• Title/Summary/Keyword: Aluminum(III)

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Efficient White Organic Light-emitting Device by utilizing a Blue-emitter Doped with a Red Fluorescent Dopant

  • Lim, Jong-Tae;Ahn, Young-Joo;Kang, Gi-Wook;Lee, Nam-Heon;Lee, Mun-Jae;Kang, Hee-Young;Lee, Chang-Hee;Ko, Young-Wook;Lee, Jin-Ho
    • Journal of Information Display
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    • v.4 no.2
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    • pp.13-18
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    • 2003
  • We synthesized bis (2-methyl-8-quinolinolato)(triphenylsiloxy) aluminum (III) (SAlq), a blue-emitting material having a high luminous efficiency, through a homogeneous-phase reaction. The photoluminescence (PL) and electroluminescence (EL) spectra of SAlq show two peaks at 454 nm and 477 nm. Efficient white light-emitting devices are fabricated by doping SAlq with a red fluorescent dye of 4-dicyanomethylene-2-methyl-6-{2-(2,3,6,7-tetrahydro-1H,5H-benzo[i,j]quinolizin-8yl) vinyl}-4H-pyran (DCM2). The incomplete energy transfer from blue-emitting SAlq to red-emitting DCM2 results in light-emission of both blue and orange colors. Devices with the structure of ITO/TPD (50 nm)/SAlq:DCM2 (30 nm, 0.5 %)/$Alq_3$ (20 nm)/LiF (0.5 nmj/Al show EL peaks at 456 nm and 482 nm originating from SAlq and at 570 nm from DCM2, resulting in the Commission Internationale d'Eclairage (CIE) chromaticity coordinates of (0.32, 0.37). The device exhibits an external quantum efficiency of about 2.3 % and a luminous efficiency of about 2.41m/W at 100 $cd/m^2$. A maximum luminance of about 23,800 $cd/m^2$ is obtained at the bias voltage of 15 V.

Effect of the Al(III) Coagulant Basicity on Phosphorus Removal in Sewage Treated Water (하수처리수의 인 제거에 미치는 Al(III) 응집제 염기도의 영향)

  • Han, Seung-Woo;Lee, Chul-Hee;Lee, Jae-Kwan;Kang, Lim-Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.3
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    • pp.149-154
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    • 2012
  • According to the coagulation tests for PACs with various basicities, the PACB with lower basicity showed higher coagulation efficiencies of organics and phosphorus than the PAC with higher basicity. The PACB contained higher amount of monomeric Al (III) hydrolytic species comparing with PAC. In case of the coagulation for the sewage treated water, the coagulation efficiency by the charge neutralization and sweep floc formation was higher with PACB than with PAC. Accordingly, when $Al_2O_3$ concentration was similar in the coagulant, PACB showed higher removal efficiencies of turbidity, $COD_{Mn}$, TP, and $PO_4$-P comparing with PAC, especially in the lower range of coagulant dose.

The tunnel model tests of material development in different surrounding rock grades and the force laws in whole excavation-support processes

  • Jian Zhou;Zhi Ding;Jinkun Huang;Xinan Yang;Mingjie Ma
    • Geomechanics and Engineering
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    • v.36 no.1
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    • pp.51-69
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    • 2024
  • Currently, composite lining mountain tunnels in China are generally classified based on the [BQ] method for the surrounding rock grade. Increasingly, tunnel field construction is replicated indoors for scale down model tests. However, the development of analogous materials for model tests of composite lining tunnels with different surrounding rock grades is still unclear. In this study, typical Class III and V surrounding rock analogous materials and corresponding composite lining support materials were developed. The whole processes of excavation-support dynamics of the mountain tunnels were simulated. Data on the variation of deformations, contact pressures and strains on the surrounding rock were obtained. Finally, a comparative analysis between model tests and numerical simulations was performed to verify the rationality of analogous material development. The following useful conclusions were obtained by analyzing the data from the tests. The main analogous materials of Class III surrounding rock are barite powder, high-strength gypsum and quartz sand with fly ash, quartz sand, anhydrous ethanol and rosin for Class V surrounding rock. Analogous materials for rockbolts, steel arches are replaced by aluminum bar and iron bar respectively with both shotcrete and secondary lining corresponding to gypsum and water. In addition, load release rate of Class V surrounding rock should be less than Class III surrounding rock. The fenestration level had large influence on the load sharing ratio of the secondary lining, with a difference of more than 30%, while the influence of the support time was smaller. The Sharing ratios of secondary lining in Class III surrounding rock do not exceed 12%, while those of Class V surrounding rock exceed 40%. The overall difference between the results of model tests and numerical simulations is small, which verifies the feasibility of similar material development in this study.

Acoustic Emission Characteristics of Notched Aluminum Plate Repaired with a Composite Patch (복합재 패치로 보수된 노치형 알루미늄 합금 평판의 음향방출 특성)

  • Yoon, Hyun-Sung;Choi, Nak-Sam
    • Journal of the Korean Society for Nondestructive Testing
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    • v.31 no.1
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    • pp.53-61
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    • 2011
  • Edge notched A16061-T6 aluminum was repaired with a GFRP composite patch as a function of the number of stacking, Damage progress of specimen for tension load has been monitored by acoustic emission(AE), AE energy rate, hit rate, amplitude, waveform and 1st peak frequency distribution were analyzed. Fracture processes were classified into Al cracking, Fiber breakage, Resin cracking and Delamination. Displacement of a specimen can be divided into Region I, II and ill according to acoustic emission characteristics. Region II where the patch itself was actually fractured was focused on to clarify the AE characteristics difference for the number of stacking.

Sag Behavior of STACIR/AW 410SQmm Overhead Conductor in accordance with the Aging (STACIR/AW 410SQmm 가공송전선의 경년열화와 이도거동(III))

  • Kim Shang-Shu;Kim Byung-Geol;Sin Goo-Yong;Lee Dong-Il;Min Byung-Uk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.3
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    • pp.280-286
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    • 2006
  • As a way to expand electric capacity in conductor with electric power demand, STACIR/AW (Super Thermal-resistant Aluminum-alloy Conductors Aluminum-clad Invar-Reinforced) conductor which has high electric current and heat resistance characteristics have been developed. STACIR/AW power line is mechanical composite wire composed of steel cores for dip control and aluminum conductors for sending electric current. Recently, to ensure stable operation and prediction of wire life span of STACIR/AW conductor, a heat property of STACIR/AW conductor have been investigated. In the present work, a change of essential property with long term-heat exposure of STACIR/AW conductor and its structure material, INVAR wire and Al conductor, have been investigated. INVAR/AW is approximately $3.2\;{\mu}m/m^{\circ}C$. thermal expansion coefficient of INVAR/AW wire increases with time of heat exposure. the thermal expansion coefficient of INVAR/AW is markedly influenced by heat and mechanical treatment. creep rate(0.242) of STACIR/AW $410\;mm^2$ conductor at room temperature is much higher than that(0.022) at $210\;^{\circ}C$ STACIR/AW $410\;mm^2$ conductor has minimum creep rate at operating temperature. To lower creep rate with increase temperature is more unique characteristics in STACIR/AW. It is expected that STACIR/AW turned its tension to INVAR/AW at the transition temperature. at room temperature, the tension apportionment of INVAR/AW in STACIR/AW is about $50\;\%$. but whole tension of STACIR/AW is placed on the INVAR/AW alone of core metal above transition temperature.

Relationship between Pattern of Fatigue Crack Surface and Fatigue Crack Growth Behavior under $K_{III}$ Mode-Four Point Shear in Al 5083-O (Al 5083-O재에 있어서 $K_{III}$ 모드 4점 전단 하에서의 피로파단면 무늬와 피로균열진전거동의 관계)

  • Kim, Gun-Ho;Won, Young-Jun;Sakakura, Keigo;Fujimoto, Takehiro;Nishioka, Toshihisa
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2006.06a
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    • pp.43-44
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    • 2006
  • Generally almost all fatigue crack growth is affected by model. For this reason a study on model has concentrated in the field of fracture mechanics. However the fatigue crack initiation and growth in machines and structures usually occur in mixed mode loading. If there is any relationship between the cause of fracture in mixed mode loading and fracture surface, fracture surface pattern will be the main mean explaining reasons of fatigue fracture and obtaining further information about fracture process. In this paper four point shear-fatigue test with Aluminum alloy Al 5083-O is carried out from this prospect and then the mixed mode distribution of fracture surface is examined from the result after identifying the generation of fatigue crack surface pattern. It was found from the experimental results that the fatigue crack surface pattern and the fatigue crack shear direction are remarkably consistent. Furthermore It is possible that the analysis of distribution of mixed mode through the fatigue crack surface pattern.

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Preparation and Characteristics of Ceramic Composite Powders Coated with $Al_2O_3$: (III) Composite Powders of $Al_2O_3-ZrO_2$ ($Al_2O_3$로 피복시킨 세라믹 복합분체의 제조 및 특성: (III) $Al_2O_3-ZrO_2$ 복합분체)

  • 현상훈;이지현;송원선
    • Journal of the Korean Ceramic Society
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    • v.29 no.8
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    • pp.667-673
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    • 1992
  • The alumina-zirconia composite powders of core particle ZrO2 coated with Al2O3 were prepared by the hydrolysis-deposition of the mixed aluminum salt solution of Al2(SO4)3-Al(NO3)3-Urea. The effects of hydrolysis reaction and coating parameters on characteristics of coated powders and composites were also investigated. The degree of coating could be estimated from the ratio of tetra-/mono-ZrO2 present at the room temperature after heat-treating coated powders at 120$0^{\circ}C$ and the result of TEM observations. When the content of ZrO2 in the dispersed coating system, the coating time, and the volume ratio of water/solution were 50 mg/g, 180 min, and 5, respectively the coating efficiency was maximum (the ratio of tetra-/mono-ZrO2 was 87/13). The relative densities of coated Al2O3-ZrO2 composites sintered at 1$650^{\circ}C$ for 4 hrs were about 91~98% and the maximum ratio of tetra-/mono-ZrO2 in Al2O3-20wt% ZrO2 composites was 62/38.

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Optimization of chemical precipitation for phosphate removal from domestic wastewater (생활하수내 인 제거를 위한 화학적 침전의 최적화)

  • Lee, Sunkyung;Park, Munsik;Yeon, Seungjae;Park, Donghee
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.6
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    • pp.663-671
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    • 2016
  • Coagulation/precipitation process has been widely used for the removal of phosphate within domestic wastewater. Although Fe and Al are typical coagulants used for phosphate removal, these have some shortages such as color problem and low sedimentation velocity. In this study, both Fe and Al were used to overcome the shortages caused by using single one, and anionic polymer coagulant was additionally used to enhance sedimentation velocity of the precipitate formed. Batch experiments using a jar test were conducted with real wastewater, which was an effluent of the second sedimentation tank in domestic wastewater treatment plant. Response Surface Methodology was used to examine the responsibility of each parameter on phosphate removal as well as to optimize the dosage of the three coagulants. Economic analysis was also done on the basis of selling prices of the coagulants in the field. Phosphate removal efficiency of Fe(III) was 30% higher than those of Fe(II). Considering chemical price, optimum dosage for achieving residual phosphate concentration below 0.2 mg/L were determined to be 18.14 mg/L of Fe(III), 2.60 mg/L of Al, and 1.64 mg/L of polymer coagulant.

Pore structure evolution characteristics of sandstone uranium ore during acid leaching

  • Zeng, Sheng;Shen, Yuan;Sun, Bing;Zhang, Ni;Zhang, Shuwen;Feng, Song
    • Nuclear Engineering and Technology
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    • v.53 no.12
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    • pp.4033-4041
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    • 2021
  • To better understand the permeability of uranium sandstone, improve the leaching rate of uranium, and explore the change law of pore structure characteristics and blocking mechanism during leaching, we systematically analyzed the microstructure of acid-leaching uranium sandstone. We investigated the variable rules of pore structure characteristics based on nuclear magnetic resonance (NMR). The results showed the following: (1) The uranium concentration change followed the exponential law during uranium deposits acid leaching. After 24 h, the uranium leaching rate reached 50%. The uranium leaching slowed gradually over the next 4 days. (2) Combined with the regularity of porosity variation, Stages I and II included chemical plugging controlled by surface reaction. Stage I was the major completion phase of uranium displacement with saturation precipitation of calcium sulfate. Stage II mainly precipitated iron (III) oxide-hydroxide and aluminum hydroxide. Stage III involved physical clogging controlled by diffusion. (3) In the three stages of leaching, the permeability of the leaching solution changed with the pore structure, which first decreased, then increased, and then decreased.

Phosphorus Removal Characteristic of the Aluminum (III)-loess Composite (알루미늄-황토 복합체의 인 제거 특성)

  • Shin, Gwan-Woo;Kim, Jin-Sik;Kim, Keum-Yong;Lee, Sang-Ill
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.7
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    • pp.530-535
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    • 2011
  • In this work, the adsorption characteristic of the composites by adding loess with aluminum ("Al-loess") and Loess with lanthanum ("La-loess") which have been developed to effectively remove phosphorus, the substance which causes the eutrophic lake has been evaluated. According to the result of the work, as the amount of aluminum or lanthanum put in 1g of loess increases, the combined amount also increases accordingly. When the loess with no aluminum or lanthanum attached was used, the rate of removing phosphorus was different in comparison with the case of using the composites of 0.5, 1 and 2 mg of aluminum and 0.5, 1 and 3 mg of lanthanum in each gram of loess. It was observed the amount required to remove 1 mg $PO_4^{3-}$-P/L of phosphorus completely is approximately 2 to 10 times less for the composite of Al-loess than loess alone. Also, in case of the composite of La-loess, the amount was decreased by about 1.5 to 10 times. In order to observe the rate of adsorption phosphorus with Al-loess and La-loess, the composites were used for the observation up to three times by water washing. As a result, the water washing of the composite did not affect phosphorus removal. According to the effect of pH, there is a high rate of removing phosphorus in the pH range of 5~8. It seems that the developed composite will effectively remove phosphorus when it is spread in the natural water system. Also, since Al-loess and La-loess composites are rapidly precipitated within 30 minutes, it is stabilized quickly at the bottom of the eutrophic lake and becomes responsible for the removal of phosphorus in water and eluted from the water and the sedimentary layer.