• 제목/요약/키워드: Aluminate cement

검색결과 83건 처리시간 0.022초

High-velocity impact of large caliber tungsten projectiles on ordinary Portland and calcium aluminate cement based HPSFRC and SIFCON slabs -Part I: experimental investigations

  • Korucu, H.;Gulkan, P.
    • Structural Engineering and Mechanics
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    • 제40권5호
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    • pp.595-616
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    • 2011
  • Impact experiments have been carried out on concrete slabs. The first group was traditionally manufactured, densely reinforced concrete targets, and the next were ordinary Portland and calcium aluminate cement based HPSFRC (High performance steel fiber reinforced concrete) and SIFCON (Slurry infiltrated concrete) targets. All specimens were hit by anti-armor tungsten projectiles at a muzzle velocity of over 4 Mach causing destructive perforation. In Part I of this article, production and experimental procedures are described. The first group of specimens were ordinary CEM I 42.5 R cement based targets including only dense reinforcement. In the second and third groups, specimens were produced using CEM I 42.5 R cement and Calcium Aluminate Cement (CAC40) with ordinary reinforcement and steel fibers 2 percent in volume. In the fourth group, SIFCON specimens including 12 percent of steel fibers without reinforcement were tested. A high-speed camera was used to capture impact and residual velocities of the projectile. Sample tests were performed to obtain mechanical properties of the materials. In the companion Part II of this study, numerical investigations and simulations performed will be presented. Few studies exist that examine high-velocity impact effects on CAC40 based HPSFRC targets, so this investigation gives an insight for comparison of their behavior with Portland cement based and SIFCON specimens.

명반석을 이용한 알루미나 시멘트의 제조(I) (Monocalcium Aluminate의 합성) (Studies on Alumina Cement from Alunite (I) (Synthesis of monocalcium aluminate))

  • 한기성
    • 한국세라믹학회지
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    • 제15권4호
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    • pp.199-204
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    • 1978
  • In the present investigation, refined alumina obtained from alunite locally available was used as a aluminous source to synthesize monocalcium aluminate $(CA)_3$ the major mineral constituent of alumina cement. The influence of $SiO_2$ and $Fe_2O_3$ contents on the formation of monocalcium aluminate was studied by X-ray diffraction analysis mainly. About 0.8-1.0 of $Al_2O_3/C_3O$ mol ratio and less than 4 percent of $SiO_2$ were desirable for the effective formation of CA. The small amount of alkali and sulphur contents contained in refined alumina from alunite as the impurities were affected to form $C_4A_3S$ and $C_3S_2$, disadvantageous compounds for the alumina cement, therefore the impurities should be restricted in minimum content as possible.

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Calcium Sulfo Aluminate (CSA) Cement from Coal Ash Utilized as Barriers for Radioactive Waste Disposal

  • Ramakrishna, Chilakala;Thriveni, Thenepalli;Whan, Ahn Ji
    • 에너지공학
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    • 제27권1호
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    • pp.33-39
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    • 2018
  • In this paper, we reviewed briefly about the barrier materials for the radioactive waste disposal. The primary concept of the radioactive waste disposal is safety. The goal of the radioactive waste management is to assure that the environment is not adversely affected and also public. There are a wide variety of materials are available for the radioactive waste disposal or storage. Among those coal fly ash is one of the significant materials are used as a barrier material. Here we reported, the Calcium sulfo aluminate (CSA) from coal fly ash is effectively suitable for the radioactive waste disposal. This is one of the ways of utilization of waste and manufactured the valuable materials for future indeeds.

저온환경에서 알루미나시멘트를 사용한 모르타르의 단열양생에 따른 기초물성 평가 (Fundamental Properties of Alumina Cement Mortar by Insulation Curing Method under Low Temperature)

  • 박정훈;기경국
    • 한국건축시공학회지
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    • 제17권5호
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    • pp.419-427
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    • 2017
  • 동절기에 콘크리트를 시공할 경우 초기동해와 강도발현이 지연되는 문제가 있으며, 이를 방지하기 위해서는 콘크리트가 동결하기 이전에 시멘트의 수화반응이 일정수준 이하 진행되는 것이 중요하다. 이에 본 연구는 저온에서도 수화열이 높게 발생되는 $Al_2O_3$성분이 함량이 높은 CSA, 알루미나시멘트를 OPC에 치환하여 물성평가를 수행하였다. 그 결과 CSA, 알루미나시멘트를 사용하여 $-5^{\circ}C$의 저온환경에서 초기에 수화반응이 빠르게 진행되며, 급결현상 및 유동성저하현상이 발생되었고, 석고를 사용하여 응결시간을 지연하며 유동성을 확보하여 작업성을 개선하였다. 또한 단열양생공법을 적용하여 모르타르의 동결시간을 지연하였으며 수축보상효과를 증진시켰고 3일, 7일 강도가 증진되었다. 따라서 본 연구 결과 저온환경에서 CSA, 알루미나시멘트 및 석고를 사용하여 조기에 강도발현 증진효과가 우수하였으며, 석고 및 단열양생공법을 적용하여 작업성, 동결저항성, 조기강도 발현 성능이 개선되어 초기동해를 방지하는데 효과가 있을 것으로 판단된다.

하수관거 보수용 CAC 모르타르 성능평가에 대한 실험적 연구 (An Experimental Study on Evaluation of Repair Mortars with CAC (Calcium Aluminate Cement) for Sewer Pipe)

  • 정지승;강원대
    • 한국안전학회지
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    • 제27권4호
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    • pp.68-75
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    • 2012
  • The biogenic corrosion of mortars adopted in sewage repair by sulfuric acid-producing bacteria was considered in this paper. Calcium aluminate cement (CAC) was known to resist microbiologically-induced corrosion significantly better than portland and blended portland cement.In this study, CAC as well portland cement mortars were tested as main binder to evaluate the corrosion resistance by the chemical immersion test. Replacement ratios of CAC were changed as 0, 20, 40, 50, 60% of OPC binder and 0, 2, 4, 6% of EVA(Ethylene Vinyl Acetate) were also adopted to increase properties of CAC repair mortars in sewage application. Setting time, compressive strength, acid resistance and adhesive strength were measured for various experiments. As a results of the experiments, the proper formulation of repair mortars was found at 40% of CAC and 4% of EVA. Finally, the CAC mortars adopted in field sewer pipe and were demonstrated to superior in adhesion and workability.

High-velocity impact of large caliber tungsten projectiles on ordinary Portland and calcium aluminate cement based HPSFRC and SIFCON slabs -Part II: numerical simulation and validation

  • Gulkan, P.;Korucu, H.
    • Structural Engineering and Mechanics
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    • 제40권5호
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    • pp.617-636
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    • 2011
  • We present the numerical implementation, simulation, and validation of the high-velocity impact experiments that have been described in the companion article. In this part, numerical investigations and simulations performed to mimic the tests are presented. The experiments were analyzed by the explicit integration-based software ABAQUS for improved simulations. Targets were modeled with a damaged plasticity model for concrete. Computational results of residual velocity and crater dimensions yielded acceptable results.

CaAl2O4-CaAl4O7 혼입 포틀랜드 시멘트 결합재의 염소이온 고정 특성 (Chloride Binding Properties of Portland Cement Binder Incorporating CaAl2O4-CaAl4O7)

  • 한재도;이윤수;이한승
    • 한국구조물진단유지관리공학회 논문집
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    • 제24권4호
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    • pp.1-9
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    • 2020
  • 본 연구는 철근콘크리트 구조물의 염해 내구성 향상의 일환으로써, 보통 포틀랜드 시멘트에 실험체별 다른 비율의 칼슘 알루미네이트 시멘트와 합성 CA2를 혼입하여 혼입 비율에 따른 염소이온 고정능력을 평가하였다. 침지 후 실험체의 물리·화학적 특성을 압축강도, 공극 구조, 수화물 분석으로 염소이온침투깊이를 EPMA를 통하여 고찰하였다. 클링커 조성에 CA가 34%미만일 경우 실험체의 조밀성이나 강도 발현 양상이 구조재료로서 사용 제한이 없을 것이라고 판단되었으며 CAC와 CA2를 5:5비율로 혼입하여 실험체에 치환한 실험체가 CAC 혹은 CA2만 치환한 실험체보다 염소이온 침투억제능력 과 AFm상 및 프리델 염 생성이 높은 것으로 확인할 수 있었다. 결과적으로, 시멘트 페이스트 대비 칼슘 알루미네이트 클링커 치환율이 증가함에 따라 일반적으로 염소이온 고정능력이 향상하였고, CA-CA2비율에 따라 염소이온 고정 능력 및 염소이온 침투억제 능력에 차이가 있음을 확인할 수 있었다. 실험 범위 내에서 CA-CA2비율이 39:60이며 시멘트 페이스트 대비 10% 치환한 실험체인 M 10 가 가장 우수한 것으로 나타났다.