• Title/Summary/Keyword: Aluminide

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A Study of Weld Cracking Susceptibility of Gamma Titanium Aluminides (Gamma Titanium Aluminide의 용접균열 감수성에 관한 연구)

  • ;W.A. Baeslack III;T.J. Kelly
    • Proceedings of the KWS Conference
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    • 1995.10a
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    • pp.208-211
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    • 1995
  • Five cast gamma titanium aluminides, Ti-45~48%Al-2%Nb-2%Cr (nominal composition in at. %), were laser welded and their weld cracking susceptibilities were evaluated. Laser power, traversing rate and preheat temperature were systematically varied to generate a series of welds exhibiting a wide range of cooling rate ($100^{\circ}C/s-10,000^{\circ}C/s$). As Al content increased and the weld cooling rate decreased, solidification cracking susceptibility increased while solid-state cracking susceptibility decreased. Through laser beam energy input control and preheat, it was determined possible to produce high quality laser welds.

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Oxidation Resistance of Al Diffusion Coating Layer on TiAl (TiAl합금의 Al 피복시 Al확산 피복층의 내고온산화성)

  • Lee, C.H.;Choe, J.I.
    • Journal of the Korean Society for Heat Treatment
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    • v.10 no.2
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    • pp.150-156
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    • 1997
  • The effect of variation of pack activators, compositions, temperature and time on the thickness and structure of aluminide coatings formed on the TiAl alloy was studied in one-step packs and two-step packs containing aluminum for the purpose of improvement of oxidation resistance. The thickness of coating layer was increased with increasing $NH_4Cl$ content up to 3wt% and then it was saturated. Oxidation resistance of coating layers carried out at one step pack was superior to that of ones through of two step pack. The improvement of high temperature oxidation resistance was due to the formation of a protective $Al_2O_3$ surface layers and coating the alloys with $TiAl_3$ phase.

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DEVELOPMENT OF HIGH-DENSITY U/AL DISPERSION PLATES FOR MO-99 PRODUCTION USING ATOMIZED URANIUM POWDER

  • Ryu, Ho Jin;Kim, Chang Kyu;Sim, Moonsoo;Park, Jong Man;Lee, Jong Hyun
    • Nuclear Engineering and Technology
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    • v.45 no.7
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    • pp.979-986
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    • 2013
  • Uranium metal particle dispersion plates have been proposed as targets for Molybdenum-99 (Mo-99) production to improve the radioisotope production efficiency of conventional low enriched uranium targets. In this study, uranium powder was produced by centrifugal atomization, and miniature target plates containing uranium particles in an aluminum matrix with uranium densities up to 9 $g-U/cm^3$ were fabricated. Additional heat treatment was applied to convert the uranium particles into UAlx compounds by a chemical reaction of the uranium particles and aluminum matrix. Thus, these target plates can be treated with the same alkaline dissolution process that is used for conventional $UAl_x$ dispersion targets, while increasing the uranium density in the target plates.

Magnetic, Magneto-Optical, and Transport Properties of Ordered and Disordered 3d-Transition Metal Aluminide Films

  • Lee, Y.P.;Kim, K.W.;Rhee, J.Y.;Kudryavtsev, Y.V.
    • Journal of the Korean Vacuum Society
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    • v.7 no.s1
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    • pp.1-6
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    • 1998
  • The influence of the order-disorder structural transition on the magnetic and mageto-optical, and transport properties of Fe-Al and Co-Al alloy films has been investigated. The disordered states in the alloy films were prepared by vapor quenching deposition on glass substrates cooled by liquid nitrogen. The experimental study of the magento-optical properties of the ordered and disordered Fe-Al and Co-Al alloy films has been carried out in 1.05-5.0 eV energy range at room temperature. The transport properties have been measured in 2-300K temperature range with and without magnetic field of 0.5T. The influence of the order-disorder structural transition on the magnetic and magneto-optical properties was discussed by using the effective medium approximation and the structural defect approach. That on the temperature dependence of the resistivity was analyzed in a framework of the partial localization of the electronic states and the variable range hopping conductivity.

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Corrosion Behaviour of Fe-XAl-0.3Y Alloys at High Temperature Sulfidation Environment(Ps2=10-3Pa) (Fe-XAl-0.3Y 합금의 고온 황화환경(Ps2=10-3Pa)에서의 부식거동)

  • Lee Byung Woo;Park Hwa Soon
    • Korean Journal of Materials Research
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    • v.14 no.8
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    • pp.547-551
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    • 2004
  • The sulfidation behaviour of Fe-XAl-0.3Y(X=5, 10, 14, 25 $wt.\%$) alloys was investigated at 1123 K in $H_2/H_{2}S$ gas atmosphere for $1\sim24$ hrs using SEM/EDX, XRD and EPMA. The weight changes of Fe-XAl-0.3Y alloys followed the parabolic rate law, Sulfidation rates of iron aluminide alloys with high Al content were one-twentieth lower than that of 5Al alloys. This is due to the formation of protective $Al_{2}O_3$ oxides on the surface of 10Al, 14Al and 25Al alloys. By calculating partial pressure of impurity oxygen contained $H_2/H_{2}S$ gas, the $Al_{2}O_3$ oxides formation could be explained using Fe-Al-S-O thermodynamic stability diagram. The sulfidation product scales of the 5Al alloy showed that thick iron sulfide scale(FeS) containing porosities formed during early stages of sulfidation. With continued sulfidation, aluminum sulfide was formed at the alloy/scale interface.

Al 확산침투처리를 통한 Inconel 617의 코팅층의 상분석 및 고온산화특성평가

  • Im, Jeong-Hun;Jo, Tae-Seon;Kim, Dae-Geon;Kim, Yeong-Do
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.11a
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    • pp.51-51
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    • 2009
  • Ni 기 초내열합금은 원자력 발전설비의 열교환기용 재료를 비롯한 발전용 가스터빈, 제트엔진, 화학공장용 튜브 및 파이프재료 등 우수한 고온 기계적 특성 및 고온 내식성을 요구하는 각종 부품재에 광범위하게 이용되고 있다. Al 확산침투처리는 Ni기 초내열합금에 Al 혼합분말을 이용하여 금속간합화물을 코팅함으로써 고온산화특성 향상에 효과적인 방법이다. 본 연구에서는 Al 확산침투처리를 통하여 Inconel 617 표면에 Aluminide 코팅층을 형성함으로써 고온 내산화특성을 향상시키고자 하였다. Al 확산침투처리는 Al :$Al_2O_3$ : $NH_4Cl$ = 15g : 83g : 2g(wt.%)의 비율의 혼합분말을 사용하여 $900^{\circ}C$에서 1 시간 동안 Ar 분위기에서 수행되었다. Al 확산침투처리 후 $950^{\circ}C$에서 1000 시간 동안 air 분위기에서 열화시험을 수행하였다. Al 확산침투처리 후 고온열화를 통해 고온산화특성을 평가였으며, 고온 열화에 의해 형성된 코팅층의 석출물과 계면상의 상분석을 수행하였다.

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Effect of Cr Addition on the High Temperature Deformation Behavior of Fe-Al Intermetallics (Fe-Al 금속간 화합물의 고온변형거동에 미치는 Cr 첨가의 효과)

  • Bang W.;Lim H. T.;Ha T. K.;Song J. H.;Chang Y. W.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2001.05a
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    • pp.167-171
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    • 2001
  • High temperature deformation behavior of Fe-28Al-5Cr alloy has been investigated known to show anomalous temperature dependence of yield strength. Specifically, the effect of Cr addition has been examined. A series of tensile and load relaxation tests have been carried out to obtain the flow behavior of Fe-28Al-5Cr alloy at the elevated temperatures. The flow curves have then been analyzed using the inelastic deformation theory recently proposed. Firstly, high temperature flow stress of iron aluminides can be resolved into internal stress and frictional stress. Secondly, the temperature corresponding to peak strength gets higher level at faster strain rate, which presumably due to the increased contribution of internal stress in observed flow stress. And thirdly, the alloying of Cr seems to cause solid-solution strengthening of frictional stress level and the elevation of 2nd order transition temperature. In this analogy, Fe-28Al-5Cr exhibits better strength especially at relatively higher temperature and lower strain rate than Fe-28Al.

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Dynamic Oxidation Behaviors of Aluminide Coated Titanium Alloys (알루미나이드 코팅된 티타늄 합금의 동적산화거동)

  • Son, Youngil;Park, Jinsoo;Park, Joonsik
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.5
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    • pp.84-90
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    • 2015
  • Titanium alloys has been received an attention due to their excellent specific strength and many other superior properties in the application of components of flying subjects. In this study, Ti-6Al-4V (Ti64 alloy) has been selected in order to evaluate oxidation and degradation behaviors under the exposure of high temperature flame. The alloy has been coated with Al diffusion coating routes. The coated alloys showed an improved oxidation and degradation behaviors. The oxidation and degradation mechanism for the coated and uncoated alloys has been discussed in terms of microstructural observations.

A Study on the High Temperature Deformation and the Cavity Initiation of Gamma TiAl Alloy ($\gamma$-TiAl 합금의 고온변형 및 Cavity 형성 연구)

  • Kim J. H.;Ha T. K.;Chang Y. W.;Lee C. S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2001.05a
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    • pp.172-175
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    • 2001
  • The high temperature deformation behavior of two-phase gamma TiAl alloy has been investigated with the variation of temperature and ${\gamma}/{\alpha}_2$ volume fraction. For this purpose, a series of load relaxation tests and tensile tests have been conducted at temperature ranging from 800 to $1050^{\circ}C$. In the early stage of the deformation as in the load relaxation test experimental flow curves of the fine-grained TiAl alloy are well fitted with the combined curves of two processes (grain matrix deformation and dislocation climb) in the inelastic deformation theory. The evidence of grain boundary sliding has not been observed at this stage. However, when the amount of deformation is large (${\epsilon}{\approx}$ 0.8), flow curves significantly changes its shape indicating that grain boundary sliding also operates at this stage, which has been attributed to the occurrence of dynamic recrystallization during the deformation. With the increase in the volume fraction of ${\alpha}_2$-phase, the flow stress for grain matrix deformation increases since ${\alpha}_2$-Phase is considered as hard phase acting as barrier for dislocation movement. It is considered that cavity initiation is more probable to occur at ${\alpha}_2/{\gamma}$ interface rather than at ${\gamma}/{\gamma}$ interface.

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Characteristics of Transient Performance in a Turbocharged GDI Engine with TiAl Turbine (TiAl 터빈을 적용한 과급 직분식 전기점화 엔진의 과도운전 성능특성)

  • Park, Chansoo;Jung, Jinyoung;Bae, Choongsik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.23 no.3
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    • pp.299-306
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    • 2015
  • Turbocharged gasoline direct injection engine is one of promising technologies in the automotive industry. However, reduction in turbo-lag under transient operation is one of important challenging points to improve drivability. Engine transient performance was investigated in a 4-cylinder 2.0 L turbo-gasoline direct injection (T-GDI) engine using Inconel and TiAl (Titanium Aluminide alloy) turbine wheel turbochargers. The TiAl turbocharger performed superior transient boost pressure and torque rises under various engine transient operation conditions. These were mainly due to lower turbine rotational inertia of TiAl turbocharger. The Maximum boost pressure and torque build up were founded in 1500 rpm and 2000 rpm, instant load change from 20% to 100% of pedal position.