• Title/Summary/Keyword: All-Organic

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Composition and Evaluation of the Thermal Desorption-Gas Chromatographic System for the Measurement of Volatile Organic Compounds in Air (공기 중 휘발성 유기화합물의 측정을 위한 열탈착-분석시스템의 구성 및 평가)

  • 이수형;송희남;김희갑
    • Environmental Analysis Health and Toxicology
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    • v.17 no.1
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    • pp.63-71
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    • 2002
  • The thermal desorption-gas chromatographic (TD-GC) system has been constructed for the measurement of volatile organic compounds. The thermal desortion unit is composed of four major parts: 1) the control part; 2) the thermal desorption part; 3) the focusing part; and 4) the injection part. The peltier element was introduced to the focusing part for the temperature of the focusing tube to reach-35$^{\circ}C$. The system was tested for the linearity of the calibration curves and reproducibility of instrumental analyses using some disinfection by-products (DBPs) and BTXs (benzene, toluene and p-xylene). The coefficients of determination (r$^2$) for all the calibration curves made were higher than 0.998, and the coefficients of variation (CV) for triplicate measurements were all within 10%. The system also has been tested for field applicability. The analysis of field samples showed that there was no breakthrough problem in the sampling system and that the system could be applied to field measurements.

Zinc Chloride Toxicity on Free Proline and Organic Acids in Germinating Rice Seed

  • Kim, Sang-Kuk;Chung, Sang-Hwan;Lee, Sang-Chul;Lee, Seong-Phil
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.44 no.2
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    • pp.163-165
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    • 1999
  • The study was conducted to find the critical concentrations of zinc toxicity and to determine the changes of the contents of free proline and organic acids with treatment of different zinc chloride concentrations during rice germination and seedlings grown for seven days. The concentration of zinc chloride, 140 ppm, inhibited root elongation as much as 46 times compared with the control, and the germination rate was also decreased in all treatments of zinc chloride, showing that the germination rate decreased more with increasing concentrations of zinc chloride. Its rate was only 13% with treatment of 140 ppm zinc chloride. The content of free proline with treatment of zinc chloride, 140 ppm, was highest about 4,873 $\mu$M at 3 days compared with the control. Malic acid concentration with treatment of zinc chloride, 140 ppm, increased to approximately 4 times compared to the control. Citric and succinic acid content were also slightly increased in all treatments of zinc chloride.

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Electrical properties of Organic TFT patterned by shadow-mask with all layer

  • Lee, Joo-Won;Kim, Jai-Kyeong;Jang, Jin;Ju, Byeong-Kwon
    • Proceedings of the IEEK Conference
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    • 2006.06a
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    • pp.543-544
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    • 2006
  • Pentacene thin film transistors fabricated without photolithographic patterning were fabricated on the plastic substrates. Both the organic/inorganic thin films and metallic electrode were patterned by shifting the position of the shadow mask which accompanies the substrate throughout the deposition process. By using an optically transparent zirconium oxide ($ZrO_2$) as a gate insulator and octadecyltrimethoxysilane (OTMS) as an organic molecule for self-assembled monolayer (SAM) to increase the adhesion between the plastic substrate and gate insulator and the mobility with surface treatment, high-performance transistor with field effect mobility $.66\;cm^2$/V s and $I_{on}/I_{off}$>$10^5$ was formed on the plastic substrate. This technique will be applicable to all structure deposited at low temperature and suitable for an easy process for flexible display.

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All printed organic thin film transistors with high-resolution patterned Ag nanoparticulate electrode using non-relief pattern lithography

  • Eom, You-Hyun;Park, Sung-Kyu;Kim, Yong-Hoon;Kang, Jung-Won;Han, Jeong-In
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.568-570
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    • 2009
  • Octadecyltrichlorosilane (OTS) self-assembled monolayer was selectively patterned by deep ultraviolet exposure, resulting in differential surface state, hydrophilic area with OTS hydrophobic surroundings. High-resolution (<10 ${\mu}m$) nanoparticulate Ag electrodes and organic semiconductors were patterned from simple dip-casting and ink-jetting on the pre-patterned hydrophilic surface, forming all solution-processed organic thin film transistors. The devices typically have shown a mobility of 0.065 $cm^2/V{\cdot}s$ and on-off current ratio of $8{\times}10^5$.

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Synthesis and Characterization of Fluorinated Polybenzoxazole Copolymers

  • Sohn, Jeong Sun;Park, A Ram;Choi, Jae Kon
    • Elastomers and Composites
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    • v.50 no.3
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    • pp.175-183
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    • 2015
  • A series of fluorinated aromatic poly(hydroxyamide)s (PHAs) were synthesized by direct polycondensation of diacides containing 2,6-dimethylphenoxy group and quinoxaline ring in the main chain with 2,2-bis-(3-amino-4-hydroxyphenyl) hexafluoropropane. The PHAs had relatively low inherent viscosities in the range of 0.35~0.43 dL/g at $35^{\circ}C$ in DMAc solution. All PHAs exhibited excellent solubility in aprotic solvents such as NMP, DMAc, DMF and DMSO as well as in common organic solvents such as pyridine, THF, and m-cresol at room temperature. However, the poly(benzoxazole)s (PBOs) were quite insoluble in all organic solvents except partially soluble in concentrated sulfuric acid. The PBOs showed glass transition temperatures between 233 and $284^{\circ}C$ by DSC and maximum weight loss temperatures in the range of $536-546^{\circ}C$ by TGA.

Fibers Flocculation and Physical Properties Changes of Paper Depending on Microparticle Retention Mechanisms (마이크로파티클 보류 기작에 따른 섬유의 응집 및 종이 물성 변화)

  • Yoon, Doo-Hoon;Park, Jong-Moon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.4 s.107
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    • pp.25-32
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    • 2004
  • Flocculation of fibers and its distribution in paper are related to flocculation mechanisms, retention and drainage. Relationship between flocculation mechanisms and physical properties of paper has not been fully studied. In this study, flocculation of fibers was investigated by changing microparticles for flocculation mechanism analysis. When fillers were not added, formation and strength were deteriorated by 100, 300, or 500 ppm of linear PAM (all L-PAM), All L-PAM + 1200 ppm inorganic microparticle (1200-IM), all L-PAM + 120 ppm organic microparticle (120-OM), all L-PAM + 1200 ppm organic microparticle (1200-OM) because of too much flocculation. When 5, 15, $25\%$ (od.w/w) fillers were added, retention and drainage process were not affected by the extent flocculation when 500 ppm L - PAM, 500 ppm L - PAM + 1200- IM, and 500 ppm L - PAM + 120 ppm OM were added.

Anti-inflammatory activity of organic germanium

  • Yoon, Mi-Yun;Cho, Nam-Young;Kim, Kyung-Won;Lee, Ji-Yun;Kim, Chang-Jong;Sim, Sang-Soo
    • Proceedings of the PSK Conference
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    • 2003.04a
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    • pp.191.1-191.1
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    • 2003
  • Germanium is present in all living plant and animal matter in micro-trace quantities. Clinical trials and use in private practices for more than a decade have demonstrated germanium's efficacy in treating a wide range of serious afflications. including cancer, arthritis and senile osteoporosis. To investigate anti-inflammatory activity of organic germanium, we measured the effect of organic germanium on histamine release, (omitted)

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Effects of Nutrient Source on Soil Physical, Chemical, and Microbial Properties in an Organic Pear Orchard (유기질 비료 급원이 배 과원의 토양 물리화학성 및 미생물성에 미치는 영향)

  • Choi, Hyun-Sug;Li, Xiong;Kim, Wol-Soo;Lee, Youn
    • Korean Journal of Environmental Agriculture
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    • v.30 no.1
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    • pp.16-23
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    • 2011
  • BACKGROUND: This study was conducted to investigate the effects of different organic treatments and a chemical fertilizer on the soil chemical, physical, and microbial properties in an organic pear orchard. METHODS AND RESULTS: Control was referred as a NPK chemical fertilizer (15N-9P-10K) and organic treatments included compost containing with oil cake, compost containing with humic acid, and compost containing with chitin substance. All treatments applied at rates equivalent to 200 g N per tree per year under the tree canopy in March 30 of 2008 and 2009. Soil bulk density, solid phase, liquid phase, and penetration resistance were not significantly different among the treatments. Organic treatment plots had greater organic matter, total nitrogen, potassium, and magnesium concentrations compared to control, and the nutrient concentrations were not consistently affected by the organic treatments. Microbial biomass nitrogen and carbon, dehydrogenase, acid-phosphatase, and chitinase activities overall increased from March to August. Organic treatments, especially compost containing with oil cake or chitin aicd, increased the microbial variables compared to control. CONCLUSION(s): All the organic treatments consistently stimulated soil biological activity. The consistent treatment effect, however, did not occur on the soil mineral nutrition as the trees actively taken up the nutrients during a growing season, which would have diminished treatment effects. Long-term study required for evaluating soil physical properties in a pear orchard.

Comparison of Organic Matter Distribution in Major Tributaries of the Nakdong River (낙동강 지류하천에서 TOC와 COD 유기물의 분포 비교)

  • Kim, Heung-Seop;Hong, Jong-Jin;Seong, Jin-Uk;Choi, Kwang-Soon;Park, Je-Chul
    • Journal of Korean Society on Water Environment
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    • v.29 no.5
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    • pp.618-624
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    • 2013
  • This study was conducted to suggest the concentration distribution of organic matters in 348 tributaries of Nakdong River, and to review the validity of the conversion of organic matter indexes. The average concentration of organic matters in the tributaries was TOC 2.4 mgC/L, DOC 2.1 mgC/L, COD 1.0 mgC/L, respectively. DOC ratio to TOC is 87% and COD ratio is 44%. First tributaries shows higher organic pollution than second tributaries. The correlation between TOC and COD was relatively high as 0.796 (p < 0.01, n = 670). Based upon these results, a regression analysis was conducted. The results showed that TOC concentration was 2.5 times higher than COD concentration. In conclusion, it is appropriate to use TOC for the management of all organic matters. Furthermore, there is a need to build organic matter-related Databases for more rivers so as to establish TOC standards and manage the water quality.

Behavior of Hazardous Organic Compounds in Low-Pressure Nanofiltration Process (저압 나노여과 공정에서의 유해성 유기물질의 거동)

  • Oh, Jeong-Ik;Lee, Seockheon;Lee, Bo-Young
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.2
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    • pp.165-173
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    • 2004
  • Behavior of hazardous organic compounds including bisphenol A, phtalic acid, and phosphoric acid in low pressure nanofiltration process were investigated. In the case of NTR729HF, rejection of all target organic compounds except 2-H-Benzothiazol and 2-isopropyl phenol was more than 90%. The lowest rejection for 2-H-Benzothiazol was observed in another membranes. The UTC60 and UTC20 showed similar rejection characteristics of hazardous organic compounds. Although the rejection of Bisphenol A, n-buthyl benzenesulfoneamide, N-ethyl-p-toluensulfonamide, 2-H-benzothiazol, p-t-butylphenol and 2-isopropyl phenol was less than 30%, the rejection of tributyl phosphate, triethyl phosphate, camphor, 2,2,4 trimethyl 1,3 pentandiol and diphenyl amine was more than 90% in the case of UTC60 and UTC20. The rejection characteristics of various hazardous organic compounds were converted into one parameter Ks, which was proposed in the diffusion-convection model. The Ks of hazardous organic compounds were discussed by comparing with their solute size represented by Stokes radius. The diffusion convection model considering Ks was successful to interpret rejection characteristics of hazardous organic compounds by low-pressure nanofiltration membranes.