• Title/Summary/Keyword: Alkaline Pre-treatment

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Development of Auto-hydrolysis Method for Preparing Cotton Linter Regenerated Fibers of Textile Fabrics (방직용 재생펄프 제조를 위한 면 린터의 자기가수분해 공정 개발)

  • Sohn, Ha Neul;Park, Hee Jung;Seo, Yung Bum
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.6
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    • pp.81-88
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    • 2015
  • The molecular weight (MW) and crystallinity of cotton linter need to be controlled to be dissolved well in N-methylmorpholine N-oxide (NMMO) solvent for manufacturing regenerated fibers of clothing fabrics. Electron beam irradiation or sulfuric acid pre-treatment followed by alkaline peroxide bleaching has been used to control MW effectively and to improve brightness of cotton linter. Auto-hydrolysis of cotton linter without electron beam irradiation or chemical pre-treatment was found to be effective as an alternative pre-treatment method. Removal of metal ions, that hampered dissolution of cotton linter by NMMO, was also investigated when the auto-hydrolysis was accompanied with ionic polymers and chelating agent.

Evaluating optimal preprocessing method for separation of microalgae colonies into single cells for image quality (미세조류 이미지 품질 성능 향상을 위한 최적 전처리방법 선정 연구)

  • Sang Yeob Kim;Sung Kyu Maeng
    • Journal of Korean Society of Water and Wastewater
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    • v.38 no.2
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    • pp.109-117
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    • 2024
  • In this study, various pre-treatment methods were evaluated for microalgae separation. These methods aimed to facilitate safe, rapid, and cost-effective online imaging for real-time observation and cell counting. As pre-treatment techniques, heating, chemical hydrolysis, heating combined with chemical hydrolysis, and sonication were employed. The effectiveness of these methods was evaluated in the context of online imaging quality through experimentation on cultivated microalgae (Chlorella vulgaris and Scenedesmus quadricauda). The chemical treatment method was found to be inappropriate for improving image acquisition. The heating pre-treatment method exhibited a drawback of prolonged cell dispersion time. Additionally, the heating combined with chemical hydrolysis method was confirmed to have the lowest dispersion effect for Chlorella vulgaris. Conversely, ultrasonication emerged as a promising technique for microalgae separation in terms of repeatability and reproducibility. This study suggests the potential for selecting optimal pre-treatment methods to effectively operate real-time online monitoring devices, paving the way for future research and applications in microalgae cultivation and imaging.

Sensitization Effects of Hyperthermia on Bleomycininduced DNA Strand Breaks and Replication Inhibition in CHO-$K_1$ Cells in Vitro

  • Kim, Chan-Gil;Kim, Hyeon-Suk;Park, Sang-Dai
    • Environmental Mutagens and Carcinogens
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    • v.15 no.2
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    • pp.88-93
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    • 1995
  • Effects of hyperthermia on the induction of DNA single strand breaks and replication inhibition were studied in bleomycin-treated CHO-K$_1$ cells by alkaline elution and alkaline sucrose gradient sedimentation. Bleomycin-induced DNA single strand breaks of DNA were dose-and time-dependently increased, and these strand breaks of DNA were gradually rejoined as post-incubation time passed. Treatment with hyperthermia alone did not affect the induction of DNA single strand breaks. However, pre-exposure of cells to hyperthermia followed by bleomycin treatment greatly increased the single strand breaks, and also reduced the rejoining processes of bleomycin-induced DNA single strand breaks. Bleomycin selectively inhibited the replicon initiation. The combined treatment with hyperthermia and bleomycin markedly potentiated the nonspecific inhibition of replication.

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Enzyme-Assisted Delignification of Several Pulps by Laccase from Botrytis Cinerea

  • Kim, Myung-Kil
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.34 no.2
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    • pp.67-72
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    • 2002
  • The two stage laccase-assisted delignification process led to significant lignin removal in the non-pressurized treatments. It is clearly shown that an alkaline extraction prior to the second laccase treatment significantly increased the overall delignification by ∼15%. This is in line with the contention that the residual lignin has undergone structural changes during the alkaline extraction, and the resulting modified structures are susceptible to the laccase oxidation. In phenolic hydroxyl group, the pre- methylated sample was very responsive to the delignification process. The phenolic hydroxyl groups could be increased during side chain cleavage catalyzed by laccase. This finding demonstrates that the delignification oi etherified structures is an important reaction in the delignificaton by laccase.

Enzymatic Hydrolysis of Pre-treated Ulva pertusa with Alkaline Peroxide (구멍갈파래의 알칼리 과산화수소 전처리 및 효소 가수분해 특성)

  • Yoon, Byung-Tae;Kim, Young-Wun;Chung, Keun-Wo;Kim, Jin-Seog
    • Applied Chemistry for Engineering
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    • v.22 no.3
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    • pp.336-339
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    • 2011
  • Algae is an abundant and potential fermentation substrate. The enzymatic hydrolysis of algae was investigated by pre-treating an alkaline hydrogen peroxide with commercial cellulase and viscozyme. Algae used in this study was the Ulva pertusa. The evaluated response was the yield of released glucose after the enzymatic hydrolysis. Alkaline hydrogen peroxide containing mixtures of 1 wt% hydrogen peroxide and 1~1.75 wt% sodium hydroxide was also used. The results show that the highest glucose conversion was obtained for Ulva pertusa using 5 wt% hydrogen peroxide at $60^{\circ}C$ for 3 h. The required amount of enzymes after the pre-treatment with alkaline hydrogen peroxide were reduced by far compared to that of untreated Ulva pertusa. Also, the amount of glucose that is released during the enzymatic hydrolysis was increased.

A Study of Sewage Sludge Solubilization by Alkali and Ultrasonic pretreatment (알칼리처리와 초음파처리를 이용한 슬러지 가용화 연구)

  • Kim, Jae-Hyung;Yang, Hong-Gyu;Lee, Joon-Cheol;Park, Hong-Sun;Choi, Gwang-Geun;Pak, Dae-Won
    • Journal of Energy Engineering
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    • v.20 no.2
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    • pp.84-89
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    • 2011
  • In this study, individual(alkaline, ultrasonic) and combined(alkaline+ultrasonic) pretreatment effect on sewage sludge solubilization was investigated. COD solubilization rates increased with the dose of NaOH added: solubilization reached 27.6%. Additional alkaline agents did not increase solubilization further. Ultrasonic pretreatment achieved 33~39% solubilization when 140 W/L amplitude. In(alkaline(pre-treatment)+ultrasonic (after-treatment)) treatment, solubilization increased as the combined intensity in creased($70.4{\pm}9.4%$). SCOD rising rate(0.076) was achieved.

Hot AC Anodising as a Cr(VI)-free Pre-treatment for Structural Bonding of Aluminium

  • Lapique, Fabrice;Bjorgum, Astrid;Johnsen, Bernt;Walmsley, John
    • Journal of Adhesion and Interface
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    • v.4 no.2
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    • pp.21-29
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    • 2003
  • Hot AC anodising has been evaluated us pre-treatment for aluminium prior to structural adhesive bonding. Phosphoric and sulphuric acid hot AC anodising showed very promising adhesion promoter capabilities with durability comparable with the best standard DC anodising procedures. AC anodising does not required etching prior to anodising and offers u pre-treatment time down to 20 seconds. The interface/interphase between the aluminium substrate and the adhesive was investigated in order to get a better understanding of the involved adhesion mechanisms and to explain the long-tenn properties. The alkaline medium formed at the oxide layer/adhesive interface has been shown to induce a partial dissolution of the oxide layer leading to the formation of metallic ions which diffuse in the adhesive (EPMA measurements). The effect of diffusion of the Al ions on adhesion and joint durability is still uncertain but studies showed that pre-bond moisture affected the joints durability and to some extent the diffusion length. specially for DC anodised samples. So far no direct correlation could be established between the diffusion length d and the joints durability but new trials with better control over the elapsed time between bonding and adhesive curing are expected to help getting a better understanding of the involved mechanisms.

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Lateral Growth of PEO Films on Al1050 Alloy in an Alkaline Electrolyte

  • Moon, Sungmo;Kim, Yeajin
    • Journal of the Korean institute of surface engineering
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    • v.50 no.1
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    • pp.10-16
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    • 2017
  • This article reports for the first time on the lateral growth of PEO (plasma electrolytic oxidation) films on Al1050 alloy by the application of anodic pulse current in an alkaline electrolyte. Generation of microarcs was observed at the edges initially and then moved towards the central region with PEO treatment time. Disc type PEO film islands with about $20{\mu}m$ diameter were formed first and they grew laterally by the formation of new disc type PEO films at the edge of pre-formed PEO islands. The PEO film islands were found to be interconnected completely and form a continuous PEO film when generation of small size microarcs are terminated at the central part of the specimen, resulting in very smooth surface with low surface roughness less than $1{\mu}m$ of $R_a$. Further PEO treatment after the complete interconnection of PEO films islands showed local thickening of PEO films by vertical growth. It is concluded that very smooth PEO film surface can be obtained by lateral growth mechanism rather than vertical growth of them.

The Effect of Pre-treatment on the Anaerobic Digestion of waste Activated Sludge (하수슬러지의 혐기적 소화효율 향상을 위한 전처리 효과)

  • Kang, Chang-Min;Kim, Bong-Keun;Kim, In-Su;Kim, Byung-Tae
    • Journal of the Korea Organic Resources Recycling Association
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    • v.9 no.1
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    • pp.90-98
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    • 2001
  • The slow degradation rate of sewage sludge in anaerobic digesters is due to the rate limiting step of sludge hydrolysis. Therefore, the pre-treatment process had been carried out using acidic(pH 1.5, 3, 4, 5) and alkaline(pH9, 10, 13), thermal(50, 100, 150, $200^{\circ}C$) and ultrasonic treatment(400W, 20kHz, 15, 20, 25, 30, 35, 40, 50, 60min). In the best conditions of each treatment, the SCOD ratio(%) of treated/untreared samples were increased 102% in acid(pH5), 986% in alkali(pH13), 959% in thermal($200^{\circ}C$) and 1123% in ultrasonic(35min) treatment. As the result, the ultrasonic treatment was most effective, followed by alkali, thermal, acidic treatment. In the effects of total gas productivity, the thermal($200^{\circ}C$) pretreatment was the highest, followed by thermal($150^{\circ}C$), ultrasonic(90min), alkaline(pH9) and ultrasonic(50min).

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Effect of Chitosan Treatment Methods on the Dyeing of Cotton, Nylon, and PET using Cochineal (I) - Color and Air-permeability Characteristics - (코치닐 염색(染色)에서 키토산처리(處理) 방법(方法)의 변화(變化)가 면(綿), 나일론, PET의 염색(染色)에 미치는 영향(影響) (I) - 색상(色相)과 공기투과도(空氣透過度) 특성(特性)에 관(關)하여 -)

  • Lee, Dong-Min;Jeon, Dong-Won;Kim, Jong-Jun
    • Journal of Fashion Business
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    • v.9 no.2
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    • pp.57-70
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    • 2005
  • Chitosan pre-treatment of the fabrics prior to the dyeing processes has been reported to increase the uptake of natural dyestuffs. In this study, cotton, nylon, and PET fabric specimens were pre-treated with chitosan prior to the dyeing (Method 1), or the state of chitosan acid salt formation, coated on the yarn surface, was destroyed prior to the dyeing process by alkaline neutralization process (Method 2). In case of the acid salt formed cotton (Method 1), treated fabrics showed more yellowish color component of cochineal, while alkali-treated (Method 2) cotton showed more uptake of bluish color of cochineal.