• Asian Journal of Atmospheric Environment
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• v.4 no.1
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• pp.55-61
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• 2010

The sensitivity of aerosol light extinction coefficient to the aerosol chemical composition change is estimated by (1) calculating the aerosol water content and chemical concentrations by a gas/particle equilibrium model and (2) calculating the aerosol light extinction coefficient by a Mie theory based optical model. The major chemical species are total (gas and particle phase) sulfuric acid, total nitric acid, and total ammonia which are based on the measurement data at Seoul and Gosan. At Seoul, since there were enough ammonia to neutralize both total sulfuric acid and total nitric acid, the dry ionic concentration is most sensitive to the variation of the total nitric acid level, while the total mass concentration (ionic concentration plus water content) and thus, the aerosol light extinction coefficient are primarily determined by the total sulfuric acid. At Gosan, since the concentration of ambient sulfuric acid was the highest among the inorganic species, sulfate salts determined aerosol hygroscopicity. Thus, both ionic and total mass concentration, and resultant aerosol light extinction coefficient are primarily determined by the sulfuric acid level.

• Particle and aerosol research
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• v.6 no.4
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• pp.151-164
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• 2010

Inorganic ions and water are major components of ambient fine particles. Water content in fine particles is mainly determined by ambient meteorological conditions and the concentrations of hygroscopic species such as inorganic ions. Thus, to reduce fine particle mass concentration, it is important to accurately estimate the relationship between water content and the concentration of ions in fine particles. Water content in fine particles in Seoul are estimated by using a gas/particle equilibrium model to understand the characteristics of fine particle mass concentration. In addition, sensitivity of fine particle mass concentration to the changes of particulate ionic species (sulfate, nitrate, and ammonium) is estimated. It was found that water content in Seoul is mostly determined by the concentrations of the hygroscopic ionic species, especially, sulfate and ammonium, and ambient relative humidity.

• Journal of Korean Society for Atmospheric Environment
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• v.24 no.4
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• pp.470-482
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• 2008

Seasonal variations of chemical composition and optical properties of aerosols at Seoul and Gosan were investigated using the ground-based aerosol measurements and an optical model calculation. The mass fraction of elemental carbon was $8{\sim}17%$, but its contribution on light absorption was high up to $29{\sim}48%$ in Seoul. In Gosan, the contribution of water soluble aerosols on aerosol extinction was $83{\sim}94%$ due to the high mass fraction of these particles in the range of $56{\sim}88%$. Model calculation showed that the water holding capacity of aerosols was larger in Gosan than in Seoul because of higher relative humidity and temperature along with abundant water soluble aerosols. Difference between measured and calculated aerosol optical depths was the highest in summer. This was because aerosol optical depth calculated from ground-based measurements could not consider aerosol loadings at high altitude in spite of high column-integrated aerosol loadings observed by Sun photometer. Although hygroscopic growth was expected to be dominant in summer, the mass concentration of water soluble aerosols was too low to permit this growth.

• Journal of Korean Society for Atmospheric Environment
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• v.20 no.6
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• pp.803-810
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• 2004

Water contents in fine particles at Seoul and Gosan are estimated by using a gas/particle equilibrium model, SCAPE (Simulating Composition of Atmospheric Particles at Equilibrium). Also, sensitivity of particulate inorganic ionic concentrations on the total ionic species is estimated. Water content at Gosan is more sensitive to ambient relative humidity (RH) than Seoul. At both sites water content is most sensitive to sulfate concentration among sulfate, nitrate, and ammonium. Solid salts levels and compositions are also studied.

• Journal of Korean Society for Atmospheric Environment
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• v.11 no.1
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• pp.69-76
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• 1995

Water content and strong acidity are estimated for ambient particles measured between Fall, 1991 and Summer, 1992 in Seoul using a gas/aerosol equilibrium model, called SCAPE. Particle water content and formation of solid species are closely related to ambient relative humidity and ionic concentrations. Generally, water content of particles is high during the night and summer. Estimated particle strong acidity level of Seoul is similar to that of Los Angeles, U.S.A. Acidity of wet and dry depositions in Seoul is discussed.

• Korean Journal of Food Science and Technology
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• v.29 no.1
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• pp.26-31
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• 1997

Bee venom (Apis mellifera) phospholipase $A_2$ solubilized in reversed micelles containing small amount of water stabilized by surfactant could catalyze the hydrolysis of dipalmitoyl phosphatidylcholine (DPPC). A sensitive and simple high performance liquid chromatographic (HPLC) methodology of phospholipase $A_2$ assay for the hydrolysis of DPPC was developed. Kinetic analysis of the phospholipase $A_2$-catalyzed reaction was found to be possible in reversed micelles. Among the surfactants and organic solvents tested, aerosol-OT and isooctane were most effective for the hydrolysis of DPPC in reversed micelles. Optimal temperature, optimal pH, $K_{m,app.},\;V_{max.,app.}$ and activation energy were determined to be $35{\sim}40^{\circ}C$, 7.0, 8.73 mM, 2.83 units/㎎ protein and 12.31 kcal/mole, respectively. The hydrolysis activity was dependent on water content and maximum activity was obtained at R value (=[water]/[aerosol-OT]) of 10.0.

• Korean Journal of Remote Sensing
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• v.35 no.6_3
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• pp.1299-1312
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• 2019

As land remote sensing applications are expanding to the extraction of quantitative information, the importance of atmospheric correction is increasing. Considering the difficulty of atmospheric correction for land images, it should be applied when it is necessary. The quantitative information extraction and time-series analysis on biophysical variables in land surfaces are two major applications that need atmospheric correction. Atmospheric aerosol content and column water vapor, which are very dynamic in spatial and temporal domain, are the most influential elements and obstacles in retrieving accurate surface reflectance. It is difficult to obtain aerosol and water vapor data that have suitable spatio-temporal scale for high- and medium-resolution multispectral imagery. Selection of atmospheric correction method should be based on the availability of appropriate aerosol and water vapor data. Most atmospheric correction of land imagery assumes the Lambertian surface, which is not the case for most natural surfaces. Further BRDF correction should be considered to remove or reduce the anisotropic effects caused by different sun and viewing angles. The atmospheric correction methods of optical imagery over land will be enhanced to meet the need of quantitative remote sensing. Further, imaging sensor system may include pertinent spectral bands that can help to extract atmospheric data simultaneously.

• Journal of Korean Society for Atmospheric Environment
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• v.33 no.1
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• pp.64-74
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• 2017

In this study, we have analyzed relationship between the measured Water Soluble Organic Carbon (WSOC) concentrations and the estimated aerosol water content of $PM_{10}$ (particulate matter with an aerodynamic diameter of less than or equal to $10{\mu}m$) for the period between September 2006 and August 2007 at Seoul, Korea. Water content of $PM_{10}$ was estimated by using a gas/particle equilibrium model, Simulating composition of Atmospheric Particles at Equilibrium 2 (SCAPE2). The WSOC concentrations showed low correlation with Elemental Carbon (EC), but Water Insoluble Organic Carbon (WISOC) were highly correlated with EC. It seemed that hydrophilic groups were produced by secondary formation rather than primary formation. As with the previous studies, WSOC showed good correlation with secondary ions ($NO_3{^-}$, $SO_4{^{2-}}$, $NH_4{^+}$), especially WSOC was highly correlated with $NO_3{^-}$ that is a secondary ion formed by photochemical oxidation from more local sources than $SO_4{^{2-}}$. No apparent correlation between the measured WSOC and estimated water content was observed. However, WSOC showed good correlation with estimated water content when it was assumed that relative humidity was higher than the deliquescence relative humidity of the system. In conclusion, WSOC is correlated with water content by hygroscopic ions and it is expected that nitrate play an important role among the water content and WSOC.

• Current Optics and Photonics
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• v.4 no.3
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• pp.174-185
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• 2020

Multiscattering occurs when a laser transmits into dense atmosphere targets (e.g. fogs, smoke or clouds), which can cause depolarization effects even though the scattering particles are spherical. In addition, multiscattering effects have additional information about microphysical properties of scatterers. Thus, multiscattering can be utilized to study the microphysical properties of the liquid water cloud. In this paper, a Monte Carlo method was used to simulate multi-scattering transmission properties of Lidar signals in the cloud. The results showed the slope of the degree of linear polarization (SLDLP) can be used to invert the extinction coefficient, and then the cloud effective size (CES) and the liquid water content (LWC) may be easily obtained by using the extinction coefficient and saturation of the degree of linear polarization (SADLP). Based on calculation results, a microphysical properties inversion method for a liquid cloud was presented. An innovative multiscattering polarization Lidar (MSPL) system was constructed to measure the LWC and CES of the liquid cloud, and a new method based on the polarization splitting ratio of the Polarization Beam Splitter (PBS) was developed to calibrate the polarization channels of MSPL. By analyzing the typical observation data of MSPL observation in the northern suburbs of Nanjing, China, the LWC and CES of the liquid water cloud were obtained. Comparisons between the results from the MSPL, MODIS and the Microwave radar data showed that, the microphysical properties of liquid cloud could be retrieved by combining our MSPL and the inversion method.

• Journal of Korean Society for Atmospheric Environment
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• v.26 no.1
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• pp.94-102
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• 2010

Water content of $PM_{2.5}$ (particles in the atmosphere with a diameter of less than or equal to a nominal $2.5{\mu}m$) was estimated by using a gas/aerosol equilibrium model, SCAPE2, for the particles collected at Seoul and Gosan, Korea. From measured and analyzed characteristics of the particles, the largest difference between Seoul and Gosan is the proportions of total ammonia (t-$NH_3$=gas phase $NH_3$+particle phase ${NH_4}^+$), total nitric acid (t-$HNO_3$=gas phase $HNO_3$+particle phase ${NO_3}^-$) and sulfuric acid ($H_2SO_4$). Even though both sites have sufficient t-$NH_3$ to neutralize acidic species such as $H_2SO_4$, t-$HNO_3$, and t-HCl (total chloric acid=gas phase HCl+particle phase $Cl^-$), equivalent fraction of t-$NH_3$ and t-$HNO_3$ are higher at Seoul and $H_2SO_4$ is higher at Gosan. Based on the modeling result, it is identified that the $PM_{2.5}$ at Seoul is more hygroscopic than Gosan if the meteorological conditions are the same. To reduce water content of $PM_{2.5}$, and thus, mass concentration, control measures for ammonia and nitrate reduction are needed for Seoul, and inter-governmental cooperation is required for Gosan.