• 한국산업보건학회지
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• 제19권3호
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• pp.280-287
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• 2009

High-tech microelectronics industry is known as one of the most chemical-intensive industries. In Korea, Microelectronics industry occupied 38% of export and 16% of working employees work in microelectronics industry. But, chemical information and health hazards of high-tech microelectronics manufacturing are poorly understood because of rapid development and its penchant for secrecy. We need to investigate on chemical use and exposure control. We Site-visits to 6 high-tech microelectronics manufacturing company which have cleanroom work using over 1,000kg organic solvents (5 semi-conductor chips and its related parts company, 1 liquid crystal display (LCD)). We reviewed their data on chemical use and ventilation system, and measured TVOCs (Total Volatile Organic Compounds) and carbon dioxide concentration. All cleanroom air passed through hepa filters to acheive low particle levels and only 1 cleanroom uses carbon filters to minimize the organic solvents exposures In TVOC screening test, Cleanroom for semi-conductor chips and its related parts company with laminar down flow system (e.g. class 1~100) showed nondetectable level of TVOCs concentration, but Cleanroom for liquid crystal display (LCD) with conventional flow system (e.g. class 1,000~10,000) showed 327 ppm as TVOCs. Acetone concentration in cleanroom for Jig cleaning, LC Injection, Sealing processes were 18.488ppm (n=14), 49.762 ppm (n=15), 8.656 ppm (n=14) as arithmetric mean. Acetone concentration in cleanroom for LCD inspection process was 40ppm (n=55) as geometric mean, where the range was 7.8~128.7ppm and weakly correlated with ventilation rate efficiency(r=0.44, p<0.05). To control organic solvents in cleanrooms, chemical and carbon filters should be installed with hepa filters. Even though their volatile organic compounds concentration was not exceed to occupational exposure limits, considering of entrance limited cleanroom environment, long-term period exposure effects and adverse health effects of cleanroom worker need further reseach.

• International Journal of Oral Biology
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• 제34권3호
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• pp.157-164
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• 2009

We recently described a novel animal model of trigeminal neuropathic pain following compression of the trigeminal ganglion (Ahn et al., 2009). In our present study, we adapted this model using male Sprague-Dawley rats weighing between 250-260 g and then analyzed the behavioral responses of these animals following modified chronic compression of the trigeminal ganglion. Under anesthesia, the rats were mounted onto a stereotaxic frame and a 4% agar solution ($10{\mu}L$) was injected in each case on the dorsal surface of the trigeminal ganglion to achieve compression without causing injury. In the control group, the rats received a sham operation without agar injection. Air-puff, acetone, and heat tests were performed at 3 days before and at 3, 7, 10, 14, 17, 21, 24, 30, 40, 55, and 70 days after surgery. Compression of the trigeminal ganglion produced nociceptive behavior in the trigeminal territory. Mechanical allodynia was established within 3 days and recovered to preoperative levels at approximately 60 days following compression. Mechanical hyperalgesia was also observed at 7 days after compression and persisted until the postoperative day 40. Cold hypersensitivity was established within 3 days after compression and lasted beyond postoperative day 55. In contrast, compression of the trigeminal ganglion did not produce any significant thermal hypersensitivity when compared with the sham operated group. These findings suggest that compression of the trigeminal ganglion without any injury produces prolonged nociceptive behavior and that our rat model is a useful system for further analysis of trigeminal neuralgia.

• 한국자동차공학회논문집
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• 제16권3호
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• pp.94-101
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• 2008

Since regulations of exhaust emissions are continuously reinforced, studies to reduce harmful emissions during the cold start period of SI engines have been carried out very extensively worldwide. During the cold start period, raising the temperature of cold exhaust gas is a key strategy to minimize the light-off time of three way catalysts. In this study, a synthetic gas containing a large amount of hydrogen was injected into the exhaust manifold to raise the exhaust gas temperature and to reduce harmful emissions. The authors tried to evaluate changes in exhaust gas temperature and harmful emissions through controlling the engine operating parameters such as ignition timings and lambda values. Also the authors investigated both combustion stability and reduction of harmful emissions. Experimental results showed that combustion of the synthetic gas in the exhaust manifold is a very effective way for solving the problems of harmful emissions and light-off time. The results also showed that the strategy of retarded ignition timings and increased air/fuel ratios with ESGI is effective in raising exhaust gas temperature and reducing harmful emissions. Futhermore, the results showed that engine operating parameters ought to be controlled to lambda = 1.2 and ignition timing = $0{\sim}3^{\circ}$ conditions to reduce harmful emissions effectively under stable combustion conditions.

• 대한치과기공학회지
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• 제38권3호
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• pp.157-163
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• 2016

Purpose: It is to compare and evaluate the change of the wear rate and phase variation of the Zirconia before and after the sintering after the grinding by a high speed equipment manufactured for the Zirconia. Methods: The specimen of the sintered Zirconia was manufactured as size of $15mm{\times}15mm{\times}2mm$. The grinding has been applied to each of all pieces of each test groups for a minute fit for each condition at same speed of 50,000 rpm by a diamond bur at high speed handpiece with injection of the air and water. For the observation of the surface before and after the sintering of the each test piece, the cross section of it was observed as 100 magnification by a scanning electron microscope after it was coated by PT, and the diffraction analysis was performed by XDR to compare the crystal phase of the Zirconia. The average surface roughness value of all specimens were evaluated. The wear test was performed at room temperature by applying a load of 1kg for 120,000 cycles for the chewing period 6 months. Wear was analyzed for the enamel cusps by measurement of the vertical substance loss with a laser scanner. Conclusion: The phase variation from the tetragonal phase to the monoclinic phase was confirmed in the test group of the pre-sintered Zirconia after the grinding, and the value of the surface roughness and the wear rate was increased in experimental group.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1999년도 하계학술대회 논문집 E
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• pp.2007-2009
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• 1999

In this paper, discharge domain of wire-cylindrical plasma reactor was separated from a gas flow duct to avoid unstable discharge by aerosol particle deposited on discharge electrode and grounded electrode. The NOx, SOx removal was experimentally investigated by a reaction induced to ammonium nitrate, ammonium sulfate using a low price of aqueous NaOH solution and a small quantity of ammonia. Volume percentage of aqueous NaOH solution used was 20% and $N_2$ flow rate was 2.5[$\ell$/min] for bubbling aqueous NaOH solution. Ammonia gas(14.82%) balanced by argon was diluted by air and was introduced to a main simulated flue gas duct through $NH_3$ injection system which was in downstream of reactor. The $NH_3$ molecular ratio[MR] was determined based on $NH_3$ to [NO+$SO_2$]. MR is 1.5. The NOx removal rates increased in the order of DC, AC and pulse, but SOx removal rates was not significantly effected by source of electricity. The NOx removal rate slightly decreased with increasing initial concentration but SOx removal rate was not significantly effect by initial concentration, and NOx, SOx removal rates decreased with increasing gas flow rate.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1998년도 하계학술대회 논문집 E
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• pp.1794-1796
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• 1998

In this study, the $SO_2$ addition effect on NOx removal has been conducted from a combustion flue gases by the do corona discharge-activated radical shower systems. The simulated flue gases were consisted of NO-O_2-$N_2$, NO-$CO_2-N_2-O_2$ and $NO-SO_2-CO_2-Na-O_2$([NO]o:200ppm and $[SO_2]o$:800ppm). The injection gases used as radical source gases were $NH_3$-Ar-air. $SO_2$ and NOx removal efficiency and the other by-products were measured by Fourier Transform Infrared(FTIR) as well as $SO_2$. NOx and $NO_2$ gas detectors. By-product aerosol particles were also observed by Condensation Nucleation Particle Counter(CNPC) and SEM images after sampling. The results showed that asignificant aerosol Particle formation was observed during a removal operation in corona radical shower systems. The NOx removal efficiency significantly increased with increasing applied voltage and $NH_3$ molecule ratio. The $SO_2$ removal efficiency was not significantly effected by applied voltage and slightly increased with increasing $NH_3$ molecule ratio. The NOx removal efficiency for NO-$SO_2-CO_2-N_2-O_2$ was better than that for NO-$CO_2-N_2-O_2$.

• 한국분무공학회지
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• 제25권1호
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• pp.21-26
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• 2020

The objective of this work is to numerically reveal the effect of equivalence ratio change on the simultaneous reduction of NO_X and soot emissions from the simulated-EGR compression ignition engine containing CO₂. An experiment was conducted by using a single-cylinder common-rail injection system engine, an intake control system, and exhaust emissions analyzers. The numerical analysis results were validated under the same experimental conditions. To investigate the effect of equivalence ratio by simulated-EGR containing CO₂, the O₂, N₂, and CO₂ mole fraction were changed in the initial air conditions to the cylinder. The results were analyzed in terms of peak cylinder pressure, indicated mean effective pressure, indicated specific nitrogen oxide, and indicated specific soot. It was revealed that ignition delay characteristics and heat release rate (ROHR) characteristics were not significantly different according to the equivalence ratio. However, as the equivalence ratio increased from 0.68 to 0.83, the maximum combustion pressure and IMEP decreased by about 6.5% and 9.4%, respectively. In the case of ISFC, as is well known, the trend is opposite of IMEP. In the case of ISNO, as the equivalence ratio increased, less NO was generated, and as the equivalence ratio increased by 0.05, the ISSoot value of about 10% increased.

• Nuclear Engineering and Technology
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• 제23권4호
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• pp.374-386
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• 1991

시멘트 고화체내 Cs-137의 침출에 영향을 미치는 여러 새로운 인자들에 대해 조사하였다. 조사된 인자들은 가압 상태 및 진동 상태에서의 시멘트 경화, 압력하에서의 침출, 여러 종류의 점토 첨가, 이온 교환 수지(IRN-77)의 첨가, 그리고 $CO_2$또는 공기 주입의 영향이다. 침출실험은 IAEA가 제시한 방법에 의해 수행되었고, 실험 결과를 해석하기 위해 시멘트 고화체에 대한 기공 구조를 BET방법으로 분석했다. 처분장에 처분된 고화 드럼 주위에는 뒷채움재가 채워져 있기 때문에 시멘트 고화체가 직접 지하수와 접촉할 가능성은 매우 희박하다. 그래서 뒷채움재가 침출능에 미치는 영향을 예측하였다. 잘 알려진 확산 이론을 이용하여 뒷채움재를 고려했을 때 Cs-137 또는 비방사능 물질의 장기 침출율과 누적 침출량을 예측하였다.

• Bulletin of the Korean Chemical Society
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• 제35권10호
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• pp.3052-3058
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• 2014

In this article, we have designed and synthesized a novel donor-${\pi}$-acceptor (D-${\pi}$-A) type porphyrin-based sensitizer (denoted UI-5), in which a carboxyl anchoring group and a 9,9-dimethyl fluorene were introduced at the meso-positions of porphyrin ring via phenylethynyl and ethynyl bridging units, respectively. Long alkoxy chains in ortho-positions of the phenyls were supposed to reduce the degree of dye aggregation, which tends to affect electron injection yield in a photovoltaic cell. The cyclic voltammetry was employed to determine the band gap of UI-5 to be 1.41 eV based on the HOMO and LUMO energy levels, which were estimated by the onset oxidation and reduction potentials. The incident monochromatic photon-to-current conversion efficiency of the UI-5 DSSC assembled with double-layer (20 nm-sized $TiO_2$/400 nm-sized $TiO_2$) film electrodes appeared lower upon overall ranges of the excitation wavelengths, but exhibited a higher value over the NIR ranges (${\lambda}$ = 650-700 nm) compared to the common reference sensitizer N719. The UI-5-sensitized cell yielded a relatively poor device performance with an overall conversion efficiency of 0.74% with a short circuit photocurrent density of $3.05mA/cm^2$, an open circuit voltage of 0.54 mV and a fill factor of 0.44 under the standard global air mass (AM 1.5) solar conditions. However, our report about the synthesis and the photovoltaic characteristics of a porphyrin-based sensitizer in a D-${\pi}$-A structure demonstrated a significant complex relationship between the sensitizer structure and the cell performance.

• Korean Journal of Acupuncture
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• 제35권1호
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• pp.41-45
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• 2018

Objectives : To investigate minimum pressure by verifying changes in pressure due to bleeding amount during bloodletting-cupping therapy. Methods : (1) We compared adhesion performance of four different cupping cups of same size: two disposable cupping cups(A, B) and two reusable cupping cups(A, B) each were vacuumed three times and kept in place for 10 minutes. (2) We vacuumed two different sized disposable cupping cups(A), size.1(InnerDiameter 48.8 mm) and size.3(InnerDiameter 39.1 mm), twice each(-200 mmHg) on silicon plate. We injected water and air at regular intervals in cupping cups by using a syringe, and then measured change of pressure in cupping cups and pressure at the time of dropout. Results : (1) Pressure reduction was $4.75{\pm}2.78%$ on average in the order of 'Disposable[A]>reusable[B]>Disposable[B]>reusable[A]', so that pressure retention performance of disposable cups can't be regarded as inferior to that of reusable cups. (2) Pressure of disposable cupping B(size.1) decreased by an average of -40.08 mmHg per 5 ml of water. At -24.8 mmHg, when 22 ml of water has been injected, cup has come off. Pressure of disposable cupping B(size. 3) decreased by an average of -99.4 mmHg per 5 ml of water. At -48.6 mmHg, when 13 ml of water was injected, cupping came off. Conclusions : Considering reduction rate of pressure due to water injection, in case of bleeding more than 15 ml, size.3 cup always comes off, therefore it needs to be re-operated at least once. Meanwhile, size.1 cup does not always come off in the same condition, depending on the initial pressure and therefore, re-operation may be considered.