• Title/Summary/Keyword: Ammonia/water

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Effects of Operational Condition on N2O Production from Biological Nitrogen Removal Process (생물학적 질소제거시 운전조건의 변화가 N2O 발생에 미치는 영향)

  • Jang, Hyun-Sup;Kim, Tae-Hyeong;Lee, Myoung-Joo;Hwang, Sun-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.23 no.5
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    • pp.547-555
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    • 2009
  • The objectives of this research were focused on the effects of various operating parameters on nitrous oxide emission such as C/N ratio, ammonia concentration and HRT in the hybrid and suspension reactors. With the decreasing of C/N ratios, $N_2O$ emission rates in the both processes were increased because organic carbon source for denitrification was depleted. In case of biofilm reactor operated using medium, $N_2O$ release from the nitrification was not affected by the variation of ammonia concentration. But in the suspension reactor, $N_2O$ production from the nitrification was rapidly increased with the increase of ammonia. Nitrite accumulation caused by undesirable nitrification conditions could be a important reason for the increase in the $N_2O$ production from the aerobic reactor. And rapid increase in $N_2O$ production was reflected by the decrease of HRT, similar to the results observed in the results of ammonia loading changes. So it could be said that it is very important to put in consideration both its optimum conditions for wastewater treatment efficiency and suitable conditions for $N_2O$ diminish, simultaneously, in order to development an eco-friendly and advanced wastewater treatment, especially in BNR process.

Studies on the artificial infection and the hematological change with Fasciola hepatica metacercariae in rats (흰쥐에 대(對)한 간질피낭유충(肝蛭被囊幼蟲)의 인공감염(人工感染)과 혈액상(血液像)에 관(關)한 연구(硏究))

  • Kang, Seung-won
    • Korean Journal of Veterinary Research
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    • v.34 no.3
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    • pp.549-557
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    • 1994
  • This study was done to find the method of the extermination of Fasciola hepatica matacercariae. And the artificial infection was carried out with 30 metacercarae exposed to 5% ammonia water and not-exposed to 5% ammonia water. Serial determinations of live weight, red blood cell, hemoglobin, packed cell volume, and eosinophils were performed in rats at 7 days interval for 16 weeks after infection (WAI). Recovery of worm burden and microscopic findings of livr was performed in rats at 10 WAI. The results in this work were summarized as follows; 1. Fasciola spp metacercariae exposed to 5% ammonia water have lost their ability of infection. 2. In teh exposed group, the mean of worm recovered was 2.25 and the common bile duct was swelling up to 0.71cm in diameter. 3. The value of live weight was different in two groups as the not-exposed group and the exposed group were 321.28, 384.38 at 10 WAI, respectively. 4. In the not-exposed group, at 7 WAI, hemoglobin at 5 WAI and packed cell volume at 7 WAI wre minimally decreased to $5.84{\times}10^{-6}/mm^3$, 11.53g/dl and 43.2%, respectively. But those three values were slowly increased at 10 WAI. Rercent cosinophil was increased to 12.2% at 4 WAI and slightly decreased to 7.9% at 10 WAI. But there are no stastistical singnificance between the exposed group and the normal control group. 5. In histolgical findings in the not-exposed group, the dilated common bile ducts and intrahepatic bile ducts showed distinct hyperplasia of the epithelium. Lymphocytes and eosinophils were infilterated around the bile ducts. The hepatic cells and Kupffer cells showed swollen appearance.

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Impact of urbanization on Nwaorie and Otamiri Rivers in Owerri, Imo State, Nigeria

  • Ogbomida, Emmanuel T.;Emeribe, Chukwudi N.
    • Advances in environmental research
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    • v.2 no.2
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    • pp.119-129
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    • 2013
  • The study examined the effect of urbanization on the water quality of Nwaorie and Otamiri Rivers in Owerri metropolis, Imo State, South-East Nigeria. Water samples were collected from Nwaorie and Otamiri Rivers from four sampling stations up and down stream. Water parameters analyzed using standard procedures were: color, turbidity, temperature, pH, total hardness, total solids, metals (Iron and magnesium), anions (nitrate and ammonia) and Fecal coliform. Results showed increased levels of coloration, iron, ammonia, turbidity and fecal coliform which exceeded the World Health Organization (WHO) permissible limits for drinking water. Increase in these parameters indicated influx of industrial effluent from the nearby industries and indiscriminate disposal of wastes at the bank of the rivers. Application of ANOVA showed various degree of variation in pollutants levels between the two rivers and at different sampling points. River Nwaorie was observed to be more impacted than River Otamiri. High values of iron observed from the study could be deleterious to human health if the river water is consumed without treatment. The study, therefore, recommended proper waste management and disposal as well as effluent treatments in Owerri municipal against pollution of surface water.

Evaluation of Ammonia Emission from Arable Soil applied Liquid Manure and Compost (가축분 퇴.액비 시용에 따른 암모니아 휘산량 평가)

  • Lee, Yong-Bok;Yun, Hong-Bae;Lee, Youn;Kaown, Dug-In
    • 한국환경농학회:학술대회논문집
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    • 2009.07a
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    • pp.329-338
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    • 2009
  • Emission of ammonia to the atmosphere are considered a threat to the environment. The application of livestock manure and compost contributes significantly to the emission of ammonia from agriculture. The reduction in NH3 losses from field-applied manure and compost would be a good strategy to reduce national $NH_3$ emission. In this study, various application techniques of liquid manure and compost were compared to evaluate their potential for reducing $NH_3$ emission. In compost application, the reductions in $NH_3$ emission were 70 and 15% for immediately rotary after application (IRA) and rotary at 3-day after application (RA-3d) in comparison with surface application (SA). Total ammonia emissions for 13 days, expressed as % ammonia-N applied in compost, were 42, 35.7, and 12.7% for SA, RA-3d, and IRA treatments, respectively. Mean reductions in NH3 emission from application of liquid pig manure were 26 and 50% for rotary harrow after surface broadcast application in spring and fall, respectively, in comparison with surface broadcast application. Ammonia emission rate was decreased with increasing water content in soil due to dilution effect, but this reduction only was temporary up to 12 hours after application and cumulative $NH_3$ emission was increased with increasing water content in soil. However, the delay would be beneficial because it allows time for rotary hallow of the applied liquid pig manure. Therefor, ammonia emission can be reduced by immediately incorporation of liquid manure and compost after surface application.

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Studies on the Preventive Measures of Vegetable Crops to Gases -1. Effect of ammonia gas on radish, chinese cabbage, tomato, and cucumber (채소원예작물(菜蔬園藝作物)에 대(對)한 가스피해(被害) 및 피해경감(被害輕減)에 관(關)한 연구(硏究) -1. 무우, 배추, 토마토, 오이에 대한 Ammonia 가스의 영향(影響))

  • Kim, Bok-Yong;Cho, Jae-Kyu
    • Korean Journal of Soil Science and Fertilizer
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    • v.20 no.2
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    • pp.139-145
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    • 1987
  • This study was carried out to find out the effects of ammonia gas on the leaf destruction of vegetable crops, and nitrogen contents in their leaves. Radish, chinese cabbage, tomato and cucumber were fumigated with 0.05, 0.1, $0.2mg/{\ell}$ ammonia gas for 2 hrs under different exposure time, light and soil water condition at vegetative growth stage. The results obtained were as follows. The crop damages measured by percentage of leaf destruction were more severe at the night time fumigation than treatment during the day, at the full sun condition than the shading, and at the higher soil water contents. Cucumber plant showed higher resistance to ammonia gas than tomato plant. The chrolophyll contents in leaves of each crops were remarkably decreased by increment of ammonia concentration from $0.05mg/{\ell}$ to $0.2mg/{\ell}$, but the N content in them was increased.

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Numerical analysis of an air-cooled ammonia condenser with plate fins (평판핀이 부착된 공냉형 암모니아 응축기의 열전달 성능에 대한 수치적 연구)

  • Kim, Y.I.;Kang, B.H.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.9 no.3
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    • pp.292-299
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    • 1997
  • Ammonia has been used as refrigerant for more than 100 years in absorption as well as in compression systems. Due to its poisonous and inflammable properties, however, its use has been mainly on heavy industrial plants in which regular maintenance are available. For these systems, condensers are generally water-cooled. This is suitable for large systems over 20 RT but is not suitable for small systems. In order to apply ammonia for a small system, it is important to adopt an air-cooled condenser. In this study, simple numerical analysis of an air-cooled condenser for an ammonia refrigeration system has been carried out. The condenser is designed as horizontal tubes with plate fins attached at the outer surface to enhance the air-side heat transfer rate. Effects of fin shape and arrangement are studied in detail. Since the local heat transfer coefficient is highest at the leading edge, heat flux is highest at the edge and decreases along the distance. Conditions of inlet air are also varied in the study and condenser length that is required for full condensation is calculated. The results show that it is important to enhance both the air-side and internal heat transfer coefficients.

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Comparison of the Nitrification Efficiencies of Three Biofilter Media in a Freshwater System

  • Harwanto, Dicky;Oh, Sung-Yong;Jo, Jae-Yoon
    • Fisheries and Aquatic Sciences
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    • v.14 no.4
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    • pp.363-369
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    • 2011
  • Total ammonia nitrogen (TAN) removal efficiencies of a sand filter (SF), polystyrene microbead filter (PF), and Kaldnes bead filter (KF) media were evaluated under ammonia loading rates of 5, 25, and 50 g $m^{-3}day^{-1}$. The volume of each filter media tested was 7 L, and the water flow rate for all filter media was 24 L/min. The specific surface areas of the SF, PF, and KF were 7,836, 3,287, and 500 $m^2/m^3$, respectively. Sand was fluidized and the other two media were trickle filtered. The volumetric TAN removal rate increased with increasing ammonia loading rate for all filter media. Mean volumetric TAN removal rates under the ammonia loading rates of 5, 25, and 50 g $m^{-3}day^{-1}$ in SF (39.3, 168.6, and 322.7 g $m^{-3}day^{-1}$, respectively) were higher than those in PF (35.0, 157.4, and 310.5 g $m^{-3}day^{-1}$, respectively) and KF (32.1, 142.5, and 288.1 g $m^{-3}day^{-1}$, respectively). These results were related to differences in the specific surface areas of the filter media. PF was the most economic media for efficiently removing TAN.

Effect of Ammonia Concentration in Rearing Water on Growth and Blood Components of the Parrotfish Oplegnathus fasciatus (사육수의 암모니아 농도가 돌돔(Oplegnathus fasciatus)의 성장과 혈액성분에 미치는 영향)

  • Park, Seongdeok;Kim, Pyong Kih;Jeon, Joong-Kyun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.47 no.6
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    • pp.840-846
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    • 2014
  • This study investigated growth and hematological changes in parrotfish Oplegnathus fasciatus (~200 g/fish) reared under different total ammonia nitrogen (TAN) concentrations (0, 4, or 8 mg/L) for 6 weeks. Survival rates of parrotfish in all experimental groups did not significantly differ, as they were all ~100%. Although specific growth rate (SGR), weight gain, and daily feed intake in the high TAN concentration group (TAN8) were significantly lower than in the other two groups, there was no significant difference between the TAN4 group and the control group, (TAN0), indicating that parrotfish have a strong resistance to ammonia toxicity. As for temporal changes of the major blood components, cortisol increased as a result of stress caused by the high ammonia concentration in the TAN8 group. For this reason, the concentrations of energy sources such as glucose and total cholesterol were reduced. However, there was little difference among all experimental groups in concentrations of liver function glutamic oxaloacetic transaminase (GOT) and glutamic pyruvic transaminase (GPT), and nutrient factors, such as total protein and albumin.

Numerical Analysis of an Air-cooled Ammonia Condenser with Plate Fins

  • Kim, Young-Il;Kang, Byung-Ha
    • International Journal of Air-Conditioning and Refrigeration
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    • v.6
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    • pp.104-112
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    • 1998
  • Ammonia has been used as refrigerant for more than 100 years in absorption as well as in compression systems. Due to its poisonous and inflammable properties, however, its use has been mainly on heavy industrial plants in which regular maintenance is available. For these systems, condensers are generally water∼cooled. This is suitable for large systems over 20RT but is not suitable for small systems. In order to apply ammonia for a small system, it is important to adopt an air-cooled condenser. In this study, simple numerical analysis of an air-cooled condenser for an ammonia refrigeration system has been carried out. The condenser is designed as horizontal tubes with plate fins attached at the outer surface to enhance the air-side heat transfer rate. Effect of fin shape and arrangement are studied in detail. Since the local heat transfer coefficient is highest at the leading edge, heat flux is highest at the edge and decreases along the distance. Conditions of inlet air are also varied in the study and condenser length that is required for full condensation is calculated. The results show that it is important to enhance both the air-side and internal heat transfer coefficients.

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Recovery of Ammonium Salt from Nitrate-Containing Water by Iron Nanoparticles and Membrane Contactor

  • Hwang, Yu-Hoon;Kim, Do-Gun;Ahn, Yong-Tae;Moon, Chung-Man;Shin, Hang-Sik
    • Environmental Engineering Research
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    • v.17 no.2
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    • pp.111-116
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    • 2012
  • This study investigates the complete removal of nitrate and the recovery of valuable ammonium salt by the combination of nanoscale zero-valent iron (NZVI) and a membrane contactor system. The NZVI used for the experiments was prepared by chemical reduction without a stabilizing agent. The main end-product of nitrate reduction by NZVI was ammonia, and the solution pH was stably maintained around 10.5. Effective removal of ammonia was possible with the polytetrafluoroethylene membrane contactor system in all tested conditions. Among the various operation parameters including influent pH, concentration, temperature, and contact time, contact time and solution pH showed significant effects on the ammonia removal mechanism. Also, the osmotic distillation phenomena that deteriorate the mass transfer efficiency could be minimized by pre-heating the influent wastewater. The ammonia removal rate could be maximized by optimizing operation conditions and changing the membrane configuration. The combination of NZVI and the membrane contactor system could be a solution for nitrate removal and the recovery of valuable products.