• 한국세라믹학회지
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• 제40권1호
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• pp.62-68
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• 2003

졸-겔법으로 보자력 제어에 뛰어난 첨가제인 Co와 Ti을 첨가한 Ba-ferrite 미립자를 합성하였다. 졸-겔 반응시, 반응 시간이 90분에서 120분 이내에서 온도, pH 및 점도의 변화가 없고, aging 시간에 따라 점도가 안정한 상태치 졸을 얻을 수 있었다. 이 졸을 건조 및 열처리 후, Differential Thermal Analysis(DTA)와 X-Ray Diffractometer(XRD)를 통해 Ba-ferrite 상이 약 $700^{\circ}C$부터 생성됨을 확인하였으며, 열처리 온도 증가에 의해 결정성이 좋아짐을 볼 수 있었다. Scanning Election Microscopy(SEM)로 표면형상을 관찰한 결과 열처리 온도가 증가함에 따라 입자크기가 증가하였으며, 비교적 균질한 입도 분포의 미립자를 얻을 수 있었다. 또한, Vibrating Sample Magnetometer(VSM)로 Co와 Ti의 첨가량에 따른 자기적 특성을 관찰하였으며, 포화자화(M$_{s}$ )값은 첨가량에 관계없이 변화가 없었으나, 보자력(H$_{c}$)값은 첨가량에 따라 크게 변화하였다.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2005년도 춘계학술대회 논문집
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• pp.1358-1362
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• 2005

The Ni-base superalloy GTD-111DS was designed in the 1970s and is widely used as the material of the first stage blade under a severe combination of temperature and pressure in gas turbines. But because GTD-111DS is distributed in the shape of blade and blade has a unique figure and many cooling channels, it is hard to manufacture the test specimen. In this reason, there are little data on the microstructure and mechanical properties of the alloy. Therefore through the microstructure analysis, present paper observed that the shape of $\gamma{'}$ did not change even if aging time was increased but the amount and volume of the deposition of secondary $\gamma{'}\;rose\;and\;secondary\;\gamma{'}\;grew\;among\;primary\;\gamma{'}$. Also, by tensile test for different temperature, there was difference between yield strength and tensile strength in room temperature on heat treatment and extracting region but the more increasing temperature, the more decreasing difference between yield strength and tensile strength.

• 대한기계학회논문집
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• 제18권11호
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• pp.2860-2870
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• 1994

When crack are detected in aged turbine rotors of power plants, information on fracture resistance of the aged material at operating temperature is needed for determination of critical loading condition and residual life of the turbine. In this study, fracture toughness (J$_lc$) and tearing modulus(T$_mat$) of virgin and thermally degraded 1Cr-1Mo-0.25V steel, which is one of the most widely used rotor steels, were measured at 538.deg. C according to ASTM E813 and ASTM E1152, respectively. Five kinds of specimen with different degradation levels were prepared by isothermal aging heat treatment at $630^{\circ}C.$ It was observed that J$_lc$ and T$_mat$ value decreased as the degradation level increased. Analysis of microstructures using a scanning electron microscope showed that the decrement of J$_lc$ is related to segregation of impurities at grain boundaries. It was also verified that the DC electric potential drop method is accurate and reliable for crack length monitoring at elevated temperature.

• 펄프종이기술
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• 제42권3호
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• pp.58-66
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• 2010

The Annals of beeswax applied-Joseon Dynasty have some serious damages such as cracks, brown, red or black spots, and discolorations by chemical and biological degradation, but others without any beeswax application have still been keeping good quality during over several hundred years. It would be convinced that the beeswax applied in the Annals resulted in these deteriorations. Therefore, in order to focus on the aging mechanism and conservation techniques for the beeswax-applied Annals of Joseon Dynasty, the beeswax applying and dewaxing techniques of Hanji were tried by auto bar coater with a hot plate, and by heat-pressure sensitive extracting treatments. The ageing behaviors of beeswaxed Hanji and dewaxed Hanji were investigated by measuring the changes of physical, optical, morphological, and chemical properties, through accelerated ageing treatment in dry oven at $150^{\circ}C$ during 48 hours. Consequently, the ageing actions of beeswaxed Hanji were even faster than that of Hanji. The optimum dewaxed amounts from beeswaxed Hanji was also obtained in pressure of $40\;kg_f$ under heating conditions.

• 대한기계학회논문집A
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• 제26권7호
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• pp.1262-1269
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• 2002

It is inevitable to evaluate the life of turbine rotor because the operating periods of power plants need to be extended. For the test, seven kinds of specimens with different degradation levels were prepared by the isothermal heat treatment at $630^{\circ}C$. Magnetic methods utilizing Barkhausen noise coercive force($BN_c$) were applied to detect the degradation caused by thermal aging. Magnetic property of material is related with domain dynamics and that is affected by the microstructure of material. Therefore $BN_c$ is very sensitive to the microstructure change of the material. With the increase of degradation, $BN_c$ was decreased and this phenomenon is considered due to precipitations and grain size. The result was compared with Vickers hardness($H_v$) and coercive force($H_c$) to detect the relative variation, and was related with $H_v$ and YS to estimate the change of the mechanical properties with the degradation.

• 대한기계학회논문집A
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• 제24권12호
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• pp.2995-3002
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• 2000

The remaining life estimation for the aged components in power plants as well as chemical plants are very important beacuse mechanical properties of the components are degraded with time of service exposure in high temperature. Since it is difficult to take specimens from the operating components to evaluate mechanical properties of components nondestructive techniques are needed to estimate the degradation. In this study, test materials with 4 different degradation levels were prepared by isothermal aging heat treatment at 630$\^{C}$. And the DC potential drop method and destructive methods such as tensile, K(sub)IC and hardness tests were used in order to evaluate the degradation of 1-Cr-1Mo-0.25V steels. The objective of this study is to investigate the possibility of the application of DCPD method to estimated the material degradation, and to analyse the relationship between the electrical relationship between the electrical resistivity and the degree material degradation.

• 한국주조공학회지
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• 제18권4호
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• pp.364-372
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• 1998

Effects of Si and Ca additions on the mechanical properties of AM60 based Mg alloys have been investigated. Hardness of the AM60 based Mg alloys reached a maximum value after aging for approximately 33 hours but the amount of hardness increase was negligible. The poor age hardening response of the alloys was due to low Al content, which implies that Al content must be >6 wt.% to observe age hardening effect. The tensile and yield strength increased with increasing Al, Si, and Ca content but elongation decreased with increasing Al and Si content. The best mechanical properties obtained in AM 40-2.5Si-0.2Ca alloy after T4 heat treatment were as follows; tensile strength 193.4 MPa, yield strength 79.2 MPa, and elongation 11.2%. High temperature property obtained from creep test was also improved by introducing $Mg_2Si$ which has high hardness, high melting temperature and low thermal expansion coefficient.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 춘계학술대회논문집A
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• pp.250-255
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• 2001

It is inevitable to evaluate the life of turbine rotor because the operating periods of power plants need to be extended. The magnetic methods utilizing Magnetic Barkhausen noise curve were applied to detect the degradation caused by thermal aging. The Magnetic property of material depends on the domain dynamics and it is affected by the microstructure of material. Therefore the magnetic property is very sensitive to the microstructure change of the material. It is, thus, very useful to detect the state of degradation of varying materials. The test specimen made of 1Cr-1Mo-0.25V steel was used widely for turbine rotor material, and seven kinds of specimens with different degradation levels were prepared by the isothermal heat treatment at $630^{\circ}C$. With the increase of degradation, BHN was decreased. The result was compared with coercive force and vickers hardness.

• Bulletin of the Korean Chemical Society
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• 제34권8호
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• pp.2271-2275
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• 2013

We report on the photoelectrochemical properties of partially reduced mesoporous titania thin films. The fabrication is achieved by synthesizing mesoporous titania thin films through the self-assembly of a titania precursor and a block copolymer, followed by aging and calcination, and heat-treatment under a $H_2$ (1 torr) environment. Depending on the temperature used for the reaction with $H_2$, the degree of the reduction (generation of oxygen vacancies) of the titania is controlled. The oxygen vacancies induce visible light absorption, and decrease of resistance while the mesoporosity is practically unaltered. The photoelectrochemical activity data on these films, by measuring their photocurrent-potential behavior in 1 M NaOH electrolyte under AM 1.5G 100 mW $cm^{-2}$ illumination, show that the three effects of the oxygen vacancies contribute to the enhancement of the photoelectrochemical properties of the mesoporous titania thin films. The results show that these oxygen deficient $TiO_2$ mesoporous thin films hold great promise for a solar hydrogen generation. Suggestions for the materials design for improved photoelectrochemical properties are made.

• Nuclear Engineering and Technology
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• 제48권1호
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• pp.259-267
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• 2016

Most manufacturing processes, including welding, create residual stresses. Residual stresses can reduce material strength and cause fractures. For estimating the reliability and aging of a welded structure, residual stresses should be evaluated as precisely as possible. Optical techniques such as holographic interferometry, electronic speckle pattern interferometry (ESPI), Moire interferometry, and shearography are noncontact means of measuring residual stresses. Among optical techniques, ESPI is typically used as a nondestructive measurement technique of in-plane displacement, such as stress and strain, and out-of-plane displacement, such as vibration and bending. In this study, ESPI was used to measure the residual stress on the welded part of butt-welded American Society for Testing and Materials (ASTM) A36 specimens with $CO_2$ welding. Four types of specimens, base metal specimen (BSP), tensile specimen including welded part (TSP), compression specimen including welded part (CSP), and annealed tensile specimen including welded part (ATSP), were tested. BSP was used to obtain the elastic modulus of a base metal. TSP and CSP were used to compare residual stresses under tensile and compressive loading conditions. ATSP was used to confirm the effect of heat treatment. Residual stresses on the welded parts of specimens were obtained from the phase map images obtained by ESPI. The results confirmed that residual stresses of welded parts can be measured by ESPI.