• 한국결정성장학회지
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• 제25권3호
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• pp.121-126
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• 2015

A novel $Ce^{3+}$ doped $Lu_3MgAl_3SiO_{12}$ phosphor ($Lu_{2.94}Ce_{0.06}MgAl_3SiO_{12}$) was successfully synthesized by a conventional solid-state reaction at $1450^{\circ}C$ for 5 h. The crystal structure of the synthesized phosphor powder was characterized by X-ray diffraction and Rietveld refinement. The prepared phosphor powder showed a broad peak at 550 nm, and the temperature dependence on photoluminescence properties of the prepared $Lu_{2.94}Ce_{0.06}MgAl_3SiO_{12}$ phosphor was investigated from 300 to 525 K. The activation energy for thermal quenching was determined by Arrhenius fitting. The experimental results clearly indicate that prepared $Lu_{2.94}Ce_{0.06}MgAl_3SiO_{12}$ phosphor has great potential for a down-conversion yellow phosphor in white light-emitting diodes.

• 한국주조공학회지
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• 제36권5호
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• pp.153-158
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• 2016

The lost foam casting process was used to fabricate Al-Si-Mg cast specimens, and the effects of the chemical composition and process variables on the tensile properties and the mold filling ability were investigated. Some porosity formation was observed in thick sections of the casting and better tensile properties were obtained for thin sections, presumably because of their lower porosity and the higher cooling rate. Tensile properties were not clearly enhanced by grain refining treatment with Ti; however, the elongation was significantly improved by Sr modification of the Al-Si-Mg alloy. The mold filling distance was generally proportional to the pouring temperature of the melt, and the distance was also increased by the addition of Ti.

• 한국재료학회지
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• 제18권5호
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• pp.241-246
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• 2008

Pure Mg and Mg-6wt.%Al alloy were coated by the plasma electrolytic oxidation with various coating times and the microstructural and mechanical characteristics of the coatings were investigated. The coatings on pure Mg and Mg-6wt.%Al alloy consisted of MgO and $Mg_2SiO_4$. The surface roughness and thickness of the coatings became larger as the coating time increased. The coatings on the Mg-6wt.%Al alloy were more uniform and thicker than those on pure Mg. The microhardness and friction coefficient of the coatings increased progressively as the coating time increased. In addition, the coatings on the Mg-6wt.%Al alloy compared to pure Mg showed improved microhardness and a better friction coefficient.

• 한국주조공학회지
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• 제19권5호
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• pp.433-439
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• 1999

Rapidly solidified Mg-Al-Si base alloys containing Ca were obtained by melt spinning. The melt-spun ribbons were aged isochronally or isothermally to investigate age hardening phenomena and microstructural change according to the alloy composition. Age hardening occurred after aging at $200^{\circ}C$ for 1h mainly due to the precipitation of $Al_2Ca$ and $Mg_2Ca$, which have coherent interfaces with the matrix. With the increase of Ca content, the hardness values of the alloy ribbons were increased. Among the alloys, Mg-10Al-2 Si-3Ca alloy showed a good thermal stability at elevated temperature.

• 대한금속재료학회지
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• 제49권8호
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• pp.614-618
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• 2011

Nanopowders of MgO, $Al_2O_3$ and $SiO_2$ were made by high energy ball milling. The rapid sintering of nanostructured $MgAl_2O_4-Mg_2SiO_4$ composites was investigated by a high-frequency induction heating sintering process. The advantage of this process is that it allows very quick densification to near theoretical density and inhibition of grain growth. Nanocrystalline materials have received much attention as advanced engineering materials with improved physical and mechanical properties. As nanomaterials possess high strength, high hardness, excellent ductility and toughness, undoubtedly, more attention has been paid for the application of nanomaterials. Highly dense nanostructured $MgAl_2O_4-Mg_2SiO_4$ composites were produced with simultaneous application of 80MPa pressure and induced output current of total power capacity (15 kW) within 2min. The sintering behavior, gain size and mechanical properties of $MgAl_2O_4-Mg_2SiO_4$ composites were investigated.

• 한국분말재료학회지
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• 제28권2호
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• pp.134-142
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• 2021

In this study, AlSi10Mg powders with average diameters of 44 ㎛ are additively manufactured into bulk samples using a selective laser melting (SLM) process. Post-heat treatment to reduce residual stress in the as-synthesized sample is performed at different temperatures. From the results of a tensile test, as the heat-treatment temperature increases from 270 to 320℃, strength decreases while elongation significantly increases up to 13% at 320℃. The microstructures and tensile properties of the two heat-treated samples at 290 and 320℃, respectively, are characterized and compared to those of the as-synthesized samples. Interestingly, the Si-rich phases that network in the as-synthesized state are discontinuously separated, and the size of the particle-shaped Si phases becomes large and spherical as the heat-treatment temperature increases. Due to these morphological changes of Si-rich phases, the reduction in tensile strengths and increase in elongations, respectively, can be obtained by the post-heat treatment process. These results provide fundamental information for the practical applications of AlSi10Mg parts fabricated by SLM.

• 열처리공학회지
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• 제31권6호
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• pp.300-306
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• 2018

In the present study we proposed new equations to predict the liquidus temperature curve for hypoeutectic Al-Si-Cu-Mg alloy. A thermodynamic simulation was carried out to calculate the liquidus temperature, eutectic temperature and eutectic Si concentration with different Si, Cu, and Mg contents in hypoeutectic Al-Si alloys. Regressed equations were derived using the thermodynamic simulation results by multiple regression analysis. The proposed equations were compared with the equations reported previously by other researchers and agreed better with the experimental data. The addition of Cu and Mg lowered the eutectic temperature. The eutectic Si concentration was decreased by adding Cu whereas that was increased by adding Mg. Al-Si binary phase diagram was successfully predicted with a consideration of the effect of Cu and Mg addition by using the proposed equations.

• 한국분말재료학회지
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• 제29권5호
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• pp.363-369
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• 2022

AlSi10Mg alloys are being actively studied through additive manufacturing for application in the automobile and aerospace industries because of their excellent mechanical properties. To obtain a consistently high quality product through additive manufacturing, studying the flowability and spreadability of the metal powder is necessary. AlSi10Mg powder easily forms an oxide film on the powder surface and has hydrophilic properties, making it vulnerable to moisture. Therefore, in this study, AlSi10Mg powder was hydrophobically modified through silane surface treatment to improve the flowability and spreadability by reducing the effects of moisture. The improved flowability according to the number of silane surface treatments was confirmed using a Carney flowmeter. In addition, to confirm the effects of improved spreadability, the powder prior to surface treatment and that subjected to surface treatment four times were measured and compared using s self-designed recoating tester. The results of this study confirmed the improved flowability and spreadability based on the modified metal powder from hydrophilic to hydrophobic for obtaining a high-quality additive manufacturing product.

• 광물과 암석
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• 제34권1호
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• pp.1-14
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• 2021

운산 금 광상은 한반도의 3대(대유동 광상, 광양 광상) 금 광상중의 하나였다. 이 광상의 지질은 선캠브리아기의 변성퇴적암류와 중생대의 반상화강암으로 구성된다. 이 광상은 선캠브리아기의 변성퇴적암류와 중생대의 반상화강암내에 발달된 단층대를 따라 충진한 함 금 석영맥 광상으로 조산형 금 광상에 해당된다. 이 광상의 석영맥은 광물조합에 따라 1) 방연석-석영맥형, 2) 자류철석-석영맥형, 3) 황철석-석영맥형, 4) 페크마틱 석영맥형, 5) 백운모-석영맥형 및 6) 단순석영맥형으로 분류된다. 연구된 석영맥은 황철석-석영맥형이며 견운모화작용, 녹니석화작용 및 규화작용이 관찰된다. 백색운모는 유색대에서 백색석영, 황철석, 녹니석, 금홍석, 모나자이트, 저어콘, 인회석, 칼리장석 및 방해석 등과 함께 세립질 내지 중립질 입단으로 산출된다. 이 백색운모의 화학조성은 (K0.98-0.86Na0.02-0.00Ca0.01-0.00Ba0.01-0.00 Sr0.00)1.00-0.88(Al1.70-1.57Mg0.22-0.09Fe0.23-0.10Mn0.00Ti0.04-0.02Cr0.01-0.00V0.00Ni0.00)2.06-1.95 (Si3.38-3.17Al0.83-0.62)4.00O10(OH2.00-1.91F0.09-0.00)2.00로써 이론적인 이중팔면체형 운모류 값보다 Si가 높고 K, Na, Ca는 낮다. 이 광상의 엽리상 석영맥에서 산출되는 백색운모의 화학조성 변화는 팬자이틱(phengitic) 또는 Tschermark 치환[(Al3+)VI+(Al3+)IV <-> (Fe2+ 또는 Mg2+)VI+(Si4+)IV] 및 직접적인 (Fe3+)VI <-> (Al3+)VI 치환에 의해 일어났음을 알 수 있다. 엽리상 석영맥에서 산출되는 녹니석의 화학조성은 (Mg1.11-0.80Fe3.69-3.14Mn0.01-0.00Zn0.01-0.00K0.07-0.01Na0.01-0.00Ca0.04-0.01Al1.66-1.09)5.75-5.69 (Si3.49-2.96Al1.04-0.51)4.00O10 (OH)8로써 이론적인 녹니석보다 Si 함량이 높다. 이 녹니석의 화학조성 변화는 팬자이틱(phengitic) 또는 Tschermark 치환(Al3+,VI+Al3+,IV <-> (Fe2+ 또는 Mg2+)VI+(Si4+)IV) 및 팔면체적 Fe2+ <-> Mg2+ (Mn2+) 치환에 의해 일어났음을 알 수 있다. 따라서 운산 광상의 엽리상 석영맥 및 변질광물은 조산운동 시 연성전단(ductile shear) 시기에 형성되었음을 알 수 있다.

• 한국재료학회지
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• 제33권1호
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• pp.8-14
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• 2023

In order to broaden the range of application of light weight aluminum alloys, it is necessary to enhance the mechanical properties of the alloys and combine them with other materials, such as cast iron. In this study, the effects of adding small amounts of Cu and Zr to the Al-Si-Mg based alloy on tensile properties and corrosion characteristics were investigated, and the effect of the addition on the interfacial compounds layer with the cast iron was also analyzed. Although the tensile strength of the Al-Si-Mg alloy was not significantly affected by the additions of Cu and Zr, the corrosion resistance in 3.5 %NaCl solution was found to be somewhat lowered in this research. The influence of Cu and Zr addition on the type and thickness of the interfacial compounds layer formed during compound casting with cast iron was not significant, and the main interfacial compounds were identified to be Al₅FeSi and Al₈Fe₂Si phases, as in the case of the Al-Si-Mg alloys.