• Title/Summary/Keyword: Aerosol surface area

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Determination of Cadmium and Zinc Contamination Source in Arable Soil in the Vicinity of a Zinc Smelting Factory

  • Hong, Chang-Oh;Gutierrez, Jessie;Lee, Seul-Bi;Lee, Yong-Bok;Yu, Chan;Kim, Pil-Joo
    • Korean Journal of Environmental Agriculture
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    • v.26 no.3
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    • pp.204-209
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    • 2007
  • Agricultural area in the vicinity of the ${\triangle}{\triangle}$ smelting factory in Kyeongbuk province, the third largest zinc smelting factory in the world, was contaminated by high concentration of heavy metals. However, the heavy metals source was not yet directly traced and thus, resulted to a conflict between the factory and residents within its vicinity. In order to determine the level of heavy metal contamination in the arable lands located at the north eastern part of the factory, soils were sampled systematically. To find out the major reason for the occurrence of this problem, waters and aerosols were sampled with constant intervals to the upward and downward direction from the factory and were analyzed to find out the heavy metal concentrations. Cadmium (Cd) and zinc (Zn) of the heavy metals were highly accumulated more than the Korean warning criteria (Cd 1.5, Zn 300 mg $kg^{-1}$) with mean values 1.7 and 407 mg $kg^{-1}$, respectively, at the surface soils (0-20 cm), and heavy metal concentration significantly decreased with increasing soil depth In addition, the concentration of both metals slightly decreased with increasing distance from the factory to the surface soils. Cadmium and Zn were detected in the upward stream water with low concentration and concentrations increased significantly in the downstream after passing across the factory. Aerosol samples also showed traces of Cd and Zn which could be attributed to the contamination of the water system and the surface soils. Conclusively, Cd and Zn emitted from the ${\triangle}{\triangle}$ smelting factory moved with the aerosol in the atmosphere and thus, contaminated the agricultural areas and the water system within it vicinity.

The Variation of Aerosol Number Concentrations in Relation with 3D Wind Components in the Ieodo Ocean Research Station (이어도 해양종합과학기지에서의 3차원 바람성분에 따른 에어로솔 수 농도 변동 특성)

  • Park, Sung-Hwa;Jang, Sang-Min;Lee, Dong-In;Jung, Woon-Seon;Jeong, Jong-Hoon;Jung, Sung-A;Jung, Chang Hoon;Kim, Kyungsik;Kim, Kyung-Eak
    • Atmosphere
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    • v.22 no.1
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    • pp.97-107
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    • 2012
  • To investigate variation of aerosol number concentration at each different size with three-dimensional (3D) wind components in ocean area, aerosol particles and 3D wind components were measured in the Ieodo Ocean Research Station, which is located to 419 km southwest from Marado, the southernmost island of Korea, from 25 June to 8 July 2010. The Laser Particle Counter (LPC) and ultrasonic anemometer were used to measure the size of aerosol particles and 3D wind components (zonal (u), meridional (v), and vertical (w) wind) respectively. Surface weather chart, NCEP/NCAR reanalysis data and sounding data were used to analyze the synoptic condition. The distribution of aerosol number concentration had a large variation from bigger particles more than 1.0 ${\mu}m$ in diameter by wind direction during precipitation. In the number concentration of aerosol particles with respect to the weather conditions, particles larger than 1.0 ${\mu}m$ in size were decreased and sustained to the similar concentration at smaller particles during precipitation. The increase in aerosol number concentration was due to the sea-salt particles which was suspended by southwesterly and upward winds. In addition, the aerosol number concentration with vertical wind flow could be related with the occurrence and increasing mechanism of aerosol in marine boundary layer.

Preparation of Energetic Metal Particles and Their Stabilization (에너제틱 금속입자 제조 및 안정화 기술)

  • Lee, Hye Moon;Kim, Kyung Tae;Yang, Sangsun;Yu, Ji-Hun;Kim, Yong-Jin
    • Particle and aerosol research
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    • v.9 no.3
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    • pp.173-185
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    • 2013
  • Oxidations of metal generate large quantity of thermal and light energies but no toxic pollutants, so that metals with high calorific values, such as beryllium, boron, aluminum, magnesium, and lithium, are possible to be used as clean fuels instead of fossil fuels. However, they are so explosive due to very high oxidation rates that they should be stabilized by their surface passivation with oxides, organics and inorganics. For reasonable use of energetic metal particles as solid fuel, therefore, some detail information, such as thermal properties, preparation and passivation methods, and application area, of the energetic metals is introduced in this manuscript.

Analytic Solution of Electrostatic Precipitator′s Collection Efficiency for Polydisperse Aerosol (다분산 에어로졸에 대한 전기집진 효율의 해석해)

  • 정창훈;박현설;이규원
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.04a
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    • pp.297-298
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    • 2002
  • 전기집진기(ESP)는 보일러, 소각로등 많은 산업 공정에서 발생되는 입자상 물질을 제거하는데 일반적으로 사용되어 왔다. 가장 널리 쓰이는 ESP의 집진효율을 예측하기 위한 수식으로는 Deutsch-Anderson식으로 다음과 같다.(equation omitted) 여기서 η는 포집효율, Ac는 집진판의 표면적(surface area), Ve는 전기집진기 내 입자의 유효 이동속도(effective migration velocity), 그리고 Q는 단위면적을 통과하는 가스의 부피 유량이다. (중략)

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Fabrication and Characterization of Porous TiO2 Powder by Aerosol Process (에어로졸공정에 의한 다공성 TiO2분말의 제조 및 공극특성)

  • Chang, Han Kwon;Jang, Hee Dong;Park, Jin Ho;Cho, Kuk;Kil, Dae Sup
    • Korean Chemical Engineering Research
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    • v.46 no.3
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    • pp.479-485
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    • 2008
  • Porous $TiO_2$ nanostructured particles containing both mesopores and macropores were fabricated by utilizing an aerosol templating method from two kinds of starting materials (colloidal mixture of $TiO_2$ nanoparticles and PS particles, and that of TTIP solution and PS particles). The effects of mixing ratio of PS to $TiO_2$ and reactor temperature on the particle properties were investigated. When $TiO_2$ nanoparticles were used as starting materials, the increase of macropores number was observed by SEM and the specific surface area and total pore volume were increased from $31.6m^2/g$ to $39.1m^2/g$ and $0.068cm^3/g$ to $0.089cm^3/g$, respectively, by increasing the weight mixing ratio of $PS/TiO_2$ from 0.79 to 1.31. When TTIP was used as precursor, the specific surface area and mesopore volume of particles prepared at same condition decreased by 67% and 75%, respectively.

Identifying Yellow Sand from the Ocean Color Sensor SeaWIFS Measurements (해색 센서 SeaWiFS 관측을 이용한 황사 판독)

  • 손병주;황석규
    • Korean Journal of Remote Sensing
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    • v.14 no.4
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    • pp.366-375
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    • 1998
  • Optical characteristics of the yellow sand and their influences on the ocean color remote sensing has been studied using ocean color sensor SeaWiFS measurements. Two cases of April 18 and April 25, 1998, representing yellow sand and background aerosol, are selected for emphasizing the impact of high aerosol concentration on the ocean color remote sensing. It was shown that NASA's standard atmospheric correction algorithm treats yellow sand area as either too high radiance or cloud area, in which ocean color information is not generated. Optical thickness of yellow sand arrived over the East Asian sea waters in April 18 indicates that there are two groups loaded with relatively homogeneous yellow sand, i.e.: heavy yellow sand area with optical thickness peak around 0.8 and mild area with about 0.4, which are consistent with ground observations. The movement of the yellow sand area obtained from surface weather maps and backward trajectory analysis manifest the notion that the weak yellow sand area was originated from the outer region of the dust storm. It is also noted that high optical thickness associated with the yellow sand is significantly different from what we may observe from background aerosol, which is about 0.2. These characteristics allow us to determine the yellow sand area with an aid of atmospheric correction parameter. Results indicate that the yellow sand area can be determined by applying the features revealed in scattergrams of atmospheric correction parameter and optical thickness.

Simulation of the Growth of Non-Spherical Particles in a Counterflow Diffusion Flame (대향류 확산 화염 중에서 비구형 입자 성장에 관한 해석)

  • Jeong, Jae In;Hwang, Jun Young;Lee, Bang Weon;Choi, Mansoo;Chung, Suk Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.8
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    • pp.997-1009
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    • 1999
  • Silica particle formation and growth process including chemical reaction, coagulation and sintering was studied in a counterflow diffusion flame burner. The counterflow geometry provides a one dimensional flow field, along the stagnation point streamline, which greatly simplifies interpretation of the particle growth characteristics. $SiCl_4$ has been used as the source of silicon in hydrogen/oxygen/argon flames. The temperature profiles obtained by calculation showed a good agreement with experiment data. Using one and two dimensional sectional method, aerosol dynamics equation in a flame was solved, and these two results were compared. The two dimensional section method can consider sintering effect and growth of primary particle during synthesis, thus it showed evolution of morphology of non-spherical particles (aggregates) using surface fractal dimension. The effects of flame temperature and chemical loading on particle dynamics were studied. Geometric mean diameter based on surface area and total number concentration followed the trend of experiment results, especially, the change of diameters showed the sintering effect in high temperature environment.

Effects of Particle Shapes on Unipolar Diffusion Charging of Non-Spherical Particles (비구형 입자의 형상에 따른 단극 확산 하전 특성)

  • Oh, Hyun-Cheol;Park, Hyung-Ho;Kim, Sang-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.5
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    • pp.501-509
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    • 2004
  • Unipolar diffusion charging of non-spherical particles was investigated for various particle shapes. We researched with TiO$_2$agglomerates produced by the thermal decomposition of titanium tetraisopropoxide (TTIP) vapor. TTIP was converted into TiO$_2$, in the furnace reactor and was subsequently introduced into the sintering furnace. Increasing the temperature in the sintering furnace, aggregates were restructured into higher fractal dimensions. The aggregates were classified according to their mobility using a differential mobility analyzer. The projection area and the mass fractal dimension of particles were measured with an image processing technique performed by using transmission electron microscope (TEM) photograph. The selected aggregates were charged by the indirect photoelectric-charger and the average number of charges per particle was measured by an aerosol electrometer and a condensation particle counter. For the particles of same mobility diameter, our results showed that the particle charge quantity decreases as the sintering temperature increases. This result is understandable because particles with lower fractal dimension have larger capacitance and geometric surface area.

Simultaneous Removal Characteristics of Particulate and Elemental Mercury in Convergence Particulate Collector (융합형여과집진장치에서의 먼지입자와 원소수은의 제거 성능 특성)

  • Park, Young Ok;Jeong, Ju Yeong
    • Particle and aerosol research
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    • v.6 no.4
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    • pp.173-183
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    • 2010
  • The high temperature pleated filter bags which were used during this study were made of pleated nonwoven fabric of heat and acid resistant polysulfonate fibers which can withstand the heat up to $300^{\circ}C$ and have a filtration area which is 3 to 5 times larger than the conventional round filter bags. Cartridge module packed with 3 kind of the sulfur impregnated activated-carbon based sorbents were inserted in the inner of the pleated filter bag. This type of pleated filter bag was designed to remove not only the particulate matter but also the gaseous elemental mercury. The electrostatic precipitator part can enhance the particulate removal efficiency and reduce the pressure drop of the pleated filter bag by agglomerated particles to form a more porous dust layer on the surface of the pleated bag which is increased the filter bag cleaning efficiency. In addition, the most of particles are separated from the flue gas stream through the cyclone and the electrostatic precipitator part which were installed at the lower part and main body part of the convergence particulate collector, respectively. Thus reduce particulate loading of the high temperature pleated filter bags were applied in this study to analyze the removal characteristics of particulate matter and gaseous elemental mercury.