• Advances in nano research
• /
• 제13권4호
• /
• pp.407-416
• /
• 2022

In this study, the gravitating mechanical stir casting method was used to fabricating the Nb₂O₅/AZ31 magnesium matrix nanocomposites. Niobium pentoxide (Nb₂O₅) used as reinforcement with two different weight percentages (3 wt % and 6 wt %). The influence of Nb₂O₅ on microstructure and mechanical properties has been investigated. The microstructure analysis showed that the composites are mainly composed of the primary α-magnesium phase and phase β-Mg₁₇Al₁₂ secondary phase. The secondary phase was dispersed evenly along the grain boundary of the Mg phase. The Nb₂O₅/AZ31 nanocomposites revealed that the grain size and its lamellar shape (β-Mg₁₇Al₁₂) were gradually refined. Different strengthening mechanisms were assessed in terms of their contributions. Results showed that composite material properties of hardness, yield strength, and fracture study were directly related to Nb₂O₅ as a reinforcement. The maximum values of the mechanical properties were achieved with the addition of 3 wt% Nb₂O₅ on the AZ31 alloy.

• 대한기계학회논문집A
• /
• 제35권3호
• /
• pp.273-279
• /
• 2011

입자 강화 복합재료는 입자의 크기가 감소할수록 그 항복강도가 증가하므로, 입자의 크기에 대한 길이 스케일을 보인다. 항복강도에 대한 이러한 길이 스케일은 복합재가 압밀된 후 냉각될 때 기지재와 입자간 열팽창계수의 상이함에 의하여 입자 주위 기지재에 펀칭되는 기하적 필수 전위가 주된 영향을 미치는 것으로 알려져 있다. 본 연구에서는 입자 강화 복합재의 연속체 강도해석 모델링에 사용할 수 있는 두 가지 전위 펀칭이론들에 대하여 전산적으로 검토하였다. 즉, 입자 주위에 펀치되는 전위 영역의 크기를 계산하는 대표적인 두 가지 이론들인 Shibata 등 및 Dunand and Mortensen 이론으로부터 전위 펀치 영역의 크기를 계산하고, 이를 유한요소해석에 적용하여 복합재의 항복 강도를 예측하였으며 실험값과 정성적으로 비교하였다. 본 연구에서 입자가 매우 작은 경우, 즉, 입자의 크기가 2.m이하인 경우에 두 이론 간에 극명한 차이를 보여주었으며, Shibata 등의 정식이 정성적으로 실험값에 더 근사한 것을 확인하였다.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2003년도 춘계학술대회
• /
• pp.61-66
• /
• 2003

In this paper, the effect of binder additive on the fracture toughness was metal matrix composite produced by squeeze casting method. In this study using the matrix is AC4CH and reinforcement used Aluminum borate whisker. Each MMC was produced by add inanimate binder ($SiO_2,\;Al2O_3,\;TiO_2$) to whiskers for increase the binding together of whiskers. Fracture toughness test were carry out in accordance with the ASTM E-399 standard test method, W=25mm, b=12.5mm CT(half size) specimen. However Base metal AC4CH was not meet the qualification of $P_m/P_Q<1.1$, so that test were performed $J_{IC}$ test. $K_{J_{IC}}$ value was measuring by $J_{IC}$ value change into $K_{IC}$. $J_{IC}$ test was carry out in accordance with the ASTM 1820.

• Bulletin of the Korean Chemical Society
• /
• 제34권5호
• /
• pp.1345-1348
• /
• 2013

We investigated the tribochemical and wear properties of Polytetrafluoroethylene (PTFE) based polymer matrix composites with nanoceramic (NC) ${\beta}$-sialon, and $Al_2O_3$ particles for the mechanical seal applications at low temperature. SEM showed that NC particles were homogeneously distributed in the polymer matrix and initiated the formation of the supramolecular spherulites around NC. From the temperature stimulated depolarization (TSD) current results, it was analyzed that the surface charge on nanoceramic affected the formation of the spherulites structure. 2 wt % $Al_2O_3$ NC did not degrade the mechanical properties of PTFE so that composites showed the similar values of tensile strength, elongation at the rupture and friction coefficient as those of neat PTFE. However, the composite with 2 wt % $Al_2O_3$ NC revealed the improved wear resistance, wear rate of 0.4-1.2 mg/h at room temperature and 0.28 mg/h at $-40^{\circ}C$, respectively, while the neat PTFE the 70-75 mg/h at room temperature and 70.3 mg/h at $-40^{\circ}C$.

• Membrane and Water Treatment
• /
• 제6권4호
• /
• pp.309-321
• /
• 2015

We report in this study the synthesis of mixed matrix reverse osmosis membranes by interfacial polymerization (IP) of thin film nanocomposite (TFNC) on porous polysulfone supports (PS). This paper investigates the synthesis of ZnO nanoparticles (NPs) using the sol-gel processing technique and evaluates the performance of mixed matrix membranes reached by these aerogel NPs. Aqueous m-phenyl diamine (MPD) and organic trimesoyl chloride (TMC)-NPs mixture solutions were used in the IP process. The reaction of MPD and TMC at the interface of PS substrates resulted in the formation of the thin film composite (TFC). NPs of ZnO with a size of about 25 nm were used for the fabrication of the TFNC membranes. These membranes were characterized and evaluated in comparison with neat TFC ones. Their performances were evaluated based on the water permeability and salt rejection. Experimental results indicated that the NPs improved membrane performance under optimal concentration of NPs. By changing the content of the filler, better hydrophilicity was obtained; the contact angle was decreased from $74^{\circ}$ to $32^{\circ}$. Also, the permeate water flux was increased from 26 to 49 L/m2.h when the content of NPs is 0.1 (wt.%) with the maintaining of lower salt passage of 1%.

• 한국표면공학회지
• /
• 제20권2호
• /
• pp.49-59
• /
• 1987

The properties of $Cr_2O_3-Al_2O_3-SiO_2$ composite oxide coatings on steel surface were investigated. The results obtained were as follows: The microhardness of oxide coating layer increased with increasing heat-treatment temperature and $Cr_2O_3$ content in coating layer. The hardness showed the highest value (850Hv) treated at 700$^{\circ}C$ for $SiO_2:Al_2O_3:Cr_2O_3$=1:1:4. Increasing heat-treatment temperature, corrosion current density became lower and coating layer became denser. The corrosion current density showed the lowest value $(6.5{\times}10^{-5}\;Acm^2)$ treated at 750$^{\circ}C\;for\;SiO_2:Al_2O_3:Cr_2O_3$=1:1:3. These results were explained by protective layer which was formed during heat-treatment. The bonding between matrix and coating layer is expected to be made mechanically and chemically by the inter diffusion of Ni and Fe. The composite oxide coating was formed by softening of the binder with increasing heat-treatment temperature. The strengthening of coating layer is to be resulted from the dispersion of major oxide particles.

• Composites Research
• /
• 제14권5호
• /
• pp.1-11
• /
• 2001

본 논문은 금속복합재료를 반용융상태로 재가열하여 Thixoforming을 하는데 필요한 소재를 제공하기 위한 장비 설계와 제조방법 등에 관한 내용을 소개하고 있다. 장비 설계에서 기지재내에 강화재가 균일하게 분산되도록 하기 위하여 강화재의 연속주입 방법과 강화재의 온도를 제어하는 방법을 소개하고 있다. 일정한 양의 강화재를 기지재료 내에 분산시키는 것은 균일 혼합을 위하여 필요한 기술이다. 또한 분산시 강화재의 수분제거를 위하여 강화재의 온도를 제어하면서 연속적으로 강제분산시키는 것은 균일분산을 위하여 필요하다. 기지재의 초정 $\alpha$의 크기가 강화재의 분산성에 크게 영향을 미치기 때문에 기지재의 초기 온도가 초정$\alpha$의 크기에 미치는 영향 등을 검토하여 복합재료 빌렛트의 제조조건에 이용하였다.

• 한국세라믹학회지
• /
• 제22권1호
• /
• pp.11-18
• /
• 1985

The effect of stress induced phase transformation on $Al_2 O_3$ matrix dispersed with $ZrO_2-Y_2O_3$ has been studied. In order to determinate the mechanical properties three $Al_2O_3-ZrO_2$ composite series containing 1, 3 and 5 mole% $Y_2O_3$ were prepared. The starting materials were $Al_2O_3$ and $ZrO_2-Y_2O_3$ which was prepared from the aqueous solution of high purity $YCl_3$.$6H_2O$ and $ZrOCl_2$.$8H_2O$. Powder mixtures of $Al_2O_3-ZrO_2$ containing $Y_2O_3$ have been prepared by ball-milling with methanol and the samples were formed by isostatic press and sintered at 150$0^{\circ}C$ for 2hrs. After sintering. the specimens were polished for mechanical determination. The relative density of sintered specimens were also measured. It was found that the addition of 1, 3mole% to {{{{ { ZrO}_{2 } }} allowed full retention of the tetragonal phase in $Al_2O_3-ZrO_2$ but partially stabilized zirconia (PSZ) was produced by additions of 5 mole% $Y_2O_3$.The critical stress-intensity factor KIc of $A_2O_3-ZrO_2$ (containing 1 mole% $Y_2O_3$) composite materials increased with increasing $ZrO_2$ content, The maximum value of KIC=7Mn/$m^3$/2 at 20 mole% $ZrO_2$ exhibited about twice that of the $Al_2 O_3$ The modulus of rupture exhibited a trend similiar to KIC The maximum value of MOR was 580MN/m2. As the amount of Y2O3 increase it was observed that the maximum of KIC and MOR decreased : Additions of 3 mole% $Al_2O_3$ $Y_2O_3$ allowed the maximum of KIC 6MN/$m^3$/2 MOR 540MN/$m^2$ at 15 mole% $ZrO_2$ additions of 5 mole% $Y_2O_3$ allowed the maximum of KIC 5MN/$m^3$/2 MOR 410MN/$m^2$ at 10 mole% $ZrO_2$.

• 비파괴검사학회지
• /
• 제34권3호
• /
• pp.233-240
• /
• 2014

나노/마이크로 소자의 개발이 활발해짐에 따라 나노/마이크로 박막의 기계적 물성의 정밀 측정에 대한 필요성이 점차 커지고 있다. 기존의 파괴적인 방법의 한계를 극복하기 위한 방법으로, 유도초음파를 이용한 비파괴적인 박막 물성 방법에 대한 관심이 늘어나고 있다. 유도초음파를 이용하여 박막의 물성을 측정하는 실험을 설계하거나, 물성 측정에 대한 실험 결과를 이해하는데 있어 박막의 분산선도를 이해하는 것은 필수적이라 할 수 있다. 본 연구에서는, 전달 행렬법을 이용하여 박막의 분산선도를 계산하는 방법을 제시하고, 이를 금속 박막에 적용하여 그 특성을 관찰하였다. 전달 행렬법을 이용하여 다층판에서의 주파수에 따라 유도초음파가 전파하는 속도를 계산하여 상용 프로그램과 비교하여 그 타당성을 확인하였다. 이러한 방법을 Si 기판 위에 증착된 Al 금속 박막에 적용하여 얻은 분산곡선의 분석을 통해, 박막의 두께 조건에 따른 모드와 분산 및 비분산 특성이 나타나는 구간을 관찰할 수 있었다.

• Transactions on Electrical and Electronic Materials
• /
• 제14권3호
• /
• pp.121-124
• /
• 2013

The incorporation of 90 nm alumina particles into an epoxy matrix to form a composite microstructure is described in present study. It is shown that the use of ultrafine particles results in a substantial change in the behavior of the composite, which can be traced to the mitigation of internal charges when a comparison is made with conventional $Al_2O_3$ fillers. A variety of diagnostic techniques have been used to augment pulsed electro-acoustic space charge measurement to provide a basis for understanding the underlying physics of the phenomenon. It would appear that, when the size of the inclusions becomes small enough, they act cooperatively with the host structure and cease to exhibit interfacial properties. It is postulated that the $Al_2O_3$ particles are surrounded by high charge concentrations. Since $Al_2O_3$ particles have very high specific areas, these regions allow limited charge percolation through $Al_2O_3$ filled dielectrics. The practical consequences of this have also been explored in terms of the electric strength exhibited. It would appear that there was a window in which real advantages accumulated from the nano-formulated material. An optimum filler loading of about 0.5 wt.% was indicated.