• 제목/요약/키워드: Aerosol analysis

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사이클론 집진장치의 내부온도에 따른 외부 소용돌이와 집진효율의 관계 (Relationship between the Outer Vortex and the Collection Efficiency with respect to Temperatures in the Cyclone Dust Collector)

  • 현대근;장혁상
    • 한국입자에어로졸학회지
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    • 제11권2호
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    • pp.47-55
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    • 2015
  • This study compares the results of collection efficiency of difference gas temperature in cyclone dust collector. The previous researcher's experiment results were used to confirm the reliability of CFD(Computational Fluid Dynamics) model. Based on this verified CFD model, we extended the analysis on the cyclone dust collectors. In CFD study, we used RNG k-epsilon model for analysis of turbulence flow, fluid is air, the velocity at inlet is 10 m/s, the temperature of air is $20^{\circ}C$, $100^{\circ}C$, $200^{\circ}C$, $300^{\circ}C$, $600^{\circ}C$ and $1000^{\circ}C$. As the temperature decreases, the average velocity of outer vortex and collection efficiency is increased, showed the highest collection efficiency at $20^{\circ}C$. It can be inferred smooth flow in cyclone dust collector is difficult because air viscosity increases as temperature increases. The power required at $1000^{\circ}C$ is almost 18 times greater than that of $20^{\circ}C$ to get the similar collection efficiency.

폴리머-탄소나노튜브 복합체 에어로졸 입자의 생성 및 이를 이용한 하이브리드 복합체 박막 제조 (Synthesis of Polymer-Carbon Nanotubes Composite Nanoparticles and Their Applications into Forming Hybrid Composite Thin Films)

  • 김휘동;안지영;김수형
    • 한국입자에어로졸학회지
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    • 제6권2호
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    • pp.61-67
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    • 2010
  • In this paper, we describe a new method to form polymer thin films, in which carbon nanotubes (CNTs) are homogeneously distributed so that they can strengthen the mechanical property of resulting polymer film. To do so, we first homogeneously mixed CNTs with polymer in a DMF solvent. With the assistance of ultrasonic nebulizer, the polymer/CNT solution was then aerosolized into micro-sized droplets and finally turned into solidified polymer/CNT composite particles by gas-phase drying process. As the results of SEM and TEM analysis, CNTs were found to be homogeneously immobilized in the polymer matrix particles due to rapid drying process in the gas phase. For comparison purpose, (i) the polymer/CNTs composite particles prepared by aerosol processing method and (ii) polymer/CNTs sheets prepared by simple solution-evaporation method were employed to form polymer/CNTs composite thin films using a hot press. As the result, the aerosol processing of composite particles was found to be a much more effective method to form homogeneously distributed-CNTs in the polymer matrix thin film.

서울과 부산에서 관측된 일조 시간 및 강수 강도의 장기 변동 분석 (Analysis of Long-term Variations of Sunshine Duration and Precipitation Intensity Using Surface Meteorological Data Observed in Seoul and Busan in Korea)

  • 이효정;김철희
    • 대기
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    • 제19권3호
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    • pp.243-253
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    • 2009
  • In other to interpret the long-term variations of sunshine duration, cloud lifetime, and precipitation intensity observed in and around Seoul and Busan for the period from 1986 to 2005, aerosol indirect effect was employed and applied. For the identification of long-term trend of aerosol concentration, observed visibility and AOT of AERONET sunphotometer data were also used over the same regions. The result showed that the time series of visibility was decreased and those of AOT increased, especially trends were remarkable in 2000s. In both regions, occurrence frequencies of observed cloudiness (cloud amount ${\leq}6/10$) and strong precipitation (rain rate > $0.5mmhour^{-1}$) have been steadily increased while those of cloudiness (cloud amount > 7/10) and weak precipitation (rain rate ${\leq}0.2mmhour^{-1}$) decreased. These results are corresponding to the trend of both visibility and AERONET data, implying the aerosol indirect effect that makes size of cloud droplet reduce, cloud life-time longer and precipitation efficiency decreased. Our findings demonstrate that, although these phenomena are not highly significant, weather and climate system over Korean urban area have been changed toward longer lifetime of small cloudiness and increasing precipitation intensity as a result of increased aerosol indirect effect.

VACES을 이용한 대기 중 입자상물질의 농축기술 및 특성 연구 (Characteristics of Aerosol Particle Concentration by the Versatile Aerosol Concentration Enrichment System (VACES))

  • 박정호
    • 한국환경과학회지
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    • 제21권11호
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    • pp.1339-1348
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    • 2012
  • The versatile aerosol concentration enrichment system (VACES) have proven useful for providing elevated levels of atmospheric aerosol to human and animal exposures. In this study, we describe a VACES and tests conducted to both optimize the enhancement factor (EF) and characterize how it depends on experiment conditions. Particle number concentrations were measured from upstream and downstream of the system by scanning mobility particle sizer (SMPS) with a long differential mobility analyzer (DMA) in combination with a condensation particle counter (CPC). SMPS was used for to determine VACES particle EF. Particle EF tends to increase for higher the saturator temperature ($T_{Sat}$) and lower the condenser temperature ($T_{Con}$). $T_{Con}$ higher than $0^{\circ}C$ and $T_{Sat}$ lower than $50^{\circ}C$ was the best to obtain the most increase in particle concentration. Correlation analysis of EF with factor variables of $T_{Sat}$ and $T_{Con}$ resulted in correlation 0.662 and 0.416, respectively. With all five predictor variables included in a multiple regression model, the EF had a liner correlation with $R^2=0.643$.

Aerosol Deposition Nozzle Design for Uniform Flow Rate: Divergence Angle and Nozzle Length

  • Kim, Jae Young;Kim, Young Jin;Jeon, Jeong Eun;Jeon, Jun Woo;Choi, Beom Soo;Choi, Jeong Won;Hong, Sang Jeen
    • 반도체디스플레이기술학회지
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    • 제21권2호
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    • pp.38-44
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    • 2022
  • Plasma density in semiconductor fabrication equipment becomes higher to achieve the improved the throughput of the process, but the increase of surface corrosion of the ceramic coated chamber wall has been observed by the increased plasma density. Plasma chamber wall coating with aerosol deposition prefer to be firm and uniform to prevent the potential creation of particle inside the chamber from the deformation of the coating materials, and the aerosol discharge nozzle is a good control factor for the deposited coating condition. In this paper, we investigated the design of the nozzle of the aerosol deposition to form a high-quality coating film. Computational fluid dynamics (CFD) study was employed to minimize boundary layer effect and shock wave. The degree of expansion, and design of simulation approach was applied to found out the relationship between the divergence angle and nozzle length as the key parameter for the nozzle design. We found that the trade-off tendency between divergence angle and nozzle length through simulation and quantitative analysis, and present the direction of nozzle design that can improve the uniformity of chamber wall coating.

역미셀계내에서 인지질분해효소 $A_2$에 의한 레시친의 가수분해 (Hydrolysis of Phosphatidylcholine in Aerosol-OT/Isooctane Reversed Micelles by Phospholipase $A_2$)

  • 장판식
    • 한국식품과학회지
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    • 제29권1호
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    • pp.26-31
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    • 1997
  • 물을 극미량 함유하는 미수계 효소반응계인 aerosol-OT/이소옥탄으로 구성된 역미셀계내에서 레시친의 일종인 DPPC (dipalmitoyl phosphatidylcholine)의 가수분해반응을 phospholipase $A_2$가 촉매할 수 있었다. 또한 phospholipase $A_2$에 의한 가수분해반응을 정량분석하기 위한 고성능 액체 크로마토그래피에 의한 예민하고 간편한 방법을 고안하였는 바, 이에 의하여 aerosol-OT/이소옥탄 역미셀계내에서 phospholipase $A_2$에 의한 가수분해반응의 동력학적인 분석이 가능하였다. 한편, 여러가지 유화제와 유기용매 중 aerosol-OT와 이소옥탄일 때 효소반응이 가장 효과적이었으며, 반응 적정온도는 $35{\sim}40^{\circ}C$, 적정 pH는 7.0이었다. 또한 역미셀계내에서의 가수분해반응은 수분 함량변화에 민감하였으며, R-값(=[water]/[aerosol-OT])이 10.0일 때 가장 높은 효소활성을 나타내었다. 효소반응을 위한 최적조건하에서의 $K_{m,app.}$$V_{max.,app.}$는 각각 8.73 mM, 2.83 units/㎎ protein이었으며, 역미셀계내에서 phospholipase $A_2$에 의한 DPPC가수분해반응의 활성화에너지는 12.31 kcal/mole로 산출되었다.

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중력 침강에 의한 입자 응집의 해석적 연구 (Analysis of Gravitational Coagulation of Aerosol Particles)

  • 진형아;정창훈;이규원
    • 한국대기환경학회지
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    • 제14권4호
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    • pp.303-312
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    • 1998
  • To obtain the solution to the time-dependent particle size distribution of an aerosol undergoing gravitational coagulation, the moment method was used which converts the non linear integro-differential equation to a set of ordinary differential equations. A semi-numerical solution was obtained using this method. Subsequently, an analytic solution was given by approximating the collision kernel into a form suitable for the analysis. The results show that during gravitational coagulation, the geometric standard deviation increases and the geometric mean radius decreases as time increases.

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한반도 서부유입권역에서 대기 중 에어로졸 성분의 화학적 특성 연구 II. 입자의 산성도 및 산화 특성 (A Study on Chemical Characteristics of Aerosol Composition at West Inflow Regions in the Korean Peninsula II. Characteristics of Inorganic Aerosol Acidity and Organic Aerosol Oxidation)

  • 최진수;김정호;이태형;최용주;박태현;안준영;박진수;김현재;구윤서;김신도;홍유덕;홍지형
    • 한국대기환경학회지
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    • 제32권5호
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    • pp.485-500
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    • 2016
  • We examined acidity state of inorganic aerosol and oxidation state of organic aerosol by High Resolution Time of Flight Aerosol Mass Spectrometer (HR-ToF-AMS) at Baengnyeong Super site from Jan 2012 to Dec 2013. Additionally, we carried out the analysis for the aerosol component group of organic matter ($C_xH_y$, $C_xH_yO_1$, $C_xH_yO_z$, $C_xH_yO_zN_p$) and elemental composition to calculate H/C, O/C, N/C, OM/OC and identify the oxidation state. The aerosol chemical composition in this study is dominated by sulfate ($SO_4{^{2-}}$), nitrate ($NO_3{^-}$) plays a smaller role in aerosol acidity. Ammonium ($NH_4{^+}$) was found in a formation of $(NH_4)_3H(SO_4)_2$. However, the binding formations of $NH_4NO_3$ and $NH_4Cl$ increase in the winter. $C_xH_yO_1$ indicating the oxidized state of $PM_{1.0}$ has the highest ratio of 41% while $C_xH_y$ indicating the non-oxidized state has a lower ratio of 36%, meaning that the oxidation level of $PM_{1.0}$ in Baengnyeong Island is high. The ratio between H/C and O/C was 1.33 and 0.78 respectively, showing the characteristic of LV-OOA (Low volatility-Oxygenated Organic Aerosol). Acidic and oxidized aerosols sampled during this field study were largely anthropogenic in origin from Chinese continent and photochemically aged.

구름과 에어로솔의 혼재시 에어로솔의 광학특성이 상향 단파 복사에 미치는 영향 (Effects of Aerosol Optical Properties on Upward Shortwave Flux in the Presence of Aerosol and Cloud layers)

  • 이권호
    • 대한원격탐사학회지
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    • 제33권3호
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    • pp.301-311
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    • 2017
  • 에어로솔의 광학특성과 연직고도는 태양 복사의 반사와 흡수과정을 통하여 지구복사수지에 영향을 미치게 된다. 본 연구에서는 복사전달모델과 위성관측자료를 이용하여 동북아시아 지역에서 구름의 존재 시 에어로솔 층에 의한 복사특성을 분석하였다. 복사전달 모의 결과는 구름이 하부에 존재하는 경우에 에어로솔 층의 고도가 높아짐에 따라 대기 온난화 효과가 증가하였다. 이러한 관계는 에어로솔의 광 흡수성이 커질수록, 지표 반사도가 증가할수록 비례하는 경향을 나타내었다. 그리고 연구대상지역 ($20-50^{\circ}N$, $110-140^{\circ}E$)에서 주요 에어로솔 이벤트 사례에 대하여, UV Absorbing Aerosol Index (AAI) derived from Total Ozone Mapping Spectrometer (TOMS), cloud parameters derived from the Moderate Resolution Imaging Spectro-radiometer (MODIS), with Upward Shortwave Flux (USF) Clouds and the Earth's Radiant Energy System (CERES) 위성관측자료를 이용하여 광 흡수성 에어로솔에 의한 영향을 정량적으로 분석하였다. 각 사례에 대한 평균적인 복사효과는 약 6 - 26 %에 해당하는 상향 단파 복사량의 감쇄효과가 나타났다. 이러한 결과는 에어로솔에 의한 직접효과와 간접효과를 정량화 하기 위한 중요성을 설명해 준다.

COMS/GOCI 관측값의 대기 에어러솔의 특성에 대한 민감도 분석 (Sensitivity of COMS/GOCI Measured Top-of-atmosphere Reflectances to Atmospheric Aerosol Properties)

  • 이권호;김영준
    • 대한원격탐사학회지
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    • 제24권6호
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    • pp.559-569
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    • 2008
  • 세계 최초의 정지 궤도 해양관측 센서인 Geostationary Ocean Color Imager (COMS/GOCI)가 측정하는 가시광선 영역의 파장대 ($0.4-0.9{\mu}m$)는 대기 구성성분(기체상 또는 입자상)에 의하여 영향을 받기 때문에 이에 대한 보정이 필요하다. 특히, 대기중에 존재하는 미세입자인 에어러솔은 그 물리 화학적 특성의 다양함으로 인하여 태양광과 반응하는 과정이 상당히 복잡하게 나타나므로, 정확한 해양 관측을 위하여 대기 에어러솔과 복사 과정의 상호작용에 대한 정확한 이해가 필요하다. 본 연구에서는 알려진 대기 에어 러솔 특성 자료를 이용하여 에어 러솔의 물리 적, 광학적 특성을 분석하였다. 여기서 얻어진 에어러솔 특성 값들은 복사전달 모델을 이용하여 다양한 환경 조건하(에어러솔의 종류와 양)에서 위성센서가 측정하는 이론적인 복사량과 에어러솔의 관계를 분석하는데 사용되었다. 복사전달모델 분석결과, 위성 자료 분석에서 잘못된 에어러솔의 광학 특성값의 사용으로 인한 오차는 에어러솔 광학 두께($\tau$)가 0.2보다 작은 범위에서는 비교적 작은 값을 나타내나 0.2보다 크게 되는 경우 지속적으로 증가하였다. 추가로 위성 관측값과 복사전달 모델에 의하여 계산된 값의 차이가 최소인 에어러솔 타입의 광학 특성값을 이용하여 ($\tau$)와 ${\aa}ngstr{\ddot{o}}m$ exponent 를 도출한 결과는 기존의 표준 알고리즘보다는 지상관측자료와의 비교적 잘 일치하고 있는 것으로 나타났다. 따라서 위성 관측자료에서 에어러솔 분석함에 있어서 에어러솔 타입에 따른 광학적 특성값의 중요성은 매우 크다고 할 수 있다. 이러한 결과들은 궁극적으로 향후 발사될 COMS/GOCI의 관측 자료를 이용한 대기 에어러솔 분석이나 대기 효과 보정에 있어서 도움이 될 것이다.