• Journal of ILASS-Korea
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• v.24 no.2
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• pp.51-57
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• 2019

In this study, the spray atomization characteristics of urea injector used in SCR system for construction machinery was analyzed, and the uniformity index at the front of mixer and NOx conversion efficiency were evaluated through numerical analysis. Spray visualization and droplet size/velocity measurement were performed and the measured results were used to verify the spray analysis model to calculate the uniformity index in the exhaust gas after-treatment system. For the flow analysis, STAR-CCM, a three-dimensional CFD, was used and the uniformity index of the SCR system at the front of the mixer was calculated using the droplet dissociation model and the wall collision model. Finally, the DeNOx performance for the average condition of the NRTC driving mode was calculated to understand the NOx conversion efficiency reflecting the exhaust gas temperature. The simulation results show that the uniformity index at the front of mixer was calculated as 0.862 and DeNOx efficiency was 75.9%.

• Journal of Advanced Marine Engineering and Technology
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• v.36 no.8
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• pp.1030-1035
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• 2012

In this research, we analysed design and CFD analysis of an inflow radial turbine for OTEC with an output power of 8kW using an working fluid of ammonia. The inflow radial turbine consists of scroll casing, vain nozzle with 18 blade numbers and rotor blade with 13 blade numbers. Mass flow rate, and inlet temperature are 0.5kg/s and $25^{\circ}C$ respectively, and variable rotational speeds were applied between 12,000 and 36,000 with 3,000 rpm intervals. As the results according to the rotational speeds, the designed speed is 24,000 rpm where maximum efficiency exists. The maximum efficiency and output power are 88.66% and 8.52kW, respectively. Through this study, we expect that the analysed results will be used as the design material for the composition of the turbine optimal design parameters corresponding to the target output power under various working material conditions.

• 제어로봇시스템학회:학술대회논문집
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• 2003.10a
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• pp.2304-2308
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• 2003

Ocean thermal energy conversion (OTEC) is an effective method of power generation, which has a small impact on the environment and can be utilized semi-permanently. This paper describes a dynamic model for a pilot OTEC plant built by the Institute of Ocean Energy, Saga University, Japan. This plant is based on Uehara cycle, in which binary mixtures of ammonia and water is used as the working fluid. Some simulation results attained by this model and the analysis of the results are presented. The developed computer simulation can be used to actual practice effectively, such as stable control in a steady operation, optimal determination of the plant specifications for a higher thermal efficiency and evaluation of the economic prospects and off-line training for the operators of OTEC plant.

• Journal of Aquaculture
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• v.16 no.4
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• pp.203-209
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• 2003

Nitrification efficiency of fixed film biofilters with sand, loess bead, and styrofoam bead in biofilter columns of 1-m height and 30 cm width was studied. Synthetic wastewater was continuously supplied to the culture tank to maintain total ammonia nitrogen (TAN) concentration in the inflow water at around 8 mg/L. The hydraulic loading rate was set at 200 ㎥/$m^2$/day. TAN conversion was stabilized after about 90 day conditioning for all the selected filter media but with net accumulations of nitrite. On the volumetric basis, conversion rates of TAN and nitrite were the highest in styrofoam bead filter. Mean volumetric TAN conversion rates in the final samples were 682, 269, and 79 g TAN/㎥/day in the styrofoam bead, sand and loess bead filters, respectively. Low gravity and cost of styrofoam bead render the handling easier and more cost-effective.

• Journal of the Korea Organic Resources Recycling Association
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• v.29 no.4
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• pp.5-13
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• 2021

Ammonia, primarily originating from urinary urea of the livestock manure, is known to play as a major precursor of fine particulate matter (PM2.5) generation which leads to a decrease in air quality and to harmful effects on public health. The objective of this study was to evaluate the effect of acetohydroxamic acid (AHA) addition on inhibition of ammonia conversion from urea. The experiment was performed at different urea concentration (500-4,000 mg Urea-N/L), AHA concentration (0-4,000 mg AHA/L), pHs (pH 6-10), and temperature (10-35℃). The result showed that the urease inhibition efficiency increased at higher concentration of AHA. However, the specific urease inhibition activity decreased at higher pH, showing 867.1±6.7 Unit/g AHA at pH 6 and 1,167.9±17.4 Unit/g AHA at pH 10, respectively. Decreased urease inhibition efficiency at both AHA and control was observed at higher temperature. This finding indicates that AHA can be used as the urease inhibitor for reducing ammonia emission in the management of livestock manure.

• Journal of the Korea Organic Resources Recycling Association
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• v.17 no.1
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• pp.49-57
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• 2009

This research examined the effect of ammonia nitrogen loading rate(NVLR) on the anaerobic digestion of slurry-typed swine wastewater. The anaerobic reactor was used an upflow anaerobic sludge blanket (UASB) process. This UASB reactor was operated at a NVLR of $0.02{\sim}0.96kg{NH_4}^+-N/m^3/day$. The methane content showed the range of 73.3~77.9% during the steady state period. Free ammonia(FA) concentration increased over inhibition level as pH increase from 7.3 to 8.2. However, in consideration of methane content, methane producing bacteria (MPB) inhibition by FA and total ammonia(TA) was not observed. A stepwise increase of the NVLR resulted in a deterioration in the COD removal rate in UASB reactor. The COD removal rate were 60% for NVLR up to $0.55kg{NH_4}^+-N/m^3/day$. As the NVLR increased from 0.09 to $0.96kg{NH_4}^+-N/m^3/day$, the biogas production rate varied from 3.71 to 9.14L/d and the methane conversion rate of the COD varied from 0.32 to $0.20m^3CH_4/kg$ COD removed. Consequently, in considerations of FA concentration, COD removal rate, and $CH_4$ production rate, the UASB reactor must be operated to lower than $0.40kg{NH_4}^+-N/m^3/day$ of NVLR.

• Transactions of the Korean Society of Automotive Engineers
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• v.18 no.5
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• pp.85-90
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• 2010

As the environmental regulation of vehicle emission is strengthened, investigations for $NO_x$ and PM reduction strategies are popularly conducted. Two current available technologies for continuous $NO_x$ reduction onboard diesel vehicles are Selective Catalytic Reduction (SCR) using aqueous urea and lean $NO_x$ trap (LNT) catalysts. The experiments were conducted to investigate the $NO_x$ reduction performance of SCR system which can control the ratio of $NO/NO_2$, temperature and SV(space velocity), and the model gas was used which is similar to a diesel exhaust gas. The maximum reduction efficiency is indicated when the $NO:NO_2$ ratio is 1:1 and the SV is 30,000 $h^{-1}$ in $300^{\circ}C$. Generally, ammonia slip from SCR reactors are rooted to incomplete conversion of $NH_3$ over the SCR. In this research, slip was occurred in 6cases (except low SV and $NO:NO_2$ ratio is 1:1) after SCR. Among 6 case of slip occurrence, the maximum conversion efficiency is observed when SV is 60,000 $h^{-1}$ in $400^{\circ}C$.

• Korean Chemical Engineering Research
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• v.49 no.4
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• pp.470-474
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• 2011

Rice straw is the main grain straw and is produced in large quantities every year in Korea. Pretreatment of lignocellulosic biomass using soaking process was carried out mild conditions at atmospheric pressure and temperature of $60^{\circ}C$. We found enzymatic hydrolysis condition of pretreated biomass. In case of a rice straw, compared with previous lignocellulosic biomass, we found that hydrolysis time was a shorter than others. Hydrolysis of SAA-treated rice straw has shown conversion rate was higher at $50^{\circ}C$. Hydrolysis was ended between 40~48 hour. Glucose conversion rate was higher when enzyme loading is 65 FPU/ml and 32 CbU/ml. When substrate concentration was 5%(w/v), it was that conversion rate was 83.8% after hydrolysis for 72 hr. In simultaneous saccharification and fermentation(SSF) experiment about SAA-treated rice straw, ethanol productive yield was highest from $40^{\circ}C$. The yield of that time was 33.05% from 48 hour.

• Transactions of the Korean hydrogen and new energy society
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• v.23 no.4
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• pp.382-389
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• 2012

Power generation cycle using ammonia-water mixture as working fluid has attracted much attention because of its ability to efficiently convert low-temperature heat source into useful work. If an ammonia-water power cycle is combined with a power cycle using liquefied natural gas (LNG), the conversion efficiency could be further improved owing to the cold energy of LNG at $-162^{\circ}C$. In this work parametric study is carried out on the thermodynamic performance of a power cycle consisted of an ammonia-water Rankine cycle as an upper cycle and a LNG cycle as a bottom cycle. As a driving energy the combined cycle utilizes a low-temperature heat source in the form of sensible heat. The effects on the system performance of the system parameters such as ammonia concentration ($x_b$), turbine 1 inlet pressure ($P_{H_1}$) and temperature ($T_{H_1}$), and condenser outlet temperature ($T_{L_1}$) are extensively investigated. Calculation results show that thermal efficiency increases with the increase of $P_{H_1}$, $T_{H_1}$ and the decrease of $T_{L_1}$, while its dependence on $x_b$ has a downward convex shape. The changes of net work generation with respect to $P_{H_1}$, $T_{H_1}$, $T_{L_1}$, and $x_b$ are roughly linear.

• Journal of the Korea Organic Resources Recycling Association
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• v.8 no.3
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• pp.81-88
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• 2000

Composting of N-rich wastes such as food waste and wastewater sludges can be associated loss of with substantial gaseous N, which means loss of an essential plant nutrient but may also lead to environmental pollution. We investigated the behavior of nitrogenous materials during the first high-rate phase in composting of food waste. Air dried food waste was mixed with shredded waste paper or wood chip and reacted in a bench scale composting reactor. Samples were analyzed for pH, ammonia, oxidized nitrogen and organic nitrogen. The volatilized ammonia nitrogen was also analyzed using sulfuric acid as an absorbent solution. Initial progress of composting reaction greatly influenced the ammonification of organic nitrogen. A well-balanced composting reaction with an addition of active compost as an inoculum resulted in the promoted mineralization of organic nitrogen and volatilization of ammonia. The prolongation of initial low pH period delayed the production of ammonia. It was also found that nitrogen loss was highly dependent on the air flow supplied. With an increase in input air flow, the loss of nitrogen as an ammonia also increased, resulted in substantial reduction of ammonia content in compost. The conversion ratio of initial nitrogen into ammonia was in the range of 28 to 38% and about 77~94% of the ammonia produced was escaped as a gas. Material balance on the nitrogenous materials was demonstrated to provide an information of importance on the behavior of nitrogen in composting reaction.