• Proceedings of the Korean Institute of Building Construction Conference
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• 2017.05a
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• pp.107-108
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• 2017

In this search, by evaluating the field applicability of soil mixed pavement of Red mud is mixed into the soil mixed pavement field applicability, and tries to present the basic data about the site application of recycling of red mud and low carbon construction material to. As a result, the conventional soil concrete organization standards (SPS-KSCICO-001: 2003) meets the criteria for parking lot, making use of red mud, natural color as well as the natural loess is expressed.

• Journal of the Korea Concrete Institute
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• v.28 no.2
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• pp.205-212
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• 2016

This research investigates the influence of ground granulated blast furnace slag (GGBFS) composition on the alkali-activated slag cement (AASC). Aluminum oxide ($Al_2O_3$) was added to GGBFS binder between 2% and 16% by weight. The alkaline activators KOH (potassium hydroxide) was used and the water to binder ratio of 0.50. The strength development results indicate that increasing the amount of $Al_2O_3$ enhanced hydration. The 2M KOH + 16% $Al_2O_3$ and 4M KOH + 16% $Al_2O_3$ specimens had the highest strength, with an average of 30.8 MPa and 45.2 MPa, after curing for 28days. The strength at 28days of 2M KOH + 16% $Al_2O_3$ was 46% higher than that of 2M KOH (without $Al_2O_3$). Also, the strength at 28days of 4M KOH + 16% $Al_2O_3$ was 44% higher than that of 4M KOH (without $Al_2O_3$). Increase the $Al_2O_3$ contents of the binder results in the strength development at all curing ages. The incorporation of AASC tended to increases the ultrasonic pulse velocity (UPV) due to the similar effects of strength, but increasing the amount of $Al_2O_3$ adversely decreases the water absorption and porosity. Higher addition of $Al_2O_3$ in the specimens increases the Al/Ca and Al/Si in the hydrated products. SEM and EDX analyses show that the formation of much denser microstructures with $Al_2O_3$ addition.

• Proceedings of the Korea Concrete Institute Conference
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• 1999.04a
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• pp.33-39
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• 1999

This study was conducted to confirm the effect of bypass dust on the hydration and mechanical properties of the cement pastes and mortar obtained from ordinary Portland cement (OPC), OPC-slag and OPC-fly ash system. The rate of heat evolution is accelerated with the content of By-pass Dust(BD). total heat evolution increased because alkali-chlorides activated the hydration of blended cement. Compressive strength and bound water content show maximum value at 5wt% By-pass Dust(BD) on each curing time in ordinary Portland cement and slag blended cement. Ca(OH)2 content of Ordinary Portland Cement increased as the content of BD and curing time. In blended cement, the formation of Ca(OH)2 is active at early hydration stage. By pozzolanic reaction, the content of Ca(OH)2 is decreased as curing time goes by. According to the BD content stable chlorides complex of Friedel's salt (C3A·CaCl2·10H2O) is created. Due to the hydration activation effect of chlorides and alkali we observed Type II C-S-H, which developed into densest microstructure.

• Journal of the Korea Concrete Institute
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• v.27 no.2
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• pp.95-102
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• 2015

In this paper, the effects of sodium hydroxide (NaOH) and aluminum potassium sulfate ($AlK(SO_4)_2{\cdot}12H_2O$) dosage on strength properties were investigated. For evaluating the property related to the dosage of alkali activator, sodium hydroxide (NaOH) of 4% (N1 series) and 8% (N2 series) was added to 1~5% (K1~K5) dosage of aluminum potassium sulfate ($AlK(SO_4)_2{\cdot}12H_2O$) and 1% (C1) and 2% (C2) dosage of calcium oxide (CaO). W/B ratio was 0.5 and binder/ fine aggregate ratio was 0.5, respectively. Test result clearly showed that the compressive strength development of alkali-activated slag cement (AASC) mortars were significantly dependent on the dosage of NaOH and $AlK(SO_4)_2{\cdot}12H_2O$. The result of XRD analysis indicated that the main hydration product of $NaOH+AlK (SO_4)_2{\cdot}12H_2O$ activated slag was ettringite and CSH. But at early ages, ettringite and sulfate coated the surface of unhydrated slag grains and inhibited the hydration reaction of slag in high dosage of $NaOH+AlK(SO_4)_2{\cdot}12H_2O$. The $SO_4{^{-2}}$ ions from $AlK(SO_4)_2{\cdot}12H_2O$ reacts with CaO in blast furnace slag or added CaO to form gypsum ($CaSO_4{\cdot}2H_2O$), which reacts with CaO and $Al_2O_3$ to from ettringite in $NaOH+AlK(SO_4)_2{\cdot}12H_2O$ activated slag cement system. Therefore, blast furnace slag can be activated by $NaOH+AlK(SO_4)_2{\cdot}12H_2O$.

• Computers and Concrete
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• v.21 no.5
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• pp.559-567
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• 2018

In this study alkali activation of Electric Arc Furnace Slag (EAFS) is studied with a comprehensive test program. Three different silicate moduli (1-1,5-2), three different sodium concentrations (4%-6%-8%) for each silicate module, two different curing conditions (45%-98% relative humidity) for each sodium concentration, two different curing temperatures ($400^{\circ}C-800^{\circ}C$) for each relative humidity condition and two different curing time (6h-12h) for each curing temperature variables are selected and their effects on compressive strength was evaluated then regression equations using multiple linear regressions methods are fitted. And then to select the best regression models confirm with using the variables, the regression models compared between itself. An Artificial Neural Network (ANN) models that use silicate moduli, sodium concentration, relative humidity, curing temperature and curing time variables, are formed. After the investigation of these ANN models' results, ANN and multiple linear regressions based models are compared with each other. After that, an explicit formula is developed with values of the ANN model. As a result of this study, the fluctuations of data set of the compressive strength were very well reflected using both of the methods, multiple linear regression with quadratic terms and ANN.

• Journal of the Korean Recycled Construction Resources Institute
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• v.4 no.2
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• pp.149-156
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• 2016

It has been well known that concrete structures exposed to chloride and sulfate attack environments lead to significant deterioration in their durability due to chloride ion and sulfate ion attack. The purpose of this experimental research is to evaluate the long-term durability against chloride ion and sulfate attack of the alkali activated cementless concrete replacing the cement with ground granulated blast furnace slag. For this purpose, the cementless concrete specimens were made for water-binder ratios of 40%, 45%, and 50%, respectively and then this specimens were cured in the water of $20{\pm}3^{\circ}C$ and immersed in fresh water, 10% sodium sulfate solution for 28, 91, 182, and 365 days, respectively. To evaluate the long-term durability to chloride ion and sulfate attack for the cementless concrete specimens, the diffusion coefficient for chloride ion and compressive strength ratio, mass change ratio, and length change ratio were measured according to the NT BUILD 492 and JSTM C 7401, respectively. It was observed from the test results that the resistance against chloride ion and sulfate attack of the cemetntless concrete were comparatively largely increased than those of OPC concrete irrespective of water-binder ratio.

• Journal of the Korean Recycled Construction Resources Institute
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• v.1 no.1
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• pp.58-66
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• 2013

This study investigated quality properties of alkali activated cement free mortar using industrial by-product such as cement kiln dust(CKD), silica fume(SF) and quartz sand powder(SP) to compare with previous research about blast furnace slag(BS) and fly ash(FA). The results were as following. All materials were effective to increase compressive strength, however they showed different tendency on flowability. CKD and SP increased flowability, but on the other hand SF did not because it's blain was great difference with other materials. Flowability and compressive strength were related with grading distributions of binders because CKD, SP and SF which had small particle size filled up BS and FA. Application of industrial by-products with various grading distributions could be effective for the high early strength and flowability of alkali activated cement free mortar using BS.

• Journal of the Korea Concrete Institute
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• v.24 no.2
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• pp.121-127
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• 2012

Cement has been traditionally used as a main binding material of high ductile fiber reinforced cementitious composites. The purpose of this paper is to investigate the feasibility of using alkali-activated slag and polyvinyl alcohol (PVA) fibers for manufacturing high ductile fiber reinforced cementless composites. Two mixture proportions with proper flowability and mortar viscosity for easy fiber mixing and uniform fiber dispersion were selected based on alkali activators. Then, the slump flow, compression, uniaxial tension and bending tests were performed on the mixes to evaluate the basic properties of the composites. The cementless composites showed an average slump flow of 465 mm and tensile strain capacity of approximately 2% of due to formation of multiple micro-cracks. Test results demonstrated a feasibility of manufacturing high ductile fiber reinforced composites without using cement.

• Journal of the Korean Recycled Construction Resources Institute
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• v.1 no.2
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• pp.114-119
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• 2013

The present study tested 5 concrete mixes to develop reliable mixing proportions for the sustainable alkali-activated(AA) foamed concrete as a thermal insulation material for the floor heating system of buildings. The AA binder used was composed of 73.5% ground granulated blast-furnace slag, 15% fly ash, 5% calcium hydroxide, and 6.5% sodium silicate. As a main variable, the unit binder content varied from $325kg/m^3$ to $425kg/m^3$ at a space of $25kg/m^3$. The test results revealed that AA foamed concrete has considerable potential for practical applications when the unit binder content is close to $375kg/m^3$, which achieves the minimum quality requirements specified in KS F 4039 and ensures economic efficiency. In addition, lifecycle assessment demonstrated the reduction in the environmental impact profiles of all specimens relative to typical ordinary portland cement foamed concrete as follows: 99% for photochemical oxidation potential, 87~89% for global warming potential, 78~82% for abiotic depletion, and 70~75% for both acidification potential and human toxicity.

• Advances in concrete construction
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• v.10 no.5
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• pp.403-416
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• 2020

This study investigated the effect of alkaline activators - NaOH_aq (NH) (NH: 0-16 M) and Na₂SiO_3aq (NS) (NS/NH: 0-3.5) in the synthesis of silico-manganese fume (SMF) and ground blast furnace slag (BFS) blended alkali-activated mortar (AASB). The use of individual activator was ineffective in producing AASB of sufficient fresh and hardened properties, compared to the synergy of both activators. This may be attributed to incomplete dissolution and condensation of oligomers required for gelation of the binder. An inverse relationship was noted among the fresh properties and the NH concentration or NS/NH ratio. This was influenced by the dissolution and condensation of silicate monomers under polymerization process. The maximum 28-day strength of ~45 MPa, setting time of 60 min and flow of 182 mm was obtained with the use of combined activators (10M-NH and NS/NH=2.5). The combined activators at NS/10M-NH=2.5 constituted SiO₂/Na₂O, H₂O/Na₂O and H₂O/SiO₂ molar ratio of 1.61, 17.33 and 10.77, respectively. This facilitated the formation of C-S-H, C/K-A-S-H and C-Mn-S-H in the framework together with an increase in the crystallinity due to more silicate re-organization within the aluminosilicate chain. On comparison of the high concentrated with mild alkali synthesized product, it revealed that the concentration of OH^- and Si monomers together with alkali metals influenced the dissolution of precursors and embedment of the constituent elements in the polymeric matrix. These factors eventually contributed to the microstructural densification of the mortar prepared with NS/10M-NH=2.5 thereby enhancing the compressive strength.