• Title/Summary/Keyword: Alum

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Comparison of Low Concentration and High Concentration Arsenic Removal Techniques and Evaluation of Concentration of Arsenic in Ground Water: A Case Study of Lahore, Pakistan

  • Yasar, Abdullah;Tabinda, Amtul Bari;Shahzadi, Uzma;Saleem, Pakeeza
    • Korean Chemical Engineering Research
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    • v.52 no.5
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    • pp.620-626
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    • 2014
  • The main focus of this study was the evaluation of arsenic concentration in the ground water of Lahore at different depth and application of different mitigation techniques for arsenic removal. Twenty four hours of solar oxidation gives 90% of arsenic removal as compared to 8 hr. or 16 hr. Among oxides, calcium oxide gives 96% of As removal as compared to 93% by lanthanum oxide. Arsenic removal efficiency was up to 97% by ferric chloride, whereas 95% by alum. Activated alumina showed 99% removal as compared to 97% and 95% removal with bauxite and charcoal, respectively. Elemental analysis of adsorbents showed that the presence of phosphate and silica can cause a reduction of arsenic removal efficiency by activated alumina, bauxite and charcoal. This study has laid a foundation for further research on arsenic in the city of Lahore and has also provided suitable techniques for arsenic removal.

Characteristics of Adsorption on the RO Membrane Surface by Coagulants Types (응집제 종류에 따른 RO막 표면 흡착 특성)

  • Jeong, Youngmi;Park, Chanhyuk;Lee, Sanghyup;Kweon, Jihyang
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.4
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    • pp.477-483
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    • 2007
  • A coagulation process for RO (reverse osmosis) membrane pretreatment system was an effective technology to remove colloidal and particulate matters. However, coagulant residuals from the pretreatment process may negatively affect RO membrane performance. The bench-scale coagulant exposure study was performed to investigate the effect of their residual on adsorbed mass which related to the membrane performance. Coagulant addition in this study ranged from 0 to 5mg/L ferric chloride, alum, and 2mg/L cationic polymer(poly-di-methyldiallyl ammonium chloride) as coagulant aids. This results showed that adsorbed mass is not significantly increased during short-time period, however, accumulated mass of coagulants on the membrane surface is significantly increased during long-time experimental period. The effect of pH on coagulants adsorption characteristics was significantly differed due to the electrostatic repulsive interactions between soluble coagulants and membrane surface charge. This data suggest that the RO membrane performance of drinking water treatment plant could be decreased by adsorption of residual coagulants when applied for the coagulant pretreatment process.

POTABLE WATER TREATMENT BY POLYACRYLAMIDE BASE FLOCCULANTS, COUPLED WITH AN INORGANIC COAGULANT

  • Bae, Young-Han;Kim, Hyung-Jun;Lee, Eun-Joo;Sung, Nak-Chang;Lee, Sung-Sik;Kim, Young-Han
    • Environmental Engineering Research
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    • v.12 no.1
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    • pp.21-29
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    • 2007
  • For this study, we polymerized polyacrylamide base flocculants (PAA) and tested their properties and settling efficiency as a treatment for potable water. The most common chemicals for potable water treatment in Korea are alum or PAC. However, due to various reasons (such as rainy season or algae), inorganic flocculants cannot be solely depended on to solve all the problems caused by the poor quality of inflow water. When PAA coupled with coagulants in a potable water purification process is used, the turbidity removal efficiency increases by a factor of three on a single chemical system using PAC (Raw water: 5.21 NTU; Treated PAA+PAC: 0.34 NTU; and, Treated PAC: 1.04 NTU). It is possible to offset the toxic effect of residual monomers in treated water using PAA, because the concentrations of residual acrylamide are less than 400 mg/L in the polymer itself and less than $0.04\;{\mu}g/L$ in the treated water base at a dosage of 0.1 mg/L. Therefore, PAAs may be a workable, and dependable, potable water treatment process for the high pollutant level of resource water.

Addition of Coagulants for Phosphorus Removal from Combined Sewer Overflows (CSOs) (합류식 하수관거 월류수의 인제거를 위한 응집제 투여)

  • Son, Sang-Mi;Jutidamrongphan, Warangkana;Park, Ki-Young
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.2
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    • pp.295-302
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    • 2012
  • The coagulation of combined sewer overflows ($CSO_{s}$) was investigated by jar-testing with several commercial coagulants. $CSO_{s}$ sample showed different characteristics of coagulation from secondary wastewater with three common coagulants, aluminum sulfate, ferric chloride and polyaluminum chloride (PACl). Jar-tests showed that relatively wide range of optimal SS and T-P removal yielded with alum and ferric chloride compared with cationic polymers, though efficient SS and T-P removal can be achieved with all three coagulants. The decrease of pH was caused by the increase in dosage of aluminum sulfate, ferric chloride and PACl as coagulants. The pH was changed from 7.0 to 4.7 with the dosages of ferric chloride 25 mL/L. Aluminum sulfate revealed pH of 5.0 and PACl was highest pH of 5.4 after dosing of coagulants. The optimal pH to treat $CSO_{s}$ with aluminum sulfate were 6-6.5; with PACl 6-7, and with ferric chloride higher than 7.

A study on the optimized coagulation for separation of liquid and solid from CMP waste (CMP 폐액의 고액 분리를 위한 최적 응집조건에 관한 연구)

  • Hong, Seongho;Oh, Suckhwan
    • Clean Technology
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    • v.7 no.1
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    • pp.27-34
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    • 2001
  • The waste slurry generated from CMP process contains particulate and heavy metals. It is hard to treat the waste slurry by conventional treatment method because the particulates in the waste are too fine to be easily separated the solid from the waste for the purpose of water recycling. The investigation was focused on finding the optimum condition of coagulation with two different coagulants. When the solid content in the waste slurry solution was 0.1wt%, the optimal ranges of pH and PACl concentration were 4~6 and 20~50 mg/L, respectively. When the solid content was increased to 0.5wt%, the optimal condition was 4~5 for pH and 50~100 mg/L for PACl concentration.

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Effect of Experimental Factors on Manganese Removal in Manganese Sand Filtration (망간모래여과공정에서 망간제거에 미치는 영향인자)

  • Kim, Berm-Soo;Yoon, Jaekyung;Ann, Hyo-Won;Kim, Chung-Hwan
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.1
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    • pp.86-93
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    • 2006
  • In the drinking water treatment, the aesthetic and color problem are caused by the manganese which is occurring and present in the surface, lake and ground water. The most common treatment processes for removing manganese are known for oxidation followed by filtration. In this study, the manganese sand process was used for removing manganese with river bank filtrate as a source. In the manganese sand process, the residual chlorine and pH are important factors on the continuous manganese oxidation. In addition, space velocity (SV) and alum dosage are play a role of manganese removal. Even though manganese removal increased with increasing chlorine concentration, the control of residual chlorine is actually difficult in this process As the results of tests, the residual chlorine concentration as well as manganese removal were effectively achieved at pH 7.5. The optimum attached manganese concentration on manganese sand was confirmed to 0.3mg/L by the experimental result of a typical sand converting to manganese sand.

Pollutant Removal and Characteristic of Floc by PACI Coagulation (PACI을 이용한 오염물질 제거 및 입자 특성에 관한 연구)

  • Moon, Byung-Hyun;Kim, Seung-Hyun;Lee, Hyang-In
    • Journal of Korean Society on Water Environment
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    • v.16 no.4
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    • pp.459-468
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    • 2000
  • This study is to investigate the floc structure and removal of turbidity and organic matter by PACI coagulation. The turbidity removal by PACI coagulation was obtained at larger pH range than alum coagulation. And the removal of organic matter was obtained at smaller pH range than that of turbidity. The organic matter was removed by the adsorption of $Al(OH)_3$ precipitates. Floc structure was characterized by measuring fractal dimension and volume diameter using AIA and SALLS. Fractal dimension measured by AIA did not show the different characteristics of floc produced in sweep floe and charge neutralization region. Using SALLS, floes in sweep floc region were found to be larger size and fractal dimension than flocs in charge neutralization region. As pollutant removal increased. larger fractal dimension and size of floc were measured. SALLS method was found to be more useful method to characterize flocs in coagulation than AIA method.

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Effect of Sustained-Release of Adenosine by Elvax 40P Implant on Mouse Mammary Development (생쥐의 유선발달에 있어서 Elvax 40P Implant를 이용한 서방형 Adenosine의 역할)

  • 여인서;박춘근;홍병주
    • Korean Journal of Animal Reproduction
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    • v.16 no.4
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    • pp.387-397
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    • 1993
  • To examine local response of adenosie(purine nucleoside) on the developing mammary gland, Elvax 40P implants containing adenosine were surgically implanted into mammary fat pad of the five week old female ICR mice. Inguinal(the 4th) mammary glands of anesthetized mice were exposed andplaced the implants for 12 days. One gland was treated with an adenosine implant, while the contralateral gland received a blank implant as control. For whole-mount preparations, glands were stained with alum carmine, and for histological observation, micro-selected mammary glands were stained with hematoxylin and eosin Y. Implantation with Elvax 40P did not affect on the damage of neighboring mammary tissue. Adenosie 25 or 250$\mu\textrm{g}$ per slow-release implant stimulated local mammary end bud formation of ovariectomized mice such as end bud size and numbers of end bud per gland in a dose dependent manner(P<0.05), and lower concentration of adenosie(2.5 or 25$\mu\textrm{g}$/implant) increased numbers of end bud(P<0.05) and end bud size(P<0.1) of intact mice. Adenosine treatment and intact ovarian function had moderate interation effects on the stimulation of end bud formation at 2.5$\mu\textrm{g}$ adenosine/implant(P<0.1). In histological observation, adenosine implants increased numbers of mammary epithelial type of cells at mammary duct in the presence or absece ofovary. These results indicate that adenosine should be one of regulators in mouse mammary ductal growth.

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Antigenicity Study of Recombinant Human Erythropoietin (천연형 사람 적혈구 조혈인자의 항원성시험)

  • Kang, Kyung-Koo;Cho, Hyeon;Baik, Nam-Gi;Kim, Won-Bae
    • Biomolecules & Therapeutics
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    • v.6 no.1
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    • pp.50-55
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    • 1998
  • Antigenic potential of a recombinant human erythropoietin (rhEPO) produced by Dong-A charm. Co. Ltd. was examined by active systemic anaphylaxis (ASA) test in guinea pigs, mouse-rat passive cutaneous anaphylaxis (PCA) reaction and passive hemagglutination (PHA) test. In ASA test, rhEPO induced the signs of restlessness, rubbing or licking nose, sneezing and coughing in the animals immunized with rhEPO 1000 lU/kg alone or rhEPO 1000 lU/kg incorporated into Freund\\\\`s complete adjuvant. In the mouse-rat PCA test, only one of six sera from the animals immunized with rhEPO 1000 lUng incorporated into Alum showed positive result. In the PHA test, rhEPO revealed negative results in all of the rhEPO-immunized groups. From these results, rhEPO was considered to produce IgE in guinea pigs and mice, but not IgG and/or IsM in mice. The results of this study were similar to those of the other recombinant human erythropoietin and these positive results were thought to be caused due to the fact that rhEPO were heterogeneous proteins to guinea pigs and mice. Considering the fact that rhErO has an identical structure with indigenous human erythropoietin, rhEPO is not thought to cause immunological problems in clinical use.

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Application of Coagulation-UF Hybrid Membrane Process for Reuse of Secondary Effluent (하수 2차 처리수 재이용을 위한 hybrid 응집-UF 막분리 공정의 적용)

  • Lee, Chul-Woo;Shon, Jung-Ki;Shon, In-Shik;Han, Seung-Woo;Kang, Lim-Seok
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.5
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    • pp.605-612
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    • 2005
  • The objective of this study was to evaluate the factors affecting the optimization of coagulation hybrid UF membrane processes for the reuse of secondary effluent from sewage treatment plant. The experimental results obtained from the UF membrane process showed that organic colloids in the size range of $0.2{\mu}m{\sim}1.0{\mu}m$ caused the most substantial influence on the fouling of UF membrane. When using a coagulation pretreatment to UF membrane, alum dosage of 50mg/L resulted in the least reduction in membrane permeate flux. Also, for the rapid mixing process, in-line mixer type was more efficient for organic removal than back mixer type. Therefore, it may be concluded that coagulation-UF hybrid membrane process comparing to UF alone process showed not only higher removal efficiency of organic matter, but also substantial improvement of permeate flux of UF membrane.