• Transactions of Materials Processing
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• v.31 no.3
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• pp.160-166
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• 2022

The purpose of this study is to investigate the effects of combined addition of Ca and Y on the precipitation and age-hardening behavior of an extruded AZ91 alloy by conducting the aging treatment at 200 ℃ for hot-extruded AZ91 and AZ91-0.3Ca-0.2Y alloys. In the AZ91 alloy, many Mg₁₇Al₁₂ discontinuous precipitate (DP) bands formed during air cooling immediately after extrusion are present, whereas in the AZ91-0.3Ca-0.2Y alloy, a few DP bands and numerous Al₂Y, Al₈Mn₄Y, and Al₂Ca phase particles are distributed along the extrusion direction. The peak-aging time of the AZ91-0.3Ca-0.2Y alloy is 16 hours, twice that of the AZ91 alloy. Although both alloys have similar hardness before aging treatment, the hardness after peak-aging treatment (i.e., peak hardness) of the AZ91-0.3Ca-0.2Y alloy is higher than that of the AZ91 alloy, as 93.1 and 88.7 Hv, respectively. The microstructures of both peak-aged alloys comprise DPs and continuous precipitates (CPs). However, the peak-aged AZ91-0.3Ca-0.2Y alloy has a smaller amount of DPs and a larger amount of CPs than the peak-aged AZ91 alloy. Additionally, the inter-particle spacings of DPs and CPs in the former are significantly narrower than those in the latter. These results demonstrate that the addition of small amounts of Ca and Y to a commercial AZ91 alloy considerably affects the formation rate, size, and amount of CPs and DPs during aging and resultant age-hardening behavior.

• Transactions of Materials Processing
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• v.32 no.4
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• pp.173-179
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• 2023

In this study, the age-hardening behavior and tensile properties of a cast AZ91-0.3Ca-0.2Y (SEN9) alloy are investigated and compared with those of a commercial AZ91 alloy. Even after homogenization heat treatment, the SEN9 alloy contains numerous undissolved secondary phases, Al₈Mn₄Y, Al₂Y, and Al₂Ca, which results in a higher hardness value than the homogenized AZ91 alloy. Under aging condition at 200 ℃, both the AZ91 and SEN9 alloys exhibit the same peak-aging time of 8 h, but the peak hardness of the latter (86.8 Hv) is higher than that of the former (83.9 Hv). The precipitation behavior of Mg₁₇Al₁₂ phase during aging significantly differs in the two alloys. In the AZ91 alloy, the area fraction of Mg₁₇Al₁₂ discontinuous precipitates (DPs) increases up to ~50% as the aging time increases. In contrast, in the SEN9 alloy, the formation and growth of DPs during aging are substantially suppressed by the Ca- or Y-containing particles, which leads to the formation of only a small amount of DPs with an area fraction of ~4% after peak aging. Moreover, the size and interparticle spacing of Mg₁₇Al₁₂ precipitates of the peak-aged SEN9 alloy are smaller than those of the peak-aged AZ91 alloy. The homogenized AZ91 alloy exhibits a higher tensile strength than the homogenized SEN9 alloy due to the finer grains of the former. However, the peak-aged SEN9 alloy has a higher tensile elongation than the peak-aged AZ91 alloy due to the smaller amount of brittle DPs in the former.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2017.05a
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• pp.18-19
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• 2017

In this study, hardening characteristics and microstructure of blast furnace slag-cement mortar replaced alpha-calcium sulfate hemihydrate were analyzed. As a result of replacing alpha-calcium sulfate hemihydrate with 0, 10, 20, 30%, it was confirmed that the initial and final setting times are faster than that of blast furnace slag-cement mortar. The compressive strength of the specimens containing alpha-calcium sulfate hemihydrate decreased in the range of 42 ~ 76% at age 28 days compared with blast furnace slag-cement mortar. In the case of replacing the alpha-calcium sulfate hemihydrate, the shrinkage did not occur more rapidly than the cement mortar, but the slope of the strain curve showed a linear behavior. The results of scanning electron microscopy images analysis showed that the formation of ettringite was increased at alpha-calcium sulfate hemihydrate replaced mortar.

• Journal of Technologic Dentistry
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• v.20 no.1
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• pp.37-49
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• 1998

The specimens used were Ag-25 Pd-15 Cu ternary alloy and Au addition alloy. These alloys were melted and casted by induction electric furnace and centrifugal casting machine in Ar atmosphere. These specimens were solution treated for 2hr at $800^{\circ}C$ and were then quenched into iced water, and aged at $350{\sim}550^{\circ}C$ Age- hardening characteristics of the small Au-containing Ag-Pd-Cu dental alloys were investigated by means of hardness testing. X-ray diffraction and electron microscope observations, electrical resistance, ergy dispersed spectra and electron probe microanalysis. Principal results are as follows : Hardening occured in two stages, i.e., stage I in low temperature and stage II in high temperature regions, during continuous aging. The case of hardening in stage I was due to the formation of the $L1_0$ type face-centered tetragonal PdCu-ordered phase in the grain interior and hardening in stage I was affected by the Cu concentration. In stage II, decomposition of the ${\alpha}$ solid solution to a PdCu ordered phase($L1_0$ type) and an Ag-rich ${\alpha}2$ phase occurred and a discontinuous precipitation occurred at the grain boundary. From the electron microscope study, it was conclued that the cause of age-hardening in this alloy is the precipitation of the PdCu ordered phase, which has AuCu I type face-centered tetragonal structure. Precipetation procedure was ${\alpha}{\to}{\alpha}+{\alpha}_2+PdCu {\to}{\alpha}_1+{\alpha}_2+PdCu$ at Pd/Cu = 1.7 Ag-Pd-Cu alloy is more effective dental alloy as ageing treatment and is suitable to isothermal ageing at $450^{\circ}C$.

• Journal of the Korea institute for structural maintenance and inspection
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• v.12 no.6
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• pp.173-179
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• 2008

This paper aims to calculate age coefficient of ultrasonic pulse velocity by non-destructive test. When concrete compressive strength is measured by non-destructive test, rebound test hammer method is applied to estimate age coefficient depending on the course of time after concrete casting, but ultrasonic pulse velocity method is not applied in the process. Although it is necessary to consider age coefficient with change of ultrasonic pulse velocity of concrete depending on aging, there have been little attempts to apply that method. The experiments were conducted to calculate aging effects which will be applied to establish the formula of measuring concrete strength. As a result of experiments, it was found that ultrasonic pulse velocity showed radical changes depending on concrete hardening in comparison with initial standard values. So, it was concluded that age coefficient must be applied to calculate strength. In conclusion, age coefficient of ultrasonic pulse velocity of concrete was suggested on the basis of experimental results.

• Advances in concrete construction
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• v.11 no.4
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• pp.335-345
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• 2021

It is known from the literature that there are relatively few studies on the engineering properties of ultra-high performance concrete (UHPC) in early age. In fact, in order to ensure the safety of UHPC during construction and sufficient durability and long-term performance, it is necessary to explore the early behavior of UHPC. The test parameters (test control factors) investigated included the percentage of cement replaced by silica fume (SF), the percentage of cement replaced by ultra-fine silica powder (SFP), the amount of steel fiber (volume percent), and the amount of polypropylene fiber (volume percentage). The engineering properties of UHPC in the fresh mixing stage and at the age of 7 days were investigated. These properties include freshly mixed properties (slump, slump flow, and unit weight) and hardened mechanical properties (compressive strength, elastic modulus, flexural strength, and splitting tensile strength). Moreover, the effects of the experimental factors on the performance of the tested UHPC were evaluated by range analysis and variance analysis. The experiment results showed that the compressive strength of the C8 mix at the age of 7 days was highest of 111.5 MPa, and the compressive strength of the C1 mix at the age of 28 days was the highest of 128.1 MPa. In addition, the 28-day compressive strength in each experimental group increased by 13%-34% compared to the 7-day compressive strength. In terms of hardened mechanical properties, the performance of each experimental group was superior to that of the control group (without fiber and without additional binder materials), with considerable improvement, and the experimental group did not produce explosive or brittle damage after the test. Further, the flexural test process found that all test specimens exhibited deflection-hardening behavior, resulting in continued to increase carrying capacity after the first crack.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.4
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• pp.95-103
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• 2012

Precast concrete method is known to have advantages of minimizing works in the construction, controlling concrete quality easily and saving construction period due to only fabrication work in the construction field, but it needs to apply steam curing to accelerate early concrete strength. In the meanwhile, the oil cost for steam curing has been continuously increased because of political instability in the middle East and international economic shaky. Thus, this study addresses the development of precast/ prestressed concrete which has over 14MPa at 1 day age and specified concrete strength of 40MPa at low temperature, not applying steam curing. Tests were carried out in terms of material characteristics in fresh concrete and compressive strength using 3 types of cement such as Type I, Type III and rapid hardening compound cement. As results of tests, it is found that cements for rapid hardening had disadvantages with respect to slump, slump loss, and air content, but showed higher compressive strength than specified one, especially the highest value when using rapid hardening compound.

• International Journal of Highway Engineering
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• v.17 no.3
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• pp.85-95
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• 2015

PURPOSES : Recently, bonded concrete overlay has been used as an alternative solution in concrete pavement rehabilitation since its material properties are similar to those of the existing concrete pavements. Deteriorated concrete pavements need rapid rehabilitation in order to prevent traffic jams on Korean expressways. Moreover, speedy and effective repair methods are required. Therefore, the use of bonded concrete overlay with ultra-rapid hardening cement has increased in an effort to reopen promptly the expressways in Korea. However, mobile mixer is required for ultra-rapid hardening cement concrete mixing in the construction site. The use of mobile mixer causes various disadvantages aforementioned such as limitation of the construction supply, open-air storage of mixing materials, increase in construction cost, and etc. In this study, therefore, hydration accelerator in-situ mixing on polymer modified concrete produced in concrete plant is attempted in order to avoid the disadvantages of existing bonded concrete overlay method using ultra-rapid hardening cement. METHODS : Bonded concrete overlay materials using ultra-rapid hardening cement should be meet all the requirements including structural characteristics, compatibility, durability for field application. Therefore, This study aimed to evaluate the application of hydration accelerator in-situ mixing on polymer modified concrete by evaluating structural characteristics, compatibility, durability and economic efficiency for bonded concrete overlay. RESULTS : Test results of structural characteristics showed that the compressive, flexural strength and bond strength were exceed 21MPa, 3.15MPa and 1.4MPa, respectively, which are the target strengths of four hours age for the purpose of prompt traffic reopening. In addition, tests of compatibility, such as drying shrinkage, coefficient of thermal expansion and modulus of elasticity, and durability (chloride ions penetration resistance, freezing-thawing resistance, scaling resistance, abrasion resistance and crack resistance), showed that the hydration accelerator in-situ mixing on polymer modified concrete were satisfied the required criteria. CONCLUSIONS : It was known that the hydration accelerator in-situ mixing on polymer modified concrete overlay method was applicable for bonded concrete overlay and was a good alternative method to substitute the existing bonded concrete overlay method since structural characteristics, compatibility, durability were satisfied the criteria and its economic efficiency was excellent compare to the existing bonded concrete overlay methods.

• Journal of Technologic Dentistry
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• v.21 no.1
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• pp.27-41
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• 1999

The Ag-Pd-Cu alloys containing a small amount of Au is commonly used for dental purposes, because this alloy cheaper than Au-base alloys for clinical use. However, the most important characteristic of this alloy is age-hardenability, which is not exhibited by other Ag-base dental alloys. The specimens used were Ag-30Pd-10Cu ternary alloy and Au addition alloy. These alloys were melted and casted by induction electric furnace and centrifugal casting machine in Ar atmosphere. These specimens were solution treated for 2hr at $800^{\circ}C$ and were then quenched into iced water, and aged at 350-$550^{\circ}C$ Age-hardening characteristic of the small Au-containing Ag-Pd-Cu dental alloys were investigated by means of hardness testing, X-ray diffraction and electron microscope observations, electrical resistance, differential scanning calorimetric, energy dispersed spectra and electron probe microanalysis. Principal results are as follows ; Maximum hardening occured in two co-phases of ${\alpha}_2$ + PdCu In stage II, decomposition of the $\alpha$ solid solution to a PdCu ordered phase($L1_o$ type) and an Ag-rich ${\alpha}_2$ phase occurred and a discontinuous precipitation occurred at the grain boundary. From the electron microscope study, it was concluded that the cause of age-hardening in this alloy is the precipitation of the PdCu redered phase, which has AuCu I type face-centered tetragonal structure. Precipitation procedure was ${\alpha}{\to}{\alpha}_1+PdCu{\to}{\alpha}_2+PdCu$ at Pd/Cu = 3 Pd element of Ag-Pd-Cu alloy is more effective dental alloy on anti-corrosion and is suitable to isothermal ageing at $450^{\circ}C$.

• Journal of the Korea Institute of Building Construction
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• v.2 no.4
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• pp.169-176
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• 2002

To study of binder and fine aggregate a lot of replacement fly-ash concrete, initial characteristics, standard environment of curing temperature $20^{\circ}C$, hot-weather environment, cold weather environment of curing temperature $5^{\circ}C$. Flash concrete tested slump, air contest, setting and Hardening concrete valuated setting period of form, day of age 3, 7, 28 compression strength in sealing curing. Underwater curing specimen compression strength of age 3. 7, 28day used strength change accordingly fly-ash concrete curing temperature. Purpose of study is consultation materials in field that variety of fly-ash replacement concrete mix proportion comparison and valuation. (1) Setting test result, fly-ash ratio of replacement higher delay totting time. Same volume of fly-ash ratio of replacement is lower fly-ash ratio of replacement fine aggregate delay setting time. Setting test in curing temperature $35^{\circ}C$ over twice fast setting in curing temperature $20^{\circ}C$ and all specimen setting delay in curing temperature $5^{\circ}C$. F40 specimen end of setting about 30 time. (2) Experiment result age 28day compression strength more fisher plan concrete then standard environment in curing temperature $20^{\circ}C$, cold weather environment in curing temperature $5^{\circ}C$, most strength F43 is hot-weather environment in curing temperature $35^{\circ}C$ replacement binder 25%, fine aggregate 15%. (3) Hot-weather environment replacement a mount of fly-ash is a same of plan concrete setting period of form. Age 28day compression strength replacement a mount of fly-ash more hot-weather concrete then plan concrete.