• Title/Summary/Keyword: Alkali

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Petrology of the Volcanic Rocks in the Paekrogdam Crater area, Mt. Halla, Jeju Island (제주도 한라산 백록담 분화구 일대 화산암류의 암석학적 연구)

  • 고정선;윤성효;강순석
    • The Journal of the Petrological Society of Korea
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    • v.12 no.1
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    • pp.1-15
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    • 2003
  • The Paekrogdam summit crater area, Mt. Halla, Jeju Island, Korea, composed of Paekrogdam trachyte, Paekrogdam trachybasalt, and Manseidongsan conglomerate in ascending order. Joint systems show concentric and radial patterns around the summit crate wall. The Paekrogdam crater is a summit crater lake which erupted the tuffs, scorias and lava flows of Paekrogdam trachybasalt after the emplaceent of Paekrogdam trachyte dome. SiO$_2$ contents of mafic and felsic lavas are respectively, 48.0∼53.7 wt.% and 60.7∼67.4 wt.%, reflecting bimodal volcanism. And lavas with SiO$_2$ between 53.7 wt.% and 60.7 wt.% are not found. According to TAS diagram and K$_2$O-Na$_2$O diagram, the volcanic rocks belong to the normal alkaline rock series of alkali basalt-trachybasalt-basaltic trachyandesite and trachyte association. Oxide vs. MgO diagrams represent that the mafic lavas fractionated with crystallization of olivine, clinopyroxene, magnetite and ilmenite and felsic trachyte of plagioclase and apatite. The characteristics of trace elements and REEs shows that primary magma for the trachybasalt magma would have been derived from partial melting of garnet peridotite mantle. In the discrimination diagrams, the volcanic rocks are plotted at the region of within plate basalt (WPB).

Material Property Evaluation for UFFA Rapid Setting Concrete including Calcium Hydroxide (수산화칼슘을 첨가한 UFFA 초속경 콘크리트의 물성특성 평가)

  • Jeon, Sung-Il;Nam, Jeong-Hee;An, Ji-Hwan;Kwon, Soo-Ahn
    • International Journal of Highway Engineering
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    • v.10 no.4
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    • pp.189-198
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    • 2008
  • Generally, UFF A(Ultra Fine Fly Ash) has merit that advances a greater concrete workability and activates a greater pozzolanic reaction than common fly ash due to its ultra fine particle size. These properties enhance concrete durability by reducing permeability and increasing resistance of alkali silica reaction(ASR) and sulfate attack, etc. Due to these reasons, UFFA can be used in a rapid setting concrete. The purpose of this study is to develop and evaluate the rapid setting concrete with UFF A as a repair material for early-opening-to-traffic. In previous studies, if only UFFA is added to the rapid setting concrete mixture, pozzolanic reaction doesn't happen actively. Therefore, in this study, the chemical and physical tests were performed for rapid setting concrete with UFFA including calcium hydroxide and the activity of pozzolanic reaction was evaluated. Finally, the effectiveness of this mixture on enhancing concrete durability was investigated. As results, adding UFF A decreased the water/cement ratio of concrete, and compensated the reduced portion of the early strength of concrete. Also, rapid setting concrete with UFFA including calcium hydroxide activated a greater pozzolanic reaction than normal-UFF A concrete. As calcium hydroxide increases, electrical indication of concrete's ability to resist chloride ion penetration is promoted significantly.

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Clean Room Structure, Air Conditioning and Contamination Control Systems in the Semiconductor Fabrication Process (반도체 웨이퍼 제조공정 클린룸 구조, 공기조화 및 오염제어시스템)

  • Choi, Kwang-Min;Lee, Ji-Eun;Cho, Kwi-Young;Kim, Kwan-Sick;Cho, Soo-Hun
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.25 no.2
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    • pp.202-210
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    • 2015
  • Objectives: The purpose of this study was to examine clean room(C/R) structure, air conditioning and contamination control systems and to provide basic information for identifying a correlation between the semiconductor work environment and workers' disease. Methods: This study was conducted at 200 mm and 300 mm semiconductor wafer fabrication facilities. The C/R structure and air conditioning method were investigated using basic engineering data from documentation for C/R construction. Furthermore, contamination parameters such as airborne particles, temperature, humidity, acids, ammonia, organic compounds, and vibration in the C/R were based on the International Technology Roadmap for Semiconductors(ITRS). The properties of contamination control systems and the current status of monitoring of various contaminants in the C/R were investigated. Results: 200 mm and 300 mm wafer fabrication facilities were divided into fab(C/R) and sub fab(Plenum), and fab, clean sub fab and facility sub fab, respectively. Fresh air(FA) is supplied in the plenum or clean sub fab by the outdoor air handling unit system which purifies outdoor air. FA supply or contaminated indoor air ventilation rates in the 200 mm and 300 mm wafer fabrication facilities are approximately 10-25%. Furthermore, semiconductor clean rooms strictly controlled airborne particles(${\leq}1,000{\sharp}/ft^3$), temperature($23{\pm}0.5^{\circ}C$), humidity($45{\pm}5%$), air velocity(0.4 m/s), air change(60-80 cycles/hr), vibration(${\leq}1cm/s^2$), and differential pressure(atmospheric pressure$+1.0-2.5mmH_2O$) through air handling and contamination control systems. In addition, acids, alkali and ozone are managed at less than internal criteria by chemical filters. Conclusions: Semiconductor clean rooms can be a pleasant environment for workers as well as semiconductor devices. However, based on the precautionary principle, it may be necessary to continuously improve semiconductor processes and the work environment.

Phytochemical-based Tannic Acid Derivatives as Draw Solutes for Forward Osmosis Process (정삼투 공정의 유도용질로서의 식물 화학물질 기반의 탄닌산 유도체)

  • Kim, Taehyung;Ju, Changha;Kang, Hyo
    • Membrane Journal
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    • v.28 no.3
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    • pp.157-168
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    • 2018
  • Potassium tannate (TA-K), which is prepared by base treatment of the bio-renewable tannic acid (TA), was evaluated for its potential application as a draw solute for water purification by forward osmosis. The forward osmosis and recovery properties of TA-K were systematically investigated. In the application of forward osmosis through the active layer facing feed solution (AL-FS) method, the water flux of TA-K draw solution was significantly higher than that of the TA draw solution, while that of the latter was not identified. At a low concentration of 100 mM, the osmotic pressure (1,135 mOsmol/kg) of the TA-K draw solution was approximately 6.5 times that (173 mOsmol/kg) of the NaCl draw solution. Furthermore, the water flux and specific salt flux (6.14 LMH, 1.26 g/L) of the TA-K draw solution at 100 mM were approximately 2.5 and 0.5 times those of the NaCl draw solution (2.46 LMH, 2.63 g/L) at the same concentration, respectively. For reuse, TA-K was precipitated by using a metal ion and recovered through membrane filtration. This study demonstrates the applicability of a phytochemical material as a draw solute for forward osmosis.

In-Vitro Development of Early Stage Mouse and Bovine Embryos to Blastocysts in TCM 199 Supplemented with nonspecific Immunostimulator $Barodon-FX^{(R)}$ (비특이 면역증강제 $Barodon-FX^{(R)}$ 첨가 TCM199에서 생쥐 및 소 초기배의 체외 배반포 발달에 관한 연구)

  • 정영채;나광빈;김창근;류재원;최수일;전경수;류범룡
    • Korean Journal of Animal Reproduction
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    • v.25 no.2
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    • pp.131-138
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    • 2001
  • This experiment was designed to evaluate effects of nonspecific immunostimulator(NIS) Barodon-FX(equation omitted), anionic alkali mineral complex and far-infrared radiation solution on in vivo-produced mouse and in vitro-produced bovine embryos to blastocyst development. Proportion of mouse embryos developing into blastocyst was not greater in BSA- and Barodon-added medium than in BSA-control, but there was signifcantly different(P < 0.05) in hatching and hatched blastocyst development between 0.25% Barodon-and PVP-contained medium(54.7%) than PVP-control(32.5%). BOEC and GC resulted in higher proliferation rate(24∼40% and 17∼22%, respectively) in 0.25∼0.5% Barodon-added medium than in controls, but proliferation of GC and CC greatly decreased in 1∼2% Barodon-added medium. Effect of Barodon on cell proliferation greatly varied among somatic cells. Proportion of early bovine embryos developing into morula and blastocyst was significantly greater(P < 0.05) in 0.5% Barodon-added medium(50% and 63.6%) than in control(31.6% and 27.4%) under co-culture with BOEC and GC, but developmental rate was not different between other Barodon treatments and control. These data indicate that effect of Barodon on cell proliferation significantly varied between somatic cells and that addition of 0.5% Barodon in BOEC-coculture system may further improve blastocyst development in early bovine embryos.

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Study on the Damage Mechanism by Salt of White Porcelain Figurine in Underglaze Iron (백자 철화 인물형 명기의 염 손상 메커니즘 연구)

  • Lee, Sun Myung;Jin, Hong Ju;Yun, Ji Hyeon;Kwon, Oh Young
    • Journal of Conservation Science
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    • v.36 no.5
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    • pp.368-382
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    • 2020
  • It was confirmed that a white porcelain figurine in underglaze iron was damaged after exhibition. This study analyzes the current state of salt damage on the artifact and identifies the factors contributing to its deterioration by examining the material characteristics of the artifact and exhibition environment. The analysis will thus assist in preparing a conservation scheme for artifacts. The crystallized carbonate on the surface of the white porcelain figurine is a water-soluble alkali salt with high hygroscopicity and high solubility in water. This solubility increases as the temperature increases. The figurine was low-fired at approximately 1000℃. A lead glaze was applied, and thin cracks were formed on the glazed surface, indicating poor surface properties. Our analysis suggested that the showcase used in the exhibition likely created a moist environment resulting from condensation, as it was exposed to high temperature and relative humidity, particularly in comparison to the exhibition room where the temperature was regulated using an air conditioner. In addition, the artifacts in the showcase were exposed to sudden changes in temperature and relative humidity as the air conditioner was repeatedly turned on and off. Therefore, it can be deduced that the soluble salt remaining on the white porcelain figurine moved toward the surface of the relatively weak glaze as a result of the temperature, and the crystallized salt exacerbated surface damage as the moisture evaporated in a dry environment.

A Study on the Silica Removal in Primary System using the Membrane Process (막 분리 공정을 이용한 1차 계통 실리카 제거에 관한 연구)

  • Kim Bong-Jin;Lee Sang-Jin;Yang Ho-Yeon;Kim Kyung-Duk;Jung Hee-Chul;Jo Hang-Rae
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.137-144
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    • 2005
  • Silica in primary system combines with an alkali grammatical particle metal and forms the zeolite layer which is hindering the heat transfer on the surface of the cladding. Zeolite layer becomes the cause of the damage in this way. The problems of the NPP's primary system have been issued steadily by EPRI. Through a series of experiments of the laboratory scale, we confirmed the applicability of NF membrane for silica removal, as silica rejection rate of NF membrane is about $60\;{\sim}\;70\%$ and boron rejection rate is about $10\;{\sim}\;20\%$. We accomplished a site experiment about four NF membranes manufactured by FilmTec and Osmonics Inc. In experiment using 400L of SFP water, when operation pressure is $10kg_{f}/cm^2$, we confirmed that the silica rejection rate of NF90-2540 manufactured by FilmTec Inc. is about $98\%$, boron rejection rate is about $43\%$. The silica rejection rate of NF270-2540 is about $38\%$, boron rejection rate is about $3.5\%$. Afterward, through additional experiments, such as long term characteristic experiments, we are going to design a optimum NF membrane system for silica removal.

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Comparison of Rice Yield and Grain Quality Characteristics between Mature and Reclaimed Paddy Fields in Honam Plain Area (호남평야지 숙답과 간척답의 수량 및 미질 특성 비교)

  • 정진일;이선용;김종호
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.40 no.3
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    • pp.382-390
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    • 1995
  • To compare the rice yield and grain quality characteristics between mature(MPF) and reclaimed paddy field(RPF), grain yield and its components, some physicochemical properties of rice grain and palatability of cooked rice were investigated for Dongjinbyeo grown at three different locations of mature and reclaimed paddy field, respectively, in south western part of Korea. Variation of culm length in mature paddy area was larger than that in reclaimed saline area. Panicle number per m$^2$ in RPF was more then that in MPF but grain number per m$^2$, filled grain ratio and 1, 000-grain weight in RPF were lower than those in MPT. Average yield of milled rice in RPF was 12% lower than that in MPF (5.l1t /ha). Daejeon showed the highest yielding among MPF and Yeongam reveald the highest grain production among RPF. RPF rices had slightly higher carbohydrate content and alkali digestibility but lower protein, fat and amylose content compared with MPF rices. RPF rices also exhibited higher mineral contents, Mg/K ratio, peak and hot viscosity compared with MPF rices. RPF rice showed slightly poor apparent grain quality but a little better eating quality of cooked rice compared with MPF rice.

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Studies on the Ripening Characteristics, Germination Speed and Quality among Different Floret of Japonica and Tongil Type of Rice under Different Growing Season (수도재배시기별 Japonica 및 Tongil형 품종의 영화간 등숙특성 발아세 및 미질연구)

  • 권규칠;박성규
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.34 no.3
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    • pp.310-323
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    • 1989
  • This study was carried out to find out the difference of ripening and growth characteristics among the different florets in same panicle. There were 2 different transplanting date (May 25 and June 10) and 6 varieties were used. Physiological ripening period, ripening speed, 1000 grain weight, germination speed and grain quality were studied among the different florets (1, 5 and 8 days after heading) in same panicle. Physiological ripening period was long in late transplanting, late flowering floret, and late varieties by 3-9 days in Japonica. Ripening speed and 1000 grain weight were high in early transplanting and early flowering florets. There was positive correlation among the ripening speed, 1000 grain weight and a average temperature but negative correlation between the ripening and physiological ripening period. Germination speed was excellent in early flowering floret after heading. There was difference in amylose content within varieties and different flowering grains and there was significant correlation between grain quality and meteorological factors in some varieties.

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A Preliminary Survey Result of Cu Occurrence in Tsogttsetsii Area, Mongolia (몽골 촉트체치 지역 동 산출지 예비조사결과)

  • Kim, In Joon;Lee, Jae Ho;Ryoo, Chung-Ryul;Lee, Bum-Han;Jin, Kwang Min;Davaasuren, Otgon-Erdene;Heo, Chul-Ho;Nam, Hyeong Tae
    • Economic and Environmental Geology
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    • v.50 no.4
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    • pp.313-324
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    • 2017
  • Tsogttsetsii area, an intrusive complex associated with Cu mineralization, is located in the South Gobi, Mongolia. We performed the cross geochemical and extended exploration survey in Tsogttsetsii area. Cu mineralization in Tsogttsetsii area is porphyry Cu type related with alkali granite intruded in Late Carboniferous to Early Permian. In the concentrated occurring to malachite appears extensively prophylitic alteration zone having a chlorite and epidote. As results of the survey, Cu contents of potable XRF and of chemical composition for altered rocks ranges 1.08 to 18.3% in the 30 points and 1.08 to 32.9% in the 13 points, respectively. Ore minerals identified in XRD analysis and polarizing microscope that samples of copper oxides were composed mainly of malachite, azurite, permingeatite and cuprite and the other minerals are pyrite, chalcopyrite, pyrargyrite, dickite, calcite, chlorite and epidote. Mineralization can be considered occurring to selectively some granite of the surrounding aplite and faults in the only upper part coming up the hydrothermal solution of the remaining residual magma after the aplite intrusion.