• Proceedings of the Korean Society for Agricultural Machinery Conference
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• 2000.11c
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• pp.525-532
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• 2000

A new spectroscopic method for pesticide residues detection on agricultural products was developed. The general determination methods are high performance liquid chromatography (HPLC), gas chromatography (GC) or GC-mass spectrometry. They have provided relatively good detection limit and accuracy with complicated and time-consuming (5hrs above) procedures. In addition freshness is very important for evaluating qualities of agricultural products. This requires a simple and fast method for detection of pesticides. Reflectance, transmittance and fluorescence spectrometry of pesticides were tested using UV range because most of pesticides contain conjugation band in the molecular structures. Fluorescence spectrometry showed better sensitive to detect pesticide residues than did reflectance and transmittance spectrometry. Intensity and shape of fluorescence spectra showed different patterns with different structures of pesticides. Detection limit for fluorescence spectrometry was 0.1 ppm to 10 ppm depending on the structures of pesticides. Application of fluorescence spectrometry appears to be an easy method for detection of pesticide residues on agricultural products.

• Journal of Environmental Health Sciences
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• v.34 no.6
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• pp.433-438
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• 2008

Much of the increase in agricultural productivity over the past half century has been due to the control of the pests with synthetic pesticides. The use of these pesticides has caused environmental problems and public health concern. The guidelines of maximum residue levels of pesticides in agricultural products has been well documented but more careful monitoring of their residues is required. Pyrethorid class pesticides are dominant in modern agricultural industry but public health concerns have been recently considered. The major route of pesticide exposure is the diet and with improved surveillance of pyrethorid residues in agricultural products their exposure should be controlled and minimized. In suitable products with reduced matrix effects such as agricultural products, aqueous samples, fruits and vegetables the use of immunoassays for pyrethorid residue monitoring could satisfy this requirement. Immunoassays have several advantages, namely they are highly sensitive, selective and cost-effective and enable large-scale sample handling and analysis in the laboratory.

• Journal of Environmental Health Sciences
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• v.26 no.2
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• pp.70-79
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• 2000

This study was done for the purpose of investigating the status of the use and perceptions of pesticides among the farmers who spray them in person. And it was also done to provide the basic statistics for the Agricultural Health Policy and study. Over the part of agricultural area in Kyungju and Ulsan City, Korea, from July to September 1999, 1032 questionnaires were distributed and 561 of them were collected and 447 were analysed. Major results of this study are as follows. The proportion of those who have special location for pesticides storage was only 5.3%, and that of those who lock hte storage location was only 13.6%. As to the treatment of bottles after use, most common response was 'burn in home'(47.7%). Most farmers purchase pesticides through 'pesticide store' or 'Agricultural Cooperatives'. The knowledge and Usage of pesticides depends in large part on experiences. The farmers who cultivate orchard spray pesticides more frequently than those cultivate paddy rice mainly. Most common pesticides in use are oganophosphates and carbamates. And also the pesticides that contains so-called 'Environmental Hormone' are used. The perception about the hazards of pesticides is rather superficial and insufficient. 'Herbicide(Gramoxon·Paraco)'(38%) is accepted as the most hazardous by farmers.

• Proceedings of the Korean Society of Food Hygiene and Safety Conference
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• 2001.10a
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• pp.120-122
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• 2001

This study was carried out to monitor suspected endocrine disrupting pesticides and industrial organic chemicals among circulated agricultural products in the north area of Seoul in 2001. Procymidone, vinclozolin, endosulfan, chlorothalonil, chloropyrifos and pendimetaline (pesticides) and butylated hydroxytoluene(industrial organic chemicals) were certified by GC-MS. Detected 6 pesticides were remained mostly in the green vegetables, spices and wild plants with $3\%$ detected. Butylated hydroxytoluene(industrial organic chemicals) used for green house cover stuffs was contained mostly in the green vegetables, spices and wild plants not in the fruits and cereals with $43\%$ detected. In the same agricultural products containing butylated hydroxy toluene showed same detection tendency with remaining endocrine disrupting pesticides.

• The Korean Journal of Pesticide Science
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• v.10 no.4
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• pp.272-278
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• 2006

Movement of pesticides applied for crop protection to the non-target environmental compartments has increasingly concerned in recent. A special review on groundwater leaching potential of pesticides registered in Korea was done by using the data submitted on half-life and adsorption of the pesticides in/on soil. Groundwater ubiquity score(GUS) of pesticides as a leaching potential was calculated by using domestic trial data on pesticide half-life in paddy or upland soils and Koc data bases of Oregon State University (OSU), British Pesticide Safety Directorate and Sweden. Of total 382 pesticides reviewed, domestic half-lives of 107 pesticides were for paddy soil and 297 pesticides for upland soil. And total 317 Koc values were collected 148 pesticides from OSU DB and 276 pesticides from UK/Sweden DB. Very highly leachable pesticides were 18 and highly leachable pesticides were 44 among 313 pesticides classified by GUS.

• The Korean Journal of Pesticide Science
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• v.15 no.1
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• pp.28-35
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• 2011

The investigation of 218 residual pesticides for 19 types of tea (persimmon leaf tea, chrysanthemum tea, green tea, lavender tea, rosemary tea, dandelion leaf tea, puer tea, mulberry leaf tea, hydrangea leaf tea, jasmine tea, nuomixiang tea, buckwheat tea, mugwort tea, lotus leaf tea, oolong tea, longjing tea, rose tea, tiehkwanyin tea and huoguo tea) obtained from markets in Ansan and Suwon was carried out to assess the risk for residual pesticides in tea. The detection rate was 23.1 % (19 samples of total 65 tea samples) and the detected pesticides were 15 pesticides, such as bifenthrin, bromopropylate, chlorpyrifos, cyhalothrin, cypermethrin, chlorfenapyr, dicofol, endosulfan, fenpropathrin, fludioxonil, fenvalerate, iprobenfos, isoprothiolane, tetradifon and triazophos. The range of concentrations for the detected residual pesticides was 0.01 to 1.24 mg/kg which showed below their maximum residue limits (MRL), but the residual concentration of bifenthrin in a puer tea showed above the legal limit of 0.3 mg/kg. The result of risk assessment of residual pesticides for the detected 15 samples showed that EDI (estimated daily intake) of the pesticides detected ranged 0.0001~0.0844% of their ADI (acceptable daily intake).

• Proceedings of the Korean Society for Agricultural Machinery Conference
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• 1993.10a
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• pp.1003-1012
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• 1993

The objective of this study was to evaluate the effectiveness of tillage and cropping management systems in reducing the movement of nitrate and pesticides in surface and sub-surface flow. Nitrate and pesticides in runoff and sub-surface tile flow have been monitored for two years from fields with various tillage and cropping management practices. Samples have also been obtained along the mainstream of the watershed. Concentrations of nitrate an pesticides differed little among specific sampling locations along the river, but they definitely followed a seasonal cycle. Nitrate concentrations from the tile drains varied considerably between fields depending upon the cropping management systems used, with concentrations varying seasonally as inthe river.

• Korean Journal of Environmental Agriculture
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• v.40 no.2
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• pp.118-126
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• 2021

BACKGROUND: It is very important to monitor the residual characteristics of pesticides in pre-harvest fresh ginseng to ensure consumer safety. METHODS AND RESULTS: Forty-eight fresh ginseng samples were collected from 8 ginseng-growing fields 10 days before harvest and pesticide residues in fresh ginseng with and without rhizome (head of ginseng) and rhizome were analyzed for 320 pesticides by using GC-MS/MS and LC-MS/MS. As a result of the pesticide residue analysis, the number of pesticides detected from the fresh ginseng with rhizome, that without rhizome and rhizome were 26, 25, and 40, respectively, indicating that high number of pesticides found in rhizome, compared with the other parts. Pyraclostrobin was detected with the highest frequency in all samples, reaching to 21.2% in fresh ginseng with rhizome, 16.8% in that without rhizome, and 14.8% in rhizome. CONCLUSION: The residue levels of pesticides detected did not exceed their maximum residue limits, in spite of residual data in fresh ginseng before harvest. The amounts of the estimated daily intakes of all the detected pesticides were found to be from 0.018 to 1.818% of their acceptable daily intakes, indicating that concentrations of pesticides detected from fresh ginseng with and without rhizome collected before harvest do not pose the immediate health risks.

• The Korean Journal of Pesticide Science
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• v.14 no.2
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• pp.116-122
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• 2010

This study was carried out to estimate the risk of pesticide operators who use high toxicological pesticides. The class II (highly hazardous) pesticides registered in korea were 15 products, and 11 products were spray type pesticides at orchard file in 2009. The using information based on the pesticide label and the data searched through survey of actual condition on pesticides were used for calculate the pesticide operator exposure dose. The risk quotients of these pesticides against the pesticides operator were calculated as devide pesticide exposure dose by reference dose which were presented by EFSA (European Food Safety Authority), JMPR (Joint FAO Meeting on Pesticide Residues), and US/EPA (United States Environmental Protection Agency). Omethoate showed the highest risk quotient and the values were 338 and 75 when the operator spray using speed sprayer and motor sprayer respectively. Risk quotients of all class II pesticide were above 1. This result means that the risk potential of these pesticides are very high.

• Korean Journal of Weed Science
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• v.17 no.1
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• pp.112-123
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• 1997

Chemical pesticides have been re used for a long time to protect crops from diseases, insects, and weeds ; ample and secure supply of foods in present days would not be possible without them. However, concerns on the risk of using chemical pesticides rising steadily in recent years forced discard many of them and seek an alternate, environment-friendly control strategies. Microbial pesticide is regarded as one of the most promising methods because if properly developed, it will be effective, cheap, and environment-safe. Currently, about 180 microbial pesticides are under development throughout the world and at least 20 of them including B.t. and antibiotics are registered in Korea. This paper discusses some of the successful examples, intriguing problems, and future prospects of microbial pesticides.