• 전기화학회지
• /
• 제7권2호
• /
• pp.80-82
• /
• 2004

The a.c. technique is employed to evaluate electrochemical characteristics of Naphthalie-1,4,5,8-tetracarboxylic acid bisanilide (NTB). The measurements were carried out in dry and pure propionitrle (PCN) and acetonitrile(CAN) at the hanging mercury drop electrode [HMDE). An A.C. phase sensitive detector using computer controlled lock-in amplifier was employed. Primary goal of this report, was to establish on a firm the rare behavior of the phase angle associated with a.c. polarograms of the compound. Although, not an initial goal of this study, the electron transfer rate parameters attending the electroreduction of the compound under investigation were determined. This because the results shed some light on the electrokinetics in aprotic solvent which until recently negligible data were available. Experimental Results and comparison of data obtained are reported. The good precision of the method makes it suitable for studying electrochemical data with unusual behavior at electrodes in non aqueous media.

• 전기의세계
• /
• 제18권4호
• /
• pp.7-15
• /
• 1969

In this method the condenser excite winding has the phase angle of 90 electrical degree, with the load winding in stator. The condenser excite wing is connected with the condenser while the load winding is with the full rectifer. Direct and quardrature axis components of rotating field winding are composed, of balanced two phase winding, and each one of them is connected with half wave rectifiers. Initically, small amount of lead current can be induced at the condenser excite winding by residual magnetism of rotor. The induced lead current forces the rotating field winding to be excited by synchronous alternating magnetic field. The speed electromotive force, there for, induced in rotating field winding shall electro magnetize the rotating field pole by rotating half wave rectifiers. In the case of the charging generator directly coupled with engines at the operation of wide range speed, the generated region, such as vehicles, aircraft, ships etc, is occured. In conclusion, we can take the advantage of, omitting of voltage regurator and current limiter for charging load and reducing the consumption of fuel using the generated region which can be devided in to Impossible generated region, Generated region, and suspension generated region.

• 전기의세계
• /
• 제14권2호
• /
• pp.1-7
• /
• 1965

This paper describes the commutation current and ignition angle of current which occures in the combination of silicon rectifier with synchronous generator when the constants of rectifier circuits parameters are changed. This is precisely accomplished by setting-up the analog computer with voltage generating circuits and non-linear elements circuits. When the characteristics of rectification are properly selected in the simulation, this method is able to extend to the connection of SCR and electric machinery. We also expect that this method is helpful to the investigation of characteristics, and design of alternating exciters, self-excited synchronous generators instead of D-C machines.

• 한국멀티미디어학회논문지
• /
• 제19권7호
• /
• pp.1146-1153
• /
• 2016

The bioelectrical impedance (BI) at the inner forearms was measured using bioelectrical impedance measurement system (BIMS), which employs the multi-frequency and the two-electrode method. Experiments were performed as follows. First, while applying a constant alternating current of 800A to the inner region of the forearms, BI (Z) was measured at nineteen frequencies ranging from 5 to 500 kHz. The prediction marker (PM) was calculated for right and left forearm. The resistance (R) and the reactance (X_c) were simultaneously measured during impedance measurement. Second, a Cole-Cole plot (relationship between reactance and resistance) was obtained for left and right forearm, indicating the different characteristic frequencies (f_c). Third, the phase angle was obtained, indicating strong dependence on the applied frequency.

• 분석과학
• /
• 제12권4호
• /
• pp.290-298
• /
• 1999

임피던스 위상각 적정법을 산화환원적정, 산염기적정, 착화적정 그리고 침전적정에 적용하여 정확한 종말점 검출법을 연구하였다. 일정한 교류전류가 두 백금전극사이를 통과하도록 하였고 그중 하나는 $0.1cm^2$ 또는 $0.026cm^2$의 표면적을 가진 초소형 분극전극이었고 다른 하나는 $1cm^2$의 표면적을 비분극전극을 사용하였다. 과망간산칼륨에 의한 옥살산의 산화환원적정에서 임피던스 위상각 적정법을 적용하였을때 $50{\mu}A$, 0.0005 M 이상의 농도에서 뚜렷한 종말점을 얻었고, 50 Hz 근방의 주파수 영역에서 가장 확실한 종말점을 얻을 수 있었다. NaOH에 의한 인산의 산염기 적정에서 0.001 M 수산화나트륨에 의한 0.001 M 인산의 적정시 임피던스 위상각 적정법을 적용하여 $50{\mu}A$, 주파수 25-97 Hz의 넓은 주파수 영역에서 뚜렷한 제1당량점을 얻었다. 이는 전도도의 반대 개념으로서의 임피던스의 변화량이 종말점을 기점으로 변곡하고 이에따라 위상각이 변화하는데 원인됨을 알았다. 또한 제2당량점에서는 임피던스 위상각 적정법으로 뚜렷한 종말점을 얻지 못하였다. 이는 $Na_2HPO_4$의 가수분해를 막기 위하여 적정시 과량으로 첨가되는 NaCl에 의한 방해로 생각된다. 0.1 M EDTA에 의한 0.01 M 황산구리의 착화적정시에는 위상각 측정으로 적정종말점을 찾기 보다는 "다른위상" 임피던스 Z"을 측정하여 종말점을 알아내는 것이 유리함을 알았다. $AgNO_3$에 의한 $Cl^-$의 침전적정에 있어 $100{\mu}A$, 0.1 M 농도에서 임피던스 위상각 적정법을 적용하여 명확한 종말점을 얻었고, 15-30Hz 범위에서 가장 안정적인 뚜렷한 변화를 볼 수 있었다. 그러나 0.01 M 농도에서는 임피던스 위상각의 뚜렷한 변화를 볼 수 없었다. 본 연구에서 임피던스 위상각 적정법을 산화환원적정, 산염기적정, 착화적정 그리고 침전적정시의 종말점 검출을 위해 사용하였을 때 대부분 성공적이었으며 이는 적정시 종말점을 정확히 측정하는 목적에 활용 할수 있음을 보여주는 것이다.