• Title/Summary/Keyword: Ag particles

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Synthesis of Nano-Scale Photocatalyic TiO2 Powder Doped with Ag by Sonochemistry Reaction (초음파화학 반응에 의한 Ag 도핑 광촉매용 나노 TiO2 분말의 합성)

  • Cho, Sung-Hun;Lee, Soo-Whon
    • Korean Journal of Materials Research
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    • v.19 no.3
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    • pp.169-173
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    • 2009
  • In chemistry, the study of sonochemistry is concerned with understanding the effect of sonic waves and wave properties on chemical systems. In the area of chemical kinetics, it has been observed that ultrasound can greatly enhance chemical reactivity in a number of systems by as much as a million-fold. Nano-technology is a super microscopic technology in which structures of 100 nanometers or smaller can be investigated. This technology has been used to develop $TiO_2$ materials and $TiO_2$ devices of that size. Thus far, electrochemistry methods and photochemistry methods have generally been used to create $TiO_2$ nano-size particles. However, these methods are complicated and create pollutants as a by-product. In the present study, nano-scale silver particles (5 nm) were prepared in a sonochemistry method. Sonochemistry deals with mechanical energy that is provided by the collapse of cavitation bubbles that form in solutions during exposure to ultrasound. $TiO_2$ powders 25 nm in size doped with Ag were formed using an ultrasonic sound technique. The experimental results showed the high possibility of removing pollution through the action of a photocatalyst. This powder synthesis technique can be considered as an environmentally friendly powder-forming processing owing to its energy saving characteristics.

Electrophoretic Deposition of Superconducting $YBa_2Cu_3O_{7-\delta}$ Films Added with Silver Addition

  • Li, Fenghua;Wang, Jue;Soh, Dea-Wha;Fan, Zhanguo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.260-261
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    • 2005
  • $YBa_2Cu_3O_{7-\delta}$ superconductor films have been prepared on silver substrates by electrophoretic deposition. As silver does not react with $YBa_2Cu_3O_{7-\delta}$ compound and has little influence on its superconductivity, it is usually doped in $YBa_2Cu_3O_7$ to improve the strength of the material and eliminate micro-cracks. It has been proved that Ag additive can lower the melting temperature of $YBa_2Cu_3O_{7-\delta}$ and act as linking bridge among $YBa_2Cu_3O_{7-\delta}$ particles, thus in this paper Ag doped $YBa_2Cu_3O_{7-\delta}$ thick films are prepared by electrophoretic co-deposition. As there are only some referenced experience formula and models for co-electrophoretic deposition and does not exist unified explanation, the behavior of Ag particles during co-electrophoretic deposition is also studied.

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Rapid Thermal Annealing at the Temperature of 650℃ Ag Films on SiO2 Deposited STS Substrates

  • Kim, Moojin;Kim, Kyoung-Bo
    • Applied Science and Convergence Technology
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    • v.26 no.6
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    • pp.208-213
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    • 2017
  • Flexible opto-electronic devices are developed on the insulating layer deposited stainless steel (STS) substrates. The silicon dioxide ($SiO_2$) material as the diffusion barrier of Fe and Cr atoms in addition to the electrical insulation between the electronic device and STS is processed using the plasma enhanced chemical vapor deposition method. Noble silver (Ag) films of approximately 100 nm thickness have been formed on $SiO_2$ deposited STS substrates by E-beam evaporation technique. The films then were annealed at $650^{\circ}C$ for 20 min using the rapid thermal annealing (RTA) technique. It was investigated the variation of the surface morphology due to the interaction between Ag films and $SiO_2$ layers after the RTA treatment. The results showed the movement of Si atoms in silver film from $SiO_2$. In addition, the structural investigation of Ag annealed at $650^{\circ}C$ indicated that the Ag film has the material property of p-type semiconductor and the bandgap of approximately 1 eV. Also, the films annealed at $650^{\circ}C$ showed reflection with sinusoidal oscillations due to optical interference of multiple reflections originated from films and substrate surfaces. Such changes can be attributed to both formation of $SiO_2$ on Ag film surface and agglomeration of silver film between particles due to annealing.

Driving Forces of Silver Nano-porous Sheet Die Bonding at 145 ℃ and 175 ℃ in the Air

  • YehRi Kim;Eunjin Jo;Dongjin Kim
    • Journal of the Microelectronics and Packaging Society
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    • v.31 no.3
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    • pp.91-98
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    • 2024
  • This study reveals the feasibility and effectiveness of sinter bonding using an Ag nano-porous sheet at the lowest "theoretically" possible temperature of 145 ℃. By uniform pressure of 10 MPa for bonding times of 5 min and 10 min at 145 and 175 ℃, we achieved bonding strengths exceeding approximately 20 MPa with a only 5 min of bonding time at 145 ℃. In particular, it is interesting to note that in the pressure sintering bonding process at 145 ℃, bonding times of 5 and 10 min had no significant difference in strength. Even with a bonding temperature of 175 ℃, the difference in average bonding strength between bonding times of 5 min (i.e., 37.6 MPa) and 10 min (i.e., 43.0 MPa) was only 5 MPa. The bonding strength was fundamentally attributed to the thickness of the Ag sintered neck in the Ag sintered layer. Microstructural analysis revealed that as the bonding temperature increased to 175 ℃, the fraction of CSL Σ3 boundaries within the Ag sintered layer increased, indicating greater coalescence of Ag particles. This study systematically investigated the mechanism of bonding strength in extremely low-temperature pressure Ag sinter bonding, considering the relationship between microstructures and mechanical behaviors.

Heat Conductivity Test and Conduction Mechanism of Nanofluid (나노유체의 열전도율 실험과 열전달 메커니즘의 제시)

  • Park, Kweon-Ha;Lee, Jin-A;Kim, Hye-Min
    • Journal of Advanced Marine Engineering and Technology
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    • v.32 no.6
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    • pp.862-868
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    • 2008
  • Many studies have been conducted to increase heat transfer in fluid. One of the various heat transfer enhancement techniques is suspending fine metallic or nonmetallic solid powder in traditional fluid. Nanofluid is defined as a new kind of heat transfer fluid containing a very small quantity of nanometer particles that are uniformly and stably suspended in a liquid. This study investigates the effect of nanofluid containing diamond, CuNi and CuAg nanometer particles, and proposes the heat transport mechanism of nanofluid. The test result shows that the thermal conductivity of nanofluid is much higher than that of traditional fluid, and the increasing rate of the conductivity is dependent on the conductivity of the solid metal.

The effects of nanofluid containing metal nano-powder on heat transfer (나노금속분말을 혼합한 용액이 열전달에 미치는 영향)

  • Kim, Hye-Min;Choi, Soon-Ho;Jeong, Jae-Hyun;Jeong, Jae-Hyun
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2005.06a
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    • pp.177-182
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    • 2005
  • Many studies have been conducted to increase heat transfer in fluid. One of the various heat transfer enhancement techniques is to suspend fine metallic or nonmetallic solid powder in traditional fluid. Nanofluid is defined at a new kind of heat transfer fluid containing a very small quantity of nanometer particles that are uniformly and stably suspended in a liquid. In this study CuNi or CuAg nano particles are used to investigate heat transfer enhancement. The result shows the thermal conductivity of nanofluid is much higher than that of traditional fluid.

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The Characteristics Study on Detector for In-pipe Radioactive Contamination Counting

  • Seo B. K.;Kim G. H.;Jung Y. H.;Woo Z. H.;Oh W. Z.;Lee K. W.;Han M. J.
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.11b
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    • pp.269-279
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    • 2005
  • In this study, detectors characteristics for simultaneous counting of alpha and beta ray in a pipe were estimated. The detector were composed of thin ZnS(Ag) scintillator and plastic detector. The scintillator for counting alpha particles has been applied a polymer composite sheet, having a double layer structure of an inorganic scintillator ZnS(Ag) layer adhered onto a polymer sub-layer. The other for counting beta particles used a commercially available plastic scintillator. It was confirmed that the detectors were suitable for counting the in-pipe contamination.

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Photoelectrical Conductivity and Photodegradation Properties of $TiO_2$ and Ag Sputtered $TiO_2$ Plasma Spraying Coatings ($TiO_2$ 및 Ag 스퍼터링-$TiO_2$ 플라즈마 용사피막의 광전류 및 광분해 특성)

  • Kang, Tae-Gu;Jang, Yong-Ho;Park, Kyeung-Chae
    • Journal of Welding and Joining
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    • v.27 no.2
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    • pp.38-43
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    • 2009
  • In this study, we investigated photocatalytic ability of plasma sprayed $TiO_2$ and Ag sputtering $TiO_2$(Ag-$TiO_2$) coatings. A sputtering processes were adopted to coat the surface of $TiO_2$ with Ag(99.99%). Ag was sputtered at 10mA, 450V for $1{\sim}11$ seconds. $TiO_2$ and Ag-$TiO_2$ coatings were heat-treated at 250, 300, 350, $400^{\circ}C$ for $0{\sim}240$seconds. Photoelectrical conductivity was measured by four-point probe, and photodegradation was calculated by UV-V is spectrometer. Microstructure observation of $TiO_2$ and Ag-$TiO_2$ coatings were investigated by SEM. Crystal structure of $TiO_2$ and Ag-$TiO_2$ coatings were investigated by XRD. Qualitative analyses of $TiO_2$ and Ag-$TiO_2$ coatings were conducted by EDX. When $TiO_2$ coatings were heat-treated at $350^{\circ}C$ for 30 sec, photoelectrical conductivity and photodegradation were best. And in XRD analysis result, (101)/(110) relative intensity ratio of $TiO_2$(rutile) was comparably changed with photoelectrical conductivity. When Ag-$TiO_2$ coatings were heat-treated at $350^{\circ}C$ for 30 [sec] after sputtering Ag for 7 sec, Photoelectrical conductivity and photodegradation are best. Surface of coatings in such condition has very small and uniform Ag particles.

Preparation of Ag-impregnated Porous Ceramic Beads and Antibacterial Properties (Ag 담지 다공성 세라믹 비드 제조 및 항균 특성)

  • Seo, Won-Hak;Han, Yo-Seop;Jeong, Young;Park, Jai-Koo
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.5
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    • pp.549-554
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    • 2005
  • Porous ceramic beads that had skeleton structure were impregnated with Ag from silver nitrate solution. Ag-impregnated porous ceramic beads were performed to evaluate the antibacterial properties on Escherichia coli and Staphylococcus aureus, also, compared with commercial silver-activated carbon on antibacterial activity. As concentration of silver nitrate solution increased, deposited-Ag contents of outer and inner surface of beads were increased. The size of silver particles supported on porous ceramic bead were range of $0.5{\sim}2.0\;{\mu}m$. The observed effects of the prepared Ag-impregnated beads on antibacterial activity are as follows : i) Antibacterial activity should be directly proportional to silver nitrate solution and reaction time. ii) The antibacterial activity against Escherichia coli was better than that against Staphylococcus aureus.

Morphology Control of Ag-doped ZnO Nanowires by Hot-walled pulse Laser Deposition

  • Kim, Gyeong-Won;Song, Yong-Won;Kim, Sang-Sik;Lee, Sang-Ryeol
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.04b
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    • pp.25-26
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    • 2009
  • We design and demonstrate the controlled morphologies of Ag-dpped ZnO nanowires (NWs) adopting self-contrived hot-walled pulsed laser deposition (HW-PLD). p-type Ag-doping is ensuired by low temperature photoluminescence (PL) spectrum to find the AoX peak at 3.349 eV. Morphology of grown NWs are controlled by changing the kinetic energy and flux of the ablated particles with adjusting the target - substrate (T-S) distance. The analysis on the resultant NWs is presented.

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