• Title/Summary/Keyword: Al-중합체 $Al_{13}$-Tridecamer

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Characteristics of Water Contamination and Precipitates of Acid Mine Drainage, Bongyang Abandoned Coal Mine, Danyang, Chungbuk Province with Emphasis on Fe and Al behaviors (충북 단양 봉양폐탄광 산성광산배수의 수질오염과 침전물의 특성: 철, 알루미늄의 거동을 중심으로)

  • Choo, Chang Oh;Lee, Jin Kook
    • The Journal of Engineering Geology
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    • v.29 no.2
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    • pp.163-183
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    • 2019
  • We investigated acid mine drainage (AMD) of Bongyang abandoned coal mine, Danyang, Chungbuk Province with emphasis on geochemical contaminants in AMD and precipitates using chemical analyses, XRD, SEM, IR, and $^{27}Al$ NMR. Water chemistry changes with pH and oversaturation of chemical species. According to calculation of saturation index, the AMD is saturated with various Fe, Al minerals. Orange or orcher precipitates are composed of schwertmannite and goethite, associated with Leptothrix orchracea bacteria, whereas whitish precipitates are composed mostly of alumimous minerals such as basaluminite with poor crystallinity. The whitish precipitates include trace $Al_{13}$-Tridecamer. It is important to control the precipitation and solubility of aluminous species for ensuring remediation and control for the AMD discharged from the Bongyang abandoned coal mine.

Fe and Al Behaviors in Precipitates and Pollution Characteristics of Acid Mine Drainage from the Donghae Abandoned Coal Mine, Taebaek, Korea (태백시 동해폐탄광 산성광산배수의 오염현황과 하상퇴적물 내 철, 알루미늄의 거동특성)

  • Choo, Chang Oh;Park, Jung-Won;Lee, Jin Kook
    • The Journal of Engineering Geology
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    • v.29 no.4
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    • pp.579-598
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    • 2019
  • We investigated geochemical contaminants and Fe, Al behavior in precipitates of acid mine drainage (AMD) from the Donghae abandoned coal mine, Taebaek, Gangwon Province using aqueous chemical analyses, XRD, IR, and 27Al NMR, Our results showed that water chemistry changed with pH and Eh, and saturation indices of chemical species in the AMD. According to saturation calculated by visual MINTEQ, the AMD was saturated with various Fe-, Al-oxyhydroxide minerals. Reddish brown precipitates are composed of schwertmannite, ferrihydrite, and goethite, whereas whitish precipitates are composed mostly of alumimous minerals such as poorly crystallized basaluminite with trace Al13-Tridecamer. It is important to apply active treatment methods rather than simple storage pond and to control the precipitation and solubility of iron species and aluminous species for ensuring remediation and control for the AMD discharged from the Donghae abandoned coal mine.