• Economic and Environmental Geology
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• v.54 no.1
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• pp.21-33
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• 2021

The purpose of this study is to determine the order of priority for the use of amendments, matching the optimal amendment to the specific site in Korea. This decision-making process must prioritize the stabilization and economic efficiency of amendment for heavy metals and metalloid based on domestic site contamination scenarios. For this study, total 5 domestic heavy metal contaminated sites were selected based on different pollution scenarios and 13 amendments, which were previously studied as the soil stabilizer. Batch extraction experiments were performed to quantify the stabilization efficiency for 8 heavy metals (including As and Hg) for 5 soil samples, representing 5 different pollution scenarios. For each amendment, the analyses using XRD and XRF to identify their properties, the toxicity characteristics leaching procedure (TCLP) test, and the synthetic precipitation leaching procedure (SPLP) test were also conducted to evaluate the leaching safety in applied site. From results of batch experiments, the amendments showing > 20% extraction lowering efficiency for each heavy metal (metalloid) was selected and the top 5 ranked amendments were determined at different amount of amendment and on different extraction time conditions. For each amendment, the total number of times ranked in the top 5 was counted, prioritizing the feasible amendment for specific domestic contaminated sites in Korea. Mine drainage treatment sludge, iron oxide, calcium oxide, calcium hydroxide, calcite, iron sulfide, biochar showed high extraction decreasing efficiency for heavy metals in descending order. When the economic efficiency for these amendments was analyzed, mine drainage treatment sludge, limestone, steel making slag, calcium oxide, calcium hydroxide were determined as the priority amendment for the Korean field application in descending order.

• Korean Journal of Soil Science and Fertilizer
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• v.31 no.2
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• pp.107-113
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• 1998

We investigated the effects of a long term application of soil amendments such as lime, silicate, compost, or combinations of these materials on the contents of Cu and Zn in paddy soil and brown rice. The results obtained from a sequential extraction of Cu and Zn in paddy soils and brown rice, using $H_2O$, $KNO_3$, $Na_2$-EDTA and $HNO_3$ and showed that the most of Cu and Zn were NaOH-extractable (organically bound form) and $HNO_3$-extractable (sulfide and residual form). Cu contents of NaOH and EDTA extractable increased with the long term application of compost while the contents of Zn extracted by $KNO_3$ was decreased even though $HNO_3$ extractable-Zn was prominent chemical form in paddy soils. The percentage and contents of Zn, extracted by $KNO_3$ for each combination treatment of soil amendments, was decreased but the contents of Cu was not affected. The content of NaOH extractable-Cu was proportionally increased with increase in organic matter content irrespective of the extractants used in this experiment. The contents of Zn and exchangeable K were also increased with increase in organic matter content. However, we could not find any relationship between the extractable forms of Cu and Zn, and CEC, OM. while increase in CEC, contents of cations, and organic matter decreased the content of Cu in brown rice.

• Korean Journal of Soil Science and Fertilizer
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• v.45 no.6
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• pp.973-982
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• 2012

Crop safety in heavy metal contaminated agricultural field has been a critical issue in Korea and various remediation methods are proposed for minimizing heavy metal transfer from soil to crops. The main objective of this research was to evaluate remediation efficiency of two chemical amendments, lime and steel slag, and to decide extractant for assessing bioavailability of heavy metals. In order to select optimum extractant for evaluating bioavailability of heavy metals, four different single extractants, HCl, DTPA, $CaCl_2$, $NH_4NO_3$, and sequential extraction method were examined. Both chemical amendments showed high immobilization effect for Cd (66%, $33.62mg\;kg^{-1}$) and Pb (74%, $27.65mg\;kg^{-1}$) in soil by HCl extractant. In terms of heavy metal concentration in rice grains, concentrations for Cd (77%, $0.023mg\;kg^{-1}$) and Pb (82%, $0.039mg\;kg^{-1}$) decreased, with addition of chemical amendments. HCl, DTPA, and sequential extractant showed the higher correlation between heavy metal concentration in soil and crops than others. These results indicated that they could be used for assessing bioavailability of heavy metals.

• Korean Journal of Soil Science and Fertilizer
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• v.45 no.6
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• pp.961-967
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• 2012

There have been many studies about efficiency of amendments for heavy metal stabilization through chemical assessment. The objective of this study was to evaluate the efficiency of several soil amendments (lime, agric-lime, dolomite, steel slag, fly ash and acid mine drainage sludge) on heavy metals stabilization through not only chemical but also biological assessments (phytotoxicity test) in abandoned mining area soil. In order to achieve the goal, we conducted preliminary screening experiment targeting 12 types of crop plants such as radish, young radish, chinese cabbage, winter grown cabbage, cabbage, bok choy, chicory, crown daisy, carrot, chives, spinach, and spring onion. The results of inhibition rates of early plant growth in metal-contaminated soil against non-contaminated soil and the correlations between inhibitions items showed that the bok choy was appropriate specie with respect to confirm the effect of several amendments. Several amendment treatments on contaminated soil brought about the changes in the root and shoot elongation of bok choy after 1 week. Agric-lime, dolomite and steel slag treatments showed the great efficiency of reducing on mobility of heavy metals using chemical assessment. But in contrary, these treatments resulted in the reduction of root and shoot elongation and only AMD sludge increased that of elongation, significantly. When considering both chemical and biological assessments, AMD sludge could be recommended the compatible amendment for target contaminated soil. In conclusion, biological assessment was also important aspect of decision of successful soil remediation.

• The Korean Journal of Pesticide Science
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• v.20 no.4
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• pp.312-318
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• 2016

This study investigated the reduction of residual pesticide in soil by using eight kinds of soil amendments such as shell, quick lime, dolomite, silicic acid, leaf mold, oil cake, bed soil and husk. A total of ten pesticides most frequently detected in agricultural soil were selected (azoxystrobin etc.) and soil amendments were treated in soils at a 2% application rate and incubated for 7 days. Pesticides were analyzed by HPLC-MS/MS with QuEChERS-based sample preparation procedure and pH was measured on 1, 3 and 7 days. This study showed that, soil amemdments were effective in reducing pesticides after 7days of incubation. Over 90% of azoxystrobin, cadusafos, chlorpyrifos, fluquinconazole, imidacloprid, isoprothiolane and procymidone were decomposed from soils amended with 2% quick lime, whereas the concentration of boscalid, dimethomorph and triycyclazole were not decreased. The soil pH increased to 12.8-12.9 in soil amended with quick lime, but other soil conditioners did not change the soil pH. Quick lime was particularly effective in reducing residual pesticides.

• Asian Journal of Turfgrass Science
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• v.24 no.2
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• pp.205-210
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• 2010

This study was conducted to investigate the effect of the mixed ratio of the soil amendments, peat, humate, peatmoss and zeolite, on the soil physicochemical properties. The mixed ratios of soil amendments were 0%, 3%, 5%, 7% and 10% (v/v) incorporated with sand which met to the USGA (United State of Golf Association) recommendation. It was measured pH, EC and CEC as a chemical properties. Porosity, capillary porosity, air-filled porosity, bulk density and hydraulic conductivity were also measured to analyze the changes of physical properties. Chemical properties were significantly different by mixture ratios of peat, humate, peatmoss and zeolite. When the results were applied to the USGA standard of the soil physical properties, the optimum mixture ratios of peat, humate and peatmoss were 5%, 3% and 7%, respectively. Air-filled porosity was factor involved in soil physical properties by blending with soil amendments and it was affected on volume of porosity and hydraulic conductivity. To analyze the corelation of mixture ratio versus to physical characters, the ratio of peat and peatmoss was significantly related to capillary porosity and hydraulic conductivity (P<0.05), that of humate hydraulic conductivity (P<0.01), and that of zeolite air-filled porosity and volume of porosity (P<0.05). These results could be used as a basic data for construction USGA sand green.

• Ecology and Resilient Infrastructure
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• v.7 no.1
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• pp.63-71
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• 2020

Various types of amendments have been studied for heavy metal stabilization in soil. However, researches on the effect of amendments on alkali soil and their effects on the plants at various edible parts are insufficient. The aim of this study was to evaluate the stabilization efficiency of heavy metals and their transfer into edible parts of food crops. Abandoned mine area was selected and 3 types of amendments (lime stone, LS; steel slag, SS; acid mine drainage sludge, AMDS) was applied with 3% (w/w). in field. After 6 month aging, Chinese cabbage (leafy), bok choy (leafy), garlic (root) and red pepper (fruit) were transplanted and cultivated. For chemical assessment, total concentration and bioavailability using Mehlich-3 solution were determined. For biological assessment, fresh weight and heavy metal uptakes were analyzed. It was revealed that AMDS reduced bioavailability most effectively, resulting in the decrease in heavy metal concentration in edible parts of all crops. When explaining the heavy metal uptake of plants, the bioavailability was more appropriate than the total contents of soil heavy metals. Therefore, bioavailability-based further research and management practices should be carried out continuously for the sustainable environment management, safe crop production, and human health risk reduction.

• Korean Journal of Soil Science and Fertilizer
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• v.51 no.2
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• pp.101-110
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• 2018

There is an increasing concern over arsenic (As) contamination in rice since Codex Committee on Contaminants in Food (CCCF) discuss on maximum levels for As in rice in 2010. This study was conducted to reduce As concentration in rice by soil amendment treatments in paddy field soils contaminated by As. The selected four amendments were poultry manure, agri-lime, steel slag, and gypsum with the addition of 3% or 5% (w/w) on a dry basis. The As reduction effect could not be verified, as a result of the pot test by adding poultry manure to the paddy soil around the mine located in Yesan. Among the agri-lime treated rice cultivated pots, the As concentration increased up to 32.1%. On the other hand, the content of As in the sample pots treated with steel slag and gypsum decreased by 65.4% and 63.4%, respectively. On the basis of the results of these pot experiments, the field test was carried out in the As polluted rice field around the mine located in Yesan, and when the four amendments were treated, the As content in the brown rice reduced in all the amendment treatments compared with the control plot. The As reduction in brown rice of the amendment was confirmed to be higher efficiency by the order of gypsum > steel slag > poultry manure > agri-lime. As a result of pot experiments using paddy soil around the mine located in Seosan, As stabilization efficiency in rice and As reduction effect could not be determined by comparison to the control. From the rice cultivated from agri-lime treated pot, As concentration increased by 15.8% in rice. On the other hand, the As content of the pots treated with steel slag and gypsum decreased by 39.1% and 60.2%, respectively. In conclusion, distinguished As reducing effectiveness could be expected by soil amendment treatments for rice cultivation.

• Korean Security Journal
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• no.61
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• pp.333-352
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• 2019

In January and August 2019, there were amendments to the Unfair Competition and Trade Secrets Protection Act (UCPA) and the Industrial Technology Protection Act(ITPA). These amendments will contribute to technology protection. But these amendments need to be supplemented further. In the area of civil remedies, despite the introduction of treble damages in the case of the UCPA and ITPA, the provisions related to the submission of supporting data have not been maintained. Therefore, it is necessary to recognize the claim of the other party as true if it is maintained at the level of the revised Patent Act and the scope of submission of supporting data. And the enforcement of the case of compulsory submission for the calculation of damages, and the order of filing documents are not followed. ITPA, on the other hand, has introduced the compensation for damages, but there is no provision for estimating the amount of damages. Therefore, it is necessary to estimate the amount of lost profits, profits, and royalties. In the area of criminal remedies, both the UCPA and ITPA have raised the penalty, but the sentencing regulations are not maintained. In addition, although the recent outflow of technology has expanded beyond organizational deviations to organizational outflows, amendments need to be made in relation to the serious consequence for the punishment of related juristic persons, such as companies involved in it. It should be noted that Japan and the United States have corporate regulations and regulations. In addition, in relation to the confiscation system, Act on Regulation and Punishment of criminal proceeds concealment require that domestic defenses be confiscated by defense industry technology, while trade secrets and industrial technologies are confiscated only by "foreign" outflows, and an amendment is necessary.

• Korean Journal of Soil Science and Fertilizer
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• v.21 no.1
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• pp.3-10
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• 1988

A laboratory study was carried out to investigate the effects of application level of soil amendments, mixing method of soil amendments, and compost treatment on desalinization by examining the changes in hydraulic conductivity and chemical properties of effluent of the soil during desalinization. 1. The treatment of soil amendments brought about the increase in hydraulic conductivity. 2. The higher the application level of a soil amendment, the higher the hydraulic conductivity and the shorter the time elapsed to complete the desalinization. 3. Complete mixing of calcium compounds was more effective for desalinization than surface mixing. 4. The compost treatment induced the rise in pH and therefore brought about the remarkable drop in hydraulic conductivity. 5. During the desalinization, the changes in physical and chemical properties of the soil were influenced by the kind and application level of soil amendments, mixing method of soil amendment, and compost treatment.