• 한국기후변화학회지
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• 제10권3호
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• pp.237-242
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• 2019

Ammonia is main precursor gas of secondary particulate matter and contributes almost 78% of total ammonia emission from the agricultural sector in Korea. The current method of estimating ammonia emission from fertilizer application, which contributes 7% of the total emission, has high uncertainty and needs to be improved to better predict PM2.5 concentration. In this study, we suggest an improvement method for ammonia emission quantification from fertilizer application. The first improvement was in the emission factor of NPK fertilizer by conducting a field study to verify the currently used factor. The improved NPK emission factor of 52.2 kg NH ton-1N was confirmed by comparing with the value from the EEA (European Environment Agency) and adjusting the value for the Korean climate and soil conditions. We also improved the amount of fertilizer usage by including the sales amount to the fertilizer supply amount of the Korean Farmers Association, increasing total fertilizer usage by 39.8%. As the statistical data on fertilizer supply and sales are compiled yearly, we estimated monthly emission of ammonia by considering cultivated areas and timing of fertilization for each crop. In summary, we suggest a novel and practical method to improve estimation methodology of ammonia emission from the field of fertilizer application: 1) emission factor of NPK fertilizer was reconfirmed; 2) total amount of fertilizer use was revised considering fertilizer sales; and 3) monthly emission of ammonia was realized by considering different crop practices. A bottom-up approach to compile activity data is needed to increase the estimation accuracy of monthly emission of ammonia, which is very helpful for predicting PM2.5 concentration.

• Journal of Korean Society for Atmospheric Environment
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• 제23권E2호
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• pp.47-56
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• 2007

Among all the nitrogen species present in the atmosphere, ammonia forms a considerable portion along with the nitrogen oxides. The major sources of atmospheric ammonia are animal feedlot operations including emission from excreta of domestic animals and agricultural activities, followed by emission from synthetic fertilizers, biomass burning and to some lesser extent, fossil fuel combustion. Ammonia emission factor, expressed as the weight of ammonia per unit weight, volume, or duration of the activity emitting it, is generally used in developing emission estimates for emission inventories. The factors determining ammonia loss from soil or from manures are the temperature, pH, humidity, precipitation and the velocity of wind above it.

• 환경영향평가
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• 제19권1호
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• pp.1-13
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• 2010

Ammonia ($NH_3$) is an important pollutant that plays a key role in several air pollution problems. It can create odors and have negative impacts on animal and human health. The largest source contributing to Ammonia emission is the agricultural production, in particular animal operation, in Korea. The present study evaluated flux profiles of Ammonia emitted from the cattle housing using a dynamic flux chamber. We have developed the emission factor of Ammonia from the cow housing. Analysis of Ammonia flux variation was made with respect to manure surface temperature, pH, and ammonium concentration. Ammonia has been measured from calf and cattle housing between October and December in 2007. In the fall, average Ammonia flux from calf and cattle housing was estimated 1.342(${\pm}0.728$) and 1.323(${\pm}0.655$)mg/$m^2$/min, respectively. In the winter, average Ammonia flux was estimated 0.889(${\pm}0.362$)mg/$m^2$/min from the calf housing and 0.925(${\pm}0.511$)mg/$m^2$/min from the cattle housing. The correlation coefficient between Ammonia flux and ammonium concentration showed stronger relationship than the relationship between manure pH and temperature. In the fall, Ammonia emission factor from calf and cattle housing was estimated 4.46(${\pm}2.39$) and 6.03(${\pm}3.27$)kg-$NH_3$/animal/yr, respectively. In the winter, average Ammonia flux was estimated 2.88(${\pm}1.53$) from the calf housing and 4.24({$\pm}1.63$)kg-$NH_3$/animal/yr from the cattle housing.

• 한국환경농학회지
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• 제41권1호
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• pp.41-49
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• 2022

BACKGROUND: The main source of ammonia in soils, South Korea is agricultural emissions (e.g., fertilizer application and livestock manure), with the recent emission inventories reporting them to be approximately 80% of the total emissions. Ammonia as a pollutant is originated largely from agricultural activity and is an important contributor to air quality issues in South Korea. The importance of ammonia in agricultural land is also emerging. In this study, the characteristics of ammonia emission from Chinese cabbage cultivation fields with application rates of urea sere were evaluated. METHODS AND RESULTS: The ammonia emission characteristics were investigated at the different urea application rates (0, 160, 320, and 640 kg ha-1) and the ammonia emission factor in the Chinese cabbage cultivation field was calculated. As application rate of urea application increased, ammonia emissions increased proportionally. In 2020 and 2021, cumulative ammonia emissions with urea 320 kg ha^-1 treatment were 39.3 and 35.2 kg ha^-1, respectively for 2020 and 2021. When urea fertilizer was applied, the ammonia emission factors were 0.1217 and 0.1358 NH₄⁺-N kg N kg^-1 in 2020 and 2021, respectively. CONCLUSION(S): Ammonia emissions increased as application rate of urea increased, and the average ammonia emission factor of the Chinese cabbage cultivation field for two years was 0.129 NH₄⁺-N kg N kg^-1.

• 한국환경보건학회지
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• 제36권1호
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• pp.33-43
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• 2010

Atmospheric ammonia is a very important constituent of the environment because it is the dominant alkaline gaseous species present in the atmosphere. Ammonia is known to affect ecosystems at relatively low concentration. In this study flux profiles of ammonia emitted from the cattle housing were evaluated using a dynamic flux chamber (DFC). We have developed the emission factor of $NH_3$ from the cattle housing. Analysis of ammonia flux variation was made with respect to such variables as manure surface temperature, pH, and ammonium concentration. Ammonia flux has been measured up to summer in 2007 at calf and cattle housing. In the fall, average ammonia flux from calf and cattle housing was estimated as 1.406 (${\pm}0.947$) and 1.534 ((${\pm}0.956$) $mg\;m^2\;min^1$, respectively. In the winter, average ammonia flux was estimated 1.060 ((${\pm}0.569$) from the calf housing and 1.216 ((${\pm}0.655$) $mg\;m^2\;min^1$ from the cattle housing. The correlation coefficient (R=0.732) between ammonia flux and manure surface ammonium concentration exhibited stronger relationship than manure surface pH and temperature. In the fall, ammonia emission factor from calf and cattle housing was estimated as 3.94 ((${\pm}2.66$) and 11.41 ((${\pm}5.86$) kg-$NH_3$ animal$^1\;yr^1$, respectively. In the winter, ammonia average flux was estimated as 2.89 ((${\pm}1.59$) from the calf housing and 6.51 ((${\pm}3.67$) kg-$NH_3$ animal$^1\;yr^1$ from the cattle housing.

• 한국환경농학회지
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• 제40권3호
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• pp.149-160
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• 2021

BACKGROUND: Concerns have been raised about the impact of recent high concentrations of fine dust on human health. Ammonia(NH₃) reacts with sulfur oxides and nitrogen compounds in the atmosphere to form ultrafine ammonium sulfate and ammonium nitrate (PM2.5). There is a growing need for accurate estimates of the amount of ammonia emitted during agricultural production. Therefore, in this study, ammonia emissions generated from the cultivation of leafy perilla in plastic houses were determined. METHODS AND RESULTS: Cow manure compost, swine manure compost, and poultry manure compost each at 34.6 ton ha^-1, the amount commonly used by farmers in the field, was sprayed on the soil surface. Just after spraying cow manure compost, swine manure compost, and poultry manure compost, the ammonia was periodically measured and analyzed to be 22.5 kg ha^-1, 22.8 kg ha^-1, and 85.2 kg ha^-1, respectively. The emission factors were estimated at 70.0 kg-NH₃ ton-N, 62.8 kg-NH₃ ton-N, and 234.1 kg-NH₃ ton-N, respectively. Most ammonia was released in the two weeks after application of the compost and then the amount released gradually decreased. CONCLUSION: Therefore, it is necessary to improve the emission factor through a study on the estimation of ammonia emission by type of livestock manure and major farming types such as rice fields and uplands, and to update data on the production, distribution, and sales of livestock manure.

• 환경영향평가
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• 제14권5호
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• pp.263-273
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• 2005

In this study, the major emission procedures and emission characteristics were identified at the site of sewage treatment plant which is one of the major sources of ammonia. At the same time the emission factors and emission rates were estimated. In order to calculate the emission flux, we used a Dynamic Flux Chamber(DFC), which is found to be a proper sampling devise for area sources such as sewage treatment plant. It was found that the most stable sampling condition was when the stirrer's speed of DFC was 120RPM, and it would be the best time to take a sample 60 minutes later after setting the chamber. The relatively higher flux was shown in Autumn compared to summer and winter. Annual ammonia emission rates procedures were calculated as $906.32{\mu}g/activity-ton$, $1,114.72{\mu}g/activity-ton$ and $437.53{\mu}g/activity-ton$ each at the primary settling basin, aeration basin and the final settling basin, respectively. The ammonia emission rate the highest at in the aeration basin according to this test. This results was due to that the surface of aeration basin or the final settling basin is relatively wider than the primary settling basin.

• 한국농공학회논문집
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• 제62권6호
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• pp.33-42
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• 2020

Emission factors for ammonia and particulate matters (PMs) from livestock buildings are of increasing importance in view of the environmental protection. While the existing emission factors were determined based on the emission inventory of other countries, in situ measurement of emission factors is required to construct an accurate emission inventory for Korea. This study is to report measurements of ammonia and PMs emissions from mechanically-ventilated pig houses, which are common types of pig barns in Korea. Ventilation rates and concentrations of ammonia and PMs were measured at the ventilation outlets of a weaner unit, a growing pig unit and a fattening pig unit to calculated the emission factors. The PMs emission was characterized with different aerodynamic diameters (PM_2.5, PM₁₀, and total suspended particulates (TSP)). The measured ammonia emission factors for weaners, growing pigs and fattening pigs were 0.225, 0.869 and 1.679 kg animal^-1 yr^-1, respectively, showing linear increase with pigs' age. The PMs emission factors for three growing stages were 0.023, 0.237 and 0.241 kg animal^-1 yr^-1, respectively for TSP, 0.017, 0.072 and 0.223 kg animal^-1 yr^-1, respectively for PM₁₀, and 0.011, 0.016 and 0.151 kg animal^-1 yr^-1, respectively for PM_2.5. PMs emissions were increased with pigs' age due to increasing feed supply and animal movement. The measured emission factors were smaller than those of the existing emission inventory indicating that the existing ones overestimate the emissions from pig buildings and also suggesting that long-term in situ monitoring at various livestock buildings is required to construct the accurate emission inventory.

• 환경생물
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• 제38권1호
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• pp.71-81
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• 2020

국내 발생 암모니아 중 가축분뇨의 기여율이 높은 것은 자명한 사실이다. 암모니아 배출량 산정 과정의 정확도와 신뢰도 향상을 위해서는, 가축분뇨 발생량의 정확한 집계, 가축분뇨의 퇴비화 및 액비화 과정에서 단계별 암모니아 전환량과 발생량 산출, 퇴액비의 저장 및 운송과정에서의 암모니아 발생량 산정 그리고 토양 살포 과정과 방법에 따른 암모니아 발생량 비교 연구가 반드시 수행되어야 할 것이다. 미국과 유럽과 비교해 볼 때, 특히 국내 배출계수가 상대적으로 매우 획일적이고 시공간적으로 세분화되지 못해 국내 실정을 충분히 반영하지 못하고 있다. 암모니아 배출계수 산정의 정확도와 전문성을 향상 시킬 수 있는 방안으로, 퇴액비의 특성, 토양의 특성 그리고 기후 특성의 복합적인 고려가 가능한 챔버시스템을 활용할 수 있을 것이다. 국내외 암모니아 배출과 관련한 자료의 검토와 비교를 통해 현재 국내 시스템의 부족한 점과 나아가야할 방향을 확인할 수 있었으며, 암모니아 배출유량 산정이 가능한 챔버 시스템을 제언하였다. 향후 누락배출원의 신규 배출계수 산정과 같은 실질적인 정책과의 연계를 위해서는 실내의 챔버 시스템에서 더 나아가 현장에서의 mesocosom 시스템의 방법론 구축 또한 필요할 것으로 판단된다.

• 한국초지조사료학회지
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• 제44권2호
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• pp.133-139
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• 2024

This study aimed to evaluate the efficiency of combining acidification with adsorbents (zeolite and biochar) to mitigate the environmental impacts of pig slurry, focusing on ammonia (NH₃) emission and nitrate (NO₃^-) leaching. The four treatments were applied: 1) pig slurry (PS) alone as a control, 2) acidified PS (AP), 3) acidified pig slurry with zeolite (APZ), and 4) acidified pig slurry with biochar (APB). The AP mitigates NH₃ emission and NO₃^- leaching compared to PS alone. Acidification reduced the cumulative NH₃ emission and its emission factor by 35.9% and 12.5%, respectively. The APZ and APB increased NH₄⁺-N concentration, with the highest level in APB, compared to AP. The NH₄⁺ adsorption capacity of APB (0.90 mg g^-1) was higher than that of APZ (0.63 mg g^-1). The APB and APZ treatments induced less NH₃ emission compared to AP. The cumulative NH₃ emission was reduced by 12.2% and 27.6% in APZ and APB, respectively, compared to AP treatment. NO₃^- leaching began to appear on days 12 and 13, and its peak reached on days 16 and 17, which were later than AP. The cumulative NO₃^- leaching decreased by 17.7% and 25.0% in APZ and APB, respectively, compared to AP treatment. These results suggest that combining biochar or zeolite with acidified pig slurry is an effective method to mitigate NH₃ emission and NO₃^- leaching, with biochar being particularly effective.