• 제목/요약/키워드: Alkaline series

검색결과 131건 처리시간 0.032초

야외시험을 통한 난주입수종의 방부성능 평가 및 국내 목재보존산업에서의 시사점 (Evaluation of Preservative Efficiacy for Refractory Wood Species in Field Tests and Its Implication for Korean Wood Preservation Industry)

  • 나종범
    • Journal of the Korean Wood Science and Technology
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    • 제45권5호
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    • pp.544-558
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    • 2017
  • 본 연구는 국내야외시험을 통하여 난주입수종의 방부성능을 조사하기 위하여 수행되었다. 난주입수종의 방부처리에 적합하다고 판단되는 캐나다 방부목재 표준규격 CSA O80 Series-08 중 주거용 방부목 그룹 C와 D에 따라 방부 처리된 웨스턴 헴록과 스프루스의 방부성능을 야외시험을 통해 평가하였다. 제조된 샘플들은 자상처리를 실시한 후 alkaline copper quaternary (ACQ)와 copper azole (CA)로 방부처리를 실시하였다. 성능시험용 시편들은 2010년 11월 경남 진주에 조성된 야외시험장에서 AWPA E7-09와 AWPA E18-06 방법에 따라 지접부 및 지상부 성능시험을 수행하였으며 매년 정기점검을 통해 시편들의 부후 및 흰개미 가해상태가 조사되었다. 2017년 3월까지 약 6년 5개월 동안의 국내 야외시험 결과를 살펴보면 무처리 시편에서는 부후와 흰개미 가해가 심하게 발생되었지만 방부처리된 시편에서는 거의 발생하지 않은 것으로 나타났다. 이러한 결과는 국내 목재사용환경에서 5 mm 침윤깊이의 적용가능성을 보여준다. 본 논문에서는 국내목재방부산업에서 난주입수종의 활용을 증가시키기 위해 고려되었으면 하는 부분을 침윤도와 보유량의 관점에서 논의한다.

Performance of self-compacting geopolymer concrete with and without GGBFS and steel fiber

  • Al-Rawi, Saad;Taysi, Nildem
    • Advances in concrete construction
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    • 제6권4호
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    • pp.323-344
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    • 2018
  • The study herein reports the impact of Steel Fiber (SF) and Ground Granulated Blast Furnaces slag (GGBFS) content on the fresh and hardened properties of fly ash (FA) based Self-Compacting Geopolymer Concrete (SCGC). Two series of self-compacting geopolymer concrete (SCGC) were formulated with a constant binder content of $450kg/m^3$ and at an alkaline-to-binder (a/b) ratio of 0.50. Fly ash (FA) was substituted with GGBFS with the replacement levels being 0%, 25%, 50%, 75%, and 100% by weight in each SCGC series. Steel fiber (SF) wasn't employed in the assembly of the initial concrete series whereas, within the second concrete series, an SF combination was achieved by a constant additional level of 1% by volume. Fresh properties of mixtures were through an experiment investigated in terms of slump flow diameter, T50 slump flow time, V-funnel flow time, and L-box height ratio. Moreover, the mechanical performance of the SCGCs was evaluated in terms of compressive strength, splitting tensile strength, and fracture toughness. Furthermore, a statistical analysis was applied in order to judge the importance of the experimental parameters, like GGBFS and SF contents. The experimental results indicated that the incorporation of SF had no vital impact on the fresh characteristics of the SCGC mixtures whereas GGBFS aggravated them. However, the incorporation of GGBFS was considerably improved the mechanical properties of SCGCs. Moreover, the incorporation of SF with the total different quantity of GGBFS replacement has considerably increased the mechanical properties of SCGCs, by close to (65%) for the splitting strength and (200%) for compressive strength.

철원분지 백악기 화성암류의 암석조구조적 위치와 암석성인 (Petrotectonic Setting and Petrogenesis of Cretaceous Igneous Rocks in the Cheolwon Basin, Korea)

  • 황상구;김세현;황재하;기원서
    • 암석학회지
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    • 제19권1호
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    • pp.67-87
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    • 2010
  • 철원분지 화산암류와 관입암류에 대해 암석기재와 화학분석을 하여 층서에 따른 조성변화, 이들의 조구적 위치와 암석성인을 고찰하였다. 화산암류는 궁평층 현무암, 금학산안산암, 유문암질 암층(동막골응회암, 유문암, 지장봉응회암) 순으로 놓이고, 관입암류는 보장산안산암, 화강반암과 산성암맥으로 구성된다. 이화산암류와 관입암류는 칼크알칼리 계열에 속하는 medium-K 내지 high-K 의 현무암, 안산암 및 유문암 계열을 나타낸다. 이들은 주원소와 미량원소가 하커도에서 $SiO_2$의 증가에 따라 대개 직선적인 조성변화를 보여준다. 거미도 패턴과 REE 패턴에서 불호정성원소와 희토류원소가 MORB보다 부화되며 후기층으로 가면서 LREE/HREE의 기울기가 커지고 Eu 부이상이 커지는 화산호의 화학적 특징을 보여준다. 조구조 판별도에서도 이들은 파괴성 판연변부의 조산대 즉 화산호 중에서 대륙호에 속한다. 이들에 의하면 최하부 현무암은 해양판이 대륙지각 아래의 맨틀 속으로 침강하는 섭입대에서 상부 맨틀이 함수유체를 공급받음으로써 부분용융되어 생성된 현무암질 칼크알칼리 마그마로부터 유래되었을 것으로 생각된다. 상부의 안산암과 유문암은 현무암질 마그마로부터 분별결정작용과 약간의 지각물질 혼염에 의해 안산암질 마그마를 거쳐 유문암질 마그마로 진화되었음을 암시한다. 각 화산암은 분화된 마그마가 밀도에 따라 천부 레벨로 순차적으로 상승한 챔버로부터 분출되었을 것이다.

울산 동부 마이오세 당사리화산암류에 대한 암석학적 연구 (Petrological study on the Miocene Dangsari volcanic rocks, eastern part of Ulsan city, southeastern Korea)

  • 윤성효;고정선;박기호;이영애
    • 암석학회지
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    • 제9권3호
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    • pp.169-186
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    • 2000
  • 울산 동부지역 당사리 화산암류는 다량의 안산암질 화성쇄설암류내에 안산암 용암류가 협재되어 산출된다. 안산암은 유상구조와 판상절리가 특징적으로 나타나며, 일부 관입상에서는 소규모 주상절리가 나타나기도 하였다. 화성쇄설암류는 대부분 화성쇄설성 각력암이 우세하면서 응회질각력암, 라필리 응회암 등이 호층으로 반복되어 층상구조를 나타내면서 분포한다. 안산암은 사장석, 보통휘석($Wo_{43.2}$ /$En_{41.0}$ /$Fs_{15.8}$ ), 엔스타타이트($Wo_{2.7}$ , $En_{65.8}$ , $Fs_{31.5}$ )와 각섬석 반정이 특징적으로 나타난다. 본 역 안산암은 분류도에서 서브 알칼리 계열의 안산암 영역에 도시되며, $SiO_2$에 대한$ K_2$O의 성분도에 도시하면 중-K 칼크-알칼리암 계열에 해당한다. 미량 원소 조성과 REE 패턴에서 높은 LILE/HFSE비를 나타내며, 경희토류 원소는 부화되어 있는 특징을 나타내는 데, 이는 본 역의 화산암류가 조산대 화간호에 기인한 암석이며, 섭입과 연관된 마그마로부터 생성되었음을 강하게 지시한다. 지구조판별도에서 지판이 침강 섭입하는 지판 경계부 영역의 칼코-알칼리 계열로 구분된다. 당사리화산임의 기원이 되는 칼크-알칼리 안산암질 마그마는 섭입대에서 상부맨틀 웨지를 구성하는 석류석 페리도타이트의 약 15%의 부분용융에 의해 생성된 현무암질 초생마그마에서 유래하였으며, 마그마의 상승 중 지각내의 쳄버에 머무는 동안 분별정출작응과 지각과의 혼염을 받았음을 유추할 수 있다.

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Study of an improved and novel venturi scrubber configuration for removal of radioactive gases from NPP containment air during severe accident

  • Farooq, Mujahid;Ahmed, Ammar;Qureshi, Kamran;Shah, Ajmal;Waheed, Khalid;Siddique, Waseem;Irfan, Naseem;Ahmad, Masroor;Farooq, Amjad
    • Nuclear Engineering and Technology
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    • 제54권9호
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    • pp.3310-3316
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    • 2022
  • Owing to the rising concerns about the safety of nuclear power plants (NPP), it is essential to study the venturi scrubber in detail, which is a key component of the filtered containment venting system (FCVS). FCVS alleviates the pressurein containment byfiltering and venting out the contaminated air. Themain objective of this research was to perform a CFD investigation of different configurations of a circular, non-submerged, self-priming venturi scrubber to estimate and improve the performance in the removal of elemental iodine from the air. For benchmarking, a mass transfer model which is based on two-film theory was selected and validated by experimental data where an alkaline solution was considered as the scrubbing solution. This mass transfer model was modified and implemented on a unique formation of two self-priming venturi scrubbers in series. Euler-Euler method was used for two-phase modeling and the realizable K-ε model was used for capturing the turbulence. The obtained results showed a remarkable improvement in the removal of radioactive iodine from the air using a series combination of venturi scrubbers. The removal efficiency was improved at every single data point.

Synthesis of Hydroxylactams and Esters Derived from Thalidomide and Their Antitumor Activities

  • Sun, Guanglong;Liu, Xiangchao;Zhou, Heng;Liu, Zenglu;Mao, Zhenmin
    • Bulletin of the Korean Chemical Society
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    • 제35권5호
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    • pp.1337-1342
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    • 2014
  • A novel and convenient route for the synthesis of a series of thalidomide derivatives is described. Compound 2 was cyclized with different amines under alkaline condition to obtain 4-nitro substituted phthalimidines 3a-d. Hydroxylactams 4a-d were produced via bromination and hydroxylation. Different acyl chlorides were reacted with hydroxylactams to provide the desired esters 5a-d. All compounds were evaluated by MTT assay for their inhibitory activities against HCT-116, MG-63, MCF-7, HUVEC and HMVEC cell lines in vitro. Most of them showed no obvious cytotoxic effect on normal human cells, compounds 4a-d, $5a_2$, $5a_4$, $5a_5$, $5b_2$, $5c_2$ and $5d_2$ exhibited potent antitumor activities, among which compounds $5a_2$ and $5b_2$ were more effective than 5-FU.

Characterization of denaturation and renaturation of DNA for DNA hybridization

  • Wang, Xiaofang;Lim, Hyun Jeong;Son, Ahjeong
    • Environmental Analysis Health and Toxicology
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    • 제29권
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    • pp.7.1-7.8
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    • 2014
  • Objectives The present study was designed to systematically characterize the denaturation and the renaturation of double stranded DNA (dsDNA), which is suitable for DNA hybridization. Methods A series of physical and chemical denaturation methods were implemented on well-defined 86-bp dsDNA fragment. The degree of each denaturation was measured and the most suitable denaturation method was determined. DNA renaturation tendency was also investigated for the suggested denaturation method. Results Heating, beads mill, and sonication bath did not show any denaturation for 30 minutes. However probe sonication fully denatured DNA in 5 minutes. 1 mol/L sodium hydroxide (alkaline treatment) and 60% dimethyl sulfoxide (DMSO) treatment fully denatured DNA in 2-5 minutes. Conclusions Among all the physical methods applied, the direct probe sonication was the most effective way to denature the DNA fragments. Among chemical methods, 60% DMSO was the most adequate denaturation method since it does not cause full renaturation during DNA hybridization.

Fouling and cleaning of a tubular ultrafiltration ceramic membrane

  • Siddiqui, Farrukh Arsalan;Field, Robert W.
    • Membrane and Water Treatment
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    • 제7권5호
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    • pp.433-449
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    • 2016
  • The successful application of cleaning protocols is vital for optimized filtration processes. A series of experiments with an ultrafiltration ceramic tubular membrane were carried out for the foulants dextran and carboxymethyl cellulose. Firstly, the impact on fouling of concentration changes was investigated with the increase in resistance being used as the key parameter. In the second phase, removal of reversible fouling was also investigated by employing intermittent rinsing consisting of a cold water rinse followed by a hot one. A comparative analysis for both foulants is reported. Across a range of concentrations and for both foulants, the reduction in resistance due to rinsing was found to depend upon concentration (C); it changed as $C^n$ where n was found to be 0.3. A plausible semi-theoretical explanation is given. Thirdly, for both foulants, the application of a combination of strong alkaline solutions with oxidizing agent (mainly sodium hypochlorite) followed by acid was found to be appropriate for cleaning of the ceramic membrane. The effect of increased temperature for cleaning agents followed by a warm water rinse contributed positively to the cleaning capability.

Ca1-xSrxS:Mn 형광체의 합성과 광 특성 (Synthesis and Optical Properties of Ca1-xSrxS:Mn Phosphors)

  • 성혜진;허영덕
    • 한국재료학회지
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    • 제17권3호
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    • pp.137-141
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    • 2007
  • A series of $Ca_{1-x}Sr_{x}S:Mn$ phosphors were synthesized by solid-state reactions. The emission peaks of $Ca_{1-x}Sr_{x}S:Mn$ is blue shifted front 605 to 570 nm with increasing Sr content. Since $Ca_{1-x}Sr_{x}S:Mn$. Mn phosphors exhibit strong absorption in region of 254 nm, the emission wavelength of a fluorescent lamp, these phosphors can be used as wavelength tunable emitting phosphors from reddish orange to yellow. We investigated the optical and structural properties of $Ca_{1-x}Sr_{x}S:Mn$ phosphors.

알칼리 저감형 신문지용 복합 탈묵제 (Complex Agent for low alkalinity Deinking process of ONP)

  • 윤경동;박헌신;강윤석;엄태진
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 2006년도 추계학술발표논문집
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    • pp.9-14
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    • 2006
  • Deinking is a series of unit operations designed to detach ink from cellulose fibers and separate the dispersed ink from the pulp slurry. Deinking chemicals are process aids that enable expensive mill equipment used in these unit operations to operate more efficiently. This paper presents an overview of ONP deinking efficiency with cellulolytic enzymes and synthetic collector in low alkalinity process. The deinking efficiency of old news print even in low alkalinity condition was enhanced with enzyme contained complex agent. The brightness of deinked pulp was increased with less residual ink particles and yield of deinked pulp was improved compared to the deinked pulp of conventional alkaline method.

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