• Title/Summary/Keyword: Ag(II)

Search Result 255, Processing Time 0.027 seconds

Generation of a monoclonal antibody against AgI/II, a cellular surface protein of Streptococcus mutans GS5 (Streptococcus mutans GS5의 세포막 단백질 Ag I/II에 대한 단항체의 생산)

  • Cheon, Cheol-Wan;Baik, Byeong-Ju;Yang, Yeon-Mi;Han, Ji-Hye;Kim, Jae-Gon
    • Journal of the korean academy of Pediatric Dentistry
    • /
    • v.33 no.4
    • /
    • pp.587-596
    • /
    • 2006
  • Most of oral streptococci express the Antigen I/II (AgI/II) proteins, cell wall anchored adhesions. AgI/II protein binds to salivary agglutinin glycoprotein, a component of tooth pellicle and to ligands in other bacteria. These associations play important roles in bacterial colonization. Recently, it was reported that diverse host molecules also interact with AgI/II protein and that these interactions induce inflammatory responses from host cells. Among mutans streptococci containing -type hemolytic activity, Streptococcus mutans is a causative agent for dental caries. Compared with many other strains of S. mutans, GS-5 strain is unique in that this bacterium expresses truncated secretory AgI/II protein due to the nonsense mutation in the agI/II gene. This indicates that S. mutans GS-5 has a different clinical role and a recent report supported this idea based on the results from clinically isolated S. mutans strains. Previously, we had cloned agI/II gene from S. mutans GS-5 and generated recombinant N-terminal AgI/II protein. In this study, we further produced a hybridoma line expressing anti-AgI/II monoclonal antibodies named as 1C11A. This antibody showed high sensitivity to AgI/II protein in Western blot and ELISA. This new reagent will provide a basis for investigating the mechanisms of AgI/II-related diseases.

  • PDF

Adsorption and Separation of Ag(I) Using a Merrifield Resin Bound NTOE, NDOE in Aqueous Solution (수용액에서 NTOE, NDOE가 결합된 Merrifield 수지를 이용한 Ag(I)의 흡착 및 분리 특성)

  • Lee, Cheal-Gyu;Kim, Hae Joong
    • Analytical Science and Technology
    • /
    • v.12 no.2
    • /
    • pp.159-165
    • /
    • 1999
  • The adsorption and separation behaviors of transition metal ions using a merrifield resin bound 1,12-diaza-3,4:9,10-dibenzo-5,8-dioxacyclopentadecane (NTOE) and 1,12,15-triaza-3,4:9,10-dibenzo-5,8-dioxacycloheptadecane(NDOE) were investigated in aqueous solution. The orders of adsorption degree(E) and distribution ratio(D) of transition metal ions were Cu(II)$t_R$) of metal ions were affected by adsorption degree(E) and distribution ratio(D). This results showed good separation efficiency of Ag(I) from mixed metal solution.

  • PDF

Ag(Ⅰ) Ion Selective Macrocyclic Ligands: The Complexation and Liquid Membrane Transport Phenomena of Benzylated Nitrogen-Oxygen Donor Macrocyclic Ligands (Ag(Ⅰ) 이온 선택성을 갖는 거대고리 리간드: 벤질 치환기를 갖는 질소-산소 주개 거대고리 리간드의 착물 형성과 액체막 이동 현상)

  • Kim, Jeong;Ahn, Tae Ho;Lee, Myoung Ro;Cho, Moon Hwan;Kim, Si Joong
    • Journal of the Korean Chemical Society
    • /
    • v.43 no.2
    • /
    • pp.167-171
    • /
    • 1999
  • An investigation of the interaction of Co(II), Ni(II), Cu(II), Zn(II), Cd(II), Pb(II) and Ag(I) with two N,N'-dibenzylated nitrogen-oxygen mixed donor macrocyclic ligands, has been carried out. Tle log K values for the respective complexes in 95% methanol have been determined potentiometrically. Both ligands have formed stable complex with only Cu(II) and Ag(I) ion. Transport measurements in a bulk liquid membrane system exhibited a very high selectivity of Ag(I) ion over the other metal ions used.

  • PDF

Diffusion Coefficient of Ag(I) ion in the Concentrated Nitric Acid Solution (고농도 질산용액에서 Ag(I) 이온의 확산계수 측정)

  • Park Sang Yoon;Choi Wang Kyu;Lee Kune Woo;Moon Jei Kwon;Oh Won Zin
    • Journal of the Korean Electrochemical Society
    • /
    • v.2 no.2
    • /
    • pp.93-97
    • /
    • 1999
  • From the anodic peak currents of cyclic voltammograms for Ag(I)/Ag(II) couple obtained with the variation of nitric acid concentration, Ag(I) concentration and solution temperature at a Pt electrode in concentrated nitric acid solutions, the diffusion coefficients of Ag(I) ion were evaluated to estimate the limiting current density of Ag(II)-mediated electrochemical oxidation (MEO) process, which has been effectively used for the complete destruction of hazardous organic materials. The results showed that, due to the water decomposition reaction which occurred simultaneously with the Ag(I) ion oxidation, background subtractions for the cyclic voltammograms were required to estimate the correct peak currents. The empirical relationship for the diffusion coefficient of Ag(I) was suggested as a function of solution viscosity and temperature.

Development of Floating-Islands with a Sod Mat by Shooting and Rooting from Shoot Nodes of Common Reed (갈대 줄기의 마디부 발근을 이용한 뗏장 식물섬 개발)

  • Lee, Hyo Hye Mi;Kwon, Peter
    • Journal of the Korean Society of Environmental Restoration Technology
    • /
    • v.5 no.1
    • /
    • pp.59-65
    • /
    • 2002
  • The community of common reed (Phragmites australis) is expanded by the development of new shoots from nodes of rhizomes and old shoots in natural environments. We developed the useful technique to construct reed mats of floating islands developed from shoot nodes of reeds for the purpose of the rapid stabilization of vegetation and the application of adapted plants with their specific environmental conditions. The vegetation development was compared in the floating islands planted with the different reed samples. The reed samples were consisted of four types : long shoot in the length of 100 cm (AG I), short shoot of 15 cm (AG II), long rhizome of 100 cm (BG I) and short rhizome of 15 cm (BG II). Shooting started earlier in BG I and BG II than in AG I and AG II. But the rate of shooting was higher in AG I and AG II than in BG I and BG II. After four weeks, AG I and AG II were higher than BG I and BG II in the biomass and density of newly developed shoots. These results showed that the construction of sod mats by planting only reed shoots was a useful technique to develop vegetation on the floating islands.

Adsorption and Separation Behaviors of Metal Ions Using a Poly-Dibenzo-18-Crown-6 in Aqueous Solution (수용액에서 Poly-dibenzo-18-crown-6를 이용한 금속이온들의 흡착 및 분리 특성)

  • Kim, Hae Joong;Chang, Jeong Ho;Shin, Young-Kook
    • Analytical Science and Technology
    • /
    • v.11 no.4
    • /
    • pp.248-253
    • /
    • 1998
  • The adsorption and separation behaviors of alkali, alkaline earth and transition metal ions using a poly-dibenzo-18-crown-6 were investigated in aqueous solution. The adsorption degree(E) and distribution ratio(D) of alkali, alkaline earth metal ions were Li(I)$t_R$) of metal ions were affected by the adsorption degree(E) and distribution ratio(D). This results showed good separation efficiency of K(I), Sr(II), Ag(I) and Pb(II) from the mixed metal solution.

  • PDF

Two Crystal Structures of the Vacuum-Dehydrated Fully $Ag^+$-Exchanged Zeolite X ($Ag^+$ 이온으로 완전히 치환되고 탈수된 두개의 제올라이트 X의 결정구조)

  • Jang, Se Bok;Park, Sang Yun;Song, Seong Hwan;Jeong, Mi Suk;Kim, Yang
    • Journal of the Korean Chemical Society
    • /
    • v.40 no.7
    • /
    • pp.474-482
    • /
    • 1996
  • Two crystal structures of the vacuum dehydrated $Ag^+$-exchanged zeolite X have been determined by single-crystal X-ray diffraction techniques in the cubic space group Fd3 at 21(1)$^{\circ}C$ (a=24.922(1)${\AA}$ and a=24.901(1)${\AA}$, respectively). Each crystal was ion exchanged in flowing streams of aqueous $AgNO_3$ for three days. The first crystal was dehydrated at 300$^{\circ}C$ and $2{\times}10^{-6$torr for two days. The second crystal was similarly dehydrated at 350$^{\circ}C$. Their structures were refined to the final error indices, $R_1=0.095\;and\;R_2=0.092$ with 227 reflections, and $R_1=0.096\;and\;R_2=0.087$ with 334 reflections, respectively, for which I > 3${\sigma}$(I). In the first crystal, Ag species are found at five different crystallographic sites: sixteen $Ag^+$ ions fill the site I, the center of the double 6-ring, thirty-two Ag0 atoms fill the I' site in the sodalite cavities opposite double six-rings, seventeen $Ag^+$ ions lie at the 32-fold site II' inside the sodalite cavity at the single six-oxygen ring in the supercage, fifteen Ag+ ions lie at the 32-fold site II, in the supercage, and the remaining twelve $Ag^+$ ions lie at site III' in the supercage at a little off two-fold axes. In the second crystal, all Ag species are located similarly as crystal 1; 16 at site I, 28 at site I', 16 at site II, 16 at site II', 6 at site III and 6 at site III'. Total 88 silver species were found per unit cell. The remaining four Ag atoms were migrated out of the zeolite framework to form small silver crystallites on the surface of the zeolite single crystal. In the first structure, the numbers of Ag atoms per unit cell are approximately 32.0 and these may form tetrahedral $Ag_4$ clusters at the centers of the sodalite cavities. The probable four-atom cluster is stabilized by coordination to two $Ag^+$ ions. The Ag-Ag distance in the cluster, ca. 3.05 ${\AA}$, is a little longer than 2.89 ${\AA}$, Ag-Ag distance in silver metal. At least two six-ring $Ag^+$ ions on sodalite cavity (site II') must necessarily approach this cluster and this cluster may be viewed as a distorted octahedral silver cluster, (Ag6)2+.

  • PDF

Adsorption Characteristics of Ni, Co and Ag Ions on The Cation Exchange Resin of Demineralization Process in Primary Coolant System of PWR (원자로 일차 냉각제 계통내 탈염공정의 양이온 교환수지상에서 니켈(Ni), 코발트(Co) 및 은(Ag) 이온의 흡착 특성)

  • Yang, Hyun S.;Kim, Young H.;Kang, Duck W.;Sung, Ki B.
    • Applied Chemistry for Engineering
    • /
    • v.10 no.1
    • /
    • pp.51-57
    • /
    • 1999
  • Adsorption characteristics of Ni(II), Co(II) and Ag(I) ions on the Amberite IRN 77 cation exchange resin have been studied to suggest the guide-line for the optimum operation of demineralization process in primary coolant system during the shut-down period of pressurized water reactor(PWR). The adsorption mechanism of each metal ion, Ni(II), Co(II) or Ag(I) ion, on a cation exchange resin was well coincided with Langmuir isotherm. The adsorption and treatment capacities of $H^+$-form resin were higher than those of $Li^+$-form resin. In the continuous ion exchange process for the solution of multi-component system, the selectivity of the resin was in increasing order of Ni(II)${\approx}$Co(II)>Ag(I). In addition, the increase of the flow rate decreased the treatment capacity of the resin as well as the slope of the breakthrough curve.

  • PDF

HIGH RESOLUTION SPECTRUM OF SYMBIOTIC STAR AG PEGASI (공생형 별 AG PEGASI의 고해상 스펙트럼)

  • Yoo, Kye-Hwa
    • Publications of The Korean Astronomical Society
    • /
    • v.21 no.2
    • /
    • pp.35-42
    • /
    • 2006
  • We report a high resolution spectrum of AG Pegasi observed at Bohyunsan Optical Astronomy Observatory (BOAO) on October 2, 2004. Some of permitted emission lines, for example H I, He I, He II, Fe II and Ti II were observed in the spectrum of AG Pegasi in 2004. Lines presented in the longer wavelength region than $6500{\AA}$ are identified. And radial velocities for each element are measured. Then we carefully discuss the geometrical feature of AG Pegasi in October 2004.

Anodic Reactions at a Pb-Ag Anode in Sulfuric Acid Solutions Containing Manganese(II) (망간(II)을 함유한 황산용액에서 Pb-Ag 양극의 산화반응)

  • Lee, Man-Seung;Nicol, M.J.
    • Resources Recycling
    • /
    • v.26 no.4
    • /
    • pp.34-41
    • /
    • 2017
  • The effect of Mn(II) concentration on the anodic reactions occurring on a Pb-Ag electrode in sulfuric acid solutions has been studied by potentiostatic oxidation in the potential range of 1.8 to 2.0 V. High oxidation potentials and low initial concentrations of Mn(II) resulted in higher concentrations of soluble Mn(III) ions which were obtained from spectrophotometric analysis of the solution after oxidation. $MnO_2$ was deposited on the electrode by electrochemical oxidation of Mn(II) at 1.8 and 1.9 V, while it was formed by disproportionation of Mn(III) at 2.0 V. No $PbO_2$ was formed in the presence of Mn(II) during potentiostatic oxidation treatment for two hours at 1.8 V. Chemical reduction of $PbO_2$ with Mn(II) led to a decrease in the amount of $PbO_2$ as Mn(II) concentration increased at 1.9 and 2.0 V.