• Title/Summary/Keyword: Aging Variation

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HP-GPC Analysis for Characteristics Change of Asphalt Cement Due to Aging (노화(老化)에 의한 아스팔트 시멘트 형질변화(形質變化)의 HP-GPC 분석(分析))

  • Kim, Kwang Woo;Yeon, Kyu Seok;Choi, Joong Dae
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.12 no.4
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    • pp.49-57
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    • 1992
  • This study was conducted to evaluate physical property change of asphalt cement chromatograms (by HP-GPC) were experimentally obtained from 3 types of AC-20 virgin ACs, 5 and 24-hour artificially aged ACs, and naturally aged 4 ACs that were recovered from 4 different roads. Absolute viscosity, kinematic visoosity and penetration were the physical properties tested. THF was used for mobil phase and RI detector was used as a detector for Hp-GPC testing. Correlation between each physical property change and the chromatogram variation was evaluated. Each chromatogram was divided into ten-equal-time slices. The percentage areas of 10 slices and each physical property were used for statistical correlation evaluation. Statistical analysis results showed that eaoh physical property had a strong correlation with the chromatogram characteristics. Aging was identified as a mechanism of change of molecular size distribution - increasing large size molecules and reducing coresponding samll size molecules.

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Variation of Tensile Strength by Addition of Y2O3 and Effect of Aging Treatment in Ni Base Alloy Fabricated by MA Method (MA법으로 제조된 Ni기 합금에서 Y2O3 첨가에 따른 인장강도변화와 시효처리 효과)

  • Kim, Il-Ho;Lee, Won-Sik;Ko, Se-Hyun;Jang, Jin-Man;Kwun, Sook-In
    • Journal of Powder Materials
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    • v.15 no.1
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    • pp.23-30
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    • 2008
  • Ni-20Cr-20Fe-5Nb alloy with or without $Y_2O_3$ was manufactured by mechanical alloying process and consolidated by spark plasma sintering (SPS). The grain size of the alloy with $Y_2O_3$ was smaller than that of alloy without $Y_2O_3$ which results from the effect of $Y_2O_3$ suppressing grain growth. The tensile strength at room temperature was increased by the addition of $Y_2O_3$ but decreased abruptly at temperature above $600^{\circ}C$. It seems to result from the change of deformation mechanism due to fine grain size, that is, grain boundary sliding is predominant at above $600^{\circ}C$ while internal dislocation movement is predominant at below $600^{\circ}C$. After conventional heat treatment process of solution treatment and aging, a small amount of ${\delta}(Ni_3Nb)$ phase was formed in Ni-20Cr-20Fe-5Nb alloy while a large amount of ${\gamma}"(Ni_3Nb)$ was formed in Inconel 718 in the previous report. This is due to exhaustion of Nb content by the formation of NbC during consolidation.

Electrical Properties and Stability of ZPCCD-Based Varistors with Sintering Time (소결시간에 따른 ZPCCD계 바리스터의 전기적 특성 및 안정성)

  • Nahm, Choon-Woo;Park, Jong-Ah;Yoo, Dea-Hoon;Suh, Hyoung-Kwon
    • Journal of the Korean Ceramic Society
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    • v.42 no.7 s.278
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    • pp.490-496
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    • 2005
  • The electrical properties and stability of the varistors composed of ZnO-Pr$_{6}$O$_{11}$-CoO-Cr$_{2}$O$_{3}$-Dy$_{2}$O$_{3}$ system were investigated with sintering time in the range of 1$\~$3 h at 1350$^{\circ}C$ . As the sintering time was increased, the varistor voltage and leakage current increased, but the nonlinear exponent decreased. The varistors sintered for 1 h exhibited excellent nonlinearity, with a nonlinear exponent of 55.3 and a leakage current of 0.1 $\mu$A, whereas presented relatively low stability. The varistors sintered for 2 h exhibited not only high nonlinear exponent of 46.3, low leakage current of 0.3 $\mu$A, low dielectric dissipation factor of 0.0431, but also the highest stability, in which the variation rates of varistor voltage, nonlinear exponent, leakage current, dielectric constant, and dielectric dissipation factor were -3.0$\%$, -4.1$\%$, +3056.2$\%$, +5.1$\%$, and -12.5$\%$, respectively, after DC accelerated aging stress state of 0.95 V$_{1ma}$/150$^{\circ}C$/24 h. On the whole, the nonlinearity and stability of these varistors are greatly affected by the sintering time.

A Study on the microstructure and Surge Characteristics of ZnO varistors for distribution Arrester (배전급 피뢰기용 ZnO 바리스터 소자의 미세구조 및 서지 특성에 관한 연구)

  • 김석수;조한구;박태곤;박춘현;정세영;김병규
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.2
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    • pp.190-197
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    • 2002
  • In this thesis, ZnO varistors with various formulation, such as A∼E, were fabricated according to ceramic fabrication method. The microstructure, electrical properties, and surge characteristics of ZnO varistors were investigated according to ZnO varistors with various formulation. In the microstructure, A∼E\`s ZnO varistor ceramics sintered at 1130$\^{C}$ was consisted of ZnO grain(ZnO), spinel phase (Zn$\_$2.33/Sb$\_$0.67/O$\_$4/), Bi-rich phase(Bi$_2$O$_3$) and intergranuler phase, wholly. Lightning impulse residual voltage of A, B, C and E\`s ZnO varistors suited standard characteristics, below 12kV at current of 5kA. On the contrary, D\`s ZnO varistor exhibited high residual voltage as high reference voltage. In the accelerated aging test, leakage current and watt loss of B, C and D\`s ZnO varistors increases abruptly with stress time under the first a.c. stress(115$\^{C}$/3.213kV/300h). Consequently, C varistor exhibited a thermal run away. On the contrary, leakage current and watt loss of A and C\`s ZnO varistors which show low initial leakage current exhibited constant characteristics. After high current impulse test, A\`s ZnO varistor has broken the side of varistor but impulse current flowed. On the contrary, E\`s ZnO Varistor exhibited good discharge characteristics which the appearance of varistor was not wrong such as puncture, flashover, creaking and other significant damage. After long duration impulse current test, E\`s ZnO varistor exhibited good discharge characteristics which the appearance of varistor was not wrong such as puncture, flashover, creaking and other significant damage. After high current impulse test and long duration impulse current test, E\`s ZnO varistor exhibited very good characteristics which variation rate of residual voltage is 1.4% before and after test.

Free Volume in Polyers Note II。: Positron Annihilation lifetime Spectroscopy and Applications

  • G. Consolati;M. Pegoraro;L. Zanderighi
    • Korean Membrane Journal
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    • v.1 no.1
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    • pp.25-37
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    • 1999
  • positron annihilation Lifetime Spectroscopy has been extensively applied in recent years to investigate the free volume in polymers owing to the capability of the electron-positron bound system (positronium) to probe the typical size of sub-nanometric cavities among the macromolecular chains. In this paper we show recent results obtained through this technique in some amorphous polymeric mem-branes(olyurethanes. PUs and polytrimethilsylilpropine PTMSP) after a brief survey of the general features of the annihilation process as well as of the experimental apparatus. Lifetime of o-ps decay({{{{ tau _3}}}}) in PUs increases going from sub {{{{ TAU _g}}}} to over {{{{ TAU _g}}}} temperatures following a sigmoid curve. The coefficient of dilatation of the free volume fraction is shown to be the sum of two contributes due to the variation with T of the number of holes and of their mean volume. PAL spectrum of PTMSP freshly prepared shows four lifetime components: {{{{ tau _3}}}} and {{{{ tau _4}}}}: only are useful for free volume study. Two kinds of holes of different equivalent radius are reported ({{{{ gamma _s}}}} 4.60 nm and {{{{ gamma _1}}}} 0.754) The equivalent volume does not change in a range of 100 K. however the physical aging increases density and decreases oxygen permeability while {{{{ gamma _s}}}} goes down to 0.374 and r1 to 0.735 The number of holes obtained from the intensities{{{{ IOTA _3}}}} and {{{{ IOTA _4}}}} of PAL spectra decreases with aging 21.7% and 3.5% for large and small holes respectively.

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Table-Based Fault Tolerant Routing Method for Voltage-Frequency-Island NoC (Voltage-Frequency-Island NoC를 위한 테이블 기반의 고장 감내 라우팅 기법)

  • Yoon, Sung Jae;Li, Chang-Lin;Kim, Yong Seok;Han, Tae Hee
    • Journal of the Institute of Electronics and Information Engineers
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    • v.53 no.8
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    • pp.66-75
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    • 2016
  • Due to aggressive scaling of device sizes and reduced noise margins, physical defects caused by aging and process variation are continuously increasing. Additionally, with scaling limitation of metal wire and the increasing of communication volume, fault tolerant method in manycore network-on-chip (NoC) has been actively researched. However, there are few researches investigating reliability in NoC with voltage-frequency-island (VFI) regime. In this paper, we propose a table-based routing technique that can communicate, even if link failures occur in the VFI NoC. The output port is alternatively selected between best and the detour routing path in order to improve reliability with minimized hardware cost. Experimental results show that the proposed method achieves full coverage within 1% faulty links. Compared to $d^2$-LBDR that also considers a routing method for searching a detour path in real time, the proposed method, on average, produces 0.8% savings in execution time and 15.9% savings in energy consumption.

Accumulation of mtDNA Deletion (${\Delta}mtDNA^{4977}$) showing Tissue-Specific and Age-Related Variation (조직별 및 나이에 따른 마이토콘드리아 DNA 결손 (${\Delta}mtDNA^{4977}$)의 축적)

  • Jeong, Hye-Jin;Chung, Hyung-Min;Cho, Sung-Won;Kim, Hyun-Ah;Lee, Kyung-Sool;Kwon, Hwang;Choi, Dong-Hee;Kwak, In-Pyung;Yoon, Tae-Ki;Lee, Sook-Hwan
    • Clinical and Experimental Reproductive Medicine
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    • v.30 no.3
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    • pp.203-206
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    • 2003
  • Objectives: Controversial arguments exists on both the case for and against on the accumulation of mitochondrial DNA (mtDNA) deletion in association to tissue and age. The debate continues as to whether this mutation is a major contributor to the phenotypic expression of aging and common degenerative diseases or simply a clinical insignificant epiphenomenon. The objective of this study was to determine whether the accumulation of mtDNA deletion is correlated with age-related and tissue-specific variation. Materials and Methods: One hundred and fifty-seven tissues from blood, ovary, uterine muscle, and abdominal muscle were obtained from patients ranging in age from 31$\sim$60 years. After reviewing the clinical reports, patients with mitochondrial disorder were excluded from this study. The tissues were obtained at gynecological surgeries with the consent of the patient. Total DNA isolated from blood, ovary, uterine muscle, and abdominal muscle was amplified by two rounds of PCR using two pairs of primers corresponding to positions 8225-8247 (sense), 13551-13574 (antisense) for the area around deleted mtDNA and 8421-8440 (sense), 13520-13501 (antisense) for nested PCR product. A statistical analysis was performed by $x^2$-test. Results: About 0% of blood, 94.8% of ovary, 71.4% of uterine muscle, and 86.1% abdominal muscle harbored mtDNA deletion. When we examined the proportion of deleted mtDNA according to age deletion rate was 90% of ovary, 63.6% of uterine muscle, 77.7% of abdominal muscle in thirties and 100% of all tissue in fifties. Conclusion: The findings of this study suggest that the mtDNA deletion is varied in tissue-specific pattern and increases with aging.

Workability and Aging Behavior of Mg-Li-Al alloys (Mg-Li-Al합금의 가공성 및 시효거동)

  • Gang, Min-Cheol;Kim, Sun-Ho;Jeong, Hae-Yong;Lee, Jeong-Mu;Kim, Gyeong-Hyeon;Kim, In-Bae
    • Korean Journal of Materials Research
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    • v.2 no.6
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    • pp.389-397
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    • 1992
  • Workability and aging behavior of Mg-Li-Al alloys hate been investigated with variation of Li and Al contents. It was found that ${\alpha}$(HCP) + ${\beta}$(BCC) two phase structure reveals better workability than ${\alpha}$(HCP) single phase structure. Increase of workability is attributed to the additional slip on pyramidal and prism planes besides the slip on basal plane of HCP Mg. Workability of ${\alpha}$+${\beta}$ two phase structure is improved with increased amount of Al. Among alloys studied in the present study, reduction limit up to 62 % was obtained for Mg-8.08Li-4.26Al. MgL$i_2$Al(${\theta}$) aging precipitation was observed in ${\alpha}$+ ${\beta}$ two phase structure, while it was not in a single phase structure. Result of microhardness reveals peak hardness for ${\alpha}$ +${\beta}$ two phase structure due to $\theta$ precipitate in ${\theta}$ phase. In ${\alpha}$+${\beta}$ two phase Mg-Li-Al alloys, hardness increased with increasing amount of Al. It is believed that addition of Al raised the amount Al partition in u phase and ${\theta}$ precipitation in ${\beta}$ phase.

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Effects of Seawater & Freshwater Soaking on the Cure Properties of Accelerated Thermally Aged CSPE (가속열화 된 CSPE의 경화특성에 미치는 해수 담수 침지의 영향)

  • Shin, Yong-Deok;Lee, Jeong-U
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.65 no.5
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    • pp.819-824
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    • 2016
  • The accelerated thermal aging of CSPE (chlorosulfonated polyethylene) was carried out for 33.64 and 67.27 days at 110[$^{\circ}C$], equivalent to 40 and 80 years of aging at 50[$^{\circ}C$], respectively. These samples were referred to as CSPE-0y, CSPE-40y and CSPE-80y, respectively. As the accelerated thermally aged years of the CSPE increase, the insulation resistance[$\Omega$] at 20[Hz], 500[Hz], and 2[KHz], and the percent elongation [%EL] of the CSPE decrease. However, the dissipation factor($tan{\delta}$) at 20[Hz], 500[Hz], and 2[KHz], the apparent density[$g/cm^3$], the glass transition temperature and the melting temperature of the CSPE were increased. The period of time that the voltage has to be applied until electric breakdown of the CSPE-0y is longer than that of the CSPE-40y, and the CSPE-80y, but the dielectric strength of the CSPE-80y is lower than that of the CSPE-0y and the CSPE-40y. The differential temperatures after the AC and DC voltages are applied to CSPE-0y, CSPE-40y and CSPE-80y are 0.026~0.028[$^{\circ}C$], 0.030~0.042[$^{\circ}C$], 0.018~0.045[$^{\circ}C$], respectively. The variations of temperature for the AC voltage are higher than those for the DC voltage when an AC voltage is applied to CSPE-0y, CSPE-40y and CSPE-80y. It is found that the dielectric loss owing to the dissipation factor[$tan{\delta}$] is related to the electric dipole conduction current. It is ascertained that the ionic (electron or hole) leakage current is increased by the separation of the branch chain of CSPE polymer from the main chain of the polyethylene as a result of thermal stress due to accelerated thermal aging as well as by conducting ions such as $Na^+$, $Cl^-$, $Mg^{2+}$, $SO_4^{2-}$, $Ca^{2+}$ and $K^+$ after seawater soaking.

Analysis of the Partial Discharge Pattern in XLPE Insulators using Distribution Statistical Models (분포통계모델에 의한 가교폴리에틸렌 절연체의 부분방전 패턴해석)

  • Kim Tag-Yong;Park Hee-Doo;Cho Kyung-Soon;Park Ha-Yong;Hong Jin-Woong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.10
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    • pp.947-952
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    • 2006
  • It has been confirmed that the inner defect of insulator and the perfect diagnosis for aging are closely related to safe electric power transmission system and that the detection of accident and diagnosis technique turn out to be very important issues. But perfect diagnosis is difficult because discharge pattern is irregular. Thus, we investigated discharge pattern using the new distribution statistical models with cross-inked polyethylene(XLPE) specimens. Voltage was applied to power frequency by step method, and calibration of discharge was set to 50 pC. After the voltage was applied, it measured the discharge occurring during 10s. We investigated discharge pattern using the K-means analysis and Weibull function. We also investigated variation of centroid and shape parameter due to variation of voltage. As a result of analyzing K-means, it was confirmed that cluster including many object numbers was formed by the presence of void. And result of Weibull distribution, it was confirmed that shape parameter of discharge varied from 1.28 to 1.62 in no void specimens, and that shape parameter of discharge number varied from 1.28 to 1.62. In the void, shape parameter of discharge varied from 5.66 to 6.43, and shape parameter of discharge number varied from 5.05 to 5.08.