmental Science
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    • v.11 no.2
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    • pp.97-102
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    • 2005
  • Anaerobic decomposition is one of the most common processes in nature and has been extensively used in waste and wastewater treatment for several centuries. New applications and system modifications continue to be adapted making the process either more effective, less expensive, or suited to the particular waste in question and the operation to which it is to be applied. Animal manure is a highly biodegradable organic material and will naturally undergo anaerobic fermentation, resulting in release of noxious odors, such as in manure storage pits. Depending on the presence or absence of oxygen in the manure, biological treatment process may be either aerobic or anaerobic. Under anaerobic conditions, bacteria carry on fermentative metabolisms to break down the complex organic substances into simpler organic acids and then convert them to ultimately formed methane and carbon dioxide. Anaerobic biological systems for animal manure treatment include anaerobic lagoons and anaerobic digesters. Methane and carbon dioxide are the principal end products of controlled anaerobic digestion. These two gases are collectively called biogas. The biogas contains $60\~70\%$ methane and can be used directly as a fuel for heating or electrical power generation. Trace amounts of ammonia and hydrogen sulfide ($100\~300\;ppm$) are always present in the biogas stream. Anaerobic lagoons have found widespread application in the treatment of animal manure because of their low initial costs, ease of operation and convenience of loading by gravity flow from the animal buildings. The main disadvantage is the release of odors from the open surfaces of the lagoons, especially during the spring warm-up or if the lagoons are overloaded. However, if the lagoons are covered and gases are collected, the odor problems can be solved and the methane collected can be used as a fuel. Anaerobic digesters are air-tight, enclosed vessels and are used to digest manure in a well-controlled environment, thus resulting in higher digestion rates and smaller space requirements than anaerobic lagoons. Anaerobic digesters are usually heated and mixed to maximize treatment efficiency and biogas production. The objective of this work was to review a current anaerobic biological treatment of animal manure for effective new technologies in the future.

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Experimental Study on Characteristics of Ammonia Conversion Rate of Urea Aqueous Solution in 250℃ Exhaust Pipe (250℃ 이하 배기관에서 우레아 수용액의 암모니아 전환율 특성에 관한 실험적 연구)

  • Ku, Kun Woo;Park, Hong Min;Hong, Jung Goo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.2
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    • pp.177-182
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    • 2015
  • The NOx emissions from diesel engines and industrial boilers are a major cause of environmental pollution. The selective catalytic reduction of urea is an aftertreatment technology that is widely used for the reduction of NOx emissions. The objective of this study was to investigate the characteristics of the thermal decomposition of a urea aqueous solution using laboratory-scale experimental equipment under conditions similar to those of marine diesel engines. A 40 wt. urea aqueous solution was used in this study. It was found that the total conversion rate varied with the inflow gas conditions and flow rates of the urea aqueous solution. In addition, there were conversion rate differences between NH3 and HNCO. At inflow gas temperature conditions of $210^{\circ}C$ and $250^{\circ}C$, the $NH_3$ conversion rate was found to be higher than that of the HNCO, depending on the residence time.

A Basic Study on Physical Method for Preventing Recombination of Gas Product from the Decomposition of Ammonium Carbamate (암모니움 카바메이트 분해 시 생성된 가스의 재결합 방지를 위한 물리적 방법의 기초연구)

  • Chun, Minwoo;Yoon, Cheon Seog;Kim, Hongsuk
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.10
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    • pp.639-647
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    • 2017
  • This basic study is focused on the physically removal method of carbon dioxide from the decomposition of ammonium carbarmate to prevent the recombination of ammonium salts. A basic visual experimental set-up was designed and constructed to observe the recombination phenomena from the proper composition of ammonia gas, carbon dioxide gas, and compressed air dilution gas. To quantify the recombination phenomena, a simple device was designed to measure the weight change under severe cases for three different tube sizes. The temperature and pressure in the visual tube and the volumetric flow rates of the nitrogen dilution gas were studied and the conditions to avoid recombination were analyzed according to mean free path theory. Diffusivity values based on the Chapman-Enskog theory were calculated from the experimental data. These value may serve as an index for the prevention of recombination.

The effect of dead coral skeletons on the water quality and sessile mollusks in the closed system (폐쇄시스템 내에서 죽은 산호골격이 수질과 고착성 연체동물에 미치는 영향)

  • Lee, Nam Hyeon;Han, Kyung Nam
    • The Korean Journal of Malacology
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    • v.28 no.3
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    • pp.187-196
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    • 2012
  • Recently, for the purpose of constructing artificial ecosystem, the public aquarium and experimental mesocosm systems are receiving attention. To design and establish an aquarium and mesocosm system, there is need of several materials for simulating the environment, such as sediments, rocks, and plants. Expecially for sessile mollusks, there must be proper materials to which sessile invertebrates can adhere. Nowadays, many aquariums and mesocosm systems are using dead coral skeletons for sessile mollusks. This study was proceeded to have data on the effect of dead coral skeletons on water qualities with the experiment on the environmental factors. For this purpose, I made glass tank for experiment, chose two types of dead coral skeletons imported from the Indonesia and observed the change of water qualities and decomposition efficiency of TAN (total ammonia-nitrogen), nitrite ($NO_2{^-}$) and nitrate ($NO_3{^-}$). As a result, the lager the surface area was, the more TAN, nitrite and nitrate decomposition rate increased. In addition, coral skeletons covered with crustose algae and bacteria in the tank showed faster TAN, nitrite and nitrate removal rate and stabilization. Accordingly, this experiment suggested that dead coral skeletons could be used as a sub filter for the closed system as well as an adhering plate.

Synthesis of Nano Structured Silica and Carbon Materials and Their Application (계면활성제를 이용한 나노 실리카 및 카본 소재의 합성과 응용)

  • Park Seungkyu;Kim Jongyun;Cho Wangoo
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.30 no.3 s.47
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    • pp.321-328
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    • 2004
  • Nano silica ball and nano carbon ball are developed commercially by template synthesis method. Adsorption of unpleasant smelling substances such as ammonia, trimethylamine, acetaldehyde and methyl mercaptane onto nano carbon ball with hollow macroporous core/mesoporous shell structures, nano carbon ball, was investigated and compared with that onto odor adsorbent materials, activated carbon, commercially available. The adsorption and decomposition of malodor at nano carbon ball exhibited superior than those onto activated carbon. The physicochemical properties such as mesopore size distributions, large nitrogen BET specific surface area and large pore volume and decomposition of malodor were studied to interpret the predominant adsorption performance. The nano carbon ball is expected to be useful in many applications such as deodorizers, adsorbent of pollutants.

The effect of soil addition to oil-cake on decaying of the oil-cake and its efficiency as a ferfilizer (토양(土壤)의 첨가(添加)가 유박(油粕)의 부숙(腐熟) 및 비효(肥效)에 미치는 영향에 관(關)하여)

  • Oh, Wang Keun;Cho, Byung Lyun;Lee, Ki Eui
    • Korean Journal of Soil Science and Fertilizer
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    • v.4 no.2
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    • pp.137-141
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    • 1971
  • In order to observe the effect of soil added to oil cake in the preparation of liquid fertilizer for flower culture use, a laboratory experiment was carried out, in addition to a pot experiment done with Petunia as an indicator plant. The results obtained are as follows; 1. Faster decaying, and heavier accumulation of ammonia was observed in the mixture of soil, oil cake and water than the mixture of only oil cake and water. At the same time, the former gave better effect on the growth of Petunia than the latter. It was considered that the early raise of pH in the mixture of soil, oil cake and water stimulated the decomposition of oil cake. 2. No pH raise and a small accumulation of ammonia even at the mixture of soil, oil coke and water was observed when temperature was low, around $12-25^{\circ}C$. However, the deficiency of ammonia in the mixture of soil, oil cake and water was large enough to result in the better growth of Petunia than in the mixture without soil.

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Biodegradation of Feather Waste Keratin by the Keratin-Degrading Strain Bacillus subtilis 8

  • He, Zhoufeng;Sun, Rong;Tang, Zizhong;Bu, Tongliang;Wu, Qi;Li, Chenlei;Chen, Hui
    • Journal of Microbiology and Biotechnology
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    • v.28 no.2
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    • pp.314-322
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    • 2018
  • Bacillus subtilis 8 is highly efficient at degrading feather keratin. We observed integrated feather degradation over the course of 48 h in basic culture medium while studying the entire process with scanning electron microscopy. Large amounts of ammonia, sulfite, and $\text\tiny{L}$-cysteic acid were detected in the fermented liquid. In addition, four enzymes (gamma-glutamyltranspeptidase, peptidase T, serine protease, and cystathionine gamma-synthase) were identified that play an important role in this degradation pathway, all of which were verified with molecular cloning and prokaryotic expression. To the best of our knowledge, this report is the first to demonstrate that cystathionine gamma-synthase secreted by B. subtilis 8 is involved in the decomposition of feather keratin. This study provides new data characterizing the molecular mechanism of feather degradation by bacteria, as well as potential guidance for future industrial utilization of waste keratin.

Combination of air stripping and biological processes for landfill leachate treatment

  • Smaoui, Yosr;Bouzid, Jalel;Sayadi, Sami
    • Environmental Engineering Research
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    • v.25 no.1
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    • pp.80-87
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    • 2020
  • Landfill waste decomposition generates a dark effluent named, leachate which is characterized by high organic matter content. To minimize these polluting effects, it becomes necessary to develop an effective landfill leachate treatment process. The objective of this study was to evaluate the performance of an innovative approach based on air stripping, anaerobic digestion (AD) and aerobic activated sludge treatment. A reduction of 80% of ammonia and an increase of carbon to nitrogen ratio to 25 were obtained, which is a suitable ratio for AD. This latter AD was performed in fixed bed reactor with progressive loading rate that reached 2 and 3.2 g COD/L/d for the raw and diluted leachate (1:2), respectively. The anaerobic treatment led to significant removal of chemical oxygen demand (COD) and biogas production, especially for the diluted leachate. The COD removal was of 78% for the raw leachate and a biogas production of 4 L/d with 70% methane content. The use of the diluted leachate led to 81% of COD removal and 7 L/d biogas with 75% methane content. It allowed a removal of 77% COD and more than 97% of the organic compounds present in the initial leachate sample.

Fabrication and Characterization of Y2Ti2O7 Powder and Thick Film by Chemical Processing (화학적 공정을 이용한 Y2Ti2O7 분말과 후막 제조 및 특성)

  • Lee, Won-Joon;Choi, Yeon-Bin;Bae, Dong-Sik
    • Korean Journal of Materials Research
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    • v.27 no.5
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    • pp.289-293
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    • 2017
  • $Y_2Ti_2O_7$ nanoparticles (0.3 mol%) have been successfully synthesized by the co-precipitation process. The samples, adjusted to pH7 with ammonia solution as catalyst and calcined at $700{\sim}900^{\circ}C$, exhibit very fine particles with close to spherical shape and average size of 10-30 nm. It was possible to control the size of the synthesized $Y_2Ti_2O_7$ particles by manipulating the conditions. The $Y_2Ti_2O_7$ nanoparticles were coated on a glass substrate by a dipping coating process with inorganic binder. The $Y_2Ti_2O_7$ solution coated on the glass substrate had excellent adhesion of 5B; pencil hardness test results indicated an excellent hardness of 6H. The thickness of the thick film was about $30{\mu}m$. Decomposition of MB on the $Y_2Ti_2O_7$ thin film shows that the photocatalytic properties were excellent.