• 대한기계학회논문집A
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• 제37권12호
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• pp.1489-1495
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• 2013

유체의 고압유동은 여러 산업현장에 활용되고, 특히 그 중 내연기관의 연료분사 인젝터가 대표적이며 디젤엔진의 커먼레일 시스템의 경우 1000bar 이상의 압력이 사용된다. 이와 같이 고속으로 분출되는 유체유동의 경우, 노즐을 통해 분사되는 고속의 유체는 주위기체와의 상호작용으로 분열과정을 거치게 된다. 이 분열과정은 연소실 혼합기형성기과정에 영향을 주게 되며, 그 결과 엔진의 연소상태에 까지 영향을 미치게 된다. 따라서 연료분무의 분열과정에 대한 해석은 중요하며, 본 연구에서는 연료분무의 분열을 위한 수치해석 서브모델로 Reitz&Diwakar 및 CAB(Cascade atomization and breakup)모델을 사용하였다. 본 연구의 목적은 분사된 분무의 분열과정의 정확한 해석이며, 분사연료의 분열발생 형태의 빈도 등을 조사하였다. 결과로서 본 연구는 상용 CFD 프로그램(CFX)을 이용하여 디젤분무의 분열과정해석을 위한 적합한 분열모델을 제안한다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2010년도 제39회 하계학술대회 초록집
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• pp.145-145
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• 2010

In this paper, we report that the effects of hydrogen doping on the electrical and optical properties of typical transparent conducting oxide films such as ZnO and $SnO_2$ prepared by magnetron sputtering. Recently, density functional theory (DFT) calculations have shown strong evidence that hydrogen acts as a source of n-type conductivity in ZnO. In this work, the beneficial effect of hydrogen incorporation on Ga-doped ZnO thin films was demonstrated. It was found that hydrogen doping results a noticeable improvement of the conductivity mainly due to the increases in carrier concentration. Extent of the improvement was found to be quite dependent on the deposition temperature. A low resistivity of $4.0{\times}10^{-4}\;{\Omega}{\cdot}cm$ was obtained for the film grown at $160^{\circ}C$ with $H_2$ 10% in sputtering gas. However, the beneficial effect of hydrogen doping was not observed for the films deposited at $270^{\circ}C$. Variations of the electrical transport properties upon vacuum annealing showed that the difference is attributed to the thermal stability of interstitial hydrogen atoms in the films. Theoretical calculations also suggested that hydrogen forms a shallow-donor state in $SnO_2$, even though no experimental determination has yet been performed. We prepared undoped $SnO_2$ thin films by RF magnetron sputtering under various hydrogen contents in sputtering ambient and then exposed them to H-plasma. Our results clearly showed that the hydrogen incorporation in $SnO_2$ leads to the increase in carrier concentration. Our experimental observation supports the fact that hydrogen acting as a shallow donor seems to be a general feature of the TCOs.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2004년도 제23회 추계학술대회 논문집
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• pp.267-273
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• 2004

본 논문에서는 강한 압력파동에 구속된 액체 추진제 연소응답의 지배인자를 규명하고 비정상 거동 특성을 평가한다. 외부 압력섭동에 의해 교란된 탄화수소 계열 액체 추진제의 비정상 거동을 수치계산하고 연소응답의 관점에서 분석한다. 2상 사이의 평형을 고려한 1차원 액적기화 모델을 적용하고 압력파동은 인위적인 조화함수식으로 설정한다 외부 기상의 압력과 온도, 액적의 초기 직경과 내부온도, 외부 압력파동의 진폭과 구동 주파수 등 액체 로켓의 주요 설계인자 및 작동변수의 영향을 고찰한다. 본 연구를 통해 외부 압력파동의 구동 주파수와 외부 기상압력은 연소응답의 크기와 위상을 결정하는 지배인자임이 규명된 반면 외부 기상온도, 액적의 초기 직경과 외부온도 및 압력파동의 진폭 등은 연소응답과 약한 상관관계를 갖거나 그 영향이 미미하다. 기화열 섭동의 위상 및 액적표면과 내부의 파동에너지 전파특성이 연소응답의 크기와 위상을 결정한다.

• Nuclear Engineering and Technology
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• 제52권5호
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• pp.1013-1021
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• 2020

A combination of simultaneous thermal analysis, evolved gas analysis and non-ambient XRD techniques was used to characterise and investigate the conversion reactions of ammonium uranates into uranium oxides. Two solid phases of the ternary system NH₃ - UO₃ - H₂O were synthesised under specified conditions. Microspheres prepared by the sol-gel method via internal gelation were identified as 3UO₃·2NH₃·4H₂O, whereas the product of a typical ammonium diuranate precipitation reaction was associated to the composition 3UO₃·NH₃·5H₂O. The thermal decomposition profile of both compounds in air feature distinct reaction steps towards the conversion to U₃O₈, owing to the successive release of water and ammonia molecules. Both compounds are converted into α-U₃O₈ above 550 ℃, but the crystallographic transition occurs differently. In compound 3UO₃·NH₃·5H₂O (ADU) the transformation occurs via the crystalline β-UO₃ phase, whereas in compound 3UO₃·2NH₃·4H₂O (microspheres) an amorphous UO₃ intermediate was observed. The new insights obtained on these uranate systems improve the information base for designing and synthesising minor actinide-containing target materials in future applications.

• 한국토양비료학회지
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• 제50권6호
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• pp.554-561
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• 2017

Under the projected global warming, release of carbon as $CO_2$ through soil organic matter decomposition is expected to increase. Therefore, accurate measurement of $CO_2$ released from soil is crucial in understanding the soil carbon dynamics under increased temperature conditions. Sodium hydroxide (NaOH) traps are frequently used in laboratory soil incubation studies to measure soil respiration rate, but decreasing $CO_2$ gas solubility with increasing temperature may render the reliability of the method questionable. In this study, the influences of increasing temperature on the $CO_2$ capture capacity of NaOH traps were evaluated under $5{\sim}35^{\circ}C$ temperature range at $10^{\circ}C$ interval. Two closed-chamber experiments were performed where NaOH traps were used to capture $CO_2$ either released from acidified $Na_2CO_3$ solution or directly injected into the chamber. The sorption of ambient $CO_2$ within the incubators into NaOH traps was also measured. The amount $CO_2$ captured increased as temperature increased within 2 days of incubation, suggesting that increased diffusion rate of $CO_2$ at higher temperatures led to increases in $CO_2$ captured by the NaOH traps. However, after 2 days, over 95% of $CO_2$ emitted in the emission-absorption experiment was captured regardless of temperature, demonstrating high $CO_2$ absorption efficiency of the NaOH traps. Thus, we conclude that the influence of decreased $CO_2$ solubility by increased temperatures is negligible on the $CO_2$ capture capacity of NaOH traps, supporting that the use of NaOH traps in the study of temperature effect on soil respiration is a valid method.

• 대한조선학회논문집
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• 제58권3호
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• pp.137-143
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• 2021

In this study, the fracture strength of Flexible Secondary Barrier (FSB) composites was standardized by conducting a distribution analysis of the fracture probability, considering that the fracture strength of FSB composites such as glass fiber reinforced composites is relatively large. As the mechanical performance of FSB composites varies with the fiber direction, 20 replicate uniaxial tensile tests were performed for different temperatures ranging from the ambient to cryogenic conditions, considering the actual operating environment of liquefied natural gas. For the probability statistical analysis, the Weibull distribution analysis derived from the weakest link theory was used, considering the large variance in the fracture strength and brittle fracture behavior. The results of the Weibull distribution analysis were used to calculate the standard fracture strength of the FSB composites for different fiber directions. The findings can help ensure the reliability of the FSB mechanical properties in different fiber directions in the design of the secondary barrier and structural analyses.

• 대한조선학회논문집
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• 제58권1호
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• pp.17-23
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• 2021

The membrane-type Liquefied Natural Gas (LNG) cargo tank is equipped with a double barrier to seal the LNG, of which the secondary barrier serves to prevent LNG leakage and mainly uses fiber-reinforced composite materials. However, the composite materials have thermal expansion anisotropy, which deteriorates shape distortion and mechanical performance due to repeated thermal loads caused by temperature changes between cryogenic and ambient during the unloading of LNG. Therefore, in this study, the longitudinal thermal expansion characteristics of the composite materials were obtained using a vertical thermo-mechanical analyzer, and the elastic modulus was obtained through the tensile test for each temperature to perform thermal load analysis for each direction. This is considered that it is useful to secure reliability from the viewpoint of the design of materials for a LNG cargo hold.

• 천문학회보
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• 제43권2호
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• pp.38.3-38.3
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• 2018

We present the results of high-resolution near-IR spectral mapping toward the Orion KL outflow. In this study, we used the Immersion Grating Infrared Spectrometer (IGRINS) on the 2.7 m Harlan J. Smith Telescope at McDonald Observatory. IGRINS's large wavelength coverage over the H & K bands and high spectral resolving power (R ~ 45,000) allowed us to detect over 35 shock-excited ro-vibrational H2 transitions and to measure directly the gas temperature and velocity of the dense outflows. In our previous study toward the H2 peak 1 region in the Orion KL outflow, we identified 31 outflow fingers from a datacube of the H2 1-0 S(1) $2.122{\mu}m$ line and constructed a three-dimensional map of the fingers. The internal extinction (${\Delta}AV$ > 10 mag) and overall angular spread of the flow argue for an ambient medium with a high density (105 cm-3). In this presentation, we show preliminary results of additional mapping toward a remarkable chain of bows (HH 205 - HH 207) farther from the ejection center, and obtain a more clear view of the shock physics of a single isolated bullet that improves on the knowledge gained from observations of the more complex peak 1 region in our earlier study.

• 한국재료학회지
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• 제29권5호
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• pp.322-327
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• 2019

Hole carrier selective MoOx film is obtained by atomic layer deposition(ALD) using molybdenum hexacarbonyl[$Mo(CO)_6$] as precursor and ozone($O_3$) oxidant. The growth rate is about 0.036 nm/cycle at 200 g/Nm of ozone concentration and the thickness of interfacial oxide is about 2 nm. The measured band gap and work function of the MoOx film grown by ALD are 3.25 eV and 8 eV, respectively. X-ray photoelectron spectroscopy(XPS) result shows that the $Mo^{6+}$ state is dominant in the MoOx thin film. In the case of ALD-MoOx grown on Si wafer, the ozone concentration does not affect the passivation performance in the as-deposited state. But, the implied open-circuit voltage increases from $576^{\circ}C$ to $620^{\circ}C$ at 250 g/Nm after post-deposition annealing at $350^{\circ}C$ in a forming gas ambient. Instead of using a p-type amorphous silicon layer, high work function MoOx films as hole selective contact are applied for heterojunction silicon solar cells and the best efficiency yet recorded (21 %) is obtained.

• 한국추진공학회지
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• 제25권2호
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• pp.42-54
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• 2021

Aft-deck은 가스터빈 배기 플룸을 차폐하거나, 제트를 확산하여 외부 공기와 혼합율을 증가시켜 배기가스의 온도를 저감하기 위한 용도로 최신 무인항공기에 적용되고 있다. 본 연구에서는 Aft-deck의 설계 변수에 따라 노즐의 성능이 어떻게 영향을 받는지 알아보고자 하였다. Aft-deck의 설계 변수로는 길이, 확산각, 상부 덱 형상으로 선정하였으며, 길이 변수에 따른 추력과 차폐율 간의 상관관계를 제시하였다. 그리고 확산 각도의 범위에 따라 노즐 추력과 제트 확산에 대한 상관관계를 제시하였다. 또한, 상부 덱 제거를 통해 추력 향상 효과를 확인하였으며, 횡 방향 속도 벡터의 특성이 외부 유동과의 혼합 성능을 결정하는 것을 알게 되었다.