• Title/Summary/Keyword: Air-gap

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Solution-Processed Nontoxic and Abundant $Cu_2ZnSnS_4$ for Thin-Film Solar Cells

  • Mun, Ju-Ho
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.65-65
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    • 2012
  • Copper zinc tin sulfide ($Cu_2ZnSnS_4$, CZTS) is a very promising material as a low cost absorber alternative to other chalcopyrite-type semiconductors based on Ga or In because of the abundant and economical elements. In addition, CZTS has a band-gap energy of 1.4~1.5eV and large absorption coefficient over ${\sim}10^4cm^{-1}$, which is similar to those of $Cu(In,Ga)Se_2$(CIGS) regarded as one of the most successful absorber materials for high efficient solar cell. Most previous works on the fabrication of CZTS thin films were based on the vacuum deposition such as thermal evaporation and RF magnetron sputtering. Although the vacuum deposition has been widely adopted, it is quite expensive and complicated. In this regard, the solution processes such as sol-gel method, nanocrystal dispersion and hybrid slurry method have been developed for easy and cost-effective fabrication of CZTS film. Among these methods, the hybrid slurry method is favorable to make high crystalline and dense absorber layer. However, this method has the demerit using the toxic and explosive hydrazine solvent, which has severe limitation for common use. With these considerations, it is highly desirable to develop a robust, easily scalable and relatively safe solution-based process for the fabrication of a high quality CZTS absorber layer. Here, we demonstrate the fabrication of a high quality CZTS absorber layer with a thickness of 1.5~2.0 ${\mu}m$ and micrometer-scaled grains using two different non-vacuum approaches. The first solution-processing approach includes air-stable non-toxic solvent-based inks in which the commercially available precursor nanoparticles are dispersed in ethanol. Our readily achievable air-stable precursor ink, without the involvement of complex particle synthesis, high toxic solvents, or organic additives, facilitates a convenient method to fabricate a high quality CZTS absorber layer with uniform surface composition and across the film depth when annealed at $530^{\circ}C$. The conversion efficiency and fill factor for the non-toxic ink based solar cells are 5.14% and 52.8%, respectively. The other method is based on the nanocrystal dispersions that are a key ingredient in the deposition of thermally annealed absorber layers. We report a facile synthetic method to produce phase-pure CZTS nanocrystals capped with less toxic and more easily removable ligands. The resulting CZTS nanoparticle dispersion enables us to fabricate uniform, crack-free absorber layer onto Mo-coated soda-lime glass at $500^{\circ}C$, which exhibits a robust and reproducible photovoltaic response. Our simple and less-toxic approach for the fabrication of CZTS layer, reported here, will be the first step in realizing the low-cost solution-processed CZTS solar cell with high efficiency.

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An Experimental Study on the Freeze-Thaw Resistance of Concrete Incorporating Waste Foundry Sand (폐주물사를 혼입한 콘크리트의 동결-융해 저항성에 관한 실험적 연구)

  • 윤경구;이주형;홍창우;박제선
    • Magazine of the Korea Concrete Institute
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    • v.10 no.4
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    • pp.153-161
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    • 1998
  • Concrete structures has been deteriorated by and freezing the thawing due to temperature gap. This study was conducted to evaluate durability of concrete which are increasingly demanded recently. Therefore the research of durability must be executed for application of waste foundry sand concrete real structures. Concrete durability properties incorporating waste foundry sand was performed with the variable of W/C ratio. Sand/Waste foundry sand ratio and Air entrainment-Non air entrainment. Cylinder specimens were made and subjected to freezing and thawing cycle at -18$^{\circ}C$ and 4$^{\circ}C$. Dynamic modulus of elasticity were evaluated as F/T cycle increase. The results show that strength of concrete is increased the W/C ratio decrease, the Sand/Waste foundry sand ratio increases when the concrete contains AE agent and decreasing W/C ratio and AE concrete makes improved resistance of freezing and thawing improved. Especially, resistance of freezing and thawing is improved by Fine aggregate/Waste foundry sand ratio which is 50%, 25%, 0% in a row. Therefore it is turn out the waste foundry sand could be applied to concrete from the experiment.

Experimental study on heating performance characteristics of electric heat pump system using stack coolant in a fuel cell electric vehicle (연료전지 스택 폐열 활용 전동식 히트펌프 시스템 난방 성능 특성 연구)

  • Lee, Ho-Seong;Kim, Jung-Il;Won, Hun-Joo;Lee, Moo-Yeon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.12
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    • pp.924-930
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    • 2018
  • The objective of this study was to investigate heating performance characteristics of electric heat pump system in a fuel cell electric vehicle (FCEV). In order to analyze heating performance characteristics of electric heat pump system with plate-type heat exchanger using stack coolant to evaporate the refrigerant, R-134a, each component was installed and tested under various operating conditions, such as air inlet temperature of inner condenser and compressor speed. When the air inlet temperature of inner condenser was varied from $0.0^{\circ}C$ to $-20.0^{\circ}C$, heating capacity was not quite different due to similar temperature gap between inlet and outlet of inner condenser with electric-driven expansion valve (EEV). However, COP increased until certain EEV opening, especially under 45.0%, because of decreasing power consumption. According to the compressor speed variation from 2,000 to 4,000 RPM, heating capacity and COP were found to have opposite trend. In the future works, stack coolant conditions as the heat source for tested heat pump system were analyzed with respect to heating performance, such as heating capacity and COP.

Experimental study on vertically upward steam-water two-phase flow patterns in narrow rectangular channel

  • Zhou, Jiancheng;Ye, Tianzhou;Zhang, Dalin;Song, Gongle;Sun, Rulei;Deng, Jian;Tian, Wenxi;Su, G.H.;Qiu, Suizheng
    • Nuclear Engineering and Technology
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    • v.53 no.1
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    • pp.61-68
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    • 2021
  • Experiments of vertically upward steam-water two-phase flow have been carried out in single-side heated narrow rectangular channel with a gap of 3 mm. Flow patterns were identified and classified through visualization directly. Slug flow was only observed at 0.2 MPa but replaced by block-bubble flow at 1.0 MPa. Flow pattern maps at the pressure of 0.2 MPa and 1.0 MPa were plotted and the difference was analyzed. The experimental data has been compared with other flow pattern maps and transition criteria. The results show reasonable agreement with Hosler's, while a wide discrepancy is observed when compared with air-water two-phase experimental data. Current criteria developed based on air-water experiments poorly predict bubble-slug flow transition due to the different formation and growth of bubbles. This work is significant for researches on heat transfer, bubble dynamics and flow instability.

Selection of Scale Model Materials for Acoustical Evaluation of 1:50 Multipurpose Halls (1:50 다목적홀의 음향평가를 위한 축소모형재료의 선정)

  • Jeon, Jin-Yong;Kim, Jeong-Jun;Kim, Yong-Hee
    • The Journal of the Acoustical Society of Korea
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    • v.28 no.8
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    • pp.781-789
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    • 2009
  • The absorption coefficients of the materials used in a 1:50 scale model multipurpose hall were measured based on ISO 354 and related laws. The shape and materials for the scale model were evaluated based on reflective surfaces, variable acoustic elements and sound-absorbing quality (125Hz-1kHz average) of seats. The measured average absorption coefficients of audience seats, audience and orchestra were 0.64, 0.74 and 0,45, respectively, which were simulated with the combination of wood, absorption materials and foam board. Various mounting methods for absorption curtain and banner were considered according to the installation methods. The average absorption coefficient was measured as 0.42, 0.47 and 0.45 in the conditions of Type A mounting, E mounting with 0.9 m backing air cavity, and Type G mounting which is suspended at the ceiling, respectively. It was confirmed that the absorption coefficient was increased at low frequency by backing air gap. The finishing material of stage house was an absorption material covered with thin fabric, which aimed average absorption coefficient of 0.68 by using fiber glass board. Each part of the real materials was compared with those of 1:50 scale model and it was found that the absorption characteristics of both cases were similar.

Sparkover Voltage Estimation of Standard Sphere Gaps for Negative Polarity by Calculation of Ionization Index

  • Nishikori, Yasuo;Kojima, Soji;Kouno, Teruya
    • KIEE International Transactions on Electrophysics and Applications
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    • v.4C no.2
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    • pp.45-50
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    • 2004
  • The field utilization factor (equation omitted) (the mean electric field / the maximum electric field) of standard sphere gaps was calculated by the charge simulation method, taking into account the ground plane and shanks. n changes mainly with g/r and slightly with 1$_1$, 1$_2$ and 1, where D=2r is the sphere diameter, g is the gap length, 1$_1$ and 1$_2$, respectively, are the lengths of the upper and lower shank, and t is the shank diameter. Generally, (equation omitted) increases as 1$_1$,1$_2$ and t each becomes larger. IEC standard 60052(2002) limits t$\leq$0.2D 1$_1$$\geq$1D and prescribes A=1$_2$+D+g where A is the height of the spark point on the upper sphere. Therefore, (equation omitted) is the largest when A=9D and the smallest when A=3D. The simple equation of a straight line, (equation omitted)=1- (g/3r), can generally be used as a representative value of (equation omitted) for a wide variety of sphere diameters that are permitted by the IEC standard. The maximum electric field E$_{m}$ at sparkover of standard air gaps has also been calculated by the relation E$_{m}$=V/(equation omitted)g). E$_{m}$ describes a U-curve for g/r, up to the sphere diameter of 1 m. Moreover, for 1.5-m and 2-m diameters and especially .for negative polarity, sparkover voltages have been calculated by integration of the ionization index.index.

Analysis of Sound Transmission Characteristics of Multi-complex Panel for Noise Reduction in High Value-added Vessel Cabin (고부가가치선 선실의 소음 저감용 복합패널의 차음특성 해석)

  • Kwon, Hyun-Wung;Hong, Suk-Youn;Kil, Hyun-Gwon;Kim, Hwa-Muk;Song, Jee-Hun
    • Journal of Ocean Engineering and Technology
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    • v.26 no.3
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    • pp.13-19
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    • 2012
  • Recently, as the importance of the interior noise in a ship cabin has risen, ship builders have becomeconcerned about the use of noise reduction panels to reduce cabin noise. The results of previous researches have been based on analytical and experimental methods using simple sandwich panels. However, panel structures are becoming more complex to improve the transmission loss. Thus, researches that analyze the transmission loss of a panel are reaching the limit of study. This paper reports on research that was performed to determine the sound transmission characteristics of multi-complex panels applicable to high value-added vessels. It presents comparisons between analytical methods and experimental results by using a mini-reverberant chamber with components of sound attenuation panels, including the core and surface materials. The sound transmission loss of multi-complex panels are also analyzed in terms of the influences of the inside perforate plates and air gap thickness on the attenuation. Finally, the multi-complex panel with the highest noise attenuation is proposed based on the analysis results and experimental results in mini-reverberant chamber, which wereverified using a real-size reverberant chamber.

Development of a Model-Based Motor Fault Detection System Using Vibration Signal (진동 신호 이용 모델 기반 모터 결함 검출 시스템 개발)

  • ;A.G. Parlos
    • Journal of Institute of Control, Robotics and Systems
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    • v.9 no.11
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    • pp.874-882
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    • 2003
  • The condition assessment of engineering systems has increased in importance because the manpower needed to operate and supervise various plants has been reduced. Especially, induction motors are at the core of most engineering processes, and there is an indispensable need to monitor their health and performance. So detection and diagnosis of motor faults is a base to improve efficiency of the industrial plant. In this paper, a model-based fault detection system is developed for induction motors, using steady state vibration signals. Early various fault detection systems using vibration signals are a trivial method and those methods are prone to have missed fault or false alarms. The suggested motor fault detection system was developed using a model-based reference value. The stationary signal had been extracted from the non-stationary signal using a data segmentation method. The signal processing method applied in this research is FFT. A reference model with spectra signal is developed and then the residuals of the vibration signal are generated. The ratio of RMS values of vibration residuals is proposed as a fault indicator for detecting faults. The developed fault detection system is tested on 800 hp motor and it is shown to be effective for detecting faults in the air-gap eccentricities and broken rotor bars. The suggested system is shown to be effective for reducing missed faults and false alarms. Moreover, the suggested system has advantages in the automation of fault detection algorithms in a random signal system, and the reference model is not complicated.

ROKN's Response Strategy to North Korea's SLBM Threat (북한 SLBM 위협과 대응방향)

  • Moon, Chang-Hwan
    • Strategy21
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    • s.40
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    • pp.82-114
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    • 2016
  • The purpose of this article is to analyze the progress of North Korea's SLBM threat, and to assess the technological capacity and threat level of its SLBMs. Currently, North Korea has approximately 1000 ballistic missiles, such as the SCUD, Musudan, and Nodong, in stock. This article pays close attention to the background and strategical implication behind North Korea's obsession with developing SLBMs despite possessing sufficient means to launch provocations with its current arsenal of ground based ballistic missiles and conventional weapons. Based on the abovementioned analysis, this article will recommend possible response directions for the ROK Armed Forces to North Korea's SLBM threat. It is highly difficult to detect SLBMs due to its stealthy nature, as it is launched underwater after covert infiltration. North Korea's SLBM is considered a game changer in that even one SLBM can significantly change the strategic balance of North East Asia. North Korea's SLBM test launch in August has made a 500km flight, landing 80km inside the JADIZ (Japan Air Defense Identification Zone), and as such, it is assessed that North Korea already possesses underwater ejection and cold launch capabilities. The most realistic response to North Korea's imminent SLBM threat is bolstering anti-submarine capabilities. ROK Armed Forces need to upgrade its underwater kill-chain by modernizing and introducing new airborne anti-submarine assets and nuclear-powered submarines, among many options. Moreover, we should integrate SM-3 missiles with the Aegis Combat system that possess strong detection capabilities and flexibility, thereby establishing a sea-based Ballistic Missle Defense (BMD) system centered around the Aegis Combat System, as sea-based ballistic missile threats are best countered out in the seas. Finally, the capabilities gap that could arise as a result of budgetary concerns and timing of fielding new assets should be filled by establishing firm ROK-US-Japan combined defense posture.

Safety and efficacy of transcutaneous bone conduction implant surgery for hearing improvement in microtia patients with bilateral hearing impairment

  • Cheon, Jeong Hyun;Lee, Hyung Chul;Im, Gi Jung;Park, Jung Youl;Park, Chul
    • Archives of Plastic Surgery
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    • v.46 no.6
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    • pp.525-534
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    • 2019
  • Background In microtia patients with bilateral hearing impairment, hearing improvement is crucial for language development and performance. External auditory canal reconstruction (EACR) has been performed to improve hearing, but often results in complications. We performed transcutaneous bone conduction implant (TBCI) surgery in these patients. This study aimed to evaluate the safety and efficacy of TBCI surgery. Methods A retrospective review was performed of five patients who underwent auricular reconstruction and TBCI surgery and 12 patients who underwent EACR between March 2007 and August 2018. Hearing improvement was measured based on the air-bone gap values using pure-tone audiometry over a 6-week postoperative period. We reviewed other studies on hearing improvement using EACR and compared the findings with our results. The surgical techniques for TBCI were reviewed through case analyses. Results Postoperative hearing outcomes showed a significant improvement, with a mean gain of 34.1 dB in the TBCI cohort and 14.1 dB in the EACR cohort. Both gains were statistically significant; however, the TBCI cohort showed much larger gains. Only three of the 12 patients who underwent EACR achieved hearing gains of more than 20 dB, which is consistent with previous studies. All patients who underwent TBCI surgery demonstrated hearing gains of more than 20 dB and experienced no device-related complications. Conclusions TBCI is a safe and effective method of promoting hearing gains in microtia patients with bilateral hearing impairment. TBCI surgery provided better hearing outcomes than EACR and could be performed along with various auricular reconstruction techniques using virgin mastoid skin.