• Title/Summary/Keyword: Ammonia concentration

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Effect of Niacin Supplementation on Rumen Metabolites in Murrah Buffaloes (Bubalus bubalis)

  • Kumar, Ravindra;Dass, R.S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.18 no.1
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    • pp.38-41
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    • 2005
  • An experiment was conducted on 3 male rumen fistulated adult buffaloes fed on wheaten straw and concentrate mixture in a Latin square design to study the impact of niacin supplementation on rumen metabolites. Three animals were fed wheaten straw+concentrate mixture (group I, control), wheaten straw+concentrate mixture+100 ppm niacin (group II), and wheaten straw +concentrate mixture+200 ppm niacin (group III). After 21 days feeding, rumen liquor was drawn for 3 consecutive days at different time intervals (0, 2, 4, 6 and 8 h) to study the various rumen metabolites i.e., rumen pH, ammonia-N, total-N, trichloroacetic acid precipitable-N, non-protein nitrogen, total volatile fatty acids, their fractions and number of protozoa. Mean pH values in strained rumen liquor (SRL) of animals in 3 groups were 6.64, 6.71 and 6.67, indicating no statistically significant difference. Results revealed a significant (p<0.01) increase in TVFA concentration among the supplemented groups (group II and III) in comparison to control group. Mean TVFA concentration (meq/dl) was 9.75, 10.97 and 11.44 in 3 groups respectively. The highest concentration of TVFA was observed at 4 h and minimum at 0 h in all the 3 groups. The percentage of acetic, propionic, butyric and isobutyric acid was statistically similar among the three groups. The mean ammonia-N concentration (mg/dl SRL) was significantly (p<0.01) lower in group II (16.38) and group III (15.42) than group I (18.14). Ammonia-N concentration was higher (p<0.01) at 4 h as compared to all the time intervals. The mean total-N concentration (mg/dl SRL) was higher (p<0.01) in group II (74.16) and group III (75.47) as compared to group I (62.04). Total-N concentration was higher (p<0.01) at 4 h as compared to other time intervals and lowest value was recorded at 0 h.Concentration of TCA-ppt-N (mg/dl SRL) was significantly (p<0.01) lower in control group as compared to niacin supplemented groups. Mean value of NPN (mg/dl SRL) was significantly (p<0.01) lower in group III (23.21) as compared to group I (25.71), whereas groups I and II, and groups II and III were similar to each other. Total protozoa number (${\times}10^4$/ml SRL) ranged from 18.06 to 27.41 in group I, 20.89 to 38.44 in group II and 27.61 to 39.45 in group III. The mean protozoa number was significantly (p<0.01) higher in SRL of group II (27.60) and III (30.59) as compared to group I (22.48). It can be concluded from the study that supplementation of niacin in the diet of buffaloes had improved the rumen fermentation by decreasing the concentration of ammonia-N and increasing protein synthesis.

Effects of Dietary Quartz Porphyry Supplementation on Moisture Content of Excreta, Intestinal Ammonia Contents and Blood Composition of Growing Broilers (사료내 맥반석의 첨가가 성장중인 육계의 배설물 수분함량, 장내 암모니아 함량 및 혈액성상에 미치는 영향)

  • 손장호;박창일
    • Korean Journal of Poultry Science
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    • v.24 no.4
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    • pp.179-184
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    • 1997
  • Seven-day-old 40 broiler chicks of both sexes were fed the conventional diet containing 0, 0.3, 6 and 0.9% Quartz porphyry(QP) and water ad libitum until 28 days of age. The excreta water content and nitrogen balance were measured during the experimental period. At the end of the trial, blood samples were collected to measure ammonia, glucose, triglyceride, and total cholesterol concentrations. In addition, intestinal ammonia concentrations were measured. The excreta moisture contents decreased significantly(P < 0.05) as QP levels increased(r= -0.96). Ammonia contents in the intestine tended to increase as QP levels increased, but the ammonia concentration in the blood was not affected by the QP levels. The blood glucose concentration was not changed but blood triglyceride concentration was lower in the 0.3% QP treatment than the other groups(P < 0.05), Total cholesterol concentration in the blood tended to increase as QP levels increased. The QP 0.3% treatment showed somewhat higher positive N balance than the other groups. The results of this experiment indicate that the dietary supplementation of QP could offer some benefits to broiler growers.

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A Study on the Uniform Mixing of Ammonia-Air with the Change of Ammonia Supply Device Shape in a De-NOx System (탈질설비에서 암모니아 혼합기의 형상에 따른 암모니아-공기 균일 혼합에 관한 연구)

  • Ha, Ji Soo
    • Journal of the Korean Institute of Gas
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    • v.23 no.3
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    • pp.20-26
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    • 2019
  • Selective catalytic reduction(SCR) method is widely used among various methods for reducing nitrogen oxides in combustion devices of coal power plant. In the present study, the computational fluid dynamic analysis was accomplished to derive the optimal shape of ammonia-dilution air mixing device in a ammonia injection grid. The distribution characteristics of flow and $NH_3$ concentration had been elucidated for the reference shape of ammonia mixing device(Case 1). In the mixing device of Case 1, it could be seen that $NH_3$ distribution was shifted to the wall opposite to the inlet of the ammonia injection pipe. For the improvement of $NH_3$ distribution, the case(Case 2) with closing one upper injection hole and 4 side injection holes, the case(Case 3) with installing horizontal plate at the upper of ammonia injection pipe, the case(Case 4) with installing horizontal plate and horizontal arc plate at he upper of ammonia injection pipe were investigated by analyzing flow and $NH_3$ concentration distributions. From the present study, it was found that the % RMS of $NH_3$ for Case 4 was 4.92%, which was the smallest value among four cases, and the range of $R_{NH3}$ also has the optimally uniform distribution, -10.82~8.34%.

The Concentrations of Sulfur Compounds and Sensation of Odor in the Residential Area Around Banwol-Sihwa Industrial Complex (반월.시화공단 주변 주거지역의 악취현황 및 황화합물의 체감도)

  • Kim, Jong-Bo;Jeong, Sang-Jin;Song, Il-Seok
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.2
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    • pp.147-157
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    • 2007
  • This study was carried out to investigate the characteristics of fourteen odor compounds from a total of 10 sampling sites in residential areas around Banwol-Sihwa industrial complex. The measurement data are analyzed and compared with sensation of odor unit. Only a hydrogen sulfide out of four sulfur compounds was quantified above the detection limit (0.06 ppb) in the residential area around Banwol industrial complex with leather companies and a sewage treatment plant. The concentrations of VOCs were higher than those measured from a big city, and styrene showed the relatively high concentration from all sampling sites ($2.1{\sim}37.8\;ppb$). In the case of carbonyl compounds, acetaldehyde was found most frequently with the mean of 3.97 ppb, and its concentration difference was not significant between Banwol and Sihwa industrial complex. Of the nitrogen compounds, ammonia was measured at the relatively high concentration from all the sampling sites ($12{\sim}707\;ppb$), and a trimethylamine was found at the odor threshold level (0.1 ppb). The concentrations of styrene and ammonia showed relatively seasonal variation, the concentration of styrene in summer was five times higher than that in autumn, the concentration of ammonia in autumn was two times higher than that in summer. However other odorous compounds did not show such strong seasonal variation. Odor-concentration relationship between odor unit and $H_{2}S$ concentrations from industrial sources was examined and used as odor sensation evaluation, and thus the neighbourhood odor complaints maybe caused during the four seasons from the results.

Effects of Aerosol Hygroscopicity on Fine Particle Mass Concentration and Light Extinction Coefficient at Seoul and Gosan in Korea

  • Choi, Eun-Kyung;Kim, Yong-Pyo
    • Asian Journal of Atmospheric Environment
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    • v.4 no.1
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    • pp.55-61
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    • 2010
  • The sensitivity of aerosol light extinction coefficient to the aerosol chemical composition change is estimated by (1) calculating the aerosol water content and chemical concentrations by a gas/particle equilibrium model and (2) calculating the aerosol light extinction coefficient by a Mie theory based optical model. The major chemical species are total (gas and particle phase) sulfuric acid, total nitric acid, and total ammonia which are based on the measurement data at Seoul and Gosan. At Seoul, since there were enough ammonia to neutralize both total sulfuric acid and total nitric acid, the dry ionic concentration is most sensitive to the variation of the total nitric acid level, while the total mass concentration (ionic concentration plus water content) and thus, the aerosol light extinction coefficient are primarily determined by the total sulfuric acid. At Gosan, since the concentration of ambient sulfuric acid was the highest among the inorganic species, sulfate salts determined aerosol hygroscopicity. Thus, both ionic and total mass concentration, and resultant aerosol light extinction coefficient are primarily determined by the sulfuric acid level.

Activity of Methanogens in the High Rate Anaerobic Digestion of Swine Wastewater Containing High Ammonia (고농도 암모니아를 함유한 돈사폐수의 고율혐기성 소화시 메탄균의 활성연구)

  • Oh, Sae-Eun;Lee, Chae-Young
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.5
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    • pp.981-987
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    • 2000
  • Upflow anaerobic sludge blanket(UASB) reactor was operated for treating swine wastewater containing high ammonia nitrogen to assess their performance and toxicity of free ammonia concentration. In the reactor, chemical oxygen demand(COD) removed about 70% at $2.6kgCOD/m^3.day$ of organic loading rate(OLR) and 3 days of hydraulic retention time (HRT), while it was decreased when OLR and HRT was maintained $7kg\;COD/m^3.day$ and 2 days, respectively. Also UASB reactor was evaluated the activity of methane producing bacteria(MPB) according to change of free ammonia concentrations, MPB activity of applied sludge in the 500 and $1000mg-N/{\ell}$ of free ammonia concentration was inhibited by 4% and 40%, respectively. This clearly showed that free ammonia concentration less than $500mg-N/{\ell}$ showed no inhibition to MPB in anaerobic treatment of organics, UASB reactor was stabilized easily less than $1000mgVSS/{\ell}$ due to degradation of organic solids by the high activities of anaerobes.

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Physicochemical Changes in Fermented Skate (Raja kenojei) Treated with Organic Acids During Storage (유기산 처리 숙성홍어의 저장 중 이화학적 특성)

  • Kim, Hyung-Joo;Eo, Ji-Hyun;Kim, Seon-Jae;Eun, Jong-Bang
    • Korean Journal of Food Science and Technology
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    • v.42 no.4
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    • pp.438-444
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    • 2010
  • Fermented skate has a unique ammonia-like flavor. The flavor is preferred by a few lovers of skate muscle, while women and young people may be sensitive to the odor. Organic acids were used to reduce the ammonia-like odor in fermented skate and to investigate the physicochemical properties. Fermented skate muscles were sprayed with 20 mL of acetic acid or citric acid (3, 5, and 7%) for 30 seconds and stored at $4^{\circ}C$ for 15 days. The physicochemical properties of organic acid-treated fermented skate were investigated during storage. The control, which was treated with distilled water, showed a higher pH value than the samples treated with organic acids. The $L^*$ value increased with increasing organic acid concentration, while the $a^*$ and $b^*$ values were not significantly different among the samples. The trimethylamine (TMA) decreased with increasing in the organic acid concentration, but it was not significantly different after 9 days of storage. Ammonia-type nitrogen and ammonia-like flavoring, decreased with increasing in the organic acid concentration, whereas ammonia-type nitrogen increased with a storage period more than 6 days. In conclusion, fermented skate treated with 7% citric acid was the best treatment to reduce the ammonia-like odor.

A Study on Numerical Simulation of Gaseous Flow in SCR Catalytic Filter of Diesel Exhaust Gas Aftertreatment Device

  • Bae, Myung-Whan;Syaiful, Syaiful;Mochimaru, Yoshihiro
    • Journal of Advanced Marine Engineering and Technology
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    • v.34 no.3
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    • pp.360-368
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    • 2010
  • A SCR catalytic filter system is used for reducing $NO_x$ and soot emissions simultaneously from diesel combustors. The amount of ammonia (as a reducing agent) must be controlled with the amount of $NO_x$ to obtain an optimal $NO_x$ conversion. Hence, gas mixing between ammonia and exhaust gases is vital to ensure that the SCR catalyst is optimally used. If ammonia mass distribution is not uniform, slip potential will occur in rich concentration areas. At lean areas, on the other hand, the catalyst is not fully active. The better mixing is indicated by the higher uniformity of ammonia mass distribution which is necessary to be considered in SCR catalytic filter system. The ammonia mass distributions are depended on the flow field of fluids. In this study, the velocity field of gaseous flow is investigated to characterize the transport of ammonia in SCR catalytic filter system. The influence of different injection placements on the ammonia mass distribution is also discussed. The results show that the ammonia mass distribution is more uniform for the injector directed radially perpendicular to the main flow of inlet at the gravitational direction than that at the side wall for both laminar (Re = 640) and turbulent flows (Re = 4255). It is also found that the mixing index decreases as increasing the heating temperature in the case of ammonia injected at the side wall.

Mitigation of Ammonia Dispersion with Mesh Barrier under Various Atmospheric Stability Conditions

  • Gerdroodbary, M. Barzegar;Mokhtari, Mojtaba;Bishehsari, Shervin;Fallah, Keivan
    • Asian Journal of Atmospheric Environment
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    • v.10 no.3
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    • pp.125-136
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    • 2016
  • In this study, the effects of the mesh barrier on the free dispersion of ammonia were numerically investigated under different atmospheric conditions. This study presents the detail and flow feature of the dispersion of ammonia through the mesh barrier on various free stream conditions to decline and limit the toxic danger of the ammonia. It is assumed that the dispersion of the ammonia occurred through the leakage in the pipeline. Parametric studies were conducted on the performance of the mesh barrier by using the Reynolds-averaged Navier-Stokes equations with realizable k-${\varepsilon}$ turbulence model. Numerical simulations of ammonia dispersion in the presence of mesh barrier revealed significant results in a fully turbulent free stream condition. The results clearly show that the flow behavior was found to be a direct result of mesh size and ammonia dispersion is highly influenced by these changes in flow patterns in downstream. In fact, the flow regime becomes laminar as flow passes through mesh barrier. According to the results, the mesh barrier decreased the maximum concentration of the ammonia gas and limited the risk zone (more than 500 ppm) lower than 2 m height. Furthermore, a significant reduction occurs in the slope of the upper boundary of $NH_3$ risk zone distribution at downstream when a mesh barrier is presented. Thus, this device highly restricts the leak distribution of ammonia in the industrial plan.

Removal of a High Load of Ammonia by a Marine Bacterium, Vibrio alginolyticus in Biofilter

  • Kim, Nam-Jin;Shoda, Makoto
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.7 no.5
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    • pp.316-322
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    • 2002
  • A newly isolated heterotrophic marine bacterium, Vibrio alginolyticus, was used to remove a high load of ammonia gas under non-sterile condition. The cells were inoculated onto an inorganic packing material in a fixed-bed reactor (biofilter), and a high load of ammonia, in the range of ammonia gas concentration of 170 ppm to 880 ppm, was introduced continuously. Sucrose solution and 3% NaCl was supplied intermittently to supplement the carbon source and water to the biofilter. The average percentage of gas removed exceeded 85% for 107-day operation. The maximum removal capacity and the complete removal capacity were$19\;g-N\;kg^{-1}$ dry packing material $day^{-1}$ and $16\;g-N\;kg^{-1}$ dry packing material $day^{-1}$, respectively, which were about three times greater than those obtained in nitrifying sludge inoculated onto the same packing material. On day 82, the enhanced pressure drop was restored to the normal one by NaOH treatment, and efficient removal characteristics were later observed. During this operation, the non-sterile condition had no significantly adverse effect on the removability of ammonia by V. alginolyticus.