• Title/Summary/Keyword: Air Electrode

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Fabrication of the Functional Coatings of a Tubular Solid Oxide Fuel by Plasma Spray Processes. (플라즈마 용사법을 이용한 원통형 고체산화물 연료전지의 요소피막 제조)

  • 주원태;홍상희
    • Journal of the Korean institute of surface engineering
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    • v.30 no.5
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    • pp.333-346
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    • 1997
  • Plasma spray processes for functional coatings of tubular SOFC ( Soild oxide Fuel Cell).consisting of air electrode, oxide electrolyte, an fuel electrode, are optimized by fully saturated fractional factorial testing. Material and electric characteristics of each coating are analtsed by the implementation of SEM and optical microscope for evaluating microstructure and porosity, X-ray diffraction method for investigating compositional change between raw powder and sprayed coating, and Van der Pauw method for measuring electrical conductivity. LSM ($La_{0.65}Sr_{0.35}MnO_3$air electrode and Ni-YSL fuel electrode coatings have porosities of around 23~30% sufficient for effective fuel and oxidant gas supply to electrochemical reaction interfaces and electrical conductivities of around 90 S/cm and 1000 S/cm, respectively, enough for acting as current collecting electrodes. YSZ($ZrO_2-8mol%Y_2O_3$) electrolyte film has a high ionic conductivities of 0.05~0.07 S/cm at $1000^{\circ}C$ in air atmosphere, but appears to be somewhat too porous to reduce the thickness. for enhancing the cell efficiency. A unit tubular SOFC has beem fabricated by the optimized plasma spray processes for each functional coating and the cell. Its electrochemical chracteristics are investigated by measuring voltage-current and power density with variation of operationg temperature, radio of fuel to air gas flowrates, and total gas flowrate of reactants.

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Simulation of Electric Potential and Electric Field for Wire-Plate Type Plasma Reactor Manufacture (선 대 평판형 플라즈마 반응기 제작을 위한 전위 및 전계 해석)

  • Lee, Dong-Hoon
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.52 no.4
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    • pp.167-171
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    • 2003
  • Due to advancement of industrialization, the flue gas from the combustion of industrial factories and various means of transportation have polluted air. Therefore, it is necessary to develop new techniques of air purification. In order to produce a more effective reactor, simulation were conducted using the Flux-II D program. The condition of the simulation were as follows: The height of the plate electrode was 0 mm or 2 mm higher than that of the wire electrode. The distance between the electrodes was 12 mm, and the diameter of the wire electrode was 0.5 mm or 1.0 mm. The results of the electric potential and electric field simulations show that pollutants will be more effectively removed due to the dielectric strength between wire electrode and plate electrode which was strong, and wire electrodes which were concentrated in a high electric field.

Carbon-free Polymer Air Electrode based on Highly Conductive PEDOT Micro-Particles for Li-O2 Batteries

  • Yoon, Seon Hye;Kim, Jin Young;Park, Yong Joon
    • Journal of Electrochemical Science and Technology
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    • v.9 no.3
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    • pp.220-228
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    • 2018
  • This study introduced a carbon-free electrode for $Li-O_2$ cells with the aim of suppressing the side reactions activated by carbon material. Micro-particles of poly(3,4-ethylenedioxythiophene) (PEDOT), a conducting polymer, were used as the base material for the air electrode of $Li-O_2$cells. The PEDOT micro-particles were treated with $H_2SO_4$ to improve their electronic conductivity, and LiBr and CsBr were used as the redox mediators to facilitate the dissociation of there action products in the electrode and reduce the over-potential of the $Li-O_2$ cells. The capacity of the electrode employing PEDOT micro-particles was significantly enhanced via $H_2SO_4$ treatment, which is attributed to the increased electronic conductivity. The considerable capacity enhancement and relatively low over-potential of the electrode employing $H_2SO_4$-treated PEDOT micro-particles indicate that the treated PEDOT micro-particles can act as reaction sites and provide storage space for the reaction products. The cyclic performance of the electrode employing $H_2SO_4$-treated PEDOT micro-particles was superior to that of a carbon electrode. The results of the Fourier-transform infrared spectroscopic analysis showed that the accumulation of residual reaction products during cycling was significantly reduced by introducing the carbon-free electrode based on $H_2SO_4$-treated PEDOT micro-particles, compared with that of the carbon electrode. The cycle life was improved owing to the effect of the redox mediators. The refore, the use of the carbon -free electrode combined with redox mediators could realize excellent cyclic performance and low over-potential simultaneously.

Experimental Study on the Discharge Electrode of A Two-Stage Electrostatic Air Cleaner (2단 평행판 전기집진기의 방전부 특성 실험)

  • Kim, I.S.;Lee, J.O.;Kim, Y.J.;Choi, H.O.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.5 no.1
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    • pp.27-34
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    • 1993
  • The two-stage electrostatic air cleaner is a particle control device that uses electrical forces to move particles in the flowing gas stream onto collector plates. Despite a general understanding of electrostatic air cleaner operation and their successful use in industry, many questions regarding flow, electric fields and particle collection have remained unanswered. In this paper, an experimental investigation for designing the discharge electrode, including ionizer wire diameter, plate length and wire-to-plate spacing, is carried out. The electrical conditions, namely the electric field intensity, the space current and the particle charge intensity, in wire-plate electrostatic air cleaner are reported and examined.

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Decolorization of a Rhodamine B Using Ru-graphite Electrode (Ru-흑연 전극을 이용한 Rhodamine B의 색 제거)

  • Park, Young-Seek
    • Journal of Environmental Science International
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    • v.17 no.5
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    • pp.547-553
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    • 2008
  • For the RhB removal from the wastewater, electrochemical method was adapted to this study. Three dimensionally stable anode (Pt, Ir and Ru) and graphite and Ru cathode were used. In order to identify decolorization, the effects of electrode, current density, electrolyte and air flow rate were investigated. The effects of electrode material, current, electrolyte concentration and air flow rate were investigated on the decolorization of RhB. Electro-Fenton's reaction was evaluated by added $Fe^{2+}$ and $H_2O_2$ generated by the graphite cathode. Performance for RhB decolorization of the four electrode systems lay in: Ru-graphite > Ru-Ru > Ir-graphite > Pt-graphite. A complete color removal was obtained for RhB (30 mg/L) at the end of 30 min of electrolysis under optimum operations of 2 g/L NaCl concentration and 2 A current. $Fe^{2+}$ addition increased initial reaction and decreased final RhB concentration. However the effect was not high.

A Study on an Ion Wind Created by a Wire Electrode and Parallel Plates Assembly (와이어 전극과 평행판에서 발생되는 이온풍 특성 연구)

  • 안영철;황필재;이재근
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.4
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    • pp.318-323
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    • 2004
  • When a strong electric field is applied between a sharply curved electrode and a blunt surface, the corona may result in a gas movement in the electrode gap which is directed toward the blunt surface. That is called the corona wind. It enhances heat and mass transfer between the surface and the surrounding gas. Moreover such enhancement causes no noise or vibration, which can be applied in complex, isolated geometries, and allows simple control of surface temperatures. This paper examines the relationship between the corona wind and the relative humidity. The facility consists of high voltage power supply thin tungsten wire, plate electrode, multimeter, microammeter and flow meter. Gas velocity is a linear function of voltage, relative humidity and is proportional to the square root of the current. The maximum velocities for the positive and negative corona discharge are 1.9 m/s (2.74 CMM/m), 1.5 m/s(2.15 CMM/m), respectively.

광폭 전기집진기의 집전특성에 관한 연구 - I. 집진판 간격과 방전극의 영향 -

  • 김용진;하병길;정상현;홍원석;여석준;유주식
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.10
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    • pp.939-946
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    • 2001
  • This study investigates the electrical and collection characteristics of a wide plate spacing electrostatic precipitator (ESP), using a pilot-scale one. Electrical operating characteristics and collection efficiency were measured for various shapes of discharge electrodes. The collection plate spacing ranged from 300 to 550 mm. Results of electrical characteristic and collection efficiency tests as a function of collection plate spacing, discharge electrode type, applied voltage, and particle diameter were obtained. Increasing the collection plate pitch and altering the corona electrode geometry was found to increase the collection efficiencies without increasing input power requirement. The best efficiency is achieved for the discharge electrode of twisted pin type.

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The Study on Arc Suppression of Line-to-Line Electrodes in Air and Removal of the Metaloxide (선대 선 전극방식의 대기압 아크억제 대책 및 Metaloxide 제거에 관한 연구)

  • 정종한;김문환
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.53 no.5
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    • pp.264-267
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    • 2004
  • Recently the pulsed power systems have been widely used in many fields such as E/P(Electrostatic Precipitator), DeNOx/DeSOx power systems, ozone generators and power sources of the laser beam. In this paper, we studied various electrical characteristics for arc suppression of line-to-line electrodes in air and removal of the metaloxide using our pulsed power system. To obtain high efficiency of the pulsed power system, we repeatedly experimented and tested their characteristics. by adjusting electrode length of the load. As a result, when the value of the electrode length and pulse repetition rate were changed at the load, the value of the arc voltage changed at the electrode load. In conclusion, we controlled arc voltage of the load by ,changing electrode length and pulse repetition rate. Also. we stydied removal area of the metaloxide using area discharge according to pulse repetition rate.

A Study on the Collection Characteristics of a Moving Electrode Electrostatic Precipitator - I. Effect of Collection Plate Velocity - (이동 전극형 전기집진기의 집진특성에 관한 연구 - I. 집진판 이동 속도의 영향-)

  • Kim Yong-Jin;Ha Byung-Kil;Jeong Sang-Hyun;Moon Sang-Cheol;Yoo Joo-Sik
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.10
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    • pp.901-907
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    • 2004
  • This study investigate the effect of collection plate velocity on the electrical and collection characteristics of a moving electrode electrostatic precipitator (MEEP). Though a high resistivity fly ash is attached at the collecting electrode, the MEEP has very stable characteristics of voltage and corona current. Collection efficiency, corona current, and overall collection efficiency are increased, as the magnitude of the collection plate velocity increases.

Uncertainty and Compensation on the cell for Measurement of the Solid Permittivity Materials (고체 유전율 측정용 cell의 불확도 분석과 보상)

  • Kim, Han-Jun;Kang, Jeon-Hong;Yu, Kwang-Min;Hyun, Lee-Sei;Koo, Kyung-Wan;Han, Sang-Ok
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.482-483
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    • 2007
  • For measurement of dielectric constants, the commercial parallel plate electrodes system with guard-ring electrode have been widely used up to now. The capacitance derived from the parallel plate electrodes capacitor with guard-ring electrode is calculated by the equation of ($C={\epsilon}\;{\cdot}\;\frac{area\;of\;electrod}{distance\;between\;electrodes}$). Therefore, in parallel plate electrode capacitor, the diameter of the guarded electrode, the gap size between guarded electrode and guard ring, and distance between two active electrode should be measured precisely to calculate dielectric constants from the measured capacitance. Consequently their mechanical measurement uncertainties are directly contributed. Especially the air-gap between the electrodes and dielectric specimen at the system must be existed and the measurement error derived from the air-gap is impossible to evaluate as measurement uncertainties. In this study, we analyze the uncertainty of the commercial dielectric constant test cell using 3 kinds CRMs.

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