• Title/Summary/Keyword: Alkali treatment

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Effects of Alkali Treatment on Physical Properties of PET Fabrics (알칼리 처리에 의한 폴리에스테르 직물의 물성 변화)

  • Yu, Hye-Ja;Choe, Jong-Myeong;Lee, Hye-Ja
    • Journal of the Korean Society of Clothing and Textiles
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    • v.20 no.4
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    • pp.609-619
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    • 1996
  • Polyethylene Terephthalate (PET) has been used as a mainstream fiber to make silklike fiber. The silky characteristics such as softness, dry touch feeling and flexibility can be obtained by weight reduction treatment. In aqueous alkali solution, the surface of PET is dissolved away and reduced in weight. The PET fiber, yarn and fabric become thinner and the gaps between fibers are wider. Its mobility is greatly improved without change of basic structures of the treated PET fibrics. The alkali treatment was conducted under the various experimental conditions such as alkali (NaOH) concentration, treatment time and temperature. As the weight loss increased, drapability improved and tensile strength remarkably reduced. When the PET fabrics lost 30% in their weight, drape coefficient lowered as much as 30oA and tensile stregth lowered as much as 50%. The weight loss over 30% brings great improvement in drapability and dyeability and significant decline in durability. By the alkali treatment, absorbency in spectrophotometer of dyed PET can be increased as much as 82% due to the increase of the surface area and formation of microvoids on the surface.

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The Effect of Alkali Treatment on the Hand of Polyester Fabrics (폴리에스테르 직물의 알칼리 감량가공에 따른 촉감의 변화)

  • 신혜원
    • Journal of the Korean Society of Clothing and Textiles
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    • v.20 no.5
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    • pp.783-791
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    • 1996
  • The effect of alkali treatment on the changes in characteristics, mechanical properties, and hand of polyester fabrics was studied. Two kinds of fabrics having different yarn deniers were treated varying weight loss. The results were as follows; 1. Changes in constructional characteristics by alkali treatment were: a decrease in weight & thickness of fabric, a decrease in yarn denier, a decrease in apparent density of fabric, an increase in porosity to air, and a change fiber surface. 2. As for the changes in mechanical properties by alkali treatment, findings were : an increase in WT, RT, MIU, LC, and WC, a decrease in LT, B,2HB, G,2HG,2HGS, MMD, SMD, and RC, ana an increase in drape. 3. Changes in hand by alkali treatment were: a decrease in KOSHI and HARE, an increase in FUUURAMI, SHARI, KISHIMI, and SHENAYAUASA, and an increase in T.H.V 4. In the case of the same weight loss, the hand of 40/24 fabric being composed of thinner yarns was better than the hand of 50/24 fabric. 5. When 50/24 fabric was treated to have the same weight with 40/24 fabric, so the yam deniers of two fabrics were the same, the hand of 50/24 fabric having larger weight loss was better than the hand of 40/24 fabric.

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Mechanical Properties of Alkali Treated Kenaf Fiber Filled PP Bio-Composites (알칼리 처리된 Kenaf 섬유가 충전된 Polypropylene/Kenaf 바이오복합재의 기계적 특성)

  • Kim, Samsung;Lee, Byoung-Ho;Kim, Hyun-Joong;Oh, Sei Chang;Ahn, Sye-Hee
    • Journal of the Korean Wood Science and Technology
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    • v.37 no.3
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    • pp.222-230
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    • 2009
  • This study was to investigate the effect of alkali treatment for long kenaf fiber to improve fiber surface characterics by removal of wax, lignin and hemicellulose which affect adversely for matrix union. SEM observation was also studied to check out the interface adhesion improvement by the alkali pre-treatment. From the result, interface coherence increased by 3% alkali pre-treatment and reached a maximum by 5% alkali pre-treatment. However, the 3% the bio-composites treated with 3% alkali was highest tensile and flexural strength than other.

COLONIZATION OF ALKALI-TREATED FIBROUS ROUGHAGES BY ANAEROBIC RUMEN FUNGI

  • Wuliji, T.;McManus, W.R.
    • Asian-Australasian Journal of Animal Sciences
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    • v.1 no.2
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    • pp.65-71
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    • 1988
  • This study reports light and electron microscope examination of rumen fungal colonization of alkali-treated roughage feeds incubated in decron bags in the rumen of cannulated sheep for varying time intervals. Six roughages, pre-treated with ammonium hydroxide or sodium hydroxide at 4% (w/w) level were examined together with untreated control samples. Alkali pre-treatment was associated with an earlier and more pronounced fungal colonization than all control roughages. Sodium hydroxide pre-treatment was significantly more effective than ammonium hydroxide in improving the susceptibility of roughages to rumen fungal colonization and studies by SEM showed that the pre-treatment permitted greater penetration of feeds by fungi. Sodium hydroxide pre-treatment also significantly increased dry matter disappearance from feed held in Dacron bags in the rumen with all feeds except Lucerne stem. It is not known to what extent fungal activity contributed to increased breakdown of the feeds.

Effect of Washing Treatment of Aged Paper Materials for Better Conservation (열화된 종이자료의 보존성 개선을 위한 세척처리 특성)

  • Lee, Kwi-Bok;Seo, Yung-Bum;Park, So-Yeon;Jeon, Yang;Shin, Jong-Soon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.38 no.4 s.117
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    • pp.53-60
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    • 2006
  • Paper materials for long term conservation suffer slowly mechanical and chemical deterioration, the extent of which may depend upon their conservation environment. Those deterioration includes discoloring, low moisture content, acidification, and brittleness. To slow deterioration, washing treatment, deacidification, and polymer reinforcement on paper materials are usually used. One easy and simple method of fixing low moisture content and acidification was an washing method, and we used both distilled and alkali water in washing method in this study. Alkali water is electrolyzed cathode water of high pH, and has no alkali metal ions in it. Experiment showed that washing treatment with both distilled and alkali water gave improvement in raising moisture content, pH, and mechanical strength of paper materials even after severe accelerated aging test. Advantageous effect of alkali water over distilled water on preventing deterioation was also shown clearly.

Effect of Alkali Surface Modification on Adhesion Strength between Electroless-Plated Cu and Polyimide Films (알카리 표면개질 처리가 무전해 구리 도금피막과 폴리이미드 필름의 접합력에 미치는 효과)

  • Son, Lee-Seul;Lee, Ho-Nyun;Lee, Hong-Kee
    • Journal of the Korean institute of surface engineering
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    • v.45 no.1
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    • pp.8-14
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    • 2012
  • The effects of the alkali surface modification process on the adhesion strength between electroless-plated Cu and polyimide films were investigated. The polyimide surfaces were effectively modified by alkali surface treatments from the hydrophobic to the hydrophilic states, and it was confirmed by the results of the contact angle measurement. The surface roughness increased by alkali surface treatments and the adhesion strength was proportional to the surface roughness. The adhesion strength of Cu/polyimide interface treated by KOH + EDA (Ethylenediamine) was 874 gf/cm which is better than that treated by KOH and KOH + $KMnO_4$. The results of XPS spectra revealed that the alkali treatment formed oxygen functional groups such as carboxyl and amide groups on the polyimide films which is closely related to the interfacial bonding mechanism between electroless-plated Cu and polyimide films. It could be suggested that the species and contents of functional group on polyimide films, surface roughness and contact angle were related with the adhesion strength of Cu/polyimide in combination.

Sludge Solubilization by Pre-treatment and its Effect on Methane Production and Sludge Reduction in Anaerobic Digestion (전처리 방법에 따른 슬러지 가용화가 혐기소화에서 메탄 생산과 슬러지 감량에 미치는 영향)

  • Kim, Dong-Jin;Kim, Hye-Young
    • Korean Chemical Engineering Research
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    • v.48 no.1
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    • pp.103-109
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    • 2010
  • Anaerobic digestion has been widely used for the treatment of sludge, which is generated from the municipal and industrial wastewater treatment, for its volume reduction and methane production. Many researches on sludge pre-treatment have been carried out in order to enhance the performance of anaerobic digestion by increasing the hydrolysis of sludge which is the rate limiting step of anaerobic digestion. In this study, the effect of pre-treatment on sludge hydrolysis(solubilization), methane production and sludge reduction by anaerobic digestion after thermal, ultrasonic, and thermal-alkali sludge treatment were compared. Thermal-alkali treatment showed 67 and 70% solubilization with municipal and industrial wastewater sludge, respectively, while ultrasonic treatment and thermal treatment gave similar solubilization efficiency of 40% or more. Methane content of the anaerobic digestion gas reached 45~70% and pretreated sludge gave higher methane content than the control sludge. Methane production of thermal, ultrasonic, and thermal-alkali pre-treatment gave 2.6, 2.7, 3.5 times of municipal control sludge and 3.5, 4.1, 4.2 times of industrial control sludge, respectively. Sludge reduction of pre-treated sludge after anaerobic digestion gave 5~19% point higher than that of control sludge, and thermal-alkali treatment showed higher reduction efficiency than thermal and ultrasonic treatment. The results proved that pre-treatment contributed significantly not only for the methane production but also for the cost reduction of sludge treatment and disposal, and thermal-alkali treatment gave the best performance for the sludge treatment.

The Effect of Chemical Pretreatment on Steam Explosion and Oxygen-alkali Pulping of Oak Wood (참나무재의 약액함침 처리가 폭쇄 및 산소-알칼리펄프화에 미치는 영향)

  • 박승영;최태호;조남석
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.33 no.3
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    • pp.75-83
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    • 2001
  • The potential of oxygen delignification is a powerful tool to reduce detrimental environmental effects. This study was performed to investigate the effect of steam explosion treatment of chemically treated oak wood on oxygen-alkali pulping. Pulp yield during steam explosion treatment by ${Na_2}{O_3}$-NaOH impregnation was higher than the other impregnation chemicals. Also, NaOH extraction at room temperature after steam explosion treatment improved the kappa number from 140~116 to 90~64. Oxygen-alkali pulping of chemical steam explosion treated woods affected to pulp yields. ${Na_2}{O_3}$-NaOH impregnation was very effective to higher carbohydrate yields at same delignification level. Its carbohydrate yield seemed to be highly related to the effluent pH. Oxygen-alkali pulping after steam explosion treatment of ${Na_2}{O_3}$-NaOH impregnated wood was shown that carbohydrate yield was very high because its effluent pH was increase from natural to mild alkali. Even if oxygen bleaching limit the delignification to 50% in order to avoid unacceptable yield and viscosity losses, oxygen-alkali pulping after steam explosion by ${Na_2}{O_3}$-NaOH impregnation was possible to extend the delignification more than 80%. Considering high pulp yield with lower lignin content from steam explosion treated wood, it might be profitable to end the cook at a high kappa number instead of a low kappa number, and continuously apply the oxygen delignification, in order to better quality pulp.

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Effect of Color Developing by Alkali and Heating of Cotton Fabrics Dyed with Persimmon Extract (알칼리와 열처리에 의한 면직물의 감즙염색 발색효과)

  • Kim, Ok-Soo;Jang, Jeong-Dae
    • Fashion & Textile Research Journal
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    • v.13 no.6
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    • pp.972-982
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    • 2011
  • The purpose of this study is to improve the method of color developing with alkali solution as a promotor of color developing for feasible use. Cotton fabric was dyed with persimmon extract ranged with 0~3% alkali component with 5 types of strong to mild alkali solution. Heat treatment for color developing was applied to fabric dyed with persimmon extract and alkali mixing solution. Tests were carried out to analyze the change of surface color, ${\Delta},Ea^*b^*$, and water repellent of the dyed cotton fabric. The alkali mixing sample showed higher ${\Delta},Ea^*b^*$ value than control one without alkali mixing on the base of dyed fabric due to high color developing by alkali in the initial step of dyeing process. As alkali concentration increased, deeper dark color appeared on the fabric. The fabric color was changed to more dark in the application of sodium hydroxide, sodium carbonate, potassium carbonate in the initial step of dyeing process but color was not changed by increased heating time. However, the fabric showed a slight dark color with sodium acetate and more color change than that of the fabric dyed with persimmon extract without alkali. Therefore, sodium acetate seemed to a suitable promotor for color developing in persimmon extract dyeing. Property of water repellent was showed after color developing by heating with low concentration of alkali treatment.

Studies on Borassus fruit fiber and its composites with Polypropylene

  • Sudhakara, P.;Obi Reddy, K.;Prasad, C. Venkata;Jagadeesh, Dani.;Kim, H.S.;Kim, B.S.;Bae, S.I.;Song, J.I.
    • Composites Research
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    • v.26 no.1
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    • pp.48-53
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    • 2013
  • This paper summarizes the structural characterization of borassus fruit fibers by means of various characterization techniques, optimization of alkali treatment of borassus fruit fine fibers (BFF) with a 5% concentration sodium hydroxide solution for different time intervals (1, 4, 8 and 12 h) and the changes occurring in borassus fibers. This paper also discusses the manufacturing of BFF/PP compotes using MAPP as a compatibilizer in addition to alkali treatment. Composites were evaluated for their mechanical and morphological properties. The tensile strength and modulus, flexural strength and modulus and impact strength were increased for alkali treated/MAPP composites by 4.5%, 17%, 17.2 %, 9% and 10% respectively.