• Title/Summary/Keyword: Air Layer

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Influence of the cathode catalyst layer thickness on the behaviour of an air breathing PEM fuel cell

  • Ferreira-Aparicio, Paloma;Chaparro, Antonio M.
    • Advances in Energy Research
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    • v.2 no.2
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    • pp.73-84
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    • 2014
  • Fuel cells of proton exchange membrane type (PEMFC) working with hydrogen in the anode and ambient air in the cathode ('air breathing') have been prepared and characterized. The cells have been studied with variable thickness of the cathode catalyst layer ($L_{CL}$), maintaining constant the platinum and ionomer loads. Polarization curves and electrochemical active area measurements have been carried out. The polarization curves are analyzed in terms of a model for a flooded passive air breathing cathode. The analysis shows that $L_{CL}$ affects to electrochemical kinetics and mass transport processes inside the electrode, as reflected by two parameters of the polarization curves: the Tafel slope and the internal resistance. The observed decrease in Tafel slope with decreasing $L_{CL}$ shows improvements in the oxygen reduction kinetics which we attribute to changes in the catalyst layer structure. A decrease in the internal resistance with $L_{CL}$ is attributed to lower protonic resistance of thinner catalyst layers, although the observed decrease is lower than expected probably because the electronic conduction starts to be hindered by more hydrophilic character and thicker ionomer film.

Crack-Free Fabrications of Yttria-Stabilized Zirconia Films Using Successive-Ionic-Layer-Adsorption-and-Reaction and Air-Spray Plus Method

  • Taeyoon Kim;Sangmoon Park
    • Korean Journal of Materials Research
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    • v.34 no.2
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    • pp.79-84
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    • 2024
  • Thin films of yttria-stabilized zirconia (YSZ) nanoparticles were prepared using a low-temperature deposition and crystallization process involving successive ionic layer adsorption and reaction (SILAR) or SILAR-Air spray Plus (SILAR-A+) methods, coupled with hydrothermal (175 ℃) and furnace (500 ℃) post-annealing. The annealed YSZ films resulted in crystalline products, and their phases of monoclinic, tetragonal, and cubic were categorized through X-ray diffraction analysis. The morphologies of the as-prepared films, fabricated by SILAR and SILAR-A+ processes, including hydrothermal dehydration and annealing, were characterized by the degree of surface cracking using scanning electron microscopy images. Additionally, the thicknesses of the YSZ thin films were compared by removing diffusion layers such as spectator anions and water accumulated during the air spray plus process. Crack-free YSZ thin films were successfully fabricated on glass substrates using the SILAR-A+ method, followed by hydrothermal and furnace annealing, making them suitable for application in solid oxide fuel cells.

Equilibrium Moisture Contents and Thin Layer Drying Equations of Cereal Grains and Mushrooms (I) - Thin Layer Drying Equations of Short Grain Rough Rice - (곡류 및 버섯류의 평형함수율 및 박층건조방정식에 관한 연구(I) -벼의 박층건조방정식 -)

  • 금동혁;박춘우
    • Journal of Biosystems Engineering
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    • v.22 no.1
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    • pp.11-20
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    • 1997
  • Thin layer drying tests of short gain rough rice were conducted in an experimental dryer equiped with air conditioning unit. The drying tests were performed in triplicate at three air temperatures of $35^circ$, $45^circ$, $55^circ$, and three relative humidities of 40%, 55%, 70%, respectively. Previously published thin layer equations were reviewed and four different models widely used as thin layer drying equations for cereal grains were selected. The selected four models were Pages, simplified diffusion, Lewis's and Thompson's models. Experimental data were fitted to these equations using stepwise multiple regression analysis. The experimental constants involved in tow equations were represented as a function of temperature and relative humidity of drying air. The results of comparing coefficients of determination and root mean square errors of miosture ratio for low equations showed that Page's and Thompsons models were found to fit adequately to all drying test data with coefficient of determination of 0.99 or better and root mean square error of moisture ratio of 0.025.

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Analysis of Heat Transmission Characteristics through Air-Inflated Double Layer Film by Using Thermal Resistance Equation (열저항식을 이용한 공기막 이중필름의 관류전열량 특성 분석)

  • Kim, Hyung-Kweon;Jeon, Jong-Gil;Paek, Yee;Lee, Sang-Ho;Yun, Nam-Kyu;Yoo, Ju-Yeol
    • Journal of Bio-Environment Control
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    • v.22 no.4
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    • pp.316-321
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    • 2013
  • This study was carried out to analyze heat transfer characteristics and heat flow through air-inflated double layer PO film with thermal resistance method. The experiments was conducted in the laboratory controlled air temperature between 258.0 K and 278.0 K. The experimental materials were made up two layers PO film and an inflated-air layer. The thickness of air-inflated layer was fixed at 3 types of 110, 175, 225 mm. The electrical circuit analogy for heat transfer by conduction, radiation and convection was introduced. Experimental data shows that the dominant thermal resistance in heat transfer through the air-inflated double layer film was convection. Calculation errors were 1.1~18.5 W for heat flow. In result, the method of thermal resistance could be introduced for analysis of heat flow characteristics through air-inflated double layer film.

Heat and Mass Transfer of Parallel Plate Heat Exchanger under Frosting Condition (착상조건하에서 평행 평판 열교환기의 열 및 물질전달)

  • Lee, K.S.;Lee, T.H.;Kim, W.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.6 no.2
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    • pp.155-165
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    • 1994
  • In this study, the following factors are investigated from experiments for a vertical parallel plate heat exchanger under the frosting condition ; the growth of frost layer, the characteristics of heat and mass transfer, the change of mass flow rate of the air passing through the heat exchanger, and the pressure drop of the air in the heat exchanger. The amount of heat and mass flux of water vapor transferred from the air stream to the heat exchanger surface is large at the early stage of frosting and then decreases dramatically, and the extent of decreasing rate becomes moderate with time. The frost layer formed near the inlet of the heat exchanger is thicker and denser than that formed near the outlet. It is found that the gradient of the amount of frost along the flow direction increases with time. In the early period of frost formation, the thermal resistance between the air and the cooling plate increases dramatically and then the extent of change decreases with time. Initially the convective thermal resistance is dominant. Then, while the convective thermal resistance decreases with time, the conductive thermal resistance continues to increase with time and finally the conductive thermal resistance becomes dominant.

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An Experimental Study on Turbulent Diffusion Flame in Double Coaxial Air Jets(II) (동축이중 공기분류중의 난류확산화염에 관한 실험적 연구 II)

  • 조용대;최병윤
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.5
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    • pp.1234-1243
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    • 1990
  • Double coaxial are jets(annular and coaxial air jets) between which propane gas is fed was selected to study the structure of diffusion flames in turbulent shear flow. Schlieren and direct photographs are taken to visualize the flame structure. Mean and fluctuating temperatures and ion currents were measured to investigate the macroscopic and the instantaneous flame structure. The objective of this study is to understand the interaction between combustion and mixing process especially in the transition region of turbulent shear flow. The investigation reported in this paper focuses on the macroscopic and the instantaneous structures of three flames obtained. The increased mixing effect resulting from increase of Reynolds number of central air jet makes the flame bluish and short. When the velocity of surrounding air stream is higher than that of central air jet, the instantaneous flame structure is composed of coherent structure. It is considered that the flame structure of transitional region of mixing layer depends on the structure of mixing layer of non-reacting conditions.

A Three-Dimensional CFD Study on the Air Flow Characteristics in a Wax Spin Coater for Silicon Wafer Manufacturing (실리콘 웨이퍼 생산공정용 왁스 스핀코팅장치 내 기류 특성에 대한 3차원 전산유동해석)

  • Kim, Yong-Ki;Kim, Dong-Joo;Umarov, Alisher;Kim, Kyoung-Jin;Park, Jun-Young
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.10 no.6
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    • pp.146-151
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    • 2011
  • Wax spin coating is a part of several wafer handling processes in the silicon wafer polishing station. It is important to ensure the wax layer free of contamination to achieve the high degree of planarization on wafers after wafer polishing. Three-dimensional air flow characteristics in a wax spin coater are numerically investigated using computational fluid dynamics techniques. When the bottom of the wax spin coater is closed, there exists a significant recirculation zone over the rotating ceramic block. This recirculation zone can be the source of wax layer contamination at any rotational speed and should be avoided to maintain high wafer polishing quality. Thus, four air suction ducts are installed at the bottom of the wax spin coater in order to control the air flow pattern over the ceramic block. Present computational results show that the air suction from the bottom is quite an effective method to remove or minimize the recirculation zone over the ceramic block and the wax coating layer.

Effect of Air Exposure on ZnO Thin Film for Electron Transport Layer of Quantum Dot Light-Emitting Diode (ZnO 박막 전자수송층의 공기 노출에 의한 양자점 발광다이오드의 특성 변화)

  • Eunyong Seo;Kyungjae Lee;Jeong Ha Hwang;Dong Hyun Kim;Jaehoon Lim;Donggu Lee
    • Journal of Sensor Science and Technology
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    • v.32 no.6
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    • pp.455-461
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    • 2023
  • We investigated the electrical characteristics of ZnO nanoparticles (NPs) with air exposure that is a widely used electron transport layer for quantum dot light-emitting diodes (QLEDs). Upon air exposure, we observed changes in the density of states (DOS) of the trap levels of ZnO NPs. In particular, with air exposure, the concentration of deep trap energy levels in ZnO NPs decreased and electron mobility significantly improved. Consequently, the air-exposed ZnO reduced leakage current by approximately one order of magnitude and enhanced the external quantum efficiency at the low driving voltage region of the QLED. In addition, based on the excellent conductivity properties, high-brightness QLEDs could be achieved.

A Numerical Study on Natural Convection Between Skin and Fabrics (Phoenics를 이용한 옷감의 종류 및 두께의 변화에 따른 열전달 특성의 수치 해석적 연구)

  • 홍지명
    • Journal of the Korean Society of Clothing and Textiles
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    • v.19 no.1
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    • pp.142-148
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    • 1995
  • In this study, FVM (Finite Volume Method) which is one of the 2-dimensional numerical approach has been conducted to anticipate the temperature distribution between skin and clothes by the change of air temperature and fabric characteristics including fabric thickness. Several experimental works have been done to understand the thermal insulation effect (If fabrics on a human body by measuring the averaged temperature in the air layer between skin and clothes or by measuring the thermal resistance of fabrics. However, the formal method is inconvenient to measure the temperature distribution in the air layer to evaluate the insulation rate of the clothes on the skin because the real size of the clearance between skin and the clothes is too small to place the temperature sensor, and in the Tatter method the relationship between human body and the fabrics are ignored. However, the numerical method will be very effective and economical way to evaluate the insulation efficiency of clothes when the computational result is in the reliable range. As the result of this study, the temperature change in the sir layer between skin and clothes was linear to the fabric thickness and this result coincides with many previous experimental results. Moreover, it is possible to predict the optimum fabric thickness for the best thermal insulation in the air layer between skin and clothes.

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Numerical Investigation of Supersonic Combustion on Two-dimensional Double Shear Layer (2차원 2단 혼합층에서의 초음속 연소에 관한 수치해석)

  • Kim, Dong-Min;Baek, Seung-Wook
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.05a
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    • pp.285-288
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    • 2008
  • The Present Study describes the numerical investigations concerning a fuel(Hydrogen), inert gas (Nitrogen) or supersonic air stream issued between each other. The basic flow configuration consists of a plane, double shear/mixing layer flow. For the numerical solution, a fully conservative unsteady $2^{nd}$ order time accurate sub-iteration method and a $2^{nd}$ order Total Variation Diminishing(TVD) scheme are used with the finite volume method(FVM). The results are consist of three categories ; single shear layer consist of fuel and supersonic air stream, inert gas stream issued between supersonic air and fuel stream, fuel gas stream issued between supersonic air and fuel stream. The numerical calculations has been carried out in case of 1,2, and 4mm thickness of center stream. The width of total gas stream is 4cm.

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