• Title/Summary/Keyword: All ceramic system

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Improving Thermal Resisting Property of PZT Ceramics by Thermal Aging (열에이징에 의한 PZT세라믹스의 내열특성 개선)

  • Lee, Gae-Myung;Kim, Byung-Hyo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.18 no.1
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    • pp.43-49
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    • 2005
  • Temperature stabilities of resonance frequencies of the substrates are very important in piezoelectric ceramics oscillators and fitters. In this study, it was investigated thermal resisting property of the length-extensional vibration mode of PZT ceramics. The mode can be utilized in fabricating ultra-small 55 kHz IF devices. We fabricated the ceramic specimens with x = 0.51, 0.52, 0.53, 0.54, and 0.55 in the Pb(Zr$\sub$x/Ti$\sub$1-x/)O$_3$ system. And their resonance frequencies were measured before 1st thermal aging, after 1st and 2nd thermal aging. In order to investigate the influence of thermal aging on thermal resisting properties, thermally aged specimens were once mote thermally aged. Before 1st thermal aging, the specimens of the compositions with morphotropic phase, x = 0.53 and rhombohedral phase, x = 0.54 have weak thermal resisting property of resonance frequency, while tetragonal phase, x = 0.51 has robust thermal resisting property of resonance frequency. 1st thermal aging improved thermal resisting property of resonance frequency in all specimens.

Hybrid Technique for Active Vibration Control of Plate using Piezoceramic Actuators/Sensors (압전 작동기/감지기를 이용한 평판의 혼합형 능동 진동제어 기술)

  • Kim, Yeung-Sik;Lee, Chul;Kim, In-Soo
    • Journal of KSNVE
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    • v.10 no.6
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    • pp.1048-1058
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    • 2000
  • Thipaper presents a methodology to suppress the vibration of thin rectangular plate clamped all edges using piezo-ceramic material as actuators and sensors. Dynamic characteristics of the structure bonded with distributed actuators/sensors are identified by the Multi-Input Multi-Output (MIMO) frequency domain modeling technique based on the experimental data. Hybrid control scheme is adopted and feedback controller is designed by LQG(Linear Quadratic Gaussian). Feedforward controller is adapted by multiple filtered -$x$ LMS(least mean square) algorithm. Experiment result demonstrates the effective reduction of the vibration label for both the transient and persistent external disturbances.

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Microwave Dielectric Properties of $CaTiO_3-(Li_{1/2}Nd_{1/2})TiO_3$ ceramics ($CaTiO_3-(Li_{1/2}Nd_{1/2})TiO_3$계 세라믹스의 마이크로파 유전특성)

  • Yoon, Jung-Rag;Heo, Young-Kyu;Lee, Heon-Yong
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1459-1461
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    • 1997
  • The microwave dielectric ceramic properties of $CaTiO_3-(Li_{1/2}Nd_{1/2})TiO_3$ were investigated. The solid solution of $CaTiO_3-(Li_{1/2}Nd_{1/2})TiO_3$ had the perovskite structure in the range of all composition. The dielectric constant and temperature coefficient of resonant frequency of solid solution were decreased with the contend of $(Li_{1/2}Nd_{1/2})TiO_3$, whereas, the $Q{\times}f$ value was increased. In the $(1-X)CaTiO_3-X(Li_{1/2}Nd_{1/2})TiO_3$ system, the microwave properties could be controlled by the variation of X, X is weight fraction. Typical value of K=119, $Q{\times}f=2970$ and $TCF=14ppm/^{\circ}C$ were obtained for $0.2CaTiO_3-0.8(Li_{1/2}Nd_{1/2})TiO_3$.

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Structural Characterization of the (TEX)$Sr_2Co_0.5Nb(Ta)_0.5O_4$(/TEX) and (TEX)$Sr_3CoNb(Ta)O_7$(/TEX)

  • Jo, Han Sang;Ri-Zhu Yin;Ryu, Gwang Hyeon;Yu, Cheol Hyeon
    • Bulletin of the Korean Chemical Society
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    • v.21 no.7
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    • pp.679-684
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    • 2000
  • The Sr2Co0.5Nb(Ta)0.5O4 and Sr3CoNb(Ta)O7 compounds, both with Ruddlesden-Popper structures, have been synthesized by the ceramic method at $1150^{\circ}C$ under atmospheric pressure. The crystallographic structure of the compounds was assigned to the tetr agonal system with space group 14/mmm by X-ray diffraction(XRD) Rietveld refinement. The reduced lattice volume and lattice parameters increased as the Ta with 5d substitutes for the Nb with 4d in the compounds. The Co/Nb(Ta)O bond length has been determined by X-ray absorption spectroscopic(EXAFS/XANES) analysis and the XRD refinement. The CoO6,octahedra were tetragonally distorted by elongation of Co-O bond along the c-axis. The magnetic measurement shows the compounds Sr2Co0.5Nb(Ta)0.5O4 and Sr3CoNb(Ta)O7 have paramagnetic properties and the Co ions with intermediate spin sates between high and low spins in D4h symmetry. All the compounds showed semiconducting behavior whose electrical conductivity increased with temperature up to 1000 K. The electrical conductiviy increased and the activation energy for the conduction decreased as the number of perovskite layers increased in the compounds with chemical formula An+1BnO3n+1.

A Deterministic Safety Assessment of a Pyro-processed Waste Repository (A-KRS 처분 시스템 결정론적 안전성 평가)

  • Lee, Youn-Myoung;Jeong, Jongtae;Choi, Jongwon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.10 no.3
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    • pp.171-188
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    • 2012
  • A GoldSim template program for a safety assessment of a hybrid-typed repository system, called "A-KRS," in which two kinds of pyro-processed radioactive wastes, low-level metal wastes and ceramic high-level wastes that arise from the pyro-processing of PWR nuclear spent fuels are disposed of, has been developed. This program is ready both for a deterministic and probabilistic total system performance assessment which is able to evaluate nuclide release from the repository and farther transport into the geosphere and biosphere under various normal, disruptive natural and manmade events, and scenarios. The A-KRS has been deterministically assessed with 5 various normal and abnormal scenarios associated with nuclide release and transport in and around the repository. Dose exposure rates to the farming exposure group have been evaluated in accordance with all the scenarios and then compared among other.

Comparative analysis of men's slim pants patterns - Using a 3D CLO virtual garment system - (남성 슬림 팬츠 패턴 비교 분석 - 3D CLO 가상착의 시스템을 활용하여 -)

  • Kim, Kyung-A;Hong, Eun-Hee;Uh, Mi-Kyung
    • The Research Journal of the Costume Culture
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    • v.22 no.4
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    • pp.605-618
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    • 2014
  • This study aims to compare the ease of men's slim pants patterns, and to analyze the fit and appearance through the 3D virtual garment system. The study selected four educational materials and one industrial pattern of slim pants for a total of five items. The CLO 3D Modelist program was utilized to carry out the appearance evaluation through virtual wearing and opacity, and a comparison was performed regarding the clothing pressure when the virtual model was standing and walking. The results of our comparison of the patternmaking for slim pants showed that pattern C pants had the greatest ease on the waist circumference, while B pants showed no ease. The C and E pants also had the most ease on the hip measurement. In the appearance evaluation, A pants received the most favorable results, followed by D, E, B, and C, in descending order. The clothing pressure appeared to be mainly red on the waist, crotch, and hem when standing in all pants, so the clothing pressure was high. While walking, the stress appeared to be different for the left and right parts of the body, and the most significant difference was observed on the thigh area.

Impact Localization Using Piezoelectric Paint Sensor with Mosaic Pattern Electrodes (모자이크 패턴 전극 압전 페인트 센서를 이용한 충격 위치 검출)

  • Kang, Sang-Hyeon;Kang, Lae-Hyong
    • Journal of Aerospace System Engineering
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    • v.13 no.2
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    • pp.19-25
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    • 2019
  • To detect the impact location of a structure, the authors' group conducted a study on piezoelectric paint sensor. The piezoelectric paint sensors are used for impact detection due to their inherent characteristics: sensitivity to high-frequency signal and impact. Additionally, the paint sensor can be applied on curved and complex structures where ceramic sensor would not be applicable. Moreover it is a self-powered sensor therefore no need for an external power source. For impact localization, mosaic pattern electrodes were coated on the specimen and the impact signal obtained from any part of the electrode where the impact occurred. If we more precise impact localization is required, the electrodes should be divided into more parts and impact data acquisition conducted in all the points of the electrode. In this paper, we developed a light, cheap and simple multi-channel data acquisition system to aid in data gathering. In total four channels data acquisition have been tested using the ARM Cortex-M3.

MARGINAL FIDELITY AND FRACTURE STRENGTH OF IN-CERAM CROWNS ACCORDING TO VARIOUS RESIN CEMENTS (접착재의 종류에 따른 In-Ceram 도재관의 변연적합도와 파절강도에 관한 연구)

  • Lim, Ju-Hwan
    • The Journal of Korean Academy of Prosthodontics
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    • v.36 no.6
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    • pp.888-899
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    • 1998
  • In-Ceram system is one of contemporary esthetic all ceramic restorations and has relatively high flexural strength. The purpose of this study was to evaluate the marginal fidelity according to type of resin cement and measuring position, and to evaluate fracture strength according to type of resin cement. In this study, twenty seven In-Ceram crowns were fabricated on the metal master die of prepared maxillary right central incisor and devided into three groups. All specimens were cemented with Panavia 21 (group PV), Super-bond (group SB) and Lute-it (group LI) on the metal master die. After cementation, specimens were measured marginal gap between the margin of the In-Ceram crown and the finishing line of metal master die by using a stereomicroscope (SZ-ST, Olympus, Japan). Marginal gaps were recorded at the labial, lingual, mesial and distal measuring points on the metal master die. For the mesurement of fracture strength, lingual surfaces of cemented specimens were loaded at a distance of 1mm from incisal edge by using the Autograph S-2000 (Shimadzu, Japan). The results of marginal fidelity and fracture strength were statistically analyzed with the SPSS version 8.0 programs. The results of this study were as follows: 1. In comparison of marginal fidelity according to the measuring points, there was no significant difference. 2. The marginal fidelity according to the type of resin cement was decreased in order of group $LI\;(63.75{\mu}m),\;SB\;(77.78{\mu}m),\;PV\;(86.53{\mu}m)$, and there was significant difference between group LI and PV (p<0.05). 3. The fracture strength according to the type of resin cement was showed descending order of group $LI\;(60.00kg/cm^2),\;SB\;(56.80kg/cm^2),\;PV\;(56.11kg/m^2)$, but there was no significant difference.

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Effects of Eu3+ Concentration on the Photoluminescence Properties of Y1-xPO4:Eux3+ Red Phosphor (Eu3+ 함량비가 Y1-xPO4:Eux3+ 적색 형광체의 발광 특성에 미치는 영향)

  • Cho, Seon-Woog;Cho, Shin-Ho
    • Journal of the Korean Vacuum Society
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    • v.20 no.6
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    • pp.430-435
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    • 2011
  • $Y_{1-x}PO_4:{Eu_x}^{3+}$ red phosphors were synthesized with changing the concentration of $Eu^{3+}$ ion by using a solid-state reaction method. The crystal structures of all the red phosphors were found to be a tetragonal system composed of (200) diffraction peak centered at $25.88^{\circ}$, and the morphology of grains approached the spherical form with homeogenous size distribution as the concentration of $Eu^{3+}$ ion increased. As for the photoluminescence properties, all of the ceramic phosphors, irrespective of $Eu^{3+}$ ion concentration, showed the red-orange and the red emission peaked at 593.0 and 619.2 nm respectively. As the concentration of $Eu^{3+}$ ion increased, the excitation spectrum moved into a longer wavelength with the increase of emission intensity. The maximum excitation and the emission spectrum were observed at 0.15 mol of $Eu^{3+}$ ion.

Sintering Behavior of Borate-Based Glass Ceramic Solid Electrolytes for All-Solid Batteries (전고체전지용 붕산염 유리 세라믹 고체 전해질의 조성비에 따른 소결 특성 연구)

  • Jeong Min Lee;Dong Seok Cheong;Sung Hyun Kang;Tirtha Raj Acharya;Eun Ha Choi;Weon Ho Shin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.37 no.4
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    • pp.445-450
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    • 2024
  • The expansion of lithium-ion battery usage beyond portable electronic devices to electric vehicles and energy storage systems is driven by their high energy density and favorable cycle characteristics. Enhancing the stability and performance of these batteries involves exploring solid electrolytes as alternatives to liquid ones. While sulfide-based solid electrolytes have received significant attention for commercialization, research on amorphous-phase glass solid electrolytes in oxide-based systems remains limited. Here, we investigate the glass transition temperatures and sintering behaviors by changing the molecular ratio of Li2O/B2O3 in borate glass comprising Li2O-B2O3-Al2O3 system. The glass transition temperature is decreasing as increasing the amount of Li2O. When we sintered at 450℃, just above the glass transition temperature, the samples did not consolidate well, while the proper sintered samples could be obtained under the higher temperature. We successfully obtained the borate glass ceramics phases by melt-quenching method, and the sintering characteristics are investigated. Future studies could explore optimizing ion conductivity through refining processing conditions, adjusting the glass former-to-modifier ratio, and incorporating additional Li salt to enhance the ionic conductivity.