• Title/Summary/Keyword: Alkali

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New Approaches to the Control of Pathogenic Oral Bacteria (바이오필름을 생성하는 병원성 구강 세균을 제어하는 새로운 접근법)

  • Cho, Soo Jeong
    • Journal of Life Science
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    • v.31 no.1
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    • pp.100-108
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    • 2021
  • In the oral cavity, there are hundreds of microbial species that exist as planktonic cells or are incorporated into biofilms. The accumulation and proliferation of pathogenic bacteria in the oral biofilm can lead to caries and periodontitis, which are typical oral diseases. The oral bacteria in the biofilm not only can resist environmental stress inside the oral cavity, but also have a 1,000 times higher resistance to antibiotics than planktonic cells by genes exchange through the interaction between cells in the oral biofilm. Therefore, if the formation of oral biofilm is suppressed or removed, oral diseases caused by bacterial infection can be more effectively prevented or treated. In particular, since oral biofilms have the characteristic of forming a biofilm by gathering several bacteria, quorum sensing, a signaling system between cells, can be a target for controlling the oral biofilm. In addition, a method of inhibiting biofilm formation by using arginine, an alkali-producing substrate of oral bacteria, is used to convert the distribution of oral microorganisms into an environment similar to that of healthy teeth or inhibit the secretion of glucosyltransferase by S. mutans to inhibit the formation of non-soluble glucans. It can be a target to control oral biofilm. This method of inhibiting or removing the oral biofilm formation rather than inducing the death of pathogenic bacteria in the oral cavity will be a new strategy that can selectively prevent or therapeutic avenues for oral diseases including dental caries.

Current Research Trends for Recovery of Rare Earth Elements Contained in Coal Ash (석탄재에 포함된 희토류 회수 연구동향)

  • Kim, Young-Jin;Choi, Moon-Kwan;Seo, Jun-Hyung;Kim, Byung-Ryeol;Cho, Kye-Hong
    • Resources Recycling
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    • v.29 no.6
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    • pp.3-14
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    • 2020
  • This study aims to introduce and review on the recovery technologies of rare earth elements(REEs) from coal ash. Many researchers have been carried out by various beneficiation processes, such as particle size separation, magnetic separation, specific gravity, and flotation to recover rare earth elements from coal ash generated from Pulverized Coal(PC) boiler. Through the beneficiation process, it was confirmed that concentration of rare earth elements was much lower than the 4,700 ppm, and that additional enrichment treatment through wet process was needed for the products recovered after the beneficiation process. It was confirmed that the rare earth elements contained in coal ash were applied to the leaching process after pretreatment such as alkali-fusion to improve leaching efficiency. Although beneficiation and leaching methods have been studied, its optimum recovery technologies for rare earth elements not been confirmed up to now, research on the recovery of rare earth contained in coal ash is reported to continue. In case of Korea, the technology for the recovery of rare earth elements from coal ash and coal by-product could not been confirmed up to present. In these reasons, it is urgent to develop technologies such as beneficiation and leaching process continuously.

Inhibition of Tyrosinase by Metabolites Originating from Thrichoderma atroviride (Thrichoderma atroviride 배양액의 tyrosinase 억제제에 관한 연구)

  • Kang, Dong Woo;Kim, Kyu-Min;Kim, Ye-Seong;Seo, Yu-Jin;Song, Da-Yeong;Oh, Da-Yun;Choi, Si-On;Hwang, Ju-Hyeon;Kim, Sam Woong;Bang, Kyu Ho;Gal, Sang Wan
    • Journal of Life Science
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    • v.31 no.1
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    • pp.47-51
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    • 2021
  • In today's society, functional whitening cosmetics are important to beauty. Fungi are known to produce a variety of whitening-related metabolites. In this study, we searched for tyrosinase inhibitors with metabolic products derived from Trichoderma atroviride supernatant in order to apply a material for whitening functional cosmetics. In addition, the inhibitory effect was compared to arbutin, which has already been approved as a whitening raw material by the Korea Ministry of Food and Drug Safety (KMFDS). The metabolites from the T. atroviride supernatant showed higher tyrosinase inhibitory activity than that of arbutin. Some of the tyrosinase inhibitors were stable to heat, whereas some were unstable. The heat unstable material was exhibited in the case of samples treated with little amounts, such as 0.02~0.2%. They were very unstable in acidic and alkali pHs, especially under acidic conditions. However, it was found that a weakly-acidic to neutral pH range was the optimal working pH, especially neutral pH. Since the activity of the inhibitory substances in the T. atroviride supernatant was maintained regardless of proteinase K treatment, it was assumed that the metabolites, but not the bioactive peptides, were involved in the activity. In summary, we propose that the metabolites derived from T. atroviride supernatant have strong potential as whitening raw material.

Reviews on an Improvement and Measurement of the Hydrophobicity for Carbon Materials (탄소재료의 소수성 향상 방법 및 측정 방법에 대한 고찰)

  • Kang, Yu-Jin;Kim, Yu-Jin;Jang, Min-Hyeok;Jo, Hyung-Kun;Yoon, Seong-Jin;Han, Gyoung-Jae;Cho, Hye-Ryeong;Seo, Dong-Jin;Park, Joo-Il
    • Journal of the Korea Organic Resources Recycling Association
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    • v.30 no.4
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    • pp.41-50
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    • 2022
  • Recently, research on carbon adsorbents has been active as an interest in improving the environment such as indoor and outdoor air quality. Considering that causative substances deteriorate the air quality are basically volatile organic compounds, it is important to improve the hydrophobicity of the carbon materials for better removal efficiency. This study presents a method for improving hydrophobicity of carbon and a measurement of the hydrophobicity. Generally, methods of improving the hydrophobicity of carbon materials are heat treatment, acid/alkali treatment, coating and immersion with hydrophobic materials. However, it collapses the pore structure and reduces the adsorption capacity. Therefore, this study briefly introduce not only the general method for improving carbon materials' hydrophobicity but also the method for converting the precursor of the material is briefly introduced. Futhermore, this study introduces a analytical technique used to determine hydrophobic modification or not, and aims to enhance the understanding of carbon materials.

Utilization of Upgraded Solid Fuel Made by the Torrefaction of Indonesian Biomass (인도네시아 바이오매스 반탄화를 통해 제조된 고품위 고형연료의 활용)

  • Yoo, Jiho
    • Clean Technology
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    • v.26 no.4
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    • pp.239-250
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    • 2020
  • Biomass is an abundant renewable energy resource that can replace fossil fuels for the reduction of greenhouse gas (GHG). Indonesia has a large number of cheap biomass feedstocks, such as reforestation (waste wood) and palm residues (empty fruit bunch or EFB). In general, raw biomass contains more than 20% moisture and lacks calorific value, energy density, grindability, and combustion efficiency. Those properties are not acceptable fuel attributes as the conditions currently stand. Recently, torrefaction facilities, especially in European countries, have been built to upgrade raw biomass to solid fuel with high quality. In Korea, there is no significant market for torrefied solid fuel (co-firing) made of biomass residues, and only the wood pellet market presently thrives (~ 2 million ton yr-1). However, increasing demand for an upgraded solid fuel exists. In Indonesia, torrefied woody residues as co-firing fuel are economically feasible under the governmental promotion of renewable energy such as in feed-in-tariff (FIT). EFB, one of the chief palm residues, could replace coal in cement kiln when the emission trading system (ETS) and clean development mechanism (CDM) system are implemented. However, technical issues such as slagging (alkali metal) and corrosion (chlorine) should be addressed to utilize torrefied EFB at a pulverized coal boiler.

Application of Ferrate (VI) for Selective Removal of Cyanide from Plated Wastewater (도금폐수 중 시안(CN)의 선택적 제거를 위한 Ferrate (VI) 적용)

  • Yang, Seung-Hyun;Kim, Younghee
    • Clean Technology
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    • v.27 no.2
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    • pp.168-173
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    • 2021
  • The treatment of plated wastewater is subject to various and complex processes depending on the pH, heavy metal, and cyanide content of the wastewater. Alkali chlorine treatment using NaOCl is commonly used for cyanide treatment. However, if ammonia and cyanide are present simultaneously, NaOCl is consumed excessively to treat ammonia. To solve this problem, this study investigated 1) the consumption of NaOCl according to ammonia concentration in the alkaline chlorine method and 2) whether ferrate (VI) could selectively treat the cyanide. Experiments using simulated wastewater showed that the higher the ammonia concentration, the lower the cyanide removal rate, and the linear increase in NaOCl consumption according to the ammonia concentration. Removal of cyanide using ferrate (VI) confirmed the removal of cyanide regardless of ammonia concentration. Moreover, the removal rate of ammonia was low, so it was confirmed that the ferrate (VI) selectively eliminated the cyanide. The cyanide removal efficiency of ferrate (VI) was higher with lower pH and showed more than 99% regardless of the ferrate (VI) injection amount. The actual application to plated wastewater showed a high removal ratio of over 99% when the input mole ratio of ferrate (VI) and cyanide was 1:1, consistent with the molarity of the stoichiometry reaction method, which selectively removes cyanide from actual wastewater containing ammonia and other pollutants like the result of simulated wastewater.

A Study on Quality Improvement and Verification of Recycled Coarse Aggregate for Concrete Using an Impact Crusher with Radial Rotation (방사형 회전이 추가된 임팩트 크러셔를 이용한 콘크리트용 순환굵은골재 품질향상 및 검증 연구)

  • Jeon, Duk-Woo;Kim, Yong-Seong;Jeon, Chan-Soo;Choi, Won-Young;Cho, Won-Ig
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.2
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    • pp.133-142
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    • 2022
  • The purpose of this study is to develop an impact crusher with a radial rotating plate installed at the bottom, which is a shock absorber that can produce high-quality recycled coarse aggregate for concrete and to verify the effect of improving the quality performance of recycled coarse aggregate and its applicability through concrete tests. As a result, it showed improved quality in all items such as absolute dry density, absorption rate, abrasion resistance, Particle shape judgment rate, amount lost in the 0.08 mm sieve passing test, alkali aggregate reaction, clay mass, stability, and impurity content, and it was found to meet the criteria of recycled aggregate quality standards. In addition, the air volume and slump of concrete to which recycled coarse aggregate is applied meet all domestic standards. According to the test results of the compressive strength characteristics by age of concrete according to the mixing ratio of the recycled coarse aggregate, it was confirmed that the mixing ratio of the recycled coarse aggregate was applicable up to 60 %.

Characteristics of Carbozymethylated Substrates from Delignified Autohydrolyzed Substrates (탈리그닌한 자기가수분해 시료로부터 준비한 카복시메틸화 시료의 특성)

  • Cho, Nam-Seok
    • Journal of the Korean Wood Science and Technology
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    • v.32 no.1
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    • pp.28-34
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    • 2004
  • This study was performed to evaluate the characteristics of the carboxymethylated substrate from high reactive autohydrolyzed cellulose (HRC) and those of commercial α-cellulose (CAC) and refiner mechanical pulp (RMP). Saccharification rates of HRC substrate were achieved over 70% with 12 hr hydrolysis, about 90% with 24 hr, and 99.5% with 72 hr. CMCase and avicelase activities of cellulase onozuka were 4.09 ㎛ G/mg·min and 14.0 ㎛ G/mg·min, respectively. There were no any significant changes in cellulase activities with this substrate. The saccharification rates of CAC and RMP were very low, 57% and 38% with 72 hr, respectively. Those lignin-zero autohydrolyzed substrates, HRC and CAC, were highly carboxymethylated at the high alkali concentration, near 30%, for 3 hr. reaction, and resulted in 1.13-1.15 of D.S., besides 0.85 of D.S. from RMP. Water solubilities of carboxymethylated substrates were increased with an increase of D.S., 98-98.5% from HRC and CAC and 31.5% from RMP. RMP which has low specific surface area showed lower water retention values, compared to high values of 435 and 321% from CAC and HRC, respectively. There were no direct relationship between surface area and swelling ratio of the substrates.

Development of Alkali Stimulant-Based Reinforced Grouting Material from Blast Furnace Slag Powder (고로슬래그 미분말을 이용한 알칼리자극제 기반의 보강그라우트재 개발)

  • Seo, Hyeok;Jeong, Sugeun;Kim, Daehyeon
    • The Journal of Engineering Geology
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    • v.31 no.1
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    • pp.67-81
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    • 2021
  • Grouting is used for reinforcement and waterproofing of soft ground to increase its bearing capacity, reduce the impacts of rising or lowering groundwater levels, and reduce subsidence due to vibration and general causes. This study investigated the enhancement of grout strength and hardening time by the addition of reinforcing fibers, and the development of non-cement grouting materials from blast furnace slag. An experiment was performed to measure the increase in grout strength resulting from the addition of 0.5% increments of aramid and carbon reinforcing fibers. The results show that the uniaxial compressive strength of grout increases with increasing content of reinforcing fiber. Comparison of three admixtures of finely powdered blast furnace slag and 10%, 20%, and 30% calcium hydroxide stimulating agent showed that the uniaxial compressive strength of the mixture increases with increasing content of alkaline stimulant; however, the strength was lower than for 100% pure cement. The reaction of calcium hydroxide with blast furnace slag powder, which increases the strength of the grout, is more effective if injected as a solution rather than a powder.

Characterization of Materials and Color Formation for Black Potteries from the Proto-Three Kingdoms Period in Ulsan, Korea (울산지역 원삼국시대 흑색토기의 재질 및 발색 특성)

  • Kim, Su Kyoung;Jang, Sungyoon;Lee, Chan Hee
    • Journal of Conservation Science
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    • v.37 no.2
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    • pp.77-89
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    • 2021
  • In this study, materials and color formation techniques were assessed for black potteries excavated from the Janghyeon-dong, Jungsan-dong and Gyodong-ri sites during the Proto-Three Kingdoms period in Ulsan, Korea. Although the black potteries were black superficially, the inner cores were either black or reddish yellow. Microscopy analysis identified that body clay was used for reddish iron oxide rich soils with quartz, alkali feldspar and mica, along with grains of myrmechite texture. Additionally, as marginal differences exist in the contents of SiO2, Fe2O3 and CaO, the composition of the host rock and clay distributed around the sites was affected. Thus, we can deduce that pottery was made by soiling at a short distance. Raman spectroscopy results revealed that the black layer of the black pottery was used as amorphous combustion carbon. In addition, as a transparent layer of brown lacquer was observed on the substrate that was in contact with the surface layer, the black layer of the pottery induced black color development by a combination of combustion carbon and lacquer. Based on the mineral composition and microtexture of the body clay, the firing temperature of the potteries seemed to range from 750 to 850℃, whereas the lacquer layer was pyrolyzed at 468℃ by thermal analysis. Therefore, a combined layer of combustion carbon and lacquer, which formed the black color, was painted after the body clay was fired.