• Title/Summary/Keyword: Alkali Solution

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Development of the inorganic which uses the Fly-ash and Meta-kaolin (플라이애쉬와 메타카올린을 사용한 무기결합재의 개발)

  • Jung, Suk-Jo;Chu, Yong-Sik;Lee, Jong-Kyu
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.433-436
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    • 2005
  • The Fly-ash makes an Alumino-silicate gel when it mixes an alkali or a silicate solution. This Alumino-silicate gel is produced to the activation of an alkali silicate. And this act to the binder and makes a combine of particles. This study involved mechanical strengths of an Alumino-silicate Gel based the Fly-ash with an alkali solution. NaOH, KOH were utilized to an alkali solution. The alkali solution concentration was varied from 6 to 12M and the some added also the Meta-kaolin, Waterglass so that it made high the mechanical performance. Based on the experimental result, the compressive strengths increased as the quantity of the Meta-kaolin increased. And a mechanical strengths appeared according to the concentration of an alkali solution so that it was different. XRD, FT-IR have been used to characterize mechanical performance.

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Surface Treatment Technology for Metal Corrosion Layer Focusing on Copper Alloy

  • Yang, Eun-Hee;Han, Won-Sik;Choi, Kwang-Sun;Lee, Young-Hoon;Ham, Chul-Hee;Hong, Tae-Kee
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.2
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    • pp.176-182
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    • 2014
  • Using alkali treatment solution, neutrality treatment solution and acid treatment solution, the surface corrosion layer of copper plates and bronze plates that have been artificially corroded using HCl, $H_2SO_4$ and $HNO_3$ solutions were removed. In the case of alkali treatment solution, only air oxidation in the form of black tenorite and white cuproous chloride remained without being removed. In the case of using a neutrality treatment solution, a anhydrous type layer of reddish brown cupric chloride remained without being removed, together with this black and white corrosion substance. In the case of using an acid treatment solution, this red corrosion substance also remained, but all of the oxide was removed on the surface of the specimen that was treated by alternatively using alkali treatment solution and acid treatment solution. In the case of this treatment solution with the order of alkali-acid, oxidation no longer proceeded only through the distilled water cleaning process after treatment, thereby showing that oxidation from the cleaning solution no longer proceeded.

Effect of Color Developing by Alkali and Heating of Cotton Fabrics Dyed with Persimmon Extract (알칼리와 열처리에 의한 면직물의 감즙염색 발색효과)

  • Kim, Ok-Soo;Jang, Jeong-Dae
    • Fashion & Textile Research Journal
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    • v.13 no.6
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    • pp.972-982
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    • 2011
  • The purpose of this study is to improve the method of color developing with alkali solution as a promotor of color developing for feasible use. Cotton fabric was dyed with persimmon extract ranged with 0~3% alkali component with 5 types of strong to mild alkali solution. Heat treatment for color developing was applied to fabric dyed with persimmon extract and alkali mixing solution. Tests were carried out to analyze the change of surface color, ${\Delta},Ea^*b^*$, and water repellent of the dyed cotton fabric. The alkali mixing sample showed higher ${\Delta},Ea^*b^*$ value than control one without alkali mixing on the base of dyed fabric due to high color developing by alkali in the initial step of dyeing process. As alkali concentration increased, deeper dark color appeared on the fabric. The fabric color was changed to more dark in the application of sodium hydroxide, sodium carbonate, potassium carbonate in the initial step of dyeing process but color was not changed by increased heating time. However, the fabric showed a slight dark color with sodium acetate and more color change than that of the fabric dyed with persimmon extract without alkali. Therefore, sodium acetate seemed to a suitable promotor for color developing in persimmon extract dyeing. Property of water repellent was showed after color developing by heating with low concentration of alkali treatment.

Some Interference Studies in Alkali and Alkali-Earth Metal Determination of Silicates by Atomic Absorption Spetrophotometry (원자흡광분석법에 의한 규산염중의 알칼리 및 알칼리토금속 정량시의 간섭에 대하여)

  • 박순자
    • Journal of the Korean Ceramic Society
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    • v.13 no.4
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    • pp.15-19
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    • 1976
  • Mutual interferences of alkali and alkali-earth metals in atomic absorption were examined. For determination of Na or K interfering elements increase the absorbancy, and for Ca or Mg decrease. Since influences of coexisting elements become nearly constant by addition of large amount of same coexisting element, could be use mixed standard solution for alkali or alkali-earth metal determination in the presence of other alkali and alkali-earth metals. The metals can be readily incorporated into scheme of rapid silicate analysis. Precision and accuracy are good.

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Alkaline Hydrolysis of Polyester/Acetate Union Fabric (폴리에스테르/아세테이트 혼용직물의 알칼리 가수분해)

  • Ju, Young Min;Kim, Myung Kyoon;Ahn, Kyoung Ryoul;Lee, Jeong Min
    • Textile Coloration and Finishing
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    • v.8 no.4
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    • pp.42-51
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    • 1996
  • Alkaline hydrolysis to improve the hand of PET/acetate union fabric was studied in relation to skin saponification and retarding effect of salts on the alkaline hydrolysis of cellulose acetate fiber, accelerating effect of salts on the alkaline hydrolysis of PET fiber, and changes of total hand value(T.H.V) of PET/acetate union fabric treated with alkali/salt solution. It was found that the rate of saponification of acetate was delayed by the addition of salts such as LiCl, NaCl and CH$_{3}$COONa into NaOH solution below 10 minutes. The rate of shrinkage of acetate fabric treated with 5g/l NaOH solution at 9$0^{\circ}C$ and 60 minutes showed 20 % but it was decreased 8% by. the addition of 120g/l Concentration of inorganic salts. We could know that the rate of alkaline hydrolysis of filament yarn treated with alkali solution at 9$0^{\circ}C$ and 60 minutes was delayed about 3 % using 2,000T/M of hard twist yarn, especially acetate filament treated with alkali solution at 9$0^{\circ}C$ and 10 minutes was delayed about 10%. T.H.V. of PET/acetate union fabric was increased from 2.77 to 3.04~3.18 by the addition of salts into alkali solution.

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Phenolphthalein Solution Discoloration determined by alkali concentration in long-term concrete check surface (장기재령 콘크리트의 할렬면에서 알칼리농도에 의한 페놀프탈레인 용액의 변색)

  • Park, Hyun;Lee, Jong-Rok;Kim, Kwang-Ki;Kim, Woo-Jae;Kim, Jong-Sub;Jung, Sang-Jin
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2008.05a
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    • pp.183-186
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    • 2008
  • Carbonation is measured as Phenolphthalein Solution, it is possible to confirm the scope of alkali through acid and basic reaction. Then, Concrete Basic Reaction is decided according to alkali concentration depending on Potassium Hydroxide Now that Carbonation is gradually produced toward inner side from outer side, with time going by, it doesnt work, to some adequate depth, in as fast time as compulsory facilitating test. Thus, this research thesis made a comparative analysis on concrete phenomenal discoloration borderline following Phenolphthalein Solution, as part of a bid to measure Carbonation. Also, the thesis measured Concrete Alkali Concentration. The result showed that concrete coloring is classified into red and scarlet according to alkali concentration, and into borderline breakpoint of the speckle of scarlet and carbonation reaction. The higher chroma becomes with concrete decolorizing, the higher alkali concentration becomes.

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A Study on the Behavior of Cation in Cement Paste (시멘트 경화체내 양이온 거동에 관한 연구)

  • 윤성진;소승영;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.11a
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    • pp.549-554
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    • 2001
  • It is possible for concrete using sea sand to contain chloride ion as well as cation such as Na$^{+}$and $K^{+}$ during mixing process. It is known that some cations such as Na$^{+}$and $K^{+}$ remain in pore solution without binding In this study, therefore, we intend to inspect the behavior of cations in cement paste as well as NaCl, CaCl$_2$ and KCI through analysis of pore solution extracted from cement paste with high pressure vessel. As a result, increase of alkali ions by adding sea sand and admixtures to the fresh concrete means use of the cement contained high alkali contents. In this case, alkali ions in pore solution can decrease durability of cement products causing alkali-aggregate reaction or accelerated carbonation. So it needs to be studied.studied.

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Deterioration of Cement Matrix with Alkali-free Accelerator Exposed to Sulfate Media (황산염환경에 노출된 알카리프리계 급결제 사용 시멘트경화체의 성능저하)

  • Lee, Seung-Tae;Hooton, R.D.;Kim, Seong-Soo;Kim, Dong-Gyou
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.277-280
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    • 2006
  • This paper presents the findings on the sulfate resistance of mortar specimens with or without alkali-free accelerator exposed to sodium sulfate solution for 270 days. Test results confirms a negative effect of alkali-free accelerator on the sulfate deterioration. Additionally, the influences of exposure concentration and temperature of sulfate solution on expansion were investigated. Especially, at a high concentration of solution a significant expansion of mortar specimens with alkali-free accelerator was observed. Further, low temperature also promoted the deterioration of the cement system due to sulfate attack.

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Improving Functional Properties of Fish Meal Protein (어분 단백질의 기능성 개량)

  • YOU Byeong-Jin;LEE Kang-Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.23 no.5
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    • pp.401-406
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    • 1990
  • In order to assess fish meal as food protein source which contains heat denatured pro-tein, functional properties of fish meal protein to be treated with alkaline were examined. Ratio of fish meal to 0.2N NaOH solution for extract solvent which were 1:10 showed good results of extracted and recovered amount of fish meal protein. pH 4.5, solubility of protein treated with alkaline revealed the lowest value. Until concentrations of alkaline treated protein solution reached $0.7\%$, its emulsifying capacity steeply decreased. Emusifying capacity of alkali treated protein were higher value at pH 9.0 than pH 4.0 and 7.0, and also were higher quantity in 0.5M NaCl solution than that of 0.1M. Heating time of fish meal protein to be treated with alkaline reached until 30 mins, its fat binding capacity indicated little change and that of heating time 60 mins decreased. Gel forming concentrations of fish meal protein to be treated with alkali for 15 mins or less were $20\%$ but those of 30 and 60 mins were $25\%$. When treating time of fish meal protein with alkali solution reached till 20 mins, viscosity of alkali treated protein solution steeply decreased.

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Removal of Pb2+ ion from aqueous solution Using crab shell treated by acid and alkali (산-염기 처리한 게 껍질에 의한 수풍의 납 이온 제거)

  • 김동석
    • Journal of Environmental Science International
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    • v.12 no.4
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    • pp.469-476
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    • 2003
  • In order to examine the pre-treatment effect of crab shell en Pb$^{2+}$ removal by crab shell in aqueous solution, acid and alkali pre-treated crab shell were used. Electron microscopy techniques such as TEM (transmission electron microscopy) and SEM (scanning electron microscopy), and EDX (energy dispersive X-ray) and FTIR (Fourier transform infrared) spectrometry techniques were used to investigate the process of Pb$^{2+}$ removal by acid and alkali pre-treated crab shell. The Pb$^{2+}$ removal by acid pre-treated crab shell was much lower than that by untreated crab shell because of the decrease of CaCO$_3$ from the crab shell. However, the Pb$^{2+}$removal by alkali pre-treated crab shell increased compared to that by untreated crab shell. The results were confirmed by TEM, SEM, EDX and FTIR.nd FTIR.