• 제목/요약/키워드: Air atmosphere

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자연환경 변화와 광물의 역할

  • 김수진
    • 한국암석학회:학술대회논문집
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    • 한국암석학회.한국광물학회 2000년도 공동학술발표회 논문집
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    • pp.3-11
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    • 2000
  • The earth environment consists of four spheres : geosphere, hydrosphere, atmosphere and biosphere. The geosphere consists mostly of minerals. It, however, contains some water and air in its shallow depth. Although hydrosphere and atmosphere consist predominantly of water and air, respectively, both contain some minerals. The biosphere consisting of various organisms is present in the interfaces of geosphere, hydrosphere and atmosphere. The natural environment of the earth is continuously changing by the interaction of four spheres. It suggests that out relevant environmental problems can not be revolved without understanding the natural relationship of these four spheres. Minerals in our environment are very important because they are the main constituent materials of the earth and they control our environment. The roles of minerals in our environment have not been understood even in the scientific society. Thus their roles have been neglected. Review of studies on the environmental mineralogy so far made at our laboratory and others show that minerals control the environment in various ways. Minerals neutralize the acid water as well as acid rain. Minerals in soils and rocks are major neutralizer of the acid rain. Salinization of sea water is attributed to the ionic substitution between minerals and sea water. Some minerals control the humidity of the air. Corals, the products of biomineralization, are the main carbon controller of the air. Minerals also adsorb heavy metals, organic pollutants and radioactive nuclides. Such remarkable functions for controlling the environment come from the mineral-water reaction and biomineralization. All these phenomena are subjects of the environmental mineralogy, a new field of earth science.

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Tricalcium Silicate의 초기수화반응(II) (Early Hydration of Tricalcium Silicate(II))

  • 오희갑;최상흘
    • 한국세라믹학회지
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    • 제24권2호
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    • pp.133-138
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    • 1987
  • The behavior of CaO and SiO2 in the reaction produced which produced in the early hydration of C3S was studied by XRD and thermal analyzer. Polymerization of hydrated siltcates was also studied by TMS method. TMS derivatives were separated by gaschromatography. Cao/SiO2 molar ratios of the produced CSH gel under the air atmosphere were higher than that in the CO2. Dimerization rate of hydrated silicates was very fast in the early hydration stage. Trimer began to appear later than dimer and its increasing rate was very low. The amount of dimer and trimer formed under the CO2 atmosphere was less than that in the air.

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청정에너지 회수용 유증기/매연 포집모듈에 관한 연구 (A Study on the Oil-mist/Smoke Collecting Module for the Pure Energy Recycling)

  • 김명수;오꾸라 시게노부;함경춘
    • 한국태양에너지학회:학술대회논문집
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    • 한국태양에너지학회 2009년도 추계학술발표대회 논문집
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    • pp.279-284
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    • 2009
  • Traditionally, so-called "industrial waste gases", such ad exhaust from boilers at industrial installations and a large quantity of soot discharged from power station, before their release into the atmosphere, have been on occasion subjected to an air cleaning process to remove fine particles that may pollute the atmosphere (such as mist and dust containing various powdery or oily substances and moisture from industrial waste gases). The release of industrial waste gases containing these particles directly into the atmosphere poses a serious threat to the earth environment; and recovery of these noxious substances is required by law in some countries and local governments. in urban areas, air pollution from automobile exhaust and others creates a serious condition. Some homes are equipped with and use indoor air purifiers. In many of the kitchens of restaurants, smoke generated during cooking and otherwise contaminated air are cleansed by air purifiers before being released outside or recycled inside. For the dust collecting devices to recover the fine particles contained in contaminated air, the cause for air pollution and how to purify air, many types based on various principles are known. Specifically, classified based on theories of particle collection, filtration, gravity, inertia, centrifugation, electricity, and cleaning types are cited as available processes. Among them, an appropriate type is selected according to the size or type of fine particles to be collected and conditions for installation. For the efficiency of dust collection, a filtration system (by using bag filters and others) and electric system are particularly outstanding and are therefore used widely in various areas of industry. In this research, rotary type high performance oil mist and smoke collecting system with self auto cleaning device equipped with the cleaning fluid spraying section is investigated.

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50% NH3-Air-N2가스분위기에서 Oxynitriding시 Compound Layer의 성장 특성에 미치는 공기첨가효과 (Effect of Air Additions on the Growth Characteristics of the Compound Layer during Oxynitriding in50%NH3+Air+N2 Atmosphere)

  • 김영희;이영숙
    • 열처리공학회지
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    • 제7권3호
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    • pp.206-218
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    • 1994
  • In 50%$NH_3+Air+N_2$ atmospheres, the effect of air additions on the growth characteristics of the compound layer during oxynitriding at $570^{\circ}C$ for 2hr in carbon and alloy steels has been investigated. The ammount of apparent residual ammonia during oxynitriding has shown to be increased with air additions(9~36 Vol. %) and X-ray diffraction analysis of case oxynitreded has shown that the compound layer consist of ${\varepsilon}-Fe_{2-3}$(N, C) phase and ${\gamma}^{\prime}-Fe_4$(N,C) phase. In the case of carbon steels, the thickness of oxide layer, compound layer and porous layer and the amount of ${\varepsilon}-Fe_{2-3}$(N,C) phase in the compound layer were increased with additions of air in 50%$NH_3+N_2$ atmospheres. At the same gas composition, the thickenss of oxide layer, compound layer and porous layer in alloy steels showed slightly thin layer thickness compared to those of carbon steels and the ${\gamma}^{\prime}-Fe_4$(N,C) phase in the compound layer of alloy steels was found barely. Therefore, the most obvious effect of air addition in the gas nitriding atmosphere has been found to in crease further kinetics of nitriding reaction.

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Influence of milling atmosphere on thermoelectric properties of p-type Bi-Sb-Te based alloys by mechanical alloying

  • Yoon, Suk-min;Nagarjuna, Cheenepalli;Shin, Dong-won;Lee, Chul-hee;Madavali, Babu;Hong, Soon-jik;Lee, Kap-ho
    • 한국분말재료학회지
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    • 제24권5호
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    • pp.357-363
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    • 2017
  • In this study, Bi-Sb-Te thermoelectric materials are produced by mechanical alloying (MA) and spark plasma sintering (SPS). To examine the influence of the milling atmosphere on the microstructure and thermo-electric (TE) properties, a p-type Bi-Sb-Te composite powder is mechanically alloyed in the presence of argon and air atmospheres. The oxygen content increases to 55% when the powder is milled in the air atmosphere, compared with argon. All grains are similar in size and uniformly, distributed in both atmospheric sintered samples. The Seebeck coefficient is higher, while the electrical conductivity is lower in the MA (Air) sample due to a low carrier concentration compared to the MA (Ar) sintered sample. The maximum figure of merit (ZT) is 0.91 and 0.82 at 350 K for the MA (Ar) and MA (Air) sintered samples, respectively. The slight enhancement in the ZT value is due to the decrease in the oxygen content during the MA (Ar) process. Moreover, the combination of mechanical alloying and SPS process shows a higher hardness and density values for the sintered samples.

알루미나 세라믹스의 반복적 균열치유 특성 (Cyclic Crack Healing Effect of Al2O3 Ceramics)

  • 문창권;김부안
    • 한국해양공학회지
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    • 제27권2호
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    • pp.69-74
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    • 2013
  • In this study, the crack healing effects of $Al_2O_3$ ceramics based on the heat treatment conditions were investigated. The influence of the additive amounts of SiC nanoparticles and the cycling process of indentation-heat treatment on the crack healing effect of $Al_2O_3$ ceramics were also examined. Three-point bending tests were carried out and the morphological changes in the fracture surface were observed by using FE-SEM. As a result, heat-treated samples in a vacuum or air atmosphere showed improved bending strengths compared to un-heat treated samples. This means that cracked specimens can be healed by heat treatment in a vacuum or air atmosphere. The crack healing effect of $Al_2O_3$ ceramics that were heat treated in an air atmosphere was much higher than that of those heat treated in a vacuum. After heat treatment, the $Al_2O_3$ ceramics with 30 wt% SiC nanoparticles showed a higher bending strength than those with 15 wt% SiC. The cyclic indentation and heat treatment did not remarkably affect the crack healing effect. The SEM images showed that the median crack, indenter mark on the surface, and pores in the fracture surface of a specimen almost disappeared after being heat treated in an air atmosphere.

COMBUSTION KINETICS OF POLYETHYLENE TEREPHTHALATE

  • Oh, Sea-Cheon;Lee, Dong-Gyu;Kwak, Hyun;Bae, Seong-Youl
    • Environmental Engineering Research
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    • 제11권5호
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    • pp.250-256
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    • 2006
  • The combustion kinetics of poly(ethylene terephthalate) (PET) was studied by the dynamic model which accounts for the thermal decomposition of polymer at any time. The kinetic analysis was performed by a conventional nonisothermal thermogravimetric (TG) technique at several heating rates between 10 and 40 K/min in air atmosphere. The thermal decomposition of PET in air atmosphere was found to be a complex process composed of at least two stages for which kinetic values can be calculated. The combustion kinetic analysis of PET gave apparent activation energy for the first stage of $257.3{\sim}269.9\;kJ/mol$, with a value of $140.5{\sim}213.8\;kJ/mol$ for the second stage. To verify the effectiveness of the kinetic analysis method used in this work, the kinetic analysis results were compared with those of various analytical methods. The kinetic parameters were also compared with values of the pyrolysis of PET in nitrogen atmosphere.

The Variation of Radiocarbon-14 Content in the Atmosphere

  • Kyung Rin Yang
    • 대한화학회지
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    • 제15권6호
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    • pp.370-377
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    • 1971
  • The Carbon-14 content in surface air at Seoul, Korea, was measured from February 1970 to August 1971 and a Larix Leptolepis, Gordon tree (Ip-Gal Namu) grown at Kwang-Nung, Kyunggi-Do, Korea, having 37 growth rings, was assayde for $^{14}C$. From the results of the surface air study, it was calculated that during the above period the inventory of excess $^{14}C$ in the atmosphere decreased with a half-time of 4.6 years. The overall yearly decrease was also checked. The tree-ring study showed that the tree's atmosphere was affected by $^{14}C$ from nuclear tests after 1956. In one study, atmospheric $CO^2$ samples were collected bi-monthly by the absorption of $CO^2$ in alkaline hydroxide solution. In the other, 5 year annual growth rings were assayed for radiocarbon. For the radioactivity measurement, carbon atoms in samples were converted to carbon atoms of benzene. The resulting benzene was taken as primary solvent for liquid scintillation counting.

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대기확산의 수치모의에서 SST 효과 (SST Effect upon Numerical Simulation of Atmospheric Dispersion)

  • 이화운;원경미;조인숙
    • 한국대기환경학회지
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    • 제15권6호
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    • pp.767-777
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    • 1999
  • In the coastal region air flow changes due to the abrupt change of surface temperature between land and sea. So a numerical simulation for atmospheric flow fields must be considered the correct fields of sea surface temperature(SST). In this study, we used variables such as latent heat flux, sensible heat flux, short and long wave radiation of ocean and atmosphere which exchanged across the sea surface between atmosphere and ocean model. We found that this consideration simulated the more precise SST fields by comparing with those of the observated results. Simulated horizontal SST differences in season were 2.5~4$^{\circ}C$. Therefore we simulated the more precise atmospheric flow fields and the movement and dispersion of the pollutants with the Lagrangian particle dispersion model. In the daytime dispersion pattern of the pollutants emitted from ship sources moved toward inland, in the night time moved toward sea by land/sea breeze criculation. But air pollutants dispersion can be affected by inland topography, especially Yangsan and coastal area because of nocturnal wind speed decrease.

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