• Title/Summary/Keyword: Al(III)

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Comparison of the characteristics of Al(III) hydrolyzed species by improved ferron assay test (개선된 Ferron 분석 비교를 통한 Al(III) 가수분해종 특성 연구)

  • Yoon, Mihyoung;Kang, Limseok
    • Journal of Korean Society of Water and Wastewater
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    • v.36 no.3
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    • pp.177-186
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    • 2022
  • In this study, newly improved Ferron assay test haved on timed spectrometry was used for the determination of hyolrolytic Al species presented in PACl coagulant. The color development reagent ferron was prepared by using conventional method and two newly developed methods. Then the ferron assay test was used to compare and analyze the distribution of Al(III) hydrolyzed species presented in the prepared PACl and alum. The preparing method of reagent A required an aging period of 7 days by adding a hydroxylamine hydroxide and a 1,10-phenanthroline monohydrate reagent, whereas the preparing method of reagent B was used as a coloring agent immediately without aging time. The regression analysis between UV absorbance and Al concentrations of conventional method and newly developed method of ferron reagents in low-concentration aluminum solutions and high-concentration aluminum solutions, showed the correlation coefficients of 0.999 or higher, as showing high correlations of conventional method and newly developed method. Applying Ferron assay test, Al species in the PACls and alum were classified as Ala(monomeric Al), Alb (polymeric Al), and Alc (colloidal and precipitated Al). Distribution of Al(III) hydrolyzed species according to the preparation of ferron colorimetric reagents was similar.

Precipitation Characteristics of Heavy Metal Ions in Coal Mine Drainage (석탄광산배수에 함유된 중금속 이온의 침전 특성)

  • Jo, Young-Do;Ahn, Ji-Whan;Kim, Hyung-Seok
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.2 s.52
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    • pp.125-134
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    • 2007
  • This study has been carried out in order to examine the precipitation characteristics of Fe, Mn and Al ions in coal mine drainage before removing heavy metals by using the froth flotation method. The removal rate of Fe(III), Mn(II) and Al(III) within 1 h accounted for over 99% in pH 5.0, 10.0, and $6.0{\sim}9.0$ respectively, and residual concentrations of which were under $1mgL^{-1}$. When sodium oleate as a collector was added to the solution of Fe, Mn, and Al ions, insoluble salts was not formed by the reaction of heavy metal and sodium oleate. So, we must remove the metals from coal mine drainage by using not the ion flotation method, but the precipitation flotation method

Stimulated emission from optically pumped column-III nitride semiconductors at room temperature (III족 질화물 반도체의 실온 광여기 유도방출)

  • 김선태;문동찬
    • Electrical & Electronic Materials
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    • v.8 no.3
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    • pp.272-277
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    • 1995
  • We report the properties of optically pumped stimulated emission at room temperature (RT) from column-III nitride semiconductors of GaN, AlGaN/GaN double heterostructure (DH) and AlGaN/GaInN DH which prepared on a sapphire substrate using an AIN buffer-layer by the nietalorganic vapor phase epitaxy (MOVPE) method. The peak wavelength of the stimulated emission at RT from AIGaN/GaN DH is 369nm and the threshold of excitation pumping power density (P$\_$th/) is about 84kW/cm$\^$2/, and they from AlGaN/GaInN DH are 402nm and 130kW/cm$\^$2/ at the pumping power density of 200kW/cm$\^$2/, respectively. The P$\_$th/ of AIGaN/GaN and AlGaN/GaInN DHs are lower than the single layers of GaN and GaInN due to optical confinement within the active layers of GaN and GaInN, respectively.

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Determination of Free Acid in U(VI)-Al(III) Solutions by Gran Plot Titration (Gran Plot 적정법을 이용한 U(VI)-AI(III) 용액의 자유산 농도 측정)

  • Suh, Moo-Yul;Lee, Chang-Heon;Sohn, Se-Chul;Kim, Jung-Suk;Kim, Won-Ho;Eom, Tae-Yoon
    • Analytical Science and Technology
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    • v.12 no.3
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    • pp.177-183
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    • 1999
  • The determination method of free acid in spent U-Al nuclear fuel solutions by Gran plot titration was described. Effect of U(VI) and Al(III) on the alkalimetric titration of nitric acid was investigated in oxalate complexing media as well as in noncomplexing media. Positive biases were observed in both titration media when the end-point was estimated by the Gran plot method. It was found that the cause of the bias was U(VI) in the oxalate complexing media, but Al(III) in the noncomplexing media. The relative error was less than 1% in the titration of 0.1 M $HNO_3$ at a U(VI) : Al(III) : $H^+$ mole ratio of up to 2:12:1 as long as the pH of the oxalate titration media was sustained to be below 5.0 at the beginning of titration. The method was successfully applied to the determination of nitric acid in a solution of HANARO reactor fuel with U:Al mole ratio of 1:6.

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Shakespeare and Arab Culture: Cases of Sulayman Al-Bassam's The Al-Hamlet Summit and Richard III, an Arab Tragedy

  • Han, Younglim
    • Journal of English Language & Literature
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    • v.64 no.2
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    • pp.253-272
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    • 2018
  • Sulayman Al-Bassam is recognized as the leading adaptor-director of Shakespeare in the Arab world of today. His adaptations have gained much attention around the globe. Celebrated cases of his Arab Shakespeare are The Al-Hamlet Summit and Richard III, an Arab Tragedy. This study intends to demonstrate that these two plays form a ground for challenging and irritating dialogue between the Middle East and the West. Shakespeare's Hamlet and Richard III are used as a discourse space for engaging with the inefficiency of Arab political culture and for exposing the economic machinations of the West. This space is constituted by the ongoing process of politically inclusive affiliation and exclusive disjunction, with the result that is not relevant to notions of synthesis and symbiosis. The process corresponds with that of distancing and identification in which the strategy of subversion is employed in order to unveil Western prejudices. Al-Bassam materializes Shakespeare's text as a gateway to understanding Arab society and culture, and to investigating questions as to how the modern Arab world could negotiate their cultural currencies with the West.

Influence of High-energy Milling and Sintering Cycle on Obtaining of TiAl from Elemental Ti and Al Powders

  • Esteban, P.G.;Gordo, E.;Ruiz-Navas, E.M.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.727-728
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    • 2006
  • The present work studies the influence of high-energy milling (HEM) and sintering cycle of Ti and Al powders on the obtainment of TiAl. This study shows that HEM modifies the diffusion processes during the sintering stage. The samples were obtained by cold uniaxial and isostatic pressing, pre-sintered at different temperatures, and heated up to the sintering temperature. This study also shows the effect of powder additions processed by HEM on the sintering behavior of elemental Ti and Al powders.

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Reduction of Light Reflectance from InAlP by the Texture Formation Using Ultra-Thin Pt Layer (Pt 금속 박막을 이용한 InAlP층의 텍스쳐 구조 형성 및 반사율 측정)

  • Shin, Hyun Wook;Shin, Jae Cheol;Kim, Hyo Jin;Kim, Sung;Choe, Jeong-Woo
    • Journal of the Korean Vacuum Society
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    • v.22 no.3
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    • pp.150-155
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    • 2013
  • Textured surface has been fabricated to reduce the light reflectance from the solar cells. The textured surface is very suitable for the multi-junction III-V solar cells because it can decrease the light reflectance over a large wavelength range. In this study, we have generated a textured structure on InAlP which is used for the window layer of the multi-junction III-V solar cells. Ultra-thin Pt layer (0.7 nm) has been used for wet etching mask. An array of nanosized pyramid shape formed on InAlP surface dramatically reduces the light reflectance up to 13.7% over a large wavelength range (i.e., $0.3{\sim}1.5{\mu}m$).

Texture and Toughness of Chuncheon Nephrite, Korea (춘천산 연옥의 조직 및 인성에 관한 연구)

  • 박맹언;강정미
    • Journal of the Mineralogical Society of Korea
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    • v.8 no.1
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    • pp.29-36
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    • 1995
  • 연옥은 구성광물의 조직, 결합양상 및 화학조성 등에 의해 일반적인 투각섬석과 구분되며, 색, 경도 및 인성 등에 의해 등급과 가치가 달라진다. 본 연구에서는 춘천산 연옥을 대상으로 연옥의 물리적 특성(조직, 경도 및 인성) 등의 연구가 수행되었다. 춘천산 연옥은 구성광물인 투각섬석의 조직, 입도 및 공생광물(불순물)의 특성에 따라 세 가지 유형(유형 I, 유형 II, 유형 III)으로 구분된다. 유형 I은 치밀한 극미립의 초미정질(<5$\mu\textrm{m}$) 투감섬석의 치밀한 집합체로서 구성되며, 유형 II와 유형 III은 미정질(10~30$\mu\textrm{m}$) 및 세립 (>50$\mu\textrm{m}$)의 투각섬석 집합체로서 투휘석, 활석, 녹니석 및 사문석 등이 미량으로 함유된다.연옥을 구성하는 세 유형의 투각섬석의 화학조성은 Fe, Al 성분이 유형 III에서 가장 높은 함량(1.07~1.88wt.% FeO, 1.3~2.59wt.% Al2O3)을 나타내며, 유형 II(0.22~0.37wt.% FeO, 0.66~0.77wt.% Al2O3), 유형 I (0.20~0.24wt.% FeO, 0.05~0.12wt.% Al2O3)의 순으로 감소함을 보이고, SiO2 성분은 유형 I (59.13~59.67 wt.%), 유형 II(58.02~59.40wt.%), 유형 III (57.34~58.63 wt.%)순으로 함량이 낮아짐을 알 수 있다.연옥의 미경도(VHN=311~659)와 파괴인성치(2.38$\times$105~5.62$\times$105 dyne.cm-3/2)는 유형 I, 유형 II, 유형 III의 순으로 낮아진다. 이러한 결과는 조직 및 집합구조의 특성과 밀접한 관계를 갖고 있음을 반영한다.

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Effects of Characterization of Polymeric Al(III) Coagulants on Coagulation of Surface Water (고분자성 Al(III) 응집제의 특성이 상수원수의 응집특성에 미치는 영향)

  • Lee, Sun Gi;Han, Seung Woo;Kang, Lim Seok
    • Journal of Korean Society of Water and Wastewater
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    • v.12 no.2
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    • pp.99-105
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    • 1998
  • This research explored the feasibility of preparing and utilizing a preformed polymeric solution of Al(III) for coagulation in water treatment. Slow base(NaOH) injection into supersaturated aluminum chloride solutions did produce high yields of the type of Al polymers useful to water treatment applications. PACl's characteristic analysis showed that the quantity of polymeric Al produced at value of $r(OH_{added}/Al)=2.2$ was 83% of the total aluminum in solution, as showing maximum contents and precipitate was dramatically increased when r was increased above 2.35. And PACl was stable during sitoring period so aging effect was negligible. Results of the coagulation of Nakdong river waters with three PACls showed that the effectiveness of the three coagulants can be considered as r = 2.2 > r = 2.0 > r = 2.35 which are also the order of higher polymeric aluminum contents. Coagulation results for synthetic water exhibited optimum dose of 0.25mM Al, for three PACls, but above optimum dose, r = 2.0 and 2.2 PACl impaired the coagulation and sedimentation of turbidity and humic acid because of the restabilization of particulate. The effect of pH for on coagulation of Nak Dong River water showed that it had much effect turbidity and TOC removal, especially near pH 7. But pH effect was little for turbidity and TOC removal when r = 2.35 PACl was used for coagulation, that PACl had much more precipitates content.

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