• 제목/요약/키워드: Air Chemistry

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Observation of Water Consumption in Zn-air Secondary Batteries

  • Yang, Soyoung;Kim, Ketack
    • Journal of Electrochemical Science and Technology
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    • 제10권4호
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    • pp.381-386
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    • 2019
  • Zn-air battery uses oxygen from the air, and hence, air holes in it are kept open for cell operation. Therefore, loss of water by evaporation through the holes is inevitable. When the water is depleted, the battery ceases to operate. There are two water consumption routes in Zn-air batteries, namely, active path (electrolysis) and passive path (evaporation and corrosion). Water loss by the active path (electrolysis) is much faster than that by the passive path during the early stage of the cycles. The mass change by the active path slows after 10 h. In contrast, the passive path is largely constant, becoming the main mass loss path after 10 h. The active path contributes to two-thirds of the electrolyte consumption in 24 h of cell operation in 4.0 M KOH. Although water is an important component for the cell, water vapor does not influence the cell operation unless the water is nearly depleted. However, high oxygen concentration favors the discharge reaction at the cathode.

벼품종과 도정단계에 따른 열풍 팽화 특성 (Puffability with Hulling steps and Rice Varieties by Hot Air Puffer)

  • 김중만;김동한;백승화;최용배;한성희
    • Applied Biological Chemistry
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    • 제37권2호
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    • pp.72-76
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    • 1994
  • 고미의 효율적 소비방법에 관한 연구의 일환으로 열풍식 팽화기($210{\pm}5^{\circ}C$, $55{\pm}5\;sec.$)를 이용하여 나락의 팽화 특성을 벼의 형태와 품종별로 비교하였다. 열풍에 의한 팽화효과는 나락이 현미나 백미에 비하여 월등하게 우수하였고 형태별 팽화된 전분의 상대적 결정화도 역시 나락이 백미나 현미보다 매우 낮았다. 팽화나락과 현미의 팽화체적 증가율은 찰벼가 메벼에 비하여 높았으며 팽화적성은 운봉올찰벼와 진주벼가 양호(P=0.05)하였다. 최대 팽화력을 나타내는 나락의 수분함량은 $10{\sim}12%$이었다.

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Zinc Air 이차전지의 구성요소 (Components in Zn Air Secondary Batteries)

  • 이정혜;김기택
    • 전기화학회지
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    • 제16권1호
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    • pp.9-18
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    • 2013
  • Zinc air 전지의 구성요소와 전지의 특징을 설명하였다. 리튬 이온 전지에 비해 월등히 높은 에너지 밀도를 가지고 있지만, 충전의 비가역성으로 인한 낮은 용량 유지 특성 때문에 zinc air 이차전지는 아직 상용화되지 못하였다. Zinc air 전지는 충방전에 관여하는 반응들의 속도가 느려서 그 반응들의 속도를 촉진해야 하는 특징이 있는가 하면 동시에 부식과 수소발생 반응의 속도는 오히려 느리게 해야 하는 까다로운 조건을 만족해야 한다. 기존의 전지들과 비교하면, 기초연구뿐 아니라, 전지의 기계적구조, 부식, 복합소재적인 요소의 적용이 더욱 필요한 연구분야라고 하겠다. 출력개선과 부식방지 그리고 공기의 공급에 대비한 물의 증발의 억제 등은 상충하는 성질을 동시에 만족해야 하는 복합소재의 특성이다.

Washout Removal Efficiencies of Major Air Pollutants by Precipitation

  • Kim, Dong-Sool;Lim, Deuk-Yong;Heo, Jeong-Sook
    • Journal of Korean Society for Atmospheric Environment
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    • 제18권E2호
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    • pp.97-106
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    • 2002
  • The purpose of this study was to quantitatively estimate the washout removal efficiencies of criteria air pollutants such as SO$_2$, TSP, PM10, CO, NO$_2$, and O$_3$corresponding to the amounts and durations of precipitation. The removal patters by washout were studied with air pollutants data and the corresponding precipitation data in Seoul, Korea during the periods of 1990 to 1999. In addition, washout patterns were classified into four seasons and four time Bones, i.e., night, morning, afternoon, and evening. In this study, natures of air pollutants by sequential precipitation were also intensively studied by examining the linear relationships between removal efficiencies and the amounts and durations of precipitation for each pollutant. The results of this study showed that SO$_2$, TSP, and O$_3$were rapidly removed by initial precipitation; however, NO$_2$was slowly removed 2-hour after precipitation. Both CO and PM10 were weakly removed by washout and their removal patters showed to be irregular.

Dynamic SPME를 이용한 공기 중 지방산 분석 (Analysis of Volatile Fatty Acids in Air by Dynamic SPME)

  • 유미선;양성봉;하남기
    • 한국환경과학회지
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    • 제19권12호
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    • pp.1447-1454
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    • 2010
  • In this study, the detection limits of lower fatty acids in air were investigated by using Dynamic SPME(Solid Phase Micro-Extraction), i.e. improved Head Space - SPME method(HS-SPME). This Dynamic SPME, called SPDE(Solid Phase Dynamic Extraction), is the analytical method for volatile compounds in air with the extraction by using a stainless steel needle of which inner surface is coated with adsorption material and following the gas chromatographic analysis by inserting the needle into a injection port of GC and subsequently, desorption of the volatile compounds into a gas-chromatographic column. Extraction was carried out by passing the sample air through the needle with a suction pump which has been used for a detection tube. The result of measurement for the 6 lower fatty acids showed that the detection limits ranged from 0.10 ppm to 0.44 ppm and the linear correlation coefficients were over 0.99. Relative standard deviations obtained from 5 analytical repetition of a ca. 1.6 ppm standard mixture were in the range of 1.87%~2.47%. This method has been shown to be a adequate for the measuring C2~C5 fatty acids in air in the concentrations of over several hundreds ppb.