• Title/Summary/Keyword: Ag-coated $La_{0.7}Sr_{0.3}Co_{0.3}Fe_{0.7}O_{3-{\delta}}$

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Mössbauer Study of Silver Nanoparticle Coated Perovskites La0.7Sr0.3Co0.3Fe0.7O3-δ (LSCF) (은(Ag) 나노입자가 코팅된 페롭스카이트 La0.7Sr0.3Co0.3Fe0.7O3-δ의 Mössbauer 분광연구)

  • Uhm, Young-Rang;Rhee, Chang-Kyu;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.22 no.2
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    • pp.37-41
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    • 2012
  • The Ag nanoparticles attached $La_{0.7}Sr_{0.3}Co_{0.3}Fe_{0.7}O_{3-{\delta}}$ (LSCF) perovskites were prepared by plasma method. The Ag nanoparticles with size of several nanometers deposited from the Ag target were coated on the surface of LSCF powders with size range from 0.2 to 3 ${\mu}m$. The agglomeration of Ag particles annealed at $800^{\circ}C$ under inert gas of Ar were rarely observed. The inter-diffusion between surface Ag and core LSCF is effectively strong to prevent aggregation of Ag nanoparticles. The wave number of FT-IR spectra for LSCF were largely shifted as the concentration of Ag on LSCF up to 2.11 wt.%. The ionic states of irons in LSCF were measured by M$\ddot{o}$ssbauer spectroscopy. The small amount of $Fe^{4+}$ ions are converted to $Fe^{3+}$ ions after Ag nanopartcles were coated on LSCF.