• Title/Summary/Keyword: Air atmosphere

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Synthesis of thin-multiwalled carbon nanotubes by Fe-Mo/MgO catalyst using sol-gel method

  • Dubey, Prashant;Choi, Sang-Kyu;Kim, Bawl;Lee, Cheol-Jin
    • Carbon letters
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    • v.13 no.2
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    • pp.99-108
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    • 2012
  • The sol-gel technique has been studied to fabricate a homogeneous Fe-Mo/MgO catalyst. Ambient effects (air, Ar, and $H_2$) on thermal decomposition of the citrate precursor have been systematically investigated to fabricate an Fe-Mo/MgO catalyst. Severe agglomeration of metal catalyst was observed under thermal decomposition of citrate precursor in air atmosphere. Ar/$H_2$ atmosphere effectively restricted agglomeration of bimetallic catalyst and formation of highly-dispersed Fe-Mo/MgO catalyst with high specific surface-area due to the formation of Fe-Mo nanoclusters within MgO support. High-quality thin-multiwalled carbon nanotubes (t-MWCNTs) with uniform diameters were achieved on a large scale by catalytic decomposition of methane over Fe-Mo/MgO catalyst prepared under Ar-atmosphere. The produced t-MWCNTs had outer diameters in the range of 4-8 nm (average diameter ~6.6 nm) and wall numbers in the range of 4-7 graphenes. The as-synthesized t-MWCNTs showed product yields over 450% relative to the utilized Fe-Mo/MgO catalyst, and indicated a purity of about 85%.

Analysis on Daily Variation Mechanism of Short-wave Radiation between Downtown and Suburban Area during Summer Season (하절기 도심과밀지역과 인근 교외지역의 단파복사 일변화 메커니즘에 대한 해석)

  • Choi, Dong-Ho;Lee, Bu-Yong;Jeong, Hyeong-Se
    • Journal of the Korean Solar Energy Society
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    • v.34 no.4
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    • pp.111-122
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    • 2014
  • The purpose of this study is to understand daily variation of short-wave radiation trends according to the state of surface and observation of atmosphere conditions in downtown and suburban observation area. The followings are main results from this study. 1) We found out daily air temperature variation of downtown is less than that of suburban area because of bigger heat capacity of artificial elements such as massive buildings and pavements. 2) It is more effective to estimate of air condition by water vapor pressure than relative humidity in the atmosphere. 3) The difference of solar radiation ratio between downtown and suburban area is dependant on different atmosphere conditions at two observation stations.

Classification of Precipitation Type Using the Wind Profiler Observations and Analysis of the Associated Synoptic Conditions: Years 2003-2005 (윈드프로파일러 관측 자료를 이용한 장마철 강수 형태 분류와 관련된 종관장의 특성 분석: 2003년-2005년)

  • Won, Hye-Yeong;Jo, Cheon-Ho;Baek, Seon-Gyun
    • Atmosphere
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    • v.16 no.3
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    • pp.235-246
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    • 2006
  • Remote sensing techniques using satellites or the scanning weather radars depend mostly on the presence of clouds or precipitation, and leave the extensive regions of clear air unobserved. But wind profilers provide the most direct measurements of mesoscale vertical air motion in the troposphere, even in the context of heavy precipitation. In this paper, the precipitation events during the Changma period was classified into 4 precipitation types - stratiform, mixed stratiform/ convective, deep convective, and shallow convective. The parameters for the classification of analysis are the vertical structure of reflectivity, Doppler velocity, and spectral width measured with the wind profiler at Haenam for a three-year period (2003-2005). In addition, the synoptic fields and total amount of precipitation were analyzed using the Global Final Analyses (FNL) data and the Global Precipitation Climatology Project (GPCP) data. During the Changma period, the results show that the stratiform type was dominant under the moist-neutral atmosphere in 2003, whereas the deep convective type was under the moist unstable condition in 2004. The stratiform type was no less popular than the deep convective type among four seasons because the moist neutral layer was formed by the convergence between the upper-level jet and the low-level jet, and by the moisture transport along the western rim of the North Pacific subtropical anticyclone.

The Effect of Attraction by the Atmosphere to Gravity (중력(重力)의 대기보정(大氣補正)에 대(對)한 연구(硏究))

  • Choi, Kwang-sun
    • Economic and Environmental Geology
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    • v.16 no.2
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    • pp.79-81
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    • 1983
  • The effeet of the mass of the earth's atmosphere for gravity is studied. The computed correction value of the air mass effect is g=+0.86-0.0978 h (km) mgal and has always positive sign. In comparision with usual gravity works. this value is relatively large. So that, all gravity works always carry out this correction.

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The Static Performances of Air-Lubricated Tilting Pad Bearings With Inlet Pressure (선단압력을 고려한 공기윤활 틸팅패드베어링의 정특성)

  • 김성국;김경웅
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1998.04a
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    • pp.235-240
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    • 1998
  • The inlet pressure build-up at the leading edge of bearings and its effects on the static performances are investigated theoretically. The performance analyses of air-lubricated tilting pad bearings are carried out considering the inlet pressure which is obtained by means of momentum conservation method. The results show that inlet pressure is above atmosphere pressure in front of leading edge of tilting pad bearing and there is a significant influence of the inlet pressure on the performance of bearings.

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A Study of the Influence of Short-Term Air-Sea Interaction on Precipitation over the Korean Peninsula Using Atmosphere-Ocean Coupled Model (기상-해양 접합모델을 이용한 단기간 대기-해양 상호작용이 한반도 강수에 미치는 영향 연구)

  • Han, Yong-Jae;Lee, Ho-Jae;Kim, Jin-Woo;Koo, Ja-Yong;Lee, Youn-Gyoun
    • Journal of the Korean earth science society
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    • v.40 no.6
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    • pp.584-598
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    • 2019
  • In this study, the effects of air-sea interactions on precipitation over the Seoul-Gyeonggi region of the Korean Peninsula from 28 to 30 August 2018, were analyzed using a Regional atmosphere-ocean Coupled Model (RCM). In the RCM, a WRF (Weather Research Forecasts) was used as the atmosphere model whereas ROMS (Regional Oceanic Modeling System) was used as the ocean model. In a Regional Single atmosphere Model (RSM), only the WRF model was used. In addition, the sea surface temperature data of ECMWF Reanalysis Interim was used as low boundary data. Compared with the observational data, the RCM considering the effect of air-sea interaction represented that the spatial correlations were 0.6 and 0.84, respectively, for the precipitation and the Yellow Sea surface temperature in the Seoul-Gyeonggi area, which was higher than the RSM. whereas the mean bias error (MBE) was -2.32 and -0.62, respectively, which was lower than the RSM. The air-sea interaction effect, analyzed by equivalent potential temperature, SST, dynamic convergence fields, induced the change of SST in the Yellow Sea. In addition, the changed SST caused the difference in thermal instability and kinematic convergence in the lower atmosphere. The thermal instability and convergence over the Seoul-Gyeonggi region induced upward motion, and consequently, the precipitation in the RCM was similar to the spatial distribution of the observed data compared to the precipitation in the RSM. Although various case studies and climatic analyses are needed to clearly understand the effects of complex air-sea interaction, this study results provide evidence for the importance of the air-sea interaction in predicting precipitation in the Seoul-Gyeonggi region.

Temperature and Atmosphere Dependence of the Electrical Conduction of the Vacuum Evaporated Thin Metal Films on Glass Substrate (진공증착된 금속박막의 전기전도성에 대한 온도와 분위기 의존성)

  • 김명균;박현수
    • Journal of the Korean Ceramic Society
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    • v.28 no.6
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    • pp.437-442
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    • 1991
  • Temperature and atmosphere dependence of electrical conduction of the metal Cu, Ag, Au films, vaccum evaporated on glass, was investigated. The structural changes of the metal films were examined by SEM and high temperature XRD. The electrical resistance slightly increased with initial temperature increase up to the inflection point and decreased to minimum value, after this rapidly increased with further temperature increased below minimum. These phenomena were caused by the thermally induced film failure as a result of the mass transport. The temperature for the film failure increased in the order of O2, Air, Vacuum, N2, Ar in Cu, Ag films and Air, Vacuum, N2, Ar in Au film. The increase of resistance at the lower temperature range was attributed to the lattice distortion by disordered crystal structure, while the decreasing resistance was attributed to the removal of structural defects and film densification.

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The effect of the process parameters on the electrical properties of Ni/Cr/Al/Cu alloy thin film (공정변수에 의한 Ni/Cr/Al/Cu계 박막의 전기적 특성)

  • 이붕주;박상무;박구범;박종관;이덕출
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.725-728
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    • 2001
  • We have fabricated thin films using the DC/RF magnetron sputtering of 74wt%Ni-l8wt%Cr-4wt%Al-4wt%Cu alloy target and studied the effect of the process parameters on the electrical properties for low TCR(Temperature Coefficient of Resistance) films. In sputtering process, pressure, power and substrate temperature, are varied as controllable parameter. The films are annealed to 400$^{\circ}C$ in air and nitrogen atmosphere. The sheet resistance, TCR of the films increases with increasing annealing temperature. It abruptly increased as annealing temperature increased over 300$^{\circ}C$ in air atmosphere. From XRD, it is found that these results are due to the existence of NiO on film surface formed by annealing. As a results of them, TCR can be controlled by variation of sputter process parameter and annealing of thin film.

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Numerical Study of Snowfall Mechanism arounf Seoul Region

  • Kang, Sung-Dae
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.10 no.S_1
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    • pp.29-33
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    • 2001
  • A numerical simulation was carried out to investigate the mechanism of snowfall around the Seoul region during a cold air-outbreak in the winter season. A particular case was selected for this study(Dec. 19, 1999). The inflow directions of the synoptic flow in the upper and lower levels were westerly and north-westerly, respectively. Plus, there was a deep trough and thermal ridge at a level of 500/700/850 hPa over the Bal-Hae region, in the northern part of the Korean peninsula. According to the model results, snowfall occurred around the Seoul region with the simultaneous existence of a strong static instability in the lower atmosphere, northerly or westerly dry air advection, and strong thermal advection toward the Seoul region. There was a strong convergence thereby indicating the existence of convective rolls in the clouds. The main energy source of convection over the Yellow sea was a sensible heat flux. The main moisture source was convection. Radiative cooling in the cloud layer intensified the static instability in the lower atmosphere.

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EFFECT of PREPARATION METHODS and CONDITIONS of PRECURSORS on the PROPERTIES of $BATIO_3$ ALKOXIDE FILMS

  • N., Korobova;Soh, Dea-Wha
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.714-718
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    • 2003
  • Usually for the commercial preparation of barium titanate films or ceramics the reaction atmosphere must be preferably in air. However, normally air is not used because it contains carbon dioxide, which can easily react with barium to form the undesired product barium carbonate, leading to unwanted second-phase formation in the (mal stages of the process. In the present work a series of perovskite barium titanate films was prepared by the sol-gel method, using a metal alkoxide solutions in the electrophoretic deposition (EPD). The influence of several process parameters, like sintering temperature of sol preparation before EPD and heat-treatment temperature and non-oxidized atmosphere, on the film properties is described.

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